CN112885253A - Manufacturing process of flexible transparent LED display screen - Google Patents
Manufacturing process of flexible transparent LED display screen Download PDFInfo
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- CN112885253A CN112885253A CN202110396956.8A CN202110396956A CN112885253A CN 112885253 A CN112885253 A CN 112885253A CN 202110396956 A CN202110396956 A CN 202110396956A CN 112885253 A CN112885253 A CN 112885253A
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Classifications
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- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F9/00—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
- G09F9/30—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements
- G09F9/33—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements being semiconductor devices, e.g. diodes
-
- G—PHYSICS
- G09—EDUCATION; CRYPTOGRAPHY; DISPLAY; ADVERTISING; SEALS
- G09F—DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- G09F9/00—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements
- G09F9/30—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements
- G09F9/301—Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements in which the desired character or characters are formed by combining individual elements flexible foldable or roll-able electronic displays, e.g. thin LCD, OLED
Abstract
The invention discloses a manufacturing process of a flexible transparent LED display screen, which comprises the steps of arranging conductive circuits on one side or two sides of a flexible transparent substrate, wherein at least part of the conductive circuits are arranged in a grid shape; arranging a first low-reflection layer on the conductive circuit, wherein the reflectivity of the first low-reflection layer is less than 35%; arranging a bonding pad on the first low-reflection layer or the conducting circuit, wherein the bonding pad is positioned in a lamp bead welding area of the LED display screen; and welding the LED lamp beads on the welding disc. The flexible transparent LED display screen manufacturing process can manufacture flexible transparent LED display screens with low cost and high transparency.
Description
Technical Field
The invention relates to the technical field of LED display, in particular to a manufacturing process of a flexible transparent LED display screen.
Background
Transparent LED displays are gradually used in the market and are developed in various product forms. A transparent LED display screen technology in which LED lamps are arrayed on a transparent substrate has started to appear. The LED display screen generally adopts transparent conductive materials to manufacture a power supply circuit and a signal transmission circuit of the LED lamp bead.
The transparent conductive material is usually ITO (indium tin oxide), but ITO is expensive and has low economic efficiency. Instead, an LED display screen using copper as a conductive material appears in the market, but the light reflection rate of the copper wire is high, which is not beneficial to improving the transparency of the LED display screen.
Therefore, it is desirable to provide a manufacturing process of an LED display screen with low cost and high transparency.
Disclosure of Invention
The embodiment of the application provides a manufacturing process of a flexible transparent LED display screen, and aims to provide a manufacturing process of an LED display screen with low cost and high transparency.
In order to achieve the above object, an embodiment of the present application provides a flexible transparent LED display screen manufacturing process, including:
arranging conductive circuits on one side or two sides of the flexible transparent substrate, wherein at least part of the conductive circuits are arranged in a grid shape;
disposing a first low reflection layer on the conductive line, the first low reflection layer having a reflectivity of less than 35%;
arranging a bonding pad on the first low-reflection layer or the conducting circuit, wherein the bonding pad is positioned in a lamp bead welding area of the LED display screen;
and welding LED lamp beads on the welding pads.
In one embodiment, disposing a first low reflection layer on the conductive line includes:
and coating a first low-reflection layer on the conductive circuit by electroplating, chemical plating or vacuum plating.
In one embodiment, plating a first reflective layer on the conductive traces by electroplating or electroless plating comprises:
and adding an oxidant into the electroplating solution or the chemical plating solution, and oxidizing the metal plating layer deposited on the conductive circuit by the oxidant to obtain the first low-reflection layer.
In one embodiment, the vacuum plating includes vacuum sputtering and vacuum evaporation;
plating a first reflective layer on the conductive circuit in a vacuum plating manner, comprising:
and adding reaction gas into the carrier atmosphere of vacuum sputtering or vacuum evaporation, and oxidizing the plating metal on the conducting wire through the reaction gas to obtain the first low-reflection layer.
In an embodiment, before the conductive traces are disposed on one or both sides of the flexible transparent substrate, the manufacturing process of the flexible transparent LED display screen further includes:
arranging an adhesive layer on one side or two sides of the flexible transparent substrate, wherein the adhesive force between the adhesive layer and the flexible transparent substrate is more than 0.5kg/cm2And the conductive circuit is arranged on the bonding layer.
In an embodiment, before the conductive traces are disposed on one or both sides of the flexible transparent substrate, the flexible transparent LED display screen manufacturing process further includes:
and if the bonding layer meets the preset coloring condition, arranging a second low-reflection layer on the bonding layer, wherein the reflectivity of the second low-reflection layer is lower than 35%, and the conductive circuit is arranged on the second low-reflection layer.
In one embodiment, whether the adhesive layer satisfies a predetermined coloring condition is determined according to at least one of the thickness, the extinction coefficient and the refractive index of the adhesive layer.
In one embodiment, the method for providing conductive circuits on one side or two sides of a flexible transparent substrate comprises the following steps:
arranging a conductive layer on the bonding layer;
and etching the conductive layer into a conductive circuit according with a preset circuit design.
In one embodiment, an adhesive layer is plated on the flexible transparent substrate in an electroplating, chemical plating or vacuum plating mode; and/or the presence of a gas in the gas,
and plating a conductive layer on the bonding layer by electroplating, chemical plating or vacuum plating.
