CN112957278A - Chitin whisker modified water-based nail polish and preparation method thereof - Google Patents
Chitin whisker modified water-based nail polish and preparation method thereof Download PDFInfo
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- CN112957278A CN112957278A CN202110191970.4A CN202110191970A CN112957278A CN 112957278 A CN112957278 A CN 112957278A CN 202110191970 A CN202110191970 A CN 202110191970A CN 112957278 A CN112957278 A CN 112957278A
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- water
- nail polish
- aqueous
- chitin
- chitin whisker
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/736—Chitin; Chitosan; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The invention provides chitin whisker modified aqueous nail polish water and a preparation method thereof, wherein the components of the nail polish water mainly comprise an aqueous film-forming agent, chitin whiskers and a nutritional agent, the chitin whiskers are ultrasonically dispersed in water, and then the chitin whiskers are added into a mixture of the aqueous film-forming agent, a film-forming assistant, the nutritional agent, a volatile solvent, a liquid preservative and purified water, and the mixture is uniformly stirred, ultrasonically treated, kept stand and degassed to obtain the chitin whisker modified aqueous nail polish water. The nail water of the invention can improve or increase the water solubility resistance, the antibacterial capacity and the nursing capacity of the water-based nail water.
Description
Technical Field
The invention belongs to the field of cosmetics, and particularly relates to chitin whisker modified water-based nail polish and a preparation method thereof.
Background
The nail polish is a cosmetic for decorating and improving the aesthetic degree of nails, and can form a layer of friction-resistant film on the surface of the nails to play a role in protecting and beautifying the nails. Currently, nail polishes used by people can be classified into solvent-based nail polishes and water-based nail polishes. Solvent-based nail polishes contain volatile, irritating organic solvents, and also tend to yellow and embrittle the nail, which is a poor user experience. The components of the water-based nail polish mainly comprise additives such as water, a water-based film forming agent, pigments and the like. Therefore, the water-based nail polish has no pungent smell and no corrosiveness, and is more healthy and environment-friendly. However, the existing water-based nail polish still has some defects, such as poor gloss, poor water resistance, poor adhesion, poor wear resistance, no antibacterial property and the like, and cannot meet the requirements of consumers.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides the chitin whisker modified aqueous nail polish and the preparation method thereof so as to improve the water solubility resistance, the antibacterial capability and the nursing capability of the aqueous nail polish.
According to a first aspect of the invention, the invention provides chitin whisker modified aqueous nail polish, which is characterized by comprising an aqueous film forming agent, a film forming aid, a nutritional agent, a volatile solvent, a liquid preservative and purified water, wherein the aqueous nail polish further comprises 0.05-5 parts of chitin whiskers by mass.
In a preferred embodiment, the nail polish of the present invention comprises the following components: 15-35 parts of aqueous film forming agent, 1-10 parts of film forming auxiliary agent, 0.1-10 parts of nutrient, 0.05-5 parts of chitin whisker, 10-30 parts of volatile solvent, 0.01-0.02 part of liquid preservative, and the balance of purified water, and the balance of the total is 100 parts.
The aqueous film forming agent includes, but is not limited to, one or more of aqueous polyurethane, acrylic acid (ester) copolymer/ammonium methacrylate copolymer.
The film-forming assistant comprises one or more of dipropylene glycol monomethyl ether, dipropylene glycol monobutyl ether, ethylene glycol butyl ether, propylene glycol methyl ether, propylene glycol ethyl ether and propylene glycol butyl ether.
The nutritional agent comprises one or more of water-soluble keratin, fish scale collagen, hydrolyzed wheat protein, active peptide, amino acid, vitamin and hyaluronic acid.
According to the second aspect of the invention, the invention provides a preparation method of chitin whisker modified aqueous nail polish, which is characterized in that chitin whiskers are pre-dispersed in purified water, then mixed with an aqueous film-forming agent, a film-forming assistant, a nutrient, a volatile solvent and a liquid preservative, and the chitin whisker modified aqueous nail polish is prepared by the processes of stirring, ultrasonic dispersion, standing, degassing and the like.
Preferably, the aqueous film forming agent, the film forming aid, the nutritional agent, the volatile solvent and the liquid preservative are dissolved in water and stirred at room temperature, such as 20 ℃, for 0.5 to 2.0 hours; adding chitin whisker suspension and the rest purified water, stirring at room temperature, such as 20 deg.C for 0.5-1.0h, and performing ultrasonic treatment for 10 min; and standing and degassing the mixture for 12-24h to obtain the water-based nail polish modified by the element whiskers.
The water-based nail polish has good antibacterial effect and tensile strength.
Chitin Whiskers (CW) are Chitin fibers existing in a single crystal form, and the inventor believes that the Chitin fibers have high modulus due to regular arrangement of crystal grains and less internal defects, the transverse modulus and the longitudinal modulus of the Chitin fibers are respectively as high as 15 GPa and 150GPa, the Chitin whiskers retain the structure and the bioactivity of Chitin, have biodegradability, unique antibacterial property and good biocompatibility, and are suitable for being used as reinforcing materials. The chitin whisker is added to improve the aqueous nail polish, and the chitin whisker modified aqueous nail polish not only keeps the original performance of the aqueous nail polish, but also has better mechanical property and antibacterial property; in addition, the nail polish with different mechanical strength and antibacterial performance can be obtained by changing the content of the chitin whiskers.
