CN112759181B - Novel black and odorous river water endogenous treatment method - Google Patents
Novel black and odorous river water endogenous treatment method Download PDFInfo
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Abstract
Description
技术领域technical field
本发明涉及污水处理领域技术,尤其是指一种新型的黑臭河水内源治理方法。The invention relates to the technology in the field of sewage treatment, in particular to a novel method for treating the internal source of black and odorous river water.
背景技术Background technique
随着我国社会经济的快速发展和城镇化进程的加速,城镇规模和人口不断增加,人类生产和生活污水排放量日益增大,进入水体的污染物浓度超过水体自净能力。好氧微生物通过新陈代谢作用消耗水体中氧气,使水体处于缺氧或厌氧状态,此时大量繁殖的厌氧微生物与有机物发生腐败、分解和发酵等反应,产生有机硫化物、氨氮和甲烷等14000多种致臭气体;同时水体中铁、锰等重金属被还原,与硫离子结合形成FeS、MnS等黑色沉淀使水体变黑。另外,城市水体流动性差,水动力不足,导致水环境恶化,污染物积累,水体黑臭状况加重。黑臭河水的存在不仅给人们带来了恶劣的感官刺激,也直接对人们的饮水、用水安全构成了严重的威胁。With the rapid development of my country's social economy and the acceleration of urbanization, the scale and population of cities and towns continue to increase, the discharge of human production and domestic sewage is increasing, and the concentration of pollutants entering the water body exceeds the self-purification capacity of the water body. Aerobic microorganisms consume oxygen in the water body through metabolism, making the water body in anoxic or anaerobic state. At this time, the mass-proliferated anaerobic microorganisms react with organic matter such as corruption, decomposition and fermentation, and produce organic sulfides, ammonia nitrogen and methane, etc. 14000 A variety of odor-causing gases; at the same time, heavy metals such as iron and manganese in the water body are reduced, and combine with sulfur ions to form black precipitates such as FeS and MnS, making the water body black. In addition, urban water bodies have poor fluidity and insufficient hydropower, leading to deterioration of the water environment, accumulation of pollutants, and aggravation of black and odorous water bodies. The existence of black and smelly river water not only brings bad sensory stimulation to people, but also directly poses a serious threat to people's drinking water and water safety.
目前,治理城市黑臭河水主要包括物理治理技术、化学治理技术以及生物生态治理技术。黑臭河水治理虽然广泛运用3种治理技术,但各自都有不同的优缺点,单独运用某种技术可能不会保证其长久有效性。因此,多种技术联合运用于黑臭河水的治理取得了较好的效果。其中,黑臭河水内源治理是基础措施。At present, the treatment of urban black and odorous river water mainly includes physical treatment technology, chemical treatment technology and biological ecological treatment technology. Although three treatment technologies are widely used in the treatment of black and odorous river water, each of them has different advantages and disadvantages, and the use of a certain technology alone may not guarantee its long-term effectiveness. Therefore, the joint application of various technologies in the treatment of black and odorous river water has achieved good results. Among them, the internal source control of black and odorous river water is the basic measure.
因此,亟需一种新型的黑臭河水内源治理方法,针对低水位、河道小且窄的污水河进行处理。Therefore, there is an urgent need for a new type of internal source treatment method for black and odorous river water, which is aimed at treating sewage rivers with low water levels and small and narrow channels.
发明内容Contents of the invention
有鉴于此,本发明针对现有技术存在之缺失,其主要目的是提供一种新型的黑臭河水内源治理方法,从水底、水体、水面三个方式处理河湖污染物,达到河湖水质修复的效果。In view of this, the present invention aims at the deficiencies in the prior art, and its main purpose is to provide a new type of black and odorous river water internal source treatment method, which can deal with river and lake pollutants from the bottom, water body and water surface, so as to achieve the quality of river and lake water. The effect of repair.