In an embodiment, after the LED lamp beads are welded on the bonding pads, the manufacturing process of the flexible transparent LED display screen further includes:
the LED lamp bead is packaged by matching a surface-drying optical-grade resin with an acid value of less than 5 (KOH)/(mg/g) with a curing agent.
The manufacturing process of the flexible transparent LED display screen comprises the steps of setting a first low reflection layer on a conducting circuit, controlling the reflectivity of the first low reflection layer to be smaller than 35%, reducing the reflectivity of the conducting circuit through the first low reflection layer, and obtaining a lamp bead circuit with low reflection rate (namely obtaining a lamp bead circuit with low visibility). Therefore, even if the conductive circuit of the transparent LED display screen is made of conductive materials (such as copper, nickel, iron and the like) which are low in cost and high in light reflection rate, the low visibility of the lamp bead circuit of the LED display screen can be ensured, and the LED display screen which is low in cost and high in transparency can be made. In addition, at least part of the conducting circuits are arranged in a grid shape, so that the coverage area of the conducting circuits is facilitated, and the transparency of the transparent LED display screen can be further improved. Therefore, compared with a common transparent LED display screen, the flexible transparent LED display screen manufacturing process can manufacture the flexible transparent LED display screen with low cost and high transparency.
Drawings
In order to more clearly illustrate the embodiments of the present invention or the technical solutions in the prior art, the drawings used in the description of the embodiments or the prior art will be briefly described below, it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained according to the structures shown in the drawings without creative efforts.
FIG. 1 is a schematic flow chart of an embodiment of a flexible transparent LED display screen manufacturing process according to the present invention;
FIG. 2 is a schematic flow chart of another embodiment of a flexible transparent LED display screen manufacturing process according to the present invention;
FIG. 3 is a schematic flow chart of a manufacturing process of a flexible transparent LED display screen according to another embodiment of the present invention;
FIG. 4 is a schematic flow chart of a manufacturing process of a flexible transparent LED display screen according to still another embodiment of the present invention;
fig. 5 is a schematic flow chart of a manufacturing process of a flexible transparent LED display screen according to still another embodiment of the present invention.
The implementation, functional features and advantages of the objects of the present invention will be further explained with reference to the accompanying drawings.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
It should be noted that, if directional indications (such as up, down, left, right, front, and back … …) are involved in the embodiment of the present invention, the directional indications are only used to explain the relative positional relationship between the components, the movement situation, and the like in a specific posture (as shown in the drawing), and if the specific posture is changed, the directional indications are changed accordingly.
In addition, if there is a description of "first", "second", etc. in an embodiment of the present invention, the description of "first", "second", etc. is for descriptive purposes only and is not to be construed as indicating or implying relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defined as "first" or "second" may explicitly or implicitly include at least one such feature. In addition, the meaning of "and/or" appearing throughout is to include three juxtapositions, exemplified by "A and/or B" including either scheme A, or scheme B, or a scheme in which both A and B are satisfied. In addition, technical solutions between various embodiments may be combined with each other, but must be realized by a person skilled in the art, and when the technical solutions are contradictory or cannot be realized, such a combination should not be considered to exist, and is not within the protection scope of the present invention.
Referring to fig. 1, fig. 1 is a diagram of an embodiment of a manufacturing process of a flexible transparent LED display screen according to the present invention, and specifically, the manufacturing process of the flexible transparent LED display screen includes the following steps:
and S10, arranging conductive circuits on one side or two sides of the flexible transparent substrate, wherein at least part of the conductive circuits are arranged in a grid shape.
The flexible transparent substrate can be glass or a transparent polymer substrate. Specifically, the glass substrate includes, but is not limited to, soda-silica glass, soda-lime-silica glass, potash-silica glass, and alumino-silica glass. The transparent polymer substrate includes, but is not limited to, PET (Polyethylene terephthalate, Chinese name), PMMA (polymethyl methacrylate, Chinese name), transparent PI (polyimide, Chinese name), and PC (Polycarbonate, Chinese name). The substrate is made of a material with flexibility and transparency, so that the transparency of the LED display screen is improved, and free bending of the LED display screen is realized.
The conductive circuit is arranged on one side or two sides of the flexible transparent substrate, and the conductive circuit can be arranged on one side of the flexible transparent substrate and can also be arranged on two sides of the flexible transparent substrate. When the conductive circuit is arranged on only one side of the flexible transparent substrate, only one side of the flexible transparent LED display screen can be used for displaying pictures; when the two sides of the flexible transparent substrate are provided with the conducting circuits, the two sides of the flexible transparent LED display screen can be used for displaying pictures. Specifically, the conductive circuit can be selectively disposed on one side or both sides of the flexible transparent substrate according to the actual requirements of the product.
Specifically, the conducting circuit comprises an electrode wire and a signal wire, wherein the electrode wire is used for supplying power to the LED lamp bead and comprises a positive electrode wire and a negative electrode wire; and the signal wire is used for transmitting control signals between the LED lamp bead and the control chip (module). In this embodiment, anodal electrode line and negative pole electrode line all are latticed setting (that is the electrode line is the net setting), can understand, set up the electrode line into latticed, are favorable to improving the light transmissivity of lamp pearl circuit, and then are favorable to improving the transparency of flexible transparent LED display screen. In addition, the grid-shaped electrode wires are also favorable for improving the heat dissipation capacity of the electrode wires so as to ensure the stability of power supply of the electrode wires.