Detailed Description
In order to further understand the present invention, the following specifically describes the chitin whisker modified aqueous nail polish provided by the present invention with reference to the following examples, but the present invention is not limited to these examples, and the insubstantial modifications and adaptations made by those skilled in the art under the core teaching of the present invention still fall within the scope of the present invention.
Preparation of chitin whisker modified water-based nail polish
Example 1
S1: preparing chitin whisker suspension: adding 0.1 part of chitin whisker powder into 10 parts of water, and performing ultrasonic treatment for 10min to obtain chitin whisker suspension.
S2: preparation of aqueous nail polish: dissolving 25 parts of polyurethane-1 (film forming agent), 4 parts of dipropylene glycol monomethyl ether (film forming aid), 1 part of fish scale collagen (nutritional agent), 20 parts of ethanol (volatile solvent) and 0.01 part of phenoxyethanol (liquid preservative) in 20 parts of water, and stirring at 20 ℃ for 0.5-2.0 hours; adding chitin whisker suspension and the balance of water, stirring at 20 ℃ for 0.5-1.0h, and then carrying out ultrasonic treatment for 10 minutes; and standing and degassing the mixture for 12-24h to obtain the chitin whisker modified aqueous nail polish water.
Example 2
The procedure of example 1 was repeated except that the amount of the chitin whisker powder used was changed to 0.2 part.
Example 3
The procedure of example 1 was repeated except that the amount of the chitin whisker powder used was changed to 0.5 part.
Example 4
The procedure of example 1 was repeated except that the amount of the chitin whisker powder used was changed to 1.0 part.
Comparative example:
the procedure was as in example 1 except that no chitin whiskers were added.
(II) routine performance test of chitin whisker modified water-based armor water
Carrying out relevant performance tests on the water-based nail polish prepared in the above examples and comparative examples; the glass plate was coated with a film having a thickness of 100 μm and dried at room temperature for 24 hours before testing.
Surface dry time test: touch method, constant temperature and humidity chamber with 80% humidity and 20 deg.C.
Gloss testing: carrying out a gloss test on a black glass at an incident angle of 60 degrees;
and (3) testing pencil hardness: testing by a 750g load pencil hardness tester;
and (3) testing the adhesive force: the embroidery needle No. 9 is divided into 5 rows at intervals of 1mm, the 5 rows are vertically divided, and the division is 1-10 according to the starting edge condition, wherein the division is the worst 1, and the division is the best 10.
And (3) testing water resistance: and (3) putting the formed template into water at room temperature for 30min, and scoring for 1-10 minutes by observing the edge rising phenomenon, wherein 1 minute is worst, and 10 minutes is best.
The test results are shown in table 1:
TABLE 1 results of performance testing of aqueous nail polishes prepared in examples and comparative examples
| Test item | Comparative example | Example 1 | Example 2 | Example 3 | Example 4 |
| Time to surface dry (min) | 4 | 4 | 4 | 4 | 4 |
| Degree of gloss | 90 | 90 | 90 | 90 | 90 |
| Hardness of pencil | B | HB | HB | H | H |
| Adhesion test | 8 | 8 | 8 | 8 | 8 |
| Water resistance test | 8 | 8 | 9 | 9 | 9 |
From the above test results it appears that: the chitin crystal modified water-based nail polish prepared by the method has the advantages of high film forming speed, excellent glossiness, pencil hardness, adhesive force and water resistance.
(III) Strength test of Water-based nail-protecting Water film
And 3g of the nail polish is placed on a silicon plate, the rotating speed is 2000rpm, the redundant film forming liquid is thrown off, the reciprocating spin coating operation is carried out for 5 times in sequence, then the membrane is placed in a 60 ℃ blast drying oven for 30min, and then the membrane is taken out and removed, so that the high-strength composite membrane is obtained. And (3) measuring the elastic modulus of the chitin whisker composite film by using a universal mechanical testing machine.
The test results are shown in table 2:
table 2 results of performance test of the films obtained in examples and comparative examples
| Test item | Comparative example | Example 1 | Example 2 | Example 3 | Example 4 |
| Modulus of elasticity (Mpa) | 3525 | 3631 | 3863 | 4298 | 4615 |
From the above test results it appears that: the membrane formed by the nail polish prepared by the method is a high-strength membrane, and the strength of the membrane can be adjusted by changing the content of the chitin whiskers.
(IV) testing the bacteriostatic performance of the water-based nail polish water
The E.coli stock solution was diluted with distilled water, the bacterial suspension was mixed with nail-protecting water and water for injection and reacted for 1h, the mixed solution was smeared on an agar plate and cultured at 37 ℃ for 24h, and finally the number of colonies on the agar plate was counted. The nail polish without chitin whiskers (other components were unchanged) was used as a control. The bacteriostatic rate was calculated according to the following formula: the bacteriostatic ratio (%) ═ C-E)/C, where C is the number of colonies in the control group and E is the number of colonies in the experimental group.