为实现上述目的,本发明采用如下之技术方案:To achieve the above object, the present invention adopts the following technical solutions:
一种新型的黑臭河水内源治理方法,包括A new type of black and odorous river water endogenous treatment method, including
水体底泥污染清除:Water body sediment pollution removal:
将底泥洗脱船驾驶进入污水河或湖,洗脱底泥中轻质、有机的胶体污染物;底泥洗脱办法是在底泥洗脱船配置罩式洗脱仓,该罩式洗脱仓是四周和顶部封闭只有底部开口,用该罩式洗脱仓深入到水底且罩住泥沙,将水底局部需要处理底泥的位置隔离,以原位覆盖深层淤泥的方式阻止污染物释放,然后在罩式洗脱仓内部采用高压水柱将污水、泥沙、底泥搅拌混合,再通过控制搅拌速度使质量较轻呈胶状的浮泥悬浮到水体中再沉降形成一层有机浮泥,而重质的泥沙无机物沉降,再通过抽吸的方式将罩式洗脱仓内的有机浮泥泵出水面以外进行泥水分离,清水回至河或湖中,接着底泥洗脱船移动带动罩式洗脱仓进行下一位置的水底底泥处理,如此重复不断;Drive the sediment elution ship into the sewage river or lake to elute the light, organic colloidal pollutants in the sediment; The elution tank is closed around the top and only has an opening at the bottom. Use the hood-type elution tank to go deep into the bottom of the water and cover the sediment, isolate the part of the bottom that needs to treat the sediment, and prevent the release of pollutants by covering the deep silt in situ , and then use high-pressure water column inside the hood-type elution chamber to stir and mix the sewage, sediment, and sediment, and then control the stirring speed to suspend the light gelatinous floating mud into the water body and then settle to form a layer of organic floating mud , while the heavy sediment and inorganic matter settle, and then the organic floating mud in the hood-type elution chamber is pumped out of the water surface by suction to separate the mud and water, and the clean water is returned to the river or lake, and then the sediment is washed by the boat Move and drive the hood-type elution chamber to process the underwater sediment at the next position, and repeat it continuously;
水体水质提升:Improvement of water quality:
先通过微纳米气泡增氧,通过投加EM菌、微藻和水下森林措施,构建水体生态系统,维持水质的长效达标;微纳米气泡增氧的方式是基于微纳米曝气装置,通过气泵加压,对曝气头内部的曝气石高速旋转,在离心作用下,使曝气头内部形成负压区,空气通过进气口进入负压区,在曝气头内部分成周边液体带和中心气体带,由高速旋转的曝气石出气部将空气均匀切割成直径为5-30纳米的微纳米的微小气泡,微小气泡提高污水溶氧效率,同时具有良好的气浮性,可以在污水中长时间停留,从而能达到较好的曝气效果,EM菌和微藻的投放方式是,先采用EM菌进行污水的生物修复和植物修复,再投入微藻,与EM菌形成共生生物相结合处理;水下森林是采用可降解材料的网格状水底植物种植基铺设于河或湖底,并用固定件将种植基固定,水底植物自由生长形成水下森林;First increase oxygen through micro-nano bubbles, and then add EM bacteria, microalgae and underwater forest measures to build a water ecosystem and maintain long-term water quality compliance; the way of increasing oxygen by micro-nano bubbles is based on micro-nano aeration devices, The air pump pressurizes and rotates the aeration stone inside the aeration head at a high speed. Under centrifugal action, a negative pressure zone is formed inside the aerator head. And the central gas belt, the air is uniformly cut into micro-nano micro-bubbles with a diameter of 5-30 nanometers by the high-speed rotating aeration stone gas outlet, the micro-bubbles improve the efficiency of sewage oxygen dissolution, and have good air flotation properties Stay in the sewage for a long time, so as to achieve a better aeration effect. The delivery method of EM bacteria and microalgae is to first use EM bacteria for bioremediation and phytoremediation of sewage, and then put in microalgae to form symbiotic organisms with EM bacteria Combined treatment; the underwater forest is a grid-like underwater plant planting base of degradable materials laid on the bottom of the river or lake, and the planting base is fixed with fixing parts, and the underwater plants grow freely to form an underwater forest;
水体表面悬浮物清理:Cleaning of suspended solids on the surface of water bodies:
对水体表面悬浮物、藻类、油污,通过投加浮上型混凝剂将污染物浮上水面,再通过水面捞渣机将表面污染物收集抽送到微纳米气泡气浮设备进行处理,清水返回水体,污染物转移处置;所述浮上型混凝剂的成份是壳聚糖、聚合硫酸铁、高锰酸盐和磺化木质素盐。For suspended matter, algae, and oil on the surface of the water body, the pollutants are floated to the water surface by adding a floating coagulant, and then the surface pollutants are collected and pumped to the micro-nano bubble air flotation equipment for treatment through the surface slag removal machine, and the clear water is returned to the water body. Pollutant transfer and disposal; the components of the floating coagulant are chitosan, polyferric sulfate, permanganate and sulfonated lignin salt.
