CN113066883A - Colorful heat-insulating fireproof power generation glass and preparation method thereof - Google Patents

Colorful heat-insulating fireproof power generation glass and preparation method thereof Download PDF

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CN113066883A
CN113066883A CN202110282890.XA CN202110282890A CN113066883A CN 113066883 A CN113066883 A CN 113066883A CN 202110282890 A CN202110282890 A CN 202110282890A CN 113066883 A CN113066883 A CN 113066883A
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layer
heat
power generation
insulating fireproof
insulating
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CN113066883B (en
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彭寿
潘锦功
杨超
傅干华
孙庆华
李�浩
王金萍
蒋猛
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Cnbm Chengdu Optoelectronic Materials Co ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/04Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
    • H01L31/042PV modules or arrays of single PV cells
    • H01L31/048Encapsulation of modules
    • H01L31/0481Encapsulation of modules characterised by the composition of the encapsulation material
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62CFIRE-FIGHTING
    • A62C3/00Fire prevention, containment or extinguishing specially adapted for particular objects or places
    • A62C3/16Fire prevention, containment or extinguishing specially adapted for particular objects or places in electrical installations, e.g. cableways
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0216Coatings
    • H01L31/02161Coatings for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/02167Coatings for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S20/00Supporting structures for PV modules
    • H02S20/20Supporting structures directly fixed to an immovable object
    • H02S20/22Supporting structures directly fixed to an immovable object specially adapted for buildings
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S20/00Supporting structures for PV modules
    • H02S20/20Supporting structures directly fixed to an immovable object
    • H02S20/22Supporting structures directly fixed to an immovable object specially adapted for buildings
    • H02S20/26Building materials integrated with PV modules, e.g. façade elements
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02SGENERATION OF ELECTRIC POWER BY CONVERSION OF INFRARED RADIATION, VISIBLE LIGHT OR ULTRAVIOLET LIGHT, e.g. USING PHOTOVOLTAIC [PV] MODULES
    • H02S40/00Components or accessories in combination with PV modules, not provided for in groups H02S10/00 - H02S30/00
    • H02S40/40Thermal components
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B10/00Integration of renewable energy sources in buildings
    • Y02B10/10Photovoltaic [PV]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy

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  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
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Abstract

The invention discloses color heat-insulating fireproof power generation glass, which comprises a film power generation layer and a color heat-insulating fireproof layer; the colorful heat-insulating fireproof layer comprises a cold-rolled substrate layer in the middle, a chemical treatment layer, a primary coating and a fine coating which are sequentially arranged on two sides of the cold-rolled substrate layer, and a propylene emulsion layer and a silicon propylene layer are sequentially arranged on the upper surface of the fine coating on the upper end face. The colorful heat-preservation fireproof power generation glass disclosed by the invention is coated with the colorful color layer, so that the heat absorption can be improved, the heat preservation effect is enhanced, and the pattern effect on the back plate is realized by arranging colors on the solar cell back plate.

