CN113105951A - Formula and preparation method of high-corrosion-resistance automobile glass water - Google Patents
Formula and preparation method of high-corrosion-resistance automobile glass water Download PDFInfo
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- CN113105951A CN113105951A CN202110388708.9A CN202110388708A CN113105951A CN 113105951 A CN113105951 A CN 113105951A CN 202110388708 A CN202110388708 A CN 202110388708A CN 113105951 A CN113105951 A CN 113105951A
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- automobile glass
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0073—Anticorrosion compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
Abstract
The invention discloses a formula of high-corrosion-resistance automobile glass water and a preparation method thereof, and the formula comprises, by mass, deionized water, 0.01-0.5% of surfactant, 0.001-0.01% of gloriol preservative, 0.01-0.5% of tribenzylamine and 0.01-0.5% of polyaniline; according to the invention, oxygen molecules dissolved in water are prevented from diffusing to the surface of the metal by the tribenzylamine, meanwhile, a compact protective film is formed on the surface of the metal by the polyaniline, and the polyaniline and the metal can effectively prevent the metal from being chemically corroded under the combined action of the three, so that a better corrosion prevention effect can be achieved even if a little amount of preservative is added; meanwhile, the hydrophobic property of the automobile glass water is improved by adding the pyrflumamine in the formula.
Description
Technical Field
The invention relates to the field of automobile glass water, in particular to high-corrosion-resistance automobile glass water and a preparation method thereof.
Background
The automobile glass cleaning liquid is one kind of glass cleaning liquid capable of fast decontaminating, brightening and cleaning automobile glass, rearview mirror, etc. and belongs to one of the automobile maintaining consumable. In addition to its well-known cleaning utility, automotive glass water also has anti-freeze, anti-fog, anti-static, lubricating and anti-corrosion utility. As the consumer groups pay more attention to the cleaning performance, the antifreezing performance and the antifogging performance of the automobile glass water, automobile glass water manufacturers pay more attention to the cleaning performance, the antifreezing performance and the antifogging performance while producing the automobile glass water, and neglect the anticorrosion performance of the automobile glass water. So that most of automobile glass water on the market at present cannot pass the corrosion prevention test required by the national standard (GB-T23436-2009).
If the automobile glass water is difficult to reach the anti-corrosion standard, the automobile surface paint, rubber and the like are damaged after the automobile glass water is used for a long time, the hardening of the rubber strip of the windscreen wiper is easy to accelerate, the hardened rubber strip of the windscreen wiper can accelerate the consumption of the windscreen, the automobile glass water is easier to scratch or scrape, but the windscreen wiper is replaced again, and the cost is high.
Therefore, those skilled in the art are still working on developing an automotive glass water having high corrosion resistance.
Disclosure of Invention
In view of the above-mentioned drawbacks of the prior art, the present invention provides an automotive glass water having high corrosion resistance.
In order to achieve the purpose, the invention provides a formula of high-corrosion-resistance automobile glass water, which comprises, by mass, deionized water, 0.01-0.5% of a nonionic surfactant, 0.001-0.01% of a gloriol preservative, 0.01-0.5% of tribenzylamine and 0.01-0.5% of polyaniline.
The nonionic surfactant is added into the formula and is used as an active ingredient, so that the foaming and decontamination effects of the glass water are further enhanced. Meanwhile, by adding tribenzylamine and polyaniline into the formula, the two materials can form coordination by using N element and metal and are adsorbed on the surface of the metal. The three benzyl groups of the tribenzylamine have strong steric hindrance, oxygen molecules dissolved in water can be prevented from diffusing to the surface of the metal, meanwhile, the polyaniline can form a compact protective film on the surface of the metal, and the oxidation corrosion of the metal can be effectively prevented through the combined action of the mode of inhibiting the oxygen molecules from diffusing on the surface of the metal and forming the protective film on the surface of the metal, so that the corrosion prevention effect of the automobile glass water is obviously improved.
The formula also comprises 30-50% of glycol and 10-20% of alcohol, and the alcohol and the glycol are beneficial to reducing the freezing point of liquid, so that the automobile glass water has a better anti-freezing effect and can quickly dissolve frost.