本发明与现有技术相比具有明显的优点和有益效果,具体而言,由上述技术方案可知,针对河湖水体的内湖污染,分别从水体表面、水底淤泥和水体本身三个层面进行处理。对水体表面悬浮物、藻类、油污等,通过投加浮上型混凝剂将污染物浮上水面,再通过水面捞渣机将表面污染物收集抽送到微纳米气泡气浮设备进行处理,清水返回水体,污染物转移处置。对于水底淤泥,通过底泥洗脱技术进行处理,洗脱底泥中轻质、有机的胶体污染物,消除底泥污染物对水体水质的影响。对于水体,通过投加EM菌和水下森林措施,构建水体生态系统,维持水质的长效达标。Compared with the prior art, the present invention has obvious advantages and beneficial effects. Specifically, it can be seen from the above-mentioned technical scheme that for the inner lake pollution of river and lake water bodies, the water body surface, the bottom silt and the water body itself are respectively treated from three levels. . For suspended solids, algae, oil, etc. on the surface of the water body, the pollutants are floated to the water surface by adding a floating coagulant, and then the surface pollutants are collected and pumped to the micro-nano bubble air flotation equipment for treatment through the surface slag removal machine, and the clear water is returned to the water body , Pollutant transfer and disposal. For underwater sludge, it is treated by sediment elution technology to elute light and organic colloidal pollutants in the sediment and eliminate the impact of sediment pollutants on water quality. For water bodies, by adding EM bacteria and underwater forest measures, the water body ecosystem can be constructed to maintain long-term water quality standards.
尤其是,采用罩式洗脱仓对水体进行局部隔离,以原位处理的方式,不需要将河水排空再用挖掘机挖泥、也不需要采用围坝等将河水拦截,而是直接在活动的水体中进行污水处理,简单方便,省成本。再有,本发明的罩式洗脱仓是四周和顶部封闭只有底部开口,用该罩式洗脱仓深入到水底且罩住泥沙,将水底局部需要处理底泥的位置隔离,以原位覆盖深层淤泥的方式阻止污染物释放,使得污泥处理时不会因为自身内部水体挠动造成泥沙外溢,仅在罩式洗脱仓内进行,因此整个污泥处理过程本身是环保的。采用罩式洗脱仓将水体隔离之后,再于内部采用高压水柱将污水、泥沙、底泥搅拌混合,使质量较轻呈胶状的浮泥悬浮到水体中再沉降形成一层有机浮泥,而重质的泥沙无机物沉降,再通过抽吸的方式将罩式洗脱仓内的有机浮泥泵出水面以外进行泥水分离,清水回至河或湖中,这样的方式对河道内原有水体不会造成二次污染,整个处理方式简单且快速。In particular, the hood-type elution tank is used to partially isolate the water body, and the in-situ treatment method does not need to drain the river water and then use an excavator to dredge it, and does not need to use dams to intercept the river water, but directly in the Sewage treatment in active water bodies is simple, convenient and cost-effective. In addition, the hood-type elution chamber of the present invention is closed around the top and only has an opening at the bottom, and the hood-type elution chamber is used to go deep into the bottom of the water and cover the sediment, so as to isolate the parts of the bottom of the water that need to process the bottom mud, and in situ The method of covering the deep layer of sludge prevents the release of pollutants, so that the sludge will not overflow due to the movement of the internal water body during sludge treatment. It is only carried out in the hood-type elution chamber, so the entire sludge treatment process itself is environmentally friendly. After the water body is isolated by a hood-type elution chamber, the sewage, sediment, and sediment are stirred and mixed with a high-pressure water column inside, so that the lighter, colloidal floating mud is suspended in the water body and then settles to form a layer of organic floating mud. , while the heavy sediment and inorganic matter settle, and then the organic floating mud in the hood-type elution chamber is pumped out of the water surface by suction to separate the mud and water, and the clean water is returned to the river or lake. This method is harmful to the original The presence of water will not cause secondary pollution, and the entire treatment method is simple and fast.
