CN113085289A - 止裂防弹陶瓷板及其制备方法与应用 - Google Patents
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Abstract
一种止裂防弹陶瓷板及其制备方法与应用,属于复合材料技术领域。该止裂防弹陶瓷板的制备方法包括以下步骤：S1，在防弹陶瓷板表面涂覆粘合剂，低温半固化，形成涂胶防弹陶瓷板；S2，在涂胶防弹陶瓷板表面编织芳纶纤维，使得涂胶防弹陶瓷板封闭在编织成的芳纶纤维密封袋中，形成袋封防弹陶瓷板；S3，抽真空条件下，对袋封防弹陶瓷板热压处理，在此过程中粘结剂固化，最终制得止裂防弹陶瓷板。本发明能够对防弹陶瓷板全方位限位止裂，并且芳纶对防弹陶瓷板全方位地包覆增加了止裂层的耐高温性能进而提高防弹插板抵御穿甲弹、穿甲燃烧的的防弹能力。
Description
技术领域
本发明涉及的是一种复合材料领域的技术，具体是一种止裂防弹陶瓷板及其制备方法与应用。
背景技术
中国专利文献号为CN108859357A的发明专利申请公开了一种可防御12.7mm穿甲燃烧弹陶瓷基复合材料，该材料由聚脲层、芳纶层、石墨烯增韧碳化硼陶瓷层以及PE层通过高分子粘结而成。在穿甲燃烧弹地打击下，高分子粘结剂、特别是陶瓷表面的高分子粘结剂直接老化失效，致使陶瓷表面粘结的芳纶布止裂作用自动消失，该复合材料无法抵御后续穿甲燃烧弹的打击，不能满足复合防弹插板抵御多次枪击的需求。
为了解决现有技术存在的上述问题，本发明由此而来。
发明内容
本发明针对现有技术存在的上述不足，提出了一种止裂防弹陶瓷板及其制备方法与应用，能够对防弹陶瓷板全方位限位止裂，并且芳纶对防弹陶瓷板全方位地包覆增加了止裂层的耐高温性能进而提高防弹插板抵御穿甲弹、穿甲燃烧的的防弹能力。
本发明第一方面提供一种止裂防弹陶瓷板的制备方法，包括以下步骤：
S1，在防弹陶瓷板表面涂覆粘合剂，低温半固化，形成涂胶防弹陶瓷板；
S2，在涂胶防弹陶瓷板表面编织芳纶纤维，使得涂胶防弹陶瓷板封闭在编织成的芳纶纤维密封袋中，形成袋封防弹陶瓷板；
S3，抽真空条件下，对袋封防弹陶瓷板热压处理，在此过程中粘结剂固化，最终制得止裂防弹陶瓷板。
优选地，粘合剂的涂覆厚度为0.5～3mm。
优选的，粘合剂低温半固化温度为30～60℃，固化过程中保温0.1～0.5h。
优选的，芳纶纤维密封袋单侧厚度0.5～1mm，编织时给予20～200N拉力；进一步优选地，编织成斜纹。
优选地，抽真空条件下真空度为1×10-1～1×10-5Pa。
优选的，热压处理中压力为3～5MPa，温度为70～100℃，保温0.2～1h。
本发明第二方面提供一种止裂防弹陶瓷板，采用上述制备方法制得。
本发明第三方面提供一种止裂防弹陶瓷板在防弹复合装甲中的应用。
在一些技术方案中，止裂防弹陶瓷板与超高分子量聚乙烯背板热压复合成防弹复合装甲。进一步优选地，热压压力为3～5MPa、温度为120～150℃，保温0.5～1h。
优选地，超高分子量聚乙烯背板面密度为16～20kg/m2，厚度5～20mm，能够起到拦截穿甲弹碎片的作用。
技术效果
与现有技术相比，本发明具有如下技术效果：
1)编织过程中芳纶纤维持续处于拉伸状态，编织完成后，芳纶纤维密封袋具有一定的预应力，可整体束缚住防弹陶瓷板，达到止裂的作用；
2)编织成的芳纶纤维密封袋能够对防弹陶瓷板表面进行全方位包覆，避免了裁切粘结工艺中常见的空鼓、褶皱现象，进而能够对防弹陶瓷板全方位限位止裂，提高止裂效果；且芳纶纤维连续紧密贴合于防弹陶瓷板表面，在受到子弹冲击时，能够避免防弹陶瓷板表面出现失去止裂能力的连接面；
3)芳纶纤维构成的止裂层还可以起到隔热作用，减少热量对超高分子量聚乙烯背板的热老化破坏；
4)相对于芳纶布裁切粘结工艺，编织工艺一方面能够自动化连续生产，效率高，另一方面无芳纶边角料的产生，芳纶使用量可以减少40％，经济效益高。
附图说明
图1为本发明实施例的工艺流程图；
图中：防弹陶瓷板1，涂胶防弹陶瓷板2，袋封防弹陶瓷板3。
具体实施方式
下面结合附图及具体实施方式对本发明进行详细描述。实施例中未注明具体条件的实验方法，按照常规方法和条件进行。
实施例1
本实施例涉及一种防穿甲弹复合装甲的制备方法，包括以下步骤：
S1，在防弹陶瓷板1表面均匀涂覆粘合剂，涂覆厚度1mm，45℃半固化15min，形成涂胶防弹陶瓷板2，如图1所示；防弹陶瓷板1采用0.08m2单兵胸插板；
S2，以100N的拉力用编织机在涂胶防弹陶瓷板表面编织芳纶纤维，使得涂胶防弹陶瓷板封闭在编织成的芳纶纤维密封袋中，形成袋封防弹陶瓷板3，如图1所示；
S3，将袋封防弹陶瓷板3放入真空热压罐内，抽真空至1×10-4Pa，然后在85℃条件下以3Mpa的加压压力热压处理，保温30min，使粘结剂充分固化，形成止裂防弹陶瓷板；
