CN113025764A - Leather and repairing method thereof - Google Patents

Leather and repairing method thereof Download PDF

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Publication number
CN113025764A
CN113025764A CN202110134961.1A CN202110134961A CN113025764A CN 113025764 A CN113025764 A CN 113025764A CN 202110134961 A CN202110134961 A CN 202110134961A CN 113025764 A CN113025764 A CN 113025764A
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Prior art keywords
leather
dust
latex
repairing method
filling agent
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CN202110134961.1A
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CN113025764B (en
Inventor
黄志擎
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Huidong Weipin Integrated Products Co ltd
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Huidong Weipin Integrated Products Co ltd
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Publication of CN113025764A publication Critical patent/CN113025764A/en
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    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14BMECHANICAL TREATMENT OR PROCESSING OF SKINS, HIDES OR LEATHER IN GENERAL; PELT-SHEARING MACHINES; INTESTINE-SPLITTING MACHINES
    • C14B1/00Manufacture of leather; Machines or devices therefor
    • C14B1/44Mechanical treatment of leather surfaces
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/04Printing inks based on proteins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/06Printing inks based on fatty oils
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/08Printing inks based on natural resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D123/00Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
    • C09D123/02Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D123/04Homopolymers or copolymers of ethene
    • C09D123/06Polyethene
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D129/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
    • C09D129/02Homopolymers or copolymers of unsaturated alcohols
    • C09D129/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Abstract

The invention discloses leather and a repairing method thereof, which are completed according to the following steps: the method comprises the following steps: polishing the defective leather, and collecting the polished leather dust; step two: leather dust and latex are mixed according to the proportion of 4-7: 3-6, fully mixing to prepare a filling agent; step three: smearing the polished leather by using leather dust and then rolling until the leather is uniform; step four: repeatedly coating the leather which is coated with the leather dust for 2-5 times by using the filling agent; step five: the finished product is obtained by airing the leather which is coated, the problem that the leather with defects is difficult to use is solved by arranging the filling agent, the utilization rate of the leather with defects is improved, the texture of leather is effectively improved by the repaired leather, the hand feeling is comfortable, and the appearance is integrally higher and higher.