It should be noted that, when the two sides of the flexible transparent substrate are both provided with the conductive circuits, the projections of the conductive circuits on the two sides of the flexible transparent substrate on the flexible transparent substrate are overlapped. That is, the conductive traces on both sides of the flexible transparent substrate correspond to each other. By the arrangement, light transmission areas (wireless circuit coverage areas) on two sides of the flexible transparent substrate can be kept consistent, so that light can penetrate through the LED display screen, and the transparency of the flexible transparent LED display screen can be effectively improved. And moreover, the design of the conducting circuits with the same two sides is beneficial to reducing the production cost of the flexible transparent LED display screen.
S20, arranging a first low-reflection layer on the conductive circuit, wherein the reflectivity of the first low-reflection layer is less than 35%.
The first low reflection layer is arranged on the conductive circuit and then can be matched with the conductive circuit to form a lamp bead circuit of the LED display screen.
The reflectance is understood to be the reflectance, that is to say the reflectance of the first low-reflection layer is less than 35%. It is worth noting that the visibility of the object is higher when the light reflectance of the surface of the object is higher, whereas the visibility of the object is lower when the light reflectance of the surface of the object is lower. Generally, when the reflectivity is higher than 35%, the object has a certain visibility under light. Then, the first low-reflection layer with the reflectivity lower than 35% is covered on the conducting circuit, so that the reflectivity of the conducting circuit can be reduced through the first low-reflection layer, and further the lamp bead circuit with low reflectivity (namely the lamp bead circuit with low visibility) is obtained. Therefore, even if the conductive material (such as copper, nickel, iron and the like) with low cost and high light reflection rate is adopted to manufacture the conductive circuit of the transparent LED display screen, the low visibility of the lamp bead circuit can be ensured, and further the LED display screen with low cost and high transparency can be manufactured.
Specifically, after the conductive circuit is arranged on the flexible transparent substrate, a first low reflection layer can be further arranged on the conductive circuit to reduce the reflectivity of the lamp bead circuit of the LED display screen.
S30, arranging a pad on the first low reflection layer or the conducting circuit, wherein the pad is located in a lamp bead welding area of the LED display screen.
The lamp bead welding area is an area used for welding the LED lamp beads on a lamp bead circuit of the LED display screen, a plurality of lamp bead welding areas are usually arranged on the lamp bead circuit, and in each lamp bead welding area, a positive electrode wire, a negative electrode wire and each signal wire are respectively provided with a welding disc.
Specifically, if the pad position of the conductive trace is not covered with the first low reflection layer in step S20, the pad may be directly disposed on the conductive trace, and if the pad position of the conductive trace is covered with the first low reflection layer in step S20, the pad may be directly disposed on the first low reflection layer.
Illustratively, the material of the bonding pad is typically tin.
And S40, welding LED lamp beads on the bonding pads.
Specifically, LED lamp pearl has a plurality of fillets, and this fillet and each pad one-to-one in the lamp pearl welding zone, LED lamp pearl pass through the fillet and weld on the pad.
It can be understood that this application technical scheme's manufacturing technology of flexible transparent LED display screen is through setting up first low reflection stratum on the conducting wire way to the reflectivity of controlling first low reflection stratum is less than 35%, and thus the reflectivity of accessible first low reflection stratum reduction conducting wire, and then in order to obtain the lamp pearl circuit of low reflection of light rate (obtain low visual lamp pearl circuit promptly). Therefore, even if the conductive circuit of the transparent LED display screen is made of conductive materials (such as copper, nickel, iron and the like) which are low in cost and high in light reflection rate, the low visibility of the lamp bead circuit of the LED display screen can be ensured, and the LED display screen which is low in cost and high in transparency can be made. In addition, at least part of the conducting circuits are arranged in a grid shape, so that the coverage area of the conducting circuits is facilitated, and the transparency of the transparent LED display screen can be further improved. Therefore, compared with a common transparent LED display screen, the flexible transparent LED display screen manufacturing process can manufacture the flexible transparent LED display screen with low cost and high transparency.
It is worth mentioning that when the conductive material with higher cost, such as silver, Indium Tin Oxide (ITO), etc., is used to manufacture the conductive circuit of the transparent LED display screen, the manufacturing process of the flexible transparent LED display screen can still ensure the high transparency of the flexible transparent LED display screen. In one embodiment, the conductive traces are made of metal or a mixture of metal and a polymer. Specifically, the metal includes pure metals and metal alloys, wherein the pure metals include, but are not limited to, nickel, titanium, chromium, copper, and iron. The alloy can be an alloy of at least two metals of nickel, titanium, chromium, copper and iron. The high molecular substance includes, but is not limited to, non-volatile acrylic resin, non-volatile epoxy-acrylic resin, modified products of any of the three, silicone, and solvent-free thermoplastic resin. Exemplary, solvent-free thermoplastic resins include, but are not limited to, hot melt adhesives, polyphenylene sulfide (PPS), Polysulfones (PSU), Polysulfones (PES), polyether ether ketone (PEEK), aromatic polyester Liquid Crystal Polymers (LCP), Polyetherimides (PEI), Polyamideimides (PAI), Polyacetals (POM), chinlon (nylon) (PA), poly (propylene carbonate) (PC), polybutylene terephthalate (PBT), polyethylene terephthalate (dacron) (PET), polyphenylene oxides (polyoxy-xylene, PPE, PPO), ABS resins (ABS), styrene-acryl-acrylonitrile (ASA), Polystyrene (PS), polymethyl methacrylate (PMMA), styrene copolymers (MS), Cellulose Acetate (CA), Thermoplastic Polyurethane (TPU), thermoplastic polyester elastomers (TPEE), styrenic elastomers (TPS), and the like, Nylon 12 elastomer (PAE), Polytetrafluoroethylene (PTFE), vinylon (vinylon), polypropylene (PP), Polyethylene (PE), ethylene/vinyl acetate copolymer (EVA), polyvinyl chloride (PVC), and the like.