The formula also comprises 0.01-0.1% of the pyflumamine, and the pyflumamine is added into the formula at the same time. On one hand, the amine group on the pyflumamine and the hydroxyl group expressed by the glass form a hydrogen bond and are attached to the surface of the glass, and on the other hand, the F group on the pyflumamine has obvious hydrophobicity, so that the rainwater can quickly fall from the front windshield of the automobile, the waterproofness of the glass water is improved, and the safety of driving in rainy days is further improved.
The surfactant is an AES surfactant, and the AES surfactant is easy to dissolve in water, has excellent detergency, foaming performance, hard water resistance and mild washing performance, and is favorable for improving the corrosion resistance of the automobile glass water.
A preparation method of high-corrosion-resistance automobile glass water specifically comprises the following steps:
step one, taking deionized water for standby, adding 0.01-0.5% of AES surfactant while stirring, and uniformly stirring;
secondly, sequentially adding 0.001-0.01% of gloriol preservative, 0.01-0.5% of tribenzylamine and 0.01-0.5% of polyaniline into the liquid obtained in the first step, and uniformly stirring;
and step three, adding 30-50% of glycol and 10-20% of alcohol into the solution obtained in the step two, and slightly stirring until the solution is completely mixed to obtain the automobile glass water.
In order to ensure that the automobile glass water has certain hydrophobicity, the third step is followed by a fourth step, and the fourth step is to add 0.01 to 0.1 percent of the pyflumamine into the automobile glass water in the third step at the low temperature of between 10 and 15 ℃.
According to the invention, oxygen molecules dissolved in water are prevented from diffusing to the surface of the metal by the tribenzylamine, meanwhile, a compact protective film is formed on the surface of the metal by the polyaniline, and the polyaniline and the metal can effectively prevent the metal from being chemically corroded under the combined action of the three, so that a better corrosion prevention effect can be achieved even if a little amount of preservative is added; meanwhile, the hydrophobic property of the automobile glass water is improved by adding the pyrflumamine in the formula.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the technical solutions of the present invention are described clearly and completely below, and it is obvious that the described embodiments are some, not all embodiments of the present invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The types and brands of the raw materials used in the examples were selected as follows:
deionized water-Shanghai Kanglang Biotech limited, 99% purity;
AES surfactant-purchased from Shanghai Michelin Biotechnology, Inc., with a purity of 70%;
galena preservative-purchased from bio-technology limited of baimuda, south beijing, with a purity of 95%;
tribenzylamine-purchased from Beijing Bailingwei science and technology Limited, purity 99.3%;
polyaniline-purchased from Chongqing Yuanshan science and technology development Limited with a purity of 99%;
BUFLUORAMINE-purchased from Tianjin XiENSI Biotechnology limited, with a purity of 98%;
alcohol-purchased from chemical limited, created by south china, purity 99.9%;
ethylene glycol-Nantong Runfeng petrochemical Co., Ltd., purity 99%.
Example 1
The formula of the high-corrosion-resistance automobile glass water comprises, by mass, deionized water, 0.01% of AES surfactant, 0.001% of gloriol preservative, 0.01% of tribenzylamine and 0.01% of polyaniline.
The preparation method of the high-corrosion-resistance automobile glass water specifically comprises the following steps:
step one, taking deionized water for standby, adding 0.01 percent of AES surfactant into the deionized water while stirring, and uniformly stirring;
and step two, sequentially adding 0.001% of Jialandan preservative, 0.01% of tribenzylamine and 0.01% of polyaniline into the liquid obtained in the step one, and uniformly stirring.
Example 2
The formula of the high-corrosion-resistance automobile glass water comprises, by mass, deionized water, 0.5% of AES surfactant, 0.01% of gloriol preservative, 0.5% of tribenzylamine and 0.5% of polyaniline.
The preparation method of the high-corrosion-resistance automobile glass water specifically comprises the following steps:
taking deionized water for later use, adding 00.5 percent of AES surfactant into the deionized water while stirring, and uniformly stirring;
and step two, sequentially adding 0.01% of Jialandan preservative, 0.5% of tribenzylamine and 0.5% of polyaniline into the liquid obtained in the step one, and uniformly stirring.
Example 3
The formula of the high-corrosion-resistance automobile glass water comprises, by mass, deionized water, 0.01% of AES surfactant, 0.001% of gloriol preservative, 0.01% of tribenzylamine, 0.01% of polyaniline, 30% of ethylene glycol and 10% of alcohol.