Description

Colorful heat-insulating fireproof power generation glass and preparation method thereof
Technical Field
The invention relates to the field of power generation glass, in particular to colorful heat-insulating fireproof power generation glass and a preparation method thereof.
Background
Solar cells are a novel energy source, and can generate 'endless energy sources' by light, and at present, solar cells are mainly applied to ground power stations and are gradually applied to daily life such as BIPV (building integrated photovoltaics), photovoltaic greenhouses and the like. However, when the conventional solar cell is applied to BIPV, the thermal insulation performance is poor. When current electricity generation glass is used on the outer wall, electricity generation glass does not have any heat preservation measure, mainly relies on the wall body to insulate against heat, and the heat-proof quality of product self is relatively poor, and ordinary electricity generation glass heat transfer coefficient does: about 3.3W/m DEG C, the normal heat preservation requirement of the outer wall can not be met. Can not meet the actual market demand, so that the application is not wide. Especially in some places with high requirements on heat preservation environment, the applicability of the power generation glass is not enough, so that the popularization and the application of the product are hindered.
Disclosure of Invention
The invention provides colorful heat-insulating fireproof power generation glass with excellent heat-insulating effect and low component power loss and a preparation method thereof, aiming at overcoming the defects in the prior art.
The invention firstly provides colored heat-insulating fireproof power generation glass, which comprises a film power generation layer and a colored heat-insulating fireproof layer; the colorful heat-insulating fireproof layer comprises a cold-rolled substrate layer in the middle, and a chemical treatment layer, a primary coating and a fine coating which are sequentially arranged on two sides of the cold-rolled substrate layer, wherein a propylene emulsion layer and a silicon propylene layer are sequentially arranged on the upper surface of the fine coating on the upper end face; the primary coating and the fine coating are color layers.
The invention also provides the following optimization scheme:
preferably, the thin film power generation layer is made of one or more materials of cadmium telluride, copper indium gallium selenide and perovskite.
Preferably, the cold-rolled substrate layer comprises aluminum-zinc plated layers on two sides and an insulating layer in the middle.
Preferably, the heat-insulating layer is made of glass fiber cotton or rock wool.
Preferably, the color heat-insulating fireproof layer further comprises a silica gel connecting layer between the film power generation layer and the color heat-insulating fireproof layer.
More preferably, back rails are arranged on two sides of the silica gel connecting layer and two sides of the colorful heat-insulating fireproof layer.
More preferably, the components of the silica gel connection layer comprise polydimethylsiloxane, white carbon black and vinyl oximidosilane.
More preferably, the colorful heat-insulating fireproof layer is provided with a colorful heat-insulating fireproof layer through hole.
The invention also provides a preparation method of the color heat-insulating fireproof power generation glass, which comprises the following steps:
s1 arranging back rails on two sides of the upper surface of the film power generation layer;
s2, coating a silica gel connecting layer on the upper surface of the film power generation layer;
s3 bonding a colorful heat-insulating fireproof layer on the silica gel connecting layer;
s4, the bonded color heat-preservation fireproof power generation glass is subjected to static pressing.
Preferably, the cadmium telluride power generating glass surface is wiped and cleaned by absolute ethyl alcohol before the step S2 is carried out.
More preferably, the pressing in the step S4 is performed by pressing the whole insulating layer and the power generation glass at an ambient temperature of 24-26 ℃ under a pressure of 1 MPa.
The invention has the beneficial effects that:
1. the colorful heat-preservation fireproof power generation glass is additionally provided with the heat-preservation layer, so that the heat-preservation effect can be greatly improved;
2. the preparation method of the colorful heat-insulating fireproof power generation glass is simple and easy to operate;
3. after the heat-insulating layer is added to the colorful heat-insulating fireproof power generation glass, the power loss of the assembly is greatly reduced;
4. the colorful heat-preservation fireproof power generation glass disclosed by the invention is coated with the colorful color layer, so that the heat absorption can be improved, the heat preservation effect is enhanced, and the pattern effect on the back plate is realized by arranging colors on the solar cell back plate.
Drawings
FIG. 1 is a cross-sectional view of a colored heat-insulating fireproof power generation glass according to a preferred embodiment of the present invention;