Description

Leather and repairing method thereof
Technical Field
The invention belongs to the technical field of leather, and particularly relates to leather and a repairing method thereof.
Background
The leather is animal skin which is obtained by physical and chemical processing such as unhairing, tanning and the like and is denatured and non-perishable. The leather is formed by tightly weaving natural protein fibers in a three-dimensional space, and the surface of the leather is provided with a special grain surface layer which has natural grains and luster and comfortable hand feeling.
However, in the prior art, the leather has defects, polyurethane is generally directly adopted to wrap the leather, so that the hand feeling is poor, the texture of the leather is not generated, the whole leather looks low, and if the defective leather is directly incinerated and discarded, the treatment mode is not environment-friendly.
Disclosure of Invention
The embodiment of the application provides the leather and the repairing method thereof, the problem that the leather with defects is difficult to use is solved by arranging the filling agent, the utilization rate of the leather with defects is improved, the leather after repairing effectively improves the texture of the leather, the hand feeling is comfortable, the appearance is integrally higher and higher, and the manufacturing cost is effectively reduced.
The technical scheme provided by the embodiment of the application is as follows:
a leather repairing method comprises the following steps:
the method comprises the following steps: polishing the defective leather, and collecting the polished leather dust;
step two: leather dust and latex are mixed according to the proportion of 4-7: 3-6, fully mixing to prepare a filling agent;
step three: smearing the polished leather by using leather dust and then rolling until the leather is uniform;
step four: repeatedly coating the leather which is coated with the leather dust for 2-5 times by using the filling agent;
step five: and (5) airing the coated leather to obtain a finished product.
According to the invention, the defective leather is maintained, the same leather can be properly polished and the leather dust is collected, then the filler is blended, the polished leather is coated by the filler and then dried, and the finished product is obtained.
Further, in the step one, the leather with defects is polished to a thickness of 0.5-2mm, and by this arrangement, the thickness to be polished can be selected according to the defects of the actual leather.
Further, in the second step, in the process of manufacturing the filler, the latex is poured into the filler for clockwise stirring, the leather dust is slowly added in the stirring process until the leather dust is dissolved in the latex, and through the setting, the leather dust is slowly poured into the filler in the same sequence in batches, so that the leather dust is stirred more fully.
Further, in the second step, the temperature in the process of manufacturing the filling agent is 20-28 ℃.
Further, in the second step, the latex comprises the following components in percentage by weight: 10-20% of polyethylene, 7-9% of polyacrylamide, 3-5% of styrene-acrylic emulsion, 3-5% of chloropyridine, 20-28% of starch, 3-5% of active zinc oxide, 5-8% of formaldehyde, 3-5% of hydrochloric acid and the balance of water.
Further, in the second step, the latex comprises the following components in percentage by weight: the starch 10-27%, polyvinyl alcohol 20-37%, polyvinyl acetate emulsion 10-18%, formaldehyde 1-3%, hydrochloric acid 1-3%, water 12-58%, through this arrangement, its ingredient manufacturing process is effective to lower costs, and the non-staining environment, do not produce the pungent smell to the human body, improve the drying time.
Furthermore, the starch is corn starch or potato starch, and through the arrangement, the using amount of chemical raw materials is greatly reduced, and the cost is effectively reduced.
Further, repeating the third step for 2-3 times until the mixture is uniform; the leather dust in the third step and the filler in the fourth step are combined by adopting electrostatic adsorption, wherein the leather dust carries positive or negative charges, and the filler carries charges opposite to the leather dust, so that the leather dust and the filler are combined to form the leather dust-containing composite material
The adsorption is more smooth and stable, and the hand feeling is more comfortable.
Further, in the fifth step, the leather coated with the filler is spread and dried at the drying temperature of 23-35 ℃, so that the leather is fully fused with the filler, and the repairing effect is better.
Leather finished according to the steps of the maintenance method of claim 1, which is environmentally friendly to manufacture, and has a greatly reduced cost and a high quality.
The invention has the beneficial effects that:
by arranging the filling agent, the problem that defective leather is difficult to use is solved, the utilization rate of the defective leather is improved, the repaired leather has better light color fastness, the texture of leather is effectively improved, the hand feeling is comfortable, and the appearance is integrally higher and higher.
Drawings
FIG. 1 is a flow chart of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
To facilitate an understanding of the present invention for those skilled in the art, the present invention will be described in further detail below with reference to specific embodiments and accompanying drawings.