It can be understood that the conductive circuit prepared from metal has the advantage of good conductivity, and the conductive circuit prepared from the mixture of metal and high molecular substances can improve the transparency of the conductive circuit on the basis of ensuring the conductivity of the conductive circuit, and is favorable for improving the adhesion capability of the conductive circuit on the flexible transparent substrate, so that the service life of the LED display screen can be prolonged.
Specifically, the thickness of the conductive circuit is between 0.1um and 300 um. This wherein, if the thickness of conducting wire is too thin, if be less than 0.1um, then the electric conductivity of the lamp pearl circuit that the conducting wire formed, the power supply ability is weak to can influence the display effect of LED display screen, like luminance, homogeneity etc. and if the thickness of conducting wire is too big, if be greater than 300um, then can influence the light transmissivity of conducting wire, and then influence the transparency of LED display screen, and can increase the cost of manufacture of LED display screen. Therefore, the thickness of the conducting circuit is limited to 0.1 um-300 um, and the conductivity, the transparency and the manufacturing cost of the LED display screen of the conducting circuit can be considered at the same time. Illustratively, the thickness of the conductive trace can be 0.1um, 0.2um, 0.3um, 0.4um, 0.5um, 0.6um, 0.7um, 0.8um, 0.9um, 1um, 2um, 3um, 4um, 5um, 6um, 7um, 8um, 9um, 10um, 20um, 30um, 40um, 50um, 60um, 70um, 80um, 90um, 100um, 110um, 120um, 130um, 140um, 150um, 160um, 170um, 180um, 190um, 200um, 210um, 220um, 230um, 240um, 250um, 300um, 400um, 500um, 600um, 700um, 800um, 900um, 1000um, 1500um, 2000um, 2500um, 3000um, etc.
Preferably, the thickness of the conductive circuit is between 0.5um and 50 um. Within the range of 0.5um to 50um, the conductive circuit can be ensured to have good conductivity and transparency, and the manufacturing cost of the LED display screen can be effectively controlled.
As shown in fig. 2, in an embodiment, the method for forming a flexible transparent substrate includes:
and S11, arranging a conductive layer on the flexible transparent substrate.
Specifically, the conductive layer can be plated on the flexible transparent substrate by electroplating, electroless plating or vacuum plating. Wherein the vacuum plating comprises vacuum evaporation and vacuum sputtering.
It can be understood that the conductive layer is plated on the adhesive layer by electroplating, chemical plating or vacuum plating, which not only has low process difficulty and controllable cost, but also is beneficial to improving the bonding tightness of the adhesive layer and the conductive layer and controlling the uniformity and thickness of the conductive layer.
And S12, etching the conductive layer into a conductive circuit according to the preset circuit design.
This wherein, predetermine the circuit design and refer to the conducting circuit structure that designs according to actual product, it includes the length, the width of circuit, the interval of adjacent circuit, the interval, the quantity of lamp pearl soldering zone etc..
Specifically, the specific flow of etching is as follows:
1. covering a yellow light type resist layer on the surface of the conductive layer, wherein the resist layer can be any one of positive photoresist, negative dry film, printing type etching-proof ink or yellow light ink;
2. using a glass photomask or a negative film to perform exposure operation on the yellow light type corrosion-resistant layer, and defining the circuit shape of the corrosion-resistant layer (the shape is consistent with the design of a preset circuit);
3. and removing the redundant conducting layer by using a developing-etching-film removing mode to obtain the required conducting circuit which accords with the design of the preset circuit.
It should be noted that, if the conductive layer is adhered to the flexible transparent substrate through the adhesive layer, after etching, the non-overlapping portion of the adhesive layer and the conductive trace is removed simultaneously.
It can be understood that the conducting layer is etched in advance to prepare the conducting circuit before the first reflecting layer is arranged, so that when the first reflecting layer is coated, the first reflecting layer can be coated on the surface of the conducting circuit, and the first reflecting layer can be coated on the side surface of the conducting circuit (and the bonding layer), so that the reflectivity of the conducting circuit (and the bonding layer) can be reduced in all directions, and the transparency of the LED display screen is improved.
Of course, the design of the present application is not limited thereto, and in other embodiments, the first low reflection layer may be disposed on the conductive layer before the preparation of the conductive line.