FIG. 2 is a layered structure diagram of a colored thermal and fire-proof layer according to a preferred embodiment of the present invention;
FIG. 3 is a top view of a thin film power generation layer according to a preferred embodiment of the present invention;
FIG. 4 is a top view of a colored thermal and fire barrier layer according to a preferred embodiment of the present invention;
the specific reference numerals are:
1 thin film power generation layer; 2, a colorful heat-insulating fireproof layer; 3 a silica gel connection layer; 11, a junction box; 21 an insulating layer; 22 an aluminum-zinc plated layer; 23 chemically treating the layer; 24 primary coating; 25 fine coating; 26 a propylene latex layer; a 27 silicon acrylic layer; 28 color heat preservation fireproof layer through holes.
Detailed Description
In order that those skilled in the art will better understand the technical solutions of the present invention, the present invention will be further described in detail with reference to the following embodiments.
The invention provides a colorful heat-insulating fireproof power generation glass, which comprises a thin film power generation layer 1 and a colorful heat-insulating fireproof layer 2; the color heat-insulating fireproof layer 2 comprises a cold-rolled substrate layer in the middle, a chemical treatment layer 23, a primary coating 24 and a fine coating 25 which are sequentially arranged on two sides of the cold-rolled substrate layer, and a propylene emulsion layer 26 and a silicon-propylene layer 27 are sequentially arranged on the upper surface of the fine coating 25 on the upper end face; the primary coating 24 and the finish coating 25 are color layers; the primary coat 24 is a primer and the finish coat 25 is a secondary finish. The color is more uniform and fine by using two coating processes.
In a preferred embodiment, the cold-rolled substrate layer comprises aluminum-zinc plated layers 22 on both sides and an insulating layer 21 in the middle, and the insulating layer 21 is made of glass fiber cotton or rock wool. The glass fiber cotton or rock wool is used as the heat insulation layer 21, and can be suitable for most illumination environments. The thin film power generation layer 1 is made of one or more materials of cadmium telluride, copper indium gallium selenide and perovskite.
In a preferred embodiment, the silicon rubber connecting layer 3 between the film power generation layer 1 and the colorful heat-preservation and fire-protection layer 2 is further included. The silica gel connecting layer 3 comprises polydimethylsiloxane, white carbon black and vinyl oximidosilane.
In a preferred embodiment, back rails 4 are arranged on both sides of the silica gel connecting layer 3 and the colored heat-insulating and fireproof layer 2.
In a preferred embodiment, the colored heat-insulating and fire-resisting layer 2 is provided with a colored heat-insulating and fire-resisting layer through hole 28. The colored heat-insulating and fireproof layer through holes 28 can be arranged into circular holes or square holes which are commonly used.
The preparation method of the colorful heat-insulating fireproof power generation glass comprises the following steps:
s1, back rails 4 are arranged on two sides of the upper surface of the film power generation layer 1;
s2, coating a silica gel connecting layer 3 on the upper surface of the film power generation layer 1;
s3 bonding a colorful heat-insulating fireproof layer 2 on the silica gel connecting layer 3;
s4, the bonded color heat-preservation fireproof power generation glass is subjected to static pressing.
Preferably, the cadmium telluride power generating glass surface is wiped and cleaned by absolute ethyl alcohol before the step S2 is carried out.
More preferably, the pressing in the step S4 is performed by pressing and curing at an ambient temperature of 24-26 ℃, and the entire insulating layer 21 and the power generation glass are pressed by using a pressure of 1 MPa. The pressing time is preferably 4H.
The components of the colorful heat-insulating fireproof layer 2 are as follows: the cold-rolled base plate is composed of two high-quality aluminum-zinc-plated layers 22 with the thickness of about 0.5-0.8 mm, a middle heat-insulating layer 21 is composed of glass fiber cotton or rock wool, and a primary coating 24 and a fine coating 25 on the surface of the aluminum-zinc-plated cold-rolled base plate can be subjected to pattern or color printing according to requirements. The fireproof grade of the colorful heat-insulating fireproof layer 2 is A, the colorful heat-insulating fireproof layer is nontoxic, and the surface structure of the colorful heat-insulating fireproof layer is shown in figure 2.
The adhesive silica gel of the invention is prepared from polydimethylsiloxane and white carbon black SiO2·nH2O, and vinyl oximido silane.