S4，将步骤S3制得的止裂防弹陶瓷板与面密度16kg/m2、厚度10mm的超高分子量聚乙烯背板紧密贴合，贴合面涂覆环氧树脂；再在高温热压罐中以4MPa、125℃的热压条件处理30min，得到防穿甲弹复合装甲。
经测试，防穿甲弹复合装甲经6发M80型7.62x51mm穿甲弹枪击，弹速850m/s，无穿孔，超高分子量聚乙烯背板最大变形量(凹陷)小于25mm，满足防穿甲弹的要求。
需要强调的是：以上仅是本发明的较佳实施例而已，并非对本发明作任何形式上的限制，凡是依据本发明的技术实质对以上实施例所作的任何简单修改、等同变化与修饰，均仍属于本发明技术方案的范围内。
Claims (8)
1.一种止裂防弹陶瓷板的制备方法，其特征在于，包括以下步骤：
S1，在防弹陶瓷板表面涂覆粘合剂，低温半固化，形成涂胶防弹陶瓷板；
S2，在涂胶防弹陶瓷板表面编织芳纶纤维，使得涂胶防弹陶瓷板封闭在编织成的芳纶纤维密封袋中，形成袋封防弹陶瓷板；
S3，抽真空条件下，对袋封防弹陶瓷板热压处理，在此过程中粘结剂固化，最终制得止裂防弹陶瓷板。
2.根据权利要求1所述止裂防弹陶瓷板的制备方法，其特征是，粘合剂的涂覆厚度为0.5～3mm。
3.根据权利要求1所述止裂防弹陶瓷板的制备方法，其特征是，粘合剂低温半固化温度为30～60℃，固化过程中保温0.1～0.5h。
4.根据权利要求1所述止裂防弹陶瓷板的制备方法，其特征是，芳纶纤维密封袋单侧厚度0.5～1mm，编织时给予20～200N拉力。
5.根据权利要求1所述止裂防弹陶瓷板的制备方法，其特征是，抽真空条件下真空度为1×10-1～1×10-5Pa。
6.根据权利要求1所述止裂防弹陶瓷板的制备方法，其特征是，热压处理中压力为3～5MPa，温度为70～100℃，保温0.2～1h。
7.一种止裂防弹陶瓷板，其特征在于，采用权利要求1-6任一项所述制备方法制得。
8.权利要求7所述止裂防弹陶瓷板在防弹复合装甲中的应用。
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| CN114940016A (zh) * | 2022-06-22 | 2022-08-26 | 中国兵器装备集团西南技术工程研究所 | 一种预应力三维约束防弹装甲板的制备方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104677194A (zh) * | 2015-02-05 | 2015-06-03 | 山东大学 | 一种模块化多维复合防弹板及其制备方法 |
| CN108656691A (zh) * | 2018-06-20 | 2018-10-16 | 浙江立泰复合材料股份有限公司 | 一种可防御7.62mm穿甲燃烧弹陶瓷基复合材料 |
| CN111319318A (zh) * | 2020-01-07 | 2020-06-23 | 苏州第一元素纳米技术有限公司 | 防弹复合装甲及其制备方法 |
| CN112254581A (zh) * | 2020-09-21 | 2021-01-22 | 际华集团股份有限公司系统工程中心 | 带有吸热层的防弹插板及其制作方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104677194A (zh) * | 2015-02-05 | 2015-06-03 | 山东大学 | 一种模块化多维复合防弹板及其制备方法 |
| CN108656691A (zh) * | 2018-06-20 | 2018-10-16 | 浙江立泰复合材料股份有限公司 | 一种可防御7.62mm穿甲燃烧弹陶瓷基复合材料 |
| CN111319318A (zh) * | 2020-01-07 | 2020-06-23 | 苏州第一元素纳米技术有限公司 | 防弹复合装甲及其制备方法 |
| CN112254581A (zh) * | 2020-09-21 | 2021-01-22 | 际华集团股份有限公司系统工程中心 | 带有吸热层的防弹插板及其制作方法 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114940016A (zh) * | 2022-06-22 | 2022-08-26 | 中国兵器装备集团西南技术工程研究所 | 一种预应力三维约束防弹装甲板的制备方法 |
| CN114940016B (zh) * | 2022-06-22 | 2024-02-13 | 中国兵器装备集团西南技术工程研究所 | 一种预应力三维约束防弹装甲板的制备方法 |
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