A leather repairing method comprises the following steps:
the method comprises the following steps: polishing the defective leather, and collecting the polished leather dust;
step two: leather dust and latex are mixed according to the proportion of 4-7: 3-6, fully mixing to prepare a filling agent;
step three: smearing the polished leather by using leather dust and then rolling until the leather is uniform;
step four: repeatedly coating the leather which is coated with the leather dust for 2-5 times by using the filling agent;
step five: and (5) airing the coated leather to obtain a finished product.
According to the invention, the defective leather is maintained, the same leather can be properly polished and the leather dust is collected, then the filler is blended, the polished leather is coated by the filler and then dried, and the finished product is obtained.
Further, in the step one, the leather with defects is polished to a thickness of 0.5-2mm, and by this arrangement, the thickness to be polished can be selected according to the defects of the actual leather.
Further, in the second step, in the process of manufacturing the filler, the latex is poured into the filler for clockwise stirring, the leather dust is slowly added in the stirring process until the leather dust is dissolved in the latex, and through the setting, the leather dust is slowly poured into the filler in the same sequence in batches, so that the leather dust is stirred more fully.
Further, in the second step, the temperature in the process of manufacturing the filling agent is 20-28 ℃.
Further, in the second step, the latex comprises the following components in percentage by weight: 90g of polyethylene, 48g of polyacrylamide, 24g of styrene-acrylic emulsion, 150g of chloroparase, 24g of starch, 36g of active zinc oxide, 24g of formaldehyde, 24g of hydrochloric acid and 180g of water.
Further, in the second step, the latex comprises the following components in percentage by weight: the drying agent comprises 108g of starch, 180g of polyvinyl alcohol, 90g of polyvinyl acetate emulsion, 12g of formaldehyde, 12g of hydrochloric acid and 198g of water.
Furthermore, the starch is corn starch or potato starch, and through the arrangement, the using amount of chemical raw materials is greatly reduced, and the cost is effectively reduced.
Further, repeating the third step for 2-3 times until the mixture is uniform; the leather dust in the third step and the filler in the fourth step are combined by adopting electrostatic adsorption, wherein the leather dust carries positive or negative charges, and the filler carries charges opposite to the leather dust, so that the leather dust and the filler are combined to form the leather dust-containing composite material
The adsorption is more smooth and stable, and the hand feeling is more comfortable.
Further, in the fifth step, the leather coated with the filler is spread and dried at the drying temperature of 23-35 ℃, so that the leather is fully fused with the filler, and the repairing effect is better.
Leather finished according to the steps of the maintenance method of claim 1, which is environmentally friendly to manufacture, and has a greatly reduced cost and a high quality.
Example 2
A leather repairing method comprises the following steps:
the method comprises the following steps: polishing the defective leather, and collecting the polished leather dust;
step two: leather dust and latex are mixed according to the proportion of 4-7: 3-6, fully mixing to prepare a filling agent;
step three: smearing the polished leather by using leather dust and then rolling until the leather is uniform;
step four: repeatedly coating the leather which is coated with the leather dust for 2-5 times by using the filling agent;
step five: and (5) airing the coated leather to obtain a finished product.
According to the invention, the defective leather is maintained, the same leather can be properly polished and the leather dust is collected, then the filler is blended, the polished leather is coated by the filler and then dried, and the finished product is obtained.
Further, in the step one, the leather with defects is polished to a thickness of 0.5-2mm, and by this arrangement, the thickness to be polished can be selected according to the defects of the actual leather.
Further, in the second step, in the process of manufacturing the filler, the latex is poured into the filler for clockwise stirring, the leather dust is slowly added in the stirring process until the leather dust is dissolved in the latex, and through the setting, the leather dust is slowly poured into the filler in the same sequence in batches, so that the leather dust is stirred more fully.
Further, in the second step, the temperature in the process of manufacturing the filling agent is 20-28 ℃.
Further, in the second step, the latex comprises the following components in percentage by weight: 67.5g of polyethylene, 36g of polyacrylamide, 18g of styrene-acrylic emulsion, 112.5g of chloroparase, 18g of starch, 27g of active zinc oxide, 18g of formaldehyde, 18g of hydrochloric acid and 135g of water.
Further, in the second step, the latex comprises the following components in percentage by weight: the drying agent comprises 81g of starch, 135g of polyvinyl alcohol, 67.5g of polyvinyl acetate emulsion, 9g of formaldehyde, 9g of hydrochloric acid and 148.5g of water.
Furthermore, the starch is corn starch or potato starch, and through the arrangement, the using amount of chemical raw materials is greatly reduced, and the cost is effectively reduced.