为更清楚地阐述本发明的结构特征和功效,下面结合附图与具体实施例来对本发明进行详细说明。In order to more clearly illustrate the structural features and functions of the present invention, the present invention will be described in detail below in conjunction with the accompanying drawings and specific embodiments.
附图说明Description of drawings
图1是本发明之一种实施例的黑臭河水内源治理方法示意图。Fig. 1 is a schematic diagram of a black-smelly river water endogenous treatment method according to an embodiment of the present invention.
图2是本发明之第一种实施例的一体式底泥洗脱船示意图。Fig. 2 is a schematic diagram of an integrated sediment washing vessel according to the first embodiment of the present invention.
图3是本发明之第二种实施例的黑臭河水底泥处理流程图。Fig. 3 is the processing flowchart of the black and smelly river bottom mud of the second kind of embodiment of the present invention.
图4是本发明之第三种实施例的黑臭河水底泥处理示意图。Fig. 4 is the schematic diagram of the treatment of black and odorous river bottom mud of the third embodiment of the present invention.
图5是本发明之第三种实施例的中简易污泥处理设备的示意图。Fig. 5 is a schematic diagram of the simple sludge treatment equipment in the third embodiment of the present invention.
图6是本发明之底泥洗脱前后对比效果图。Fig. 6 is a comparative effect diagram before and after the sediment elution of the present invention.
图7是本发明之底泥洗脱前后柱状样图。Fig. 7 is a columnar sample diagram before and after elution of bottom mud of the present invention.
附图标记reference sign
10、底泥洗脱船 11、高压水泵10.
12、有机浮泥泵 13、加药泵12.
14、省力滑轮 20、罩式洗脱仓14. Labor-saving
21、金属罩体 22、高压水柱喷射头21.
23、污泥抽吸头 24、喷药嘴23.
25、微孔 30、微纳米曝气装置25.
40、水面捞渣机 50、一体化气浮设备40. Slag removal machine on
60、简易污泥处理设备 101、有机浮泥60. Simple
102、泥沙无机物。102. Inorganic sediment.
具体实施方式Detailed ways
请参照图1所示,其显示出了本发明的技术方案,是一种新型的黑臭河水内源治理方法,包括水体底泥污染清除、水体水质提升、水体表面悬浮物清理。Please refer to Fig. 1, which shows the technical solution of the present invention, which is a novel method for controlling the internal source of black and odorous river water, including the removal of sediment pollution in water bodies, the improvement of water quality in water bodies, and the cleaning of suspended solids on the surface of water bodies.