The test results are shown in table 3:
table 3 tests of antibacterial properties of armoured water obtained in examples and comparative examples
From the above test results it appears that: the nail polish remover prepared by the method has better antibacterial performance.
The above-described embodiments are merely illustrative of the principles of the present invention and are not to be construed as limiting the invention. Many changes, modifications and variations may be made therein without departing from the spirit and scope of the invention as defined in the following claims.
Claims (6)
1. The chitin whisker modified aqueous nail polish water is characterized by comprising an aqueous film forming agent, a film forming auxiliary agent, a nutritional agent, a volatile solvent, a liquid preservative and purified water, and further comprising 0.05-5 parts of chitin whiskers by mass.
2. The aqueous nail polish of claim 1, comprising the following composition: 15-35 parts of aqueous film forming agent, 1-10 parts of film forming auxiliary agent, 0.1-10 parts of nutrient, 0.05-5 parts of chitin whisker, 10-30 parts of volatile solvent, 0.01-0.02 part of liquid preservative, and the balance of purified water, and the balance of the total is 100 parts.
3. The aqueous nail polish of claim 1, wherein the aqueous film-forming agent comprises one or more of aqueous polyurethane, acrylic acid (ester) copolymer, acrylic acid (ester)/ammonium methacrylate copolymer.
4. The aqueous nail polish of claim 1, wherein the film-forming aid comprises one or more of dipropylene glycol monomethyl ether, dipropylene glycol monobutyl ether, ethylene glycol butyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, and propylene glycol butyl ether.
5. The aqueous nail polish of claim 1, wherein the nutrients comprise one or more of water-soluble keratin, fish scale collagen, hydrolyzed wheat protein, active peptides, amino acids, vitamins, hyaluronic acid.
6. A preparation method of chitin whisker modified water-based nail polish water is characterized by comprising the following steps:
s1: preparing chitin whisker suspension: adding chitin whisker powder into purified water, and performing ultrasonic treatment to obtain chitin whisker suspension;
s2: preparation of aqueous nail polish: dissolving the aqueous film forming agent, the film forming additive, the nutritional agent, the volatile solvent and the liquid preservative into water, and stirring the solution uniformly at room temperature; adding chitin whisker suspension and the balance of purified water, continuing stirring uniformly at room temperature, and then carrying out ultrasonic treatment; and standing and degassing the mixture to obtain the chitin whisker modified aqueous nail polish.
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| CN202110191970.4A CN112957278B (en) | 2021-02-19 | 2021-02-19 | Chitin whisker modified water-based nail polish and preparation method thereof |
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| CN202110191970.4A CN112957278B (en) | 2021-02-19 | 2021-02-19 | Chitin whisker modified water-based nail polish and preparation method thereof |
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| CN112957278A true CN112957278A (en) | 2021-06-15 |
| CN112957278B CN112957278B (en) | 2022-11-08 |
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102093703A (en) * | 2011-01-12 | 2011-06-15 | 华东师范大学 | Method for preparing chitin whisker modified waterborne polyurethane |
| CN105250155A (en) * | 2015-11-16 | 2016-01-20 | 杭州莱凡网络科技有限公司 | Calcium-added nail protecting liquid |
| CN106074219A (en) * | 2016-06-07 | 2016-11-09 | 杭州淳浠化妆品有限公司 | A kind of water-fast water-based nail polish and preparation method thereof |
| CN106309168A (en) * | 2016-10-21 | 2017-01-11 | 熊廷珍 | Full-nutrition type aqueous nail enamel |
| US20180177710A1 (en) * | 2016-01-15 | 2018-06-28 | Lijuan Zhen | Gel polish composition forming a nail gel film on a keratinous material of mammals and the method of using thereof |
| CN108272656A (en) * | 2018-01-12 | 2018-07-13 | 名仕科技股份有限公司 | A kind of water-soluble nail polish and preparation method thereof |
-
2021
- 2021-02-19 CN CN202110191970.4A patent/CN112957278B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102093703A (en) * | 2011-01-12 | 2011-06-15 | 华东师范大学 | Method for preparing chitin whisker modified waterborne polyurethane |
| CN105250155A (en) * | 2015-11-16 | 2016-01-20 | 杭州莱凡网络科技有限公司 | Calcium-added nail protecting liquid |
| US20180177710A1 (en) * | 2016-01-15 | 2018-06-28 | Lijuan Zhen | Gel polish composition forming a nail gel film on a keratinous material of mammals and the method of using thereof |
| CN106074219A (en) * | 2016-06-07 | 2016-11-09 | 杭州淳浠化妆品有限公司 | A kind of water-fast water-based nail polish and preparation method thereof |
| CN106309168A (en) * | 2016-10-21 | 2017-01-11 | 熊廷珍 | Full-nutrition type aqueous nail enamel |
| CN108272656A (en) * | 2018-01-12 | 2018-07-13 | 名仕科技股份有限公司 | A kind of water-soluble nail polish and preparation method thereof |
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| CN112957278B (en) | 2022-11-08 |
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