Further, repeating the third step for 2-3 times until the mixture is uniform; the leather dust in the third step and the filler in the fourth step are combined by adopting electrostatic adsorption, wherein the leather dust carries positive or negative charges, and the filler carries charges opposite to the leather dust, so that the leather dust and the filler are combined to form the leather dust-containing composite material
The adsorption is more smooth and stable, and the hand feeling is more comfortable.
Further, in the fifth step, the leather coated with the filler is spread and dried at the drying temperature of 23-35 ℃, so that the leather is fully fused with the filler, and the repairing effect is better.
Leather finished according to the steps of the maintenance method of claim 1, which is environmentally friendly to manufacture, and has a greatly reduced cost and a high quality.
Example 3
A leather repairing method comprises the following steps:
the method comprises the following steps: polishing the defective leather, and collecting the polished leather dust;
step two: leather dust and latex are mixed according to the proportion of 4-7: 3-6, fully mixing to prepare a filling agent;
step three: smearing the polished leather by using leather dust and then rolling until the leather is uniform;
step four: repeatedly coating the leather which is coated with the leather dust for 2-5 times by using the filling agent;
step five: and (5) airing the coated leather to obtain a finished product.
According to the invention, the defective leather is maintained, the same leather can be properly polished and the leather dust is collected, then the filler is blended, the polished leather is coated by the filler and then dried, and the finished product is obtained.
Further, in the step one, the leather with defects is polished to a thickness of 0.5-2mm, and by this arrangement, the thickness to be polished can be selected according to the defects of the actual leather.
Further, in the second step, in the process of manufacturing the filler, the latex is poured into the filler for clockwise stirring, the leather dust is slowly added in the stirring process until the leather dust is dissolved in the latex, and through the setting, the leather dust is slowly poured into the filler in the same sequence in batches, so that the leather dust is stirred more fully.
Further, in the second step, the temperature in the process of manufacturing the filling agent is 20-28 ℃.
Further, in the second step, the latex comprises the following components in percentage by weight: 45g of polyethylene, 24g of polyacrylamide, 12g of styrene-acrylic emulsion, 75g of chloroparase, 12g of starch, 18g of active zinc oxide, 12g of formaldehyde, 12g of hydrochloric acid and 90g of water.
Further, in the second step, the latex comprises the following components in percentage by weight: 54g of starch, 90g of polyvinyl alcohol, 45g of polyvinyl acetate emulsion, 6g of formaldehyde, 6g of hydrochloric acid and 99g of water.
Furthermore, the starch is corn starch or potato starch, and through the arrangement, the using amount of chemical raw materials is greatly reduced, and the cost is effectively reduced.
Further, repeating the third step for 2-3 times until the mixture is uniform; the leather dust in the third step and the filler in the fourth step are combined by adopting electrostatic adsorption, wherein the leather dust carries positive or negative charges, and the filler carries charges opposite to the leather dust, so that the leather dust and the filler are combined to form the leather dust-containing composite material
The adsorption is more smooth and stable, and the hand feeling is more comfortable.
Further, in the fifth step, the leather coated with the filler is spread and dried at the drying temperature of 23-35 ℃, so that the leather is fully fused with the filler, and the repairing effect is better.
Leather finished according to the steps of the maintenance method of claim 1, which is environmentally friendly to manufacture, and has a greatly reduced cost and a high quality.
The following description will discuss the present invention with reference to comparative examples in order to clarify the effects of the present invention.
Example 1 Example 2 Example 3 Comparative example
Leather maintenance method Leather dust: the latex is prepared according to the proportion of 4: 6 mixing Making into filler Leather dust: the latex is prepared according to the proportion of 5.5: 4.5 preparation by mixing Bulking agent Leather dust: the latex is prepared according to the proportion of 7: 3 mixing to obtain Filler Using polyurethanes Package
Colour fastness to light 4 stage Grade 5 Grade 6 Grade 3
Sense of dermis Grade 3 4 stage Grade 5 Stage 2
Roughness of 4 stage Grade 5 Grade 6 Grade 3
Remarking: wherein the color fastness to light is grade 8, and the higher the grade is, the better the color fastness to light is; the corium feeling is 7 grades, and the larger the grade is, the better the corium feeling is; the roughness was graded as 7, with the larger the grade, the smoother.
The utilization rate of the defective leather is improved, the color fastness of the repaired leather is good, the texture of the leather is effectively improved, the hand feeling is comfortable, and the appearance is high-grade and high-grade.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art. It should be noted that the technical features not described in detail in the present invention can be implemented by any prior art.