其中,水体底泥污染清除:是指将底泥洗脱船10驾驶进入污水河或湖,洗脱底泥中轻质、有机的胶体污染物。底泥洗脱办法是在底泥洗脱船配置罩式洗脱仓20,该罩式洗脱仓是四周和顶部封闭只有底部开口,用该罩式洗脱仓深入到水底且罩住泥沙,将水底局部需要处理底泥的位置隔离,以原位覆盖深层淤泥的方式阻止污染物释放,然后在罩式洗脱仓内部采用高压水柱、气流或机械挠动将污水、泥沙、底泥搅拌混合,再通过控制搅拌速度使质量较轻呈胶状的浮泥悬浮到水体中再沉降形成一层有机浮泥101,而重质的泥沙无机102物沉降,再通过抽吸的方式将罩式洗脱仓内的有机浮泥泵出水面以外进行泥水分离,清水回至河或湖中,接着底泥洗脱船移动带动罩式洗脱仓进行下一位置的水底底泥处理,如此重复不断,将水底下20-40mm厚的污泥去除。Wherein, water body sediment pollution removal: refers to driving the
水体水质提升:是指先通过微纳米气泡增氧,通过投加EM菌、微藻和水下森林措施,构建水体生态系统,维持水质的长效达标。微纳米气泡增氧的方式是基于微纳米曝气装置30,通过气泵加压,对曝气头内部的曝气石高速旋转,在离心作用下,使曝气头内部形成负压区,空气通过进气口进入负压区,在曝气头内部分成周边液体带和中心气体带,由高速旋转的曝气石出气部将空气均匀切割成直径为5-30纳米的微纳米的微小气泡,微小气泡提高污水溶氧效率,同时具有良好的气浮性,可以在污水中长时间停留,从而能达到较好的曝气效果,EM菌和微藻的投放方式是,先采用EM菌进行污水的生物修复和植物修复,再投入微藻,与EM菌形成共生生物相结合处理;水下森林是采用可降解材料的网格状水底植物种植基铺设于河或湖底,并用固定件将种植基固定,水底植物自由生长形成水下森林。Improvement of water quality: It refers to increasing oxygen through micro-nano bubbles, and then adding EM bacteria, microalgae and underwater forest measures to build a water ecosystem and maintain long-term water quality compliance. The micro-nano bubble oxygenation method is based on the
水体表面悬浮物清理:是指对水体表面悬浮物、藻类、油污,通过投加浮上型混凝剂将污染物浮上水面,再通过水面捞渣机40将表面污染物收集抽送到微纳米气泡气浮设备进行处理,清水返回水体,污染物转移处置;所述浮上型混凝剂的成份是壳聚糖、聚合硫酸铁、高锰酸盐和磺化木质素盐。Cleaning of suspended solids on the surface of the water body: refers to the suspension of suspended solids, algae, and oil on the surface of the water body. The pollutants are floated to the water surface by adding a floating coagulant, and then the surface pollutants are collected and pumped to the micro-nano bubble gas by the water surface
实施例1Example 1
如图2所示,对于一些水深的河流或湖,可以采用一种污泥处理一体的底泥洗脱船10,也就是将一体化汽浮设备50设于底泥洗脱船10,污泥收集池51、微纳米气泡分离装置52、贮泥池53、污泥压滤机54等均搭建于船上,这样从罩式洗脱仓20内抽出的污泥即可直接在底泥洗脱船上进行处理,最后得到脱水后的泥饼,再外运。污泥处理过程是先用罩式洗脱仓20吸取有机浮泥101,有机浮泥101通过有机浮泥泵12泵入污泥收集池51,利用微纳米气泡分离装置52实现有机浮泥的进一步分离变为上浮和下沉两种物质,用刮泥装置205将上浮物刮到贮泥池53,贮泥池53用污泥泵抽到污泥压滤机54,以及也用污泥泵将下沉物泵到污泥压滤机54,污泥压滤机54脱水后形成泥饼。这些搭建于船上的设备均会增加船的吃水深度,因此仅适合于深水区的河道。As shown in Figure 2, for rivers or lakes with some water depths, a
实施例2Example 2