Before the colored heat-insulating fireproof layer 2 is adhered, absolute ethyl alcohol (with the concentration of 98%) is needed to be used on the surface of the power generation glass provided with the back rail 4 for wiping and cleaning, and impurities and oil stains on the power generation glass back plate are removed; the surface of the power generation glass backboard is provided with a junction box 11, and the backboard is shown in figure 3.
The size of the colorful heat-insulating fireproof layer 2 is preferably long: 1573mm, width: 1173 mm; and at the distance from the short side: 273mm, long side: a position of 423mm is reserved with 70 x 70mm2A color heat-insulating fireproof layer through hole 28 (for external connection of the junction box 11 and the battery lead) as shown in fig. 4;
the silica gel is coated by using a silica gel gun, and silica gel is transversely laid on the surface of the power generation glass back plate of the mounting back rail 4 from the short side of the power generation glass junction box 11, so that the requirements are as follows: laying width of 20mm per interval: 8mm, thickness: 5mm, length: 1100mm of silica gel; then, uniformly coating silica gel on the power generation glass back plate by using a tool, wherein the tool has the following requirements: thickness of silica gel: 2-4 mm; if the power generation glass has the light transmission function, transparent bonding silica gel is used for bonding, and the colorful patterns of the heat-insulating fireproof layer can be seen from the light receiving surface by using the transparent bonding silica gel;
when the terminal box is installed, the short sides of the non-terminal box 11 are sequentially bonded from the short sides of the terminal box 11; before bonding, a cable of the junction box 11 needs to penetrate through a reserved hole position of the colorful heat-insulation fireproof layer 2 in advance; fig. 1 is a sectional view after the installation is completed.
Example one
The colorful heat-insulating fireproof power generation glass comprises a thin film power generation layer 1 and a colorful heat-insulating fireproof layer 2; the color heat-insulating fireproof layer 2 comprises a cold-rolled substrate layer in the middle, a chemical treatment layer 23, a primary coating 24 and a fine coating 25 which are sequentially arranged on two sides of the cold-rolled substrate layer, and a propylene emulsion layer 26 and a silicon-propylene layer 27 are sequentially arranged on the upper surface of the fine coating 25 on the upper end face; the primary coating 24 and the finish coating 25 are color layers. The cold rolling substrate layer comprises aluminum-zinc plated layers 22 on two sides and a heat insulation layer 21 in the middle, and the heat insulation layer 21 is made of glass fiber cotton or rock wool.
The preparation method of the color heat-preservation fireproof power generation glass comprises the following steps:
s1, back rails 4 are arranged on two sides of the upper surface of the film power generation layer 1;
s2, coating a silica gel connecting layer 3 on the upper surface of the film power generation layer 1;
s3 bonding a colorful heat-insulating fireproof layer 2 on the silica gel connecting layer 3;
s4, the bonded color heat-preservation fireproof power generation glass is subjected to static pressing.
The specific operation process comprises the steps of firstly preparing adhesive silica gel of the heat insulation layer and the silica gel connection layer 3, then preparing cadmium telluride generating glass, mounting back rails 4 on two sides of the upper surface of the cadmium telluride generating glass, cleaning the cadmium telluride generating glass mounted with the back rails 4, coating the adhesive silica gel on one side of the cadmium telluride generating glass mounted with the back rails 4, adhering the color heat-preservation fireproof layer 2 on the silica gel connection layer 3 according to the size specification, and performing static pressing on the adhered color heat-preservation fireproof generating glass.
Example two
Carrying out an outdoor illumination test, selecting the photovoltaic module which adopts the color heat-preservation fireproof power generation glass, the common cadmium telluride power generation glass and other materials prepared in the first embodiment, and adopting the following installation modes: choose outdoor no shelter from spacious department, the subassembly mounted position becomes 16 jiaos with ground, and the sensitive surface orientation is southeast direction, test time: 09:00-17:00 (summer/sunny day), the heat-insulating performance of the heat-insulating fireproof power generation glass is superior to that of other test components through the test, and the data is as follows:
Figure BDA0002979286820000061
the above is only a preferred embodiment of the present invention, and it should be noted that the above preferred embodiment should not be considered as limiting the present invention, and the protection scope of the present invention should be subject to the scope defined by the claims. It will be apparent to those skilled in the art that various modifications and adaptations can be made without departing from the spirit and scope of the invention, and these modifications and adaptations should be considered within the scope of the invention.