In one embodiment, the thickness of the first low reflection layer is between 1nm and 3000 nm. If the thickness of the first low-reflection layer is too thin, if the thickness is less than 1nm, on one hand, the covering effect on the conducting circuit is reduced, the reflectivity of the conducting circuit cannot be effectively reduced, and the light reflection rate of the circuit of the lamp bead is influenced; on the other hand, the manufacturing process of the first low reflection layer is complicated, which is not favorable for controlling the cost. If the thickness of the first low reflection layer is too thick, for example, greater than 3000nm, it is not favorable to control the reflectivity and transmittance of the first low reflection layer, and the transparency of the LED display screen is affected. In addition, the first low reflection layer is too thick, which also results in an increase in the cost of the LED display screen. Therefore, the thickness of the first low reflection layer is limited to 1 nm-3000 nm, and the low reflectivity of the first low reflection layer and the production cost of the LED display screen can be considered at the same time.
Illustratively, the first low reflection layer may have a thickness of 1nm, 10nm, 20nm, 30nm, 40nm, 50nm, 60nm, 70nm, 80nm, 90nm, 100nm, 110nm, 120nm, 130nm, 140nm, 150nm, 160nm, 170nm, 180nm, 190nm, 200nm, 210nm, 220nm, 230nm, 240nm, 250nm, 300nm, 400nm, 500nm, 600nm, 700nm, 800nm, 900nm, 1000nm, 1500nm, 2000nm, 2500nm, 3000nm, and the like.
Preferably, the thickness of the first low reflection layer is 20nm to 250 nm. In the range of 20nm to 250nm, the first low-reflection layer can be ensured to have good low reflectivity, and the production cost of the LED display screen is easy to control.
Specifically, the material of the first low reflection layer includes at least one of metal, alloy, metal compound and metal oxide. Wherein, the metal includes but is not limited to nickel, titanium, chromium, copper, iron. The alloy can be an alloy of at least two metals of nickel, titanium, chromium, copper and iron. The metal compound can be obtained by combining any two metals of nickel, titanium, chromium, copper and iron. The metal oxide can be obtained by reacting any one of nickel, titanium, chromium, copper and iron with an oxide.
In one embodiment, disposing a first low reflection layer on the conductive line includes:
and coating a first low-reflection layer on the conductive circuit by electroplating, chemical plating or vacuum plating.
Among these, vacuum plating includes vacuum evaporation and vacuum sputtering.
It can be understood that the first reflective layer is plated on the conductive circuit by electroplating, chemical plating or vacuum plating, which not only has low process difficulty and controllable cost, but also helps to improve the tightness of the combination of the first low reflective layer and the conductive circuit and helps to control the uniformity and thickness of the first low reflective layer.
In one embodiment, plating a first reflective layer on the conductive traces by electroplating or electroless plating comprises:
and adding an oxidant into the electroplating solution or the chemical plating solution, and oxidizing the metal plating layer deposited on the conductive circuit by the oxidant to obtain the first low-reflection layer.
The oxidizing agent may be added to the plating solution before the start of the electroplating or the electroless plating, or may be added to the plating solution during the electroplating or the electroless plating, or may be added to the plating solution after the completion of the electroplating or the electroless plating. The time for adding the oxidant is not limited, since the oxidant reacts only with the metal plating deposited on the conductive line.
Illustratively, the plating solution may be a copper sulfate plating solution or a nickel sulfate plating solution, and the oxidizing agent may be hydrogen peroxide.
Specifically, when the first low reflection layer is disposed on the conductive circuit by electroplating or chemical plating, hydrogen peroxide may be added to a copper sulfate plating solution or a nickel sulfate plating solution, so that the metal plating layer on the conductive circuit may be oxidized to form dark black copper oxide or nickel oxide, and further, the desired first low reflection layer may be formed on the conductive circuit.
It can be understood that the first low reflection layer with conductivity can be arranged on the conductive circuit in an electroplating or chemical plating mode, so that the conductivity of the lamp bead circuit of the LED display screen can be improved in an auxiliary mode through the first low reflection layer, and the working stability of the LED display screen is improved by the aid of the conductive uniformity, the conductivity and the like. Meanwhile, the conducting circuit also comprises metal-related materials, so that the first low-reflection layer containing metal materials is prepared, and the first low-reflection layer and the conducting circuit are favorably combined to prolong the service life of the LED display screen. In addition, when the first low-reflection layer with conductivity is obtained, the bonding pad can be directly arranged on the first low-reflection layer, so that the bonding pad can be conveniently arranged, and the process difficulty of the LED display screen is reduced.
In one embodiment, the plating of the first reflective layer on the conductive circuit by vacuum plating comprises:
and adding reaction gas into the carrier atmosphere of vacuum sputtering or vacuum evaporation, and oxidizing the plating metal on the conducting wire through the reaction gas to obtain the first low-reflection layer.
The reaction gas is added into the carrier atmosphere of the vacuum sputtering or vacuum evaporation, before the vacuum sputtering or vacuum evaporation is started, or during the electroplating or chemical plating, or after the electroplating or chemical plating is finished. The reaction gas only reacts with the plating metal plated on the conductive circuit, and thus the adding time of the reaction gas is not limited.
Illustratively, the carrier atmosphere is an argon atmosphere, and the reactive gas may be nitrogen and oxygen.
Specifically, when the first low reflection layer is disposed on the conductive line by vacuum sputtering or vacuum evaporation, a reactive gas, such as nitrogen and oxygen, may be additionally added in a carrier atmosphere (original argon atmosphere) of vacuum sputtering or vacuum evaporation, so that the plating metal on the conductive line forms a dark black copper nitride, a dark black copper oxide, a dark black nickel oxide layer, or other oxygen-depleted oxides, so as to obtain the desired first low reflection layer.