Claims (10)

1. A leather repairing method is characterized by comprising the following steps:
the method comprises the following steps: polishing the defective leather, and collecting the polished leather dust;
step two: leather dust and latex are mixed according to the proportion of 4-7: 3-6, fully mixing to prepare a filling agent;
step three: smearing the polished leather by using leather dust and then rolling until the leather is uniform;
step four: repeatedly coating the leather which is coated with the leather dust for 2-5 times by using the filling agent;
step five: and (5) airing the coated leather to obtain a finished product.
2. A leather repairing method according to claim 1, wherein in the first step, the defective leather is sanded to a thickness of 0.5-2 mm.
3. A leather repairing method according to claim 1, wherein in the second step, the latex is poured into the filler and stirred clockwise, and the leather dust is slowly added during stirring until the leather dust is dissolved in the latex.
4. A leather repairing method according to claim 3, wherein in the second step, the temperature in the process of manufacturing the filling agent is 20-28 ℃.
5. A leather repairing method according to claim 1, wherein in the second step, the latex is composed of the following components by weight percentage: 10-20% of polyethylene, 7-9% of polyacrylamide, 3-5% of styrene-acrylic emulsion, 3-5% of chloropyridine, 20-28% of starch, 3-5% of active zinc oxide, 5-8% of formaldehyde, 3-5% of hydrochloric acid and the balance of water.
6. A leather repairing method according to claim 1, wherein in the second step, the latex is composed of the following components by weight percentage: 10-27% of starch, 20-37% of polyvinyl alcohol, 10-18% of polyvinyl acetate emulsion, 1-3% of formaldehyde, 1-3% of hydrochloric acid and 12-58% of water.
7. A method of repairing leather as claimed in claim 5 or claim 6, wherein said starch is corn starch or potato starch.
8. A leather repairing method according to claim 1, wherein the three steps are repeated 2-3 times until uniform; the leather dust in the third step and the filling agent in the fourth step are combined by electrostatic adsorption.
9. A leather repairing method according to claim 1, wherein in the fifth step, the sheared and pressed leather is spread and dried, and the drying temperature is 23-35 ℃.
10. Leather, characterized in that it is finished according to the maintenance method steps of claim 1.
CN202110134961.1A 2021-02-01 2021-02-01 Leather and repairing method thereof Expired - Fee Related CN113025764B (en)

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Application Number Priority Date Filing Date Title
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB721230A (en) * 1950-12-21 1955-01-05 Deena Ges M B H Improvements in materials for the treatment of leather
CN1133870A (en) * 1995-04-17 1996-10-23 陈建祥 Modified polyvinyl acetate emulsion adhesive
CN1283661A (en) * 1999-08-05 2001-02-14 昆明五华综合精细化工厂 White starch emulsoid
CN108117763A (en) * 2018-01-11 2018-06-05 安徽情暖家具有限公司 A kind of leather sofa preparation method
CN111264972A (en) * 2020-03-16 2020-06-12 兴业皮革科技股份有限公司 Leather shoe upper surface made of natural leather and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB721230A (en) * 1950-12-21 1955-01-05 Deena Ges M B H Improvements in materials for the treatment of leather
CN1133870A (en) * 1995-04-17 1996-10-23 陈建祥 Modified polyvinyl acetate emulsion adhesive
CN1283661A (en) * 1999-08-05 2001-02-14 昆明五华综合精细化工厂 White starch emulsoid
CN108117763A (en) * 2018-01-11 2018-06-05 安徽情暖家具有限公司 A kind of leather sofa preparation method
CN111264972A (en) * 2020-03-16 2020-06-12 兴业皮革科技股份有限公司 Leather shoe upper surface made of natural leather and preparation method thereof

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