Claims (10)

1. The utility model provides a colored heat preservation fireproof electricity generation glass which characterized in that: comprises a film power generation layer and a colorful heat-insulating fireproof layer; the colorful heat-insulating fireproof layer comprises a cold-rolled substrate layer in the middle, and a chemical treatment layer, a primary coating and a fine coating which are sequentially arranged on two sides of the cold-rolled substrate layer, wherein a propylene emulsion layer and a silicon propylene layer are sequentially arranged on the upper surface of the fine coating on the upper end face; the primary coating and the fine coating are color layers.
2. The colored heat-insulating fireproof power generation glass according to claim 1, wherein: the thin film power generation layer is made of one or more materials of cadmium telluride, copper indium gallium selenide and perovskite.
3. The colored heat-insulating fireproof power generation glass according to claim 1, wherein: the cold rolling substrate layer comprises aluminum-zinc plated layers on two sides and a heat insulation layer in the middle.
4. The colored heat-insulating fireproof power generation glass according to claim 3, wherein: the heat-insulating layer is made of glass fiber cotton or rock wool.
5. The colored heat-insulating fireproof power generation glass according to claim 1, wherein: and the silica gel connecting layer is arranged between the film power generation layer and the color heat-insulation fireproof layer.
6. The colored heat-insulating fireproof power generation glass according to claim 5, wherein: and back rails are arranged on two sides of the silica gel connecting layer and the colorful heat-insulating fireproof layer.
7. The colored heat-insulating fireproof power generation glass according to claim 5, wherein: the silica gel connecting layer comprises polydimethylsiloxane, white carbon black and vinyl oximidosilane.
8. The colored heat-insulating fireproof power generation glass according to claim 5, wherein: and a colored heat-insulating fireproof layer through hole is formed in the colored heat-insulating fireproof layer.
9. A method for preparing the colored heat-insulating fireproof power generation glass according to any one of claims 5 to 8, wherein the method comprises the following steps: the method comprises the following steps:
s1 arranging back rails on two sides of the upper surface of the film power generation layer;
s2, coating a silica gel connecting layer on the upper surface of the film power generation layer;
s3 bonding a colorful heat-insulating fireproof layer on the silica gel connecting layer;
s4, the bonded color heat-preservation fireproof power generation glass is subjected to static pressing.
10. The method for preparing the colored heat-insulating fireproof power generation glass according to claim 9, wherein the method comprises the following steps: the pressing in the step S4 is to press the whole insulating layer and the power generation glass at the ambient temperature of 24-26 ℃ and under the pressure of 1 MPa.
CN202110282890.XA 2021-03-16 2021-03-16 Colored heat-insulating fireproof power generation glass and preparation method thereof Active CN113066883B (en)

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Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202473969U (en) * 2011-12-26 2012-10-03 嘉兴优太太阳能有限公司 Amorphous silicon film solar module capable of improving low temperature environment characteristic
CN203282763U (en) * 2013-05-17 2013-11-13 浙江华东轻钢建材有限公司 Fluorescent color steel plate
CN203536452U (en) * 2013-10-23 2014-04-09 无锡市大禾高分子材料有限公司 A color solar battery assembly
CN207332185U (en) * 2017-09-20 2018-05-08 广东雄杰建材有限公司 A kind of reinforcement type compound quartz stone plate
CN207484817U (en) * 2017-07-24 2018-06-12 王艺蓉 A kind of Novel multifunctional heat preservation building board
CN108493264A (en) * 2018-04-17 2018-09-04 成都中建材光电材料有限公司 A kind of colour cadmium telluride diaphragm solar battery and preparation method thereof
CN207878771U (en) * 2017-12-28 2018-09-18 成都中建材光电材料有限公司 A kind of BIPV photovoltaics walltile
CN111540793A (en) * 2020-05-11 2020-08-14 成都中建材光电材料有限公司 Cadmium telluride solar cell module with insulating layer and preparation method thereof
KR20210001841A (en) * 2019-06-26 2021-01-06 한국전자통신연구원 Colored transparent solar cell

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202473969U (en) * 2011-12-26 2012-10-03 嘉兴优太太阳能有限公司 Amorphous silicon film solar module capable of improving low temperature environment characteristic
CN203282763U (en) * 2013-05-17 2013-11-13 浙江华东轻钢建材有限公司 Fluorescent color steel plate
CN203536452U (en) * 2013-10-23 2014-04-09 无锡市大禾高分子材料有限公司 A color solar battery assembly
CN207484817U (en) * 2017-07-24 2018-06-12 王艺蓉 A kind of Novel multifunctional heat preservation building board
CN207332185U (en) * 2017-09-20 2018-05-08 广东雄杰建材有限公司 A kind of reinforcement type compound quartz stone plate
CN207878771U (en) * 2017-12-28 2018-09-18 成都中建材光电材料有限公司 A kind of BIPV photovoltaics walltile
CN108493264A (en) * 2018-04-17 2018-09-04 成都中建材光电材料有限公司 A kind of colour cadmium telluride diaphragm solar battery and preparation method thereof
KR20210001841A (en) * 2019-06-26 2021-01-06 한국전자통신연구원 Colored transparent solar cell
CN111540793A (en) * 2020-05-11 2020-08-14 成都中建材光电材料有限公司 Cadmium telluride solar cell module with insulating layer and preparation method thereof

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