It can be understood that the first low reflection layer with conductivity can be arranged on the conductive circuit in a vacuum sputtering or vacuum evaporation mode, so that the conductivity of the lamp bead circuit of the LED display screen can be improved in an auxiliary mode through the first low reflection layer, and the work stability of the LED display screen is improved by the aid of the conductivity uniformity, the conductivity and the like. Meanwhile, the conducting circuit also comprises metal-related materials, so that the first low-reflection layer containing metal materials is prepared, and the first low-reflection layer and the conducting circuit are favorably combined to prolong the service life of the LED display screen. In addition, when the first low-reflection layer with conductivity is obtained, the bonding pad can be directly arranged on the first low-reflection layer, so that the bonding pad can be conveniently arranged, and the process difficulty of the LED display screen is reduced.
As shown in fig. 3, in an embodiment, before disposing the conductive traces on one or both sides of the flexible transparent substrate, the manufacturing process of the flexible transparent LED display further includes:
s110, arranging an adhesive layer on one side or two sides of the flexible transparent substrate, wherein the adhesive force between the adhesive layer and the flexible transparent substrate is more than 0.5kg/cm2And the conductive circuit is arranged on the bonding layer.
Here, the adhesive force refers to the adhesive strength between the adhesive layer and the flexible transparent substrate, and may be understood as the adhesiveness between the adhesive layer and the flexible transparent substrate. In general, the greater the adhesion, the stronger the adhesion between the adhesive layer and the flexible transparent substrate, and the more stable the adhesion between the adhesive layer and the flexible transparent substrate.
Specifically, before the conductive traces are disposed, an adhesive layer may be disposed on the flexible transparent substrate.
It can be understood that, because the flexible transparent substrate is made of glass or organic polymer, and the conductive layer (conductive circuit) is made of metal, the two are not made of the same type of material, and if the conductive layer is directly arranged on the flexible transparent substrate, the bonding stability between the conductive layer and the flexible transparent substrate is not good. Based on this, through set up the adhesive linkage on flexible transparent substrate, accessible bonding's mode bonds flexible transparent substrate and conducting layer, can improve the adnexed steadiness of conducting layer on flexible transparent substrate, and then can improve the adnexed steadiness of conducting wire on flexible transparent substrate. Further, the adhesion force with the flexible transparent substrate by the restriction of the adhesion layer is not less than 0.5kg/cm2The stability of adhesion of the adhesive layer on the flexible transparent substrate can be ensured.
Specifically, the material of the adhesive layer includes at least one of a metal, an alloy, a metal compound, a metal oxide, and a transparent polymer substance. The metal includes, but is not limited to, nickel, titanium, chromium, copper, and iron. The alloy can be an alloy of at least two metals of nickel, titanium, chromium, copper and iron. The metal compound can be obtained by combining any two metals of nickel, titanium, chromium, copper and iron. The metal oxide can be obtained by reacting any one of nickel, titanium, chromium, copper and iron with an oxide. The transparent polymer can be at least one of non-volatile acrylic resin, non-volatile epoxy-acrylic resin, and their modified substances.
In one embodiment, when the material of the adhesion layer includes at least one of a metal, an alloy, a metal compound and a metal oxide, the thickness of the adhesion layer is between 1nm and 3000 nm. Among these, if the thickness of the adhesive layer is too thin, for example, less than 1nm, the adhesive ability of the adhesive layer is reduced, and it is difficult to secure the adhesiveness between the flexible transparent substrate and the conductive layer, and the manufacturing process of the adhesive layer is complicated, which is disadvantageous in cost control. If the thickness of the bonding layer is too thick, for example, greater than 3000nm, the thickness of the LED display screen is increased, which affects the transparency of the LED display screen. And will result in increased cost of the LED display screen. Therefore, the thickness of the bonding layer is limited to 1 nm-3000 nm, and the bonding capability of the bonding layer and the production cost of the LED display screen can be considered at the same time.
Illustratively, the adhesive layer may have a thickness of 1nm, 10nm, 20nm, 30nm, 40nm, 50nm, 60nm, 70nm, 80nm, 90nm, 100nm, 110nm, 120nm, 130nm, 140nm, 150nm, 160nm, 170nm, 180nm, 190nm, 200nm, 210nm, 220nm, 230nm, 240nm, 250nm, 300nm, 400nm, 500nm, 600nm, 700nm, 800nm, 900nm, 1000nm, 1500nm, 2000nm, 2500nm, 3000nm, and the like.
Preferably, the thickness of the bonding layer is 20nm to 250 nm. Within the range of 20nm to 250nm, the good adhesion of the adhesive layer can be ensured, and the production cost of the LED display screen can be effectively controlled.
In one embodiment, the adhesive layer can be plated on the flexible transparent substrate by electroplating, electroless plating or vacuum plating.
It can be understood that the adhesive layer is coated on the flexible transparent substrate in an electroplating, chemical plating or vacuum plating mode, so that the process difficulty is low, the cost is controllable, the bonding tightness of the adhesive layer and the flexible transparent substrate is improved, and the uniformity and the thickness of the adhesive layer are controlled.