对于河床较浅的河或湖,则需要采用以下方案:参见图3,尽可能地使用轻质的小船,将底泥洗脱船10上重的装置去除,使得小船吃水较浅才可进入浅水河或湖。而用于处理污泥的污泥收集池51、微纳米气泡分离装置52、贮泥池53形成一体设备(参见图3)均搭建在河堤上,污泥压滤机54可以为车载式。有机浮泥101抽到河堤上的一体设备,再逐步处理污泥,污泥处理方式参见实施例1。For rivers or lakes with shallower riverbeds, the following schemes need to be adopted: referring to Fig. 3, use light boats as much as possible, and remove the heavy device on the bottom
实施例3Example 3
对于一些污水河,其河道小且窄、河堤无法提供足够空间建设大型污泥处理设备的情况,采用图4的方式解决。采用轻质的泥洗脱船10,同样的尽可以减轻船身的重量。因此设置了两个吊塔14、15,一个用于吊挂罩式洗脱仓20,另一个用于吊挂简易污泥处理设备60,利用简易污泥处理设备60可以对所收集的有机污泥进行短暂的存储,储满之后再运到岸边的一体化气浮设备50进一步处理。For some sewage rivers, the river channel is small and narrow, and the embankment cannot provide enough space for the construction of large-scale sludge treatment equipment, use the method shown in Figure 4 to solve the problem. Adopt lightweight mud to wash out
具体方案如下:先介绍罩式洗脱仓的结构,所述罩式洗脱仓20是金属罩体21,自带重量可以沉到水下,用省力轮支架采用吊挂的方式安装于底泥洗脱船,例如使用省力滑轮14。以及,所述罩式洗脱仓的长宽高尺寸为1-5m、1-5m、0.5-1m为宜,当处理污水河面较窄时可选择尺寸较小的罩式洗脱仓,反之取用尺寸较大的。工作时,该罩式洗脱仓至少有0.2m是扎入到水底的泥沙层,形成原位覆盖深层淤泥,阻止污染物释放。正是由于罩式洗脱仓封闭的结构,使得搅动底泥时浑浊的污泥水仅会在仓内进行,不会将污染物扩散到外部。The specific scheme is as follows: first introduce the structure of the hood-type elution chamber. The hood-
除此之外,所述罩式洗脱仓20内置高压水柱喷射头22、污泥抽吸头23、喷药嘴24。该高压水柱喷射头22通过软管连接高压水泵11,该高压水泵11置于底泥洗脱船10的船仓中,高压水泵11的一头通过管道泵入河水,通过高压水泵增压形成高压水经由另一头的软管通向高压水柱喷射22,向罩式洗脱仓射出高压水柱,使罩式洗脱仓内的水体翻滚搅拌形成泥沙混合。所述污泥抽吸头23通过软管连接有机浮泥泵12,该有机浮泥泵12是置于底泥洗脱船10的船仓中,有机浮泥泵12的一头连接到简易污泥处理设备60,简易污泥处理设备60再连接到河岸上的一体化气浮设备或移动式污泥车;该喷药嘴24通过软管连接加药泵13,该加药泵13是置于底泥洗脱船10的船仓中,加药泵的一头连接药罐,由加药泵将加快污泥沉淀的药剂经喷药嘴投向罩式洗脱仓。In addition, the hood-
高压水柱喷射头22用于将高压水柱射向泥底,使水底的有机物和无机物全部搅动混合,随着高压水柱停止,质量较重的砂子会下沉,而质量较轻、呈胶体状的浮泥则位于砂子之上,待沉降一段时间之后,用污泥抽吸头将仓内20-40mm厚度的污泥去除,这样可以保证抽出的是污泥而不是砂子。并且,还通过加药的方式加快污泥的沉淀,便污泥处理更有效率。The high-pressure
本实施例中,所述药罐中存储聚丙烯酰胺助凝剂,聚丙烯酰胺助凝剂作为一种常用的絮凝剂,其使用效果是理想的。目前,这种絮凝剂一般应用于沉淀池中作为助剂使用,沉淀池是静态的,也是常见的。但无案例给出其直接应用于水流不停的动态河道中作为一种可配合罩式洗脱仓进行使用的絮凝剂。In this embodiment, the polyacrylamide coagulant is stored in the medicine tank, and the polyacrylamide coagulant is a commonly used flocculant, and its use effect is ideal. At present, this flocculant is generally used as an auxiliary agent in sedimentation tanks, which are static and common. However, there is no case where it is directly applied to a dynamic channel with constant water flow as a flocculant that can be used in conjunction with a hood-type elution chamber.