The preparation method of the high-corrosion-resistance automobile glass water specifically comprises the following steps:
step one, taking deionized water for standby, adding 0.01 percent of AES surfactant into the deionized water while stirring, and uniformly stirring;
and step two, sequentially adding 0.001% of Jialandan preservative, 0.01% of tribenzylamine and 0.01% of polyaniline into the liquid obtained in the step one, and uniformly stirring.
And step three, adding 30% of glycol and 10% of alcohol into the solution obtained in the step two, and slightly stirring until the solution is completely mixed to obtain the automobile glass water.
Example 4
The formula of the high-corrosion-resistance automobile glass water comprises, by mass, deionized water, 0.5% of AES surfactant, 0.01% of gloriol preservative, 0.5% of tribenzylamine and 0.5% of polyaniline.
The preparation method of the high-corrosion-resistance automobile glass water specifically comprises the following steps:
taking deionized water for later use, adding 00.5 percent of AES surfactant into the deionized water while stirring, and uniformly stirring;
step two, sequentially adding 0.01% of Jialandan preservative, 0.5% of tribenzylamine and 0.5% of polyaniline into the liquid obtained in the step one, and uniformly stirring;
and step three, adding 50% of glycol and 20% of alcohol into the solution obtained in the step two, and slightly stirring until the solution is completely mixed to obtain the automobile glass water.
Example 5
The formula of the high-corrosion-resistance automobile glass water comprises, by mass, deionized water, 0.01% of AES surfactant, 0.001% of galena preservative, 0.01% of tribenzylamine, 0.01% of polyaniline, 30% of ethylene glycol, 10% of alcohol and 0.01% of flumioxazin.
The preparation method of the high-corrosion-resistance automobile glass water specifically comprises the following steps:
step one, taking deionized water for standby, adding 0.01 percent of AES surfactant into the deionized water while stirring, and uniformly stirring;
and step two, sequentially adding 0.001% of Jialandan preservative, 0.01% of tribenzylamine and 0.01% of polyaniline into the liquid obtained in the step one, and uniformly stirring.
And step three, adding 30% of glycol and 10% of alcohol into the solution obtained in the step two, and slightly stirring until the solution is completely mixed to obtain the automobile glass water.
And step four, adding 0.01 percent of pyflumamine into the automobile glass water obtained in the step three at the low temperature of 10-15 ℃.
Example 6
The formula of the high-corrosion-resistance automobile glass water comprises, by mass, deionized water, 0.5% of AES surfactant, 0.01% of galena preservative, 0.5% of tribenzylamine, 0.5% of polyaniline, 50% of ethylene glycol, 20% of alcohol and 0.1% of flumioxazin.
The preparation method of the high-corrosion-resistance automobile glass water specifically comprises the following steps:
step one, taking deionized water for standby, adding 0.5 percent of AES surfactant into the deionized water while stirring, and uniformly stirring;
step two, sequentially adding 0.01% of Jialandan preservative, 0.5% of tribenzylamine and 0.5% of polyaniline into the liquid obtained in the step one, and uniformly stirring;
and step three, adding 50% of glycol and 20% of alcohol into the solution obtained in the step two, and slightly stirring until the solution is completely mixed to obtain the automobile glass water.
The formulations of examples 1 to 6 were summarized and a summary table was obtained as follows:
raw material | AES surfactant | Jialan pill preservative | Tribenzylamine | Polyaniline (PANI) | Ethylene glycol | Alcohol | Buffamine |
Example 1 | 0.01% | 0.001% | 0.01% | 0.01% | Is free of | Is free of | Is free of |
Example 2 | 0.5% | 0.01% | 0.5% | 0.5% | Is free of | Is free of | Is free of |
Example 3 | 0.01% | 0.001% | 0.01% | 0.01% | 30% | 10% | Is free of |
Example 4 | 0.5% | 0.01% | 0.5% | 0.5% | 50% | 20% | Is free of |
Example 5 | 0.01% | 0.001% | 0.01% | 0.01% | 30% | 10% | 0.01% |
Example 6 | 0.5% | 0.01% | 0.5% | 0.5% | 50% | 20% | 0.1% |
The automobile glass water obtained in the foregoing embodiments 1 to 6 is subjected to appearance quality detection, cleaning power detection, compatibility detection, metal corrosion detection, rubber influence detection, plastic influence detection, automobile organic coating influence detection, stability detection and water resistance detection according to the standard of GB/T23436-; the results are shown in the following table.