In one embodiment, when the material of the adhesive layer is a transparent polymer, the thickness of the adhesive layer is between 1um and 100 um. When the organic layer is formed using a transparent polymer material, a transparent organic coating is formed and then coated on the flexible transparent substrate. Because the coating mode has certain limitation and the light transmittance of the transparent organic polymer material is good, the thickness of the bonding layer manufactured by the coating mode can be between 1um and 100 um. This wherein, if the thickness of adhesive linkage is less than 1um, then be unfavorable for exerting bonding property, and if the thickness of adhesive linkage is greater than non-100 um, then the adhesive linkage is too thick, can influence the thickness and the cost of LED display screen, so prescribe the thickness of adhesive linkage in 1um ~100um and can compromise the adhesive linkage's adhesive linkage and the manufacturing cost of LED display screen simultaneously.
Illustratively, the thickness of the adhesive layer can be 1um, 2um, 3um, 4um, 5um, 6um, 7um, 8um, 9um, 10um, 15um, 20um, 25um, 30um, 40um, 50um, 60um, 70um, 80um, 90um, 100um, etc.
Preferably, the thickness of the adhesive layer is between 5um and 30 um. Within the range of 5um to 30um, the good adhesion of the adhesive layer can be ensured, and the production cost of the LED display screen can be effectively controlled.
As shown in fig. 3, in an embodiment, before disposing the conductive traces on one or both sides of the flexible transparent substrate, the manufacturing process of the flexible transparent LED display further includes:
and S220, if the bonding layer meets a preset coloring condition, arranging a second low-reflection layer on the bonding layer, wherein the reflectivity of the second low-reflection layer is lower than 35%, and the conductive circuit is arranged on the second low-reflection layer.
Specifically, the predetermined coloring condition includes at least one of a thickness, an extinction coefficient, and a refractive index of the adhesive layer. And if the thickness of the bonding layer is larger than the preset thickness, or the extinction coefficient is larger than the preset extinction coefficient, or the refractive index is larger than the preset refractive index, judging that the bonding layer meets the preset coloring condition. Among them, the thickness, extinction coefficient, and refractive index can be used to reflect the reflectivity of the adhesive layer. Illustratively, the predetermined thickness may be 60nm, that is, if the thickness of the adhesive layer is greater than 60nm, it indicates that the adhesive layer satisfies the predetermined coloring condition. It should be noted that the preset thickness, the preset extinction coefficient and the preset refractive index may be adaptively adjusted according to different materials of the actual bonding layer, which is not specifically limited in the present application.
It can be understood that after the adhesive layer meets the preset coloring condition, the second reflecting layer is arranged on the adhesive layer, so that the reflectivity of the adhesive layer can be effectively reduced, and the improvement of the transparency of the LED display screen is facilitated.
It should be noted that the material and the manufacturing method of the second low reflection layer can refer to the first low reflection layer, and are not described herein again.
As shown in fig. 5, in an embodiment, after the LED lamp beads are welded on the bonding pads, the manufacturing process of the flexible transparent LED display screen further includes:
s350, packaging the LED lamp beads by using the surface-drying optical-grade resin with the acid value less than 5 (KOH)/(mg/g) and matching with a curing agent.
Where (in chemistry) the acid number (or neutralization number, acid number, acidity) represents the number of milligrams of potassium hydroxide (KOH) required to neutralize 1 gram of chemical. Acid number is a measure of the number of free carboxylic acid groups in a compound (e.g., fatty acid) or mixture. A typical measurement procedure is to dissolve a known aliquot of the sample in an organic solvent, titrate it with a known concentration of potassium hydroxide solution, and use the phenolphthalein solution as a color indicator. The acid value can be used as an index of the deterioration degree of the grease.
Alternatively, the acid value of the resin may be 4 (KOH)/(mg/g), 3 (KOH)/(mg/g), 2 (KOH)/(mg/g), 1 (KOH)/(mg/g), 0 (KOH)/(mg/g).
Preferably, the LED lamp bead is encapsulated by selecting resin without acid value (namely, the acid value is 0 (KOH)/(mg/g)).
Surface drying, i.e. surface drying. The coating is characterized in that the surface is not completely dried after a certain time passes after the coating is coated on the surface of a substrate in the coating process, and the surface is primarily dried. Based on this, the resin is surface-dryable, that is, the resin has surface-dryability.
Optical grade resin refers to resin that can meet the transparency requirement of an LED display screen, for example, the transparency of the resin is more than 90% after the resin is solidified.
Curing agents, also known as hardeners, curing agents or setting agents, are a class of substances or mixtures that enhance or control the curing reaction.
Specifically, after the LED lamp beads are welded, the LED lamp beads can be packaged by using the surface-drying optical-grade resin with an acid value less than 5 (KOH)/(mg/g) in cooperation with a curing agent, and the packaging manner can be coating, dispensing or bonding after semi-curing a colloid into solid optical glue.
Can understand, to LED lamp pearl encapsulation, can effectively improve LED display screen's weatherability and reliability.
It is worth mentioning that when the LED lamp beads are packaged by using the resin, the resin can only cover the LED lamp beads comprehensively, and can also only cover the welding leg parts of the LED lamp beads.
While preferred embodiments of the present invention have been described, additional variations and modifications in those embodiments may occur to those skilled in the art once they learn of the basic inventive concepts. Therefore, it is intended that the appended claims be interpreted as including preferred embodiments and all such alterations and modifications as fall within the scope of the invention.
It will be apparent to those skilled in the art that various changes and modifications may be made in the invention without departing from the invention
With clear spirit and scope. Thus, if such modifications and variations of the present invention fall within the scope of the claims of the present invention and their equivalents, the present invention is also intended to include such modifications and variations.
Claims (10)
1. A manufacturing process of a flexible transparent LED display screen is characterized by comprising the following steps:
arranging conductive circuits on one side or two sides of the flexible transparent substrate, wherein at least part of the conductive circuits are arranged in a grid shape;
disposing a first low reflection layer on the conductive line, the first low reflection layer having a reflectivity of less than 35%;
arranging a bonding pad on the first low-reflection layer or the conducting circuit, wherein the bonding pad is positioned in a lamp bead welding area of the LED display screen;
and welding LED lamp beads on the welding pads.
2. The process for manufacturing a flexible transparent LED display screen according to claim 1, wherein the disposing of the first low reflection layer on the conductive line comprises:
and coating a first low-reflection layer on the conductive circuit by electroplating, chemical plating or vacuum plating.
3. The process for manufacturing the flexible transparent LED display screen according to claim 2, wherein the first reflective layer is plated on the conductive circuit by electroplating or chemical plating, and the process comprises the following steps:
and adding an oxidant into the electroplating solution or the chemical plating solution, and oxidizing the metal plating layer deposited on the conductive circuit by the oxidant to obtain the first low-reflection layer.
4. The process for manufacturing the flexible transparent LED display screen according to claim 2, wherein the vacuum plating comprises vacuum sputtering and vacuum evaporation;
plating a first reflective layer on the conductive circuit in a vacuum plating manner, comprising:
and adding reaction gas into the carrier atmosphere of vacuum sputtering or vacuum evaporation, and oxidizing the plating metal on the conducting wire through the reaction gas to obtain the first low-reflection layer.
5. The manufacturing process of the flexible transparent LED display screen according to claim 1, wherein before the conductive traces are disposed on one or both sides of the flexible transparent substrate, the manufacturing process of the flexible transparent LED display screen further comprises:
arranging an adhesive layer on one side or two sides of the flexible transparent substrate, wherein the adhesive layer is connected with the flexible transparent substrateThe bonding force of the flexible transparent substrate is more than 0.5kg/cm2And the conductive circuit is arranged on the bonding layer.
6. The manufacturing process of the flexible transparent LED display screen according to claim 5, wherein before the conductive traces are disposed on one or both sides of the flexible transparent substrate, the manufacturing process of the flexible transparent LED display screen further comprises:
and if the bonding layer meets the preset coloring condition, arranging a second low-reflection layer on the bonding layer, wherein the reflectivity of the second low-reflection layer is lower than 35%, and the conductive circuit is arranged on the second low-reflection layer.
7. The manufacturing process of the flexible transparent LED display screen according to claim 5, wherein whether the bonding layer meets a preset coloring condition is determined according to at least one of the thickness, the extinction coefficient and the refractive index of the bonding layer.
8. The manufacturing process of the flexible transparent LED display screen according to claim 5, wherein the conductive circuit is arranged on one side or two sides of the flexible transparent substrate, and the manufacturing process comprises the following steps:
arranging a conductive layer on the bonding layer;
and etching the conductive layer into a conductive circuit according with a preset circuit design.
9. The manufacturing process of the flexible transparent LED display screen according to claim 8,
plating a film adhesive layer on the flexible transparent substrate in an electroplating, chemical plating or vacuum plating mode; and/or the presence of a gas in the gas,
and plating a conductive layer on the bonding layer by electroplating, chemical plating or vacuum plating.
10. The manufacturing process of the flexible transparent LED display screen of claim 1, wherein after the LED lamp beads are welded on the bonding pads, the manufacturing process of the flexible transparent LED display screen further comprises the following steps:
the LED lamp bead is packaged by matching a surface-drying optical-grade resin with an acid value of less than 5 (KOH)/(mg/g) with a curing agent.
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| CN202697035U (en) * | 2012-08-01 | 2013-01-23 | 田茂福 | LED circuit board with conducting adhesive lines, and LED lamp band |
| CN203276222U (en) * | 2013-05-15 | 2013-11-06 | 南昌欧菲光科技有限公司 | Novel double-side flexible ITO conducting film structure |
| CN105453162A (en) * | 2013-08-09 | 2016-03-30 | 索尼公司 | Display device and electronic apparatus |
| CN105316736A (en) * | 2014-08-05 | 2016-02-10 | 上海蓝沛信泰光电科技有限公司 | Preparation method for low-reflectivity transparent conducting circuits |
| CN208819542U (en) * | 2018-08-30 | 2019-05-03 | 厦门福相传媒有限公司 | A kind of transparent display screen |
| CN110796956A (en) * | 2019-11-15 | 2020-02-14 | 大连集思特科技有限公司 | Flexible transparent display screen and manufacturing method thereof |
| CN111653556A (en) * | 2020-07-09 | 2020-09-11 | 蚌埠明微光电玻璃科技有限公司 | Transparent luminous component for visible colored line |
| CN212342654U (en) * | 2020-07-24 | 2021-01-12 | 东莞市中晶半导体科技有限公司 | LED chip, display screen module and display screen |
| CN111901968A (en) * | 2020-07-29 | 2020-11-06 | 厦门爱谱生电子科技有限公司 | Micro LED flexible circuit board manufacturing method |
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