TABLE 1 statistical table of appearance, detergency, compatibility, thermal stability and water resistance measurements
It can be seen from the data in table 1 that the cleaning solutions prepared according to the formulations of the present invention meet the specifications in terms of appearance, cleaning power, and compatible thermal stability. The formula of the pyflumamine is added, and the water resistance of the formula also meets the technical requirements.
In view of the main effect of the present invention is to improve the corrosion resistance of the automobile glass water, the following specific tests are performed on the metal corrosion, rubber influence, plastic influence and influence of the automobile organic coating, and the specific test method is still referred to GB/T23436-.
TABLE 2 statistical tables of the results of the metal corrosion tests of examples 1 to 6
As can be seen from the data in Table 2, although the corrosiveness of each example to aluminum sheet, brass sheet and galvanized copper sheet is changed, the corrosiveness of each example to metal is within the technical requirements, so that the automobile glass water prepared in examples 1 to 6 can be demonstrated to meet the technical requirements on the corrosiveness of the metal.
TABLE 3 statistical tables of the results of the tests for the influence on rubber of examples 1 to 6
Through testing, the corrosiveness of the rubber corrosion inhibitor disclosed by the invention to rubber is completely within a standard range.
Then, according to the standard of GB/T23436-:
TABLE 4 statistical tables of the test results for influence on plastics of examples 1 to 6
The influence of the plastics on examples 1 to 6 is tested, and it can be seen that the corrosiveness of examples 1 to 6 to the plastics all meet the standard requirements.
Finally, according to the standard of GB/T23436-:
TABLE 5 statistics of the test results for the influence of examples 1 to 6 on the organic coating films of automobiles
By testing the influence of the examples 1 to 6 on the organic coating film of the automobile, it can be seen that the corrosiveness of the examples 1 to 6 on the organic coating film of the automobile all meet the standard requirements.
The metal corrosivity test, the plastic influence test, the banana influence test and the influence test on the organic coating of the automobile are respectively carried out on the examples 1 to 6, and the obtained results all meet the standard requirements of GB/T23436-.
The foregoing detailed description of the preferred embodiments of the invention has been presented. It should be understood that numerous modifications and variations could be devised by those skilled in the art in light of the present teachings without departing from the inventive concepts. Therefore, the technical solutions available to those skilled in the art through logic analysis, reasoning and limited experiments based on the prior art according to the concept of the present invention should be within the scope of protection defined by the claims.
Claims (6)
1. The formula of the high-corrosion-resistance automobile glass water is characterized in that: according to the mass percentage, the polyaniline-containing aqueous solution comprises deionized water, 0.01-0.5% of surfactant, 0.001-0.01% of gloriol preservative, 0.01-0.5% of tribenzylamine and 0.01-0.5% of polyaniline.
2. The formula of the highly anticorrosive automobile glass water as claimed in claim 1, wherein the formula comprises the following components: also comprises 30 to 50 percent of glycol and 10 to 20 percent of alcohol.
3. The formula of the highly anticorrosive automobile glass water as claimed in claim 1, wherein the formula comprises the following components: also comprises 0.01 to 0.1 percent of pyflumamine.
4. The formula of the highly anticorrosive automobile glass water as claimed in claim 1, wherein the formula comprises the following components: the surfactant is an AES surfactant.
5. A preparation method of high-corrosion-resistance automobile glass water is characterized by comprising the following steps: the method specifically comprises the following steps:
step one, taking deionized water for standby, adding 0.01-0.5% of AES surfactant while stirring, and uniformly stirring;
secondly, sequentially adding 0.001-0.01% of gloriol preservative, 0.01-0.5% of tribenzylamine and 0.01-0.5% of polyaniline into the liquid obtained in the first step, and uniformly stirring;
and step three, adding 30-50% of glycol and 10-20% of alcohol into the solution obtained in the step two, and slightly stirring until the solution is completely mixed to obtain the automobile glass water.
6. The method for preparing the highly anticorrosive automobile glass water as claimed in claim 5, characterized in that: and step four, adding 0.01-0.1% of pyflumamine into the automobile glass water obtained in step three at the low temperature of 10-15 ℃.
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