除此之外,当处理一些小型的污水河,选用的罩式洗脱仓的尺寸较小较轻时,配设高压水枪冲刷底泥时,可能造成罩式洗脱仓振动,甚至翻转。因此还在罩式洗脱仓的顶部设有若干可供空气或水体排出的微孔,以保证仓内气压、水压和外界相对平衡,防止翻仓的状况。In addition, when dealing with some small sewage rivers, when the size of the hood-type elution chamber selected is small and light, when a high-pressure water gun is equipped to flush the sediment, the hood-type elution chamber may vibrate or even overturn. Therefore, a number of micropores are provided on the top of the hood-type elution chamber for the discharge of air or water, so as to ensure the relative balance between the air pressure and water pressure in the chamber and the outside world, and prevent the chamber from turning over.
在本实施例3中,简易污泥处理设备60并不是在船上,也不是在岸上,而是被底泥洗脱船10拖动随着该底泥洗脱船10一起同步地在河道中行走。简易污泥处理设备60不同于上述的一体化汽浮设备50,其作为进入一体化气浮设备50之前的一个衔接装置,主要功能是用于对污泥进行初步处理,并具有一定的污泥脱水和水体净化功能,从而给一些窄而小的臭水沟处理污泥带来方便。In this third embodiment, the simple
具体而言,如图5所示,该简易污泥处理设备60含有一个污泥收集器61,该污泥收集器61的外周设置螺旋式渗液管63,这些螺旋式渗液管63的进液口631位于污泥收集器61的下部且与污泥收集器61连通,出液口632位于污泥收集器61的上部且与污泥收集器61连通,但是出液口632不会高出污泥收集器61的最低液位。这样靠重力自流,污泥中的排水通过进液口631在螺旋式渗液管63经过,最后会从出液口632流出。尤其是,本发明还在螺旋式渗液管63上设置了一级或多级横管反应器64,横管反应器64与螺旋渗液管63之间采用弯头法兰641连接,实现各横管反应器的可拆卸更换。横管反应器64为管状的电极,能够使污泥破壁,即使污水重新回流至河道,污水的有害生物体已经被破坏,不会再产生臭味,从而达到过滤污水除臭和净化目的。Specifically, as shown in Figure 5, this simple
以及,为了防止螺旋式渗液管63被堵塞,在进液口631的位置安装单向盖板及格栅网,防止螺旋式渗液管63中的污水倒流,并且防止进液口631堵塞。这样便可以通过螺旋式渗液管63将有机浮泥101中的水分尽可以脱出回流到污水河中,以减轻重量,使泥浆更为密实,从而一次性能装载更多的泥浆。And, in order to prevent the
采用上述实施例1、2、3的方法对底泥采集对比,通过以上步骤洗脱前、洗脱后的情况可参考图6、图7。如图6的左图所示,洗脱前的底泥为黑色,含有丰富的富营养物质,这也是导致河水发黑发臭的重要原因。图6的右图是洗脱后的底泥,为灰色,富营养物被大量清除。如图7所示,图7左侧为洗脱前柱状样,右侧为洗脱后柱状样,明显将水底产生黑臭味的污杂层用洗脱层隔离,效果理想的状态下还可以将污染层全部去除。The methods of the above-mentioned Examples 1, 2, and 3 were used to collect and compare the bottom mud. The situation before and after the elution through the above steps can refer to Fig. 6 and Fig. 7 . As shown in the left picture of Figure 6, the bottom mud before elution is black and contains rich nutrient-rich substances, which is also an important reason for the black and smelly river water. The right picture of Figure 6 is the eluted bottom mud, which is gray, and a large amount of nutrient-rich substances have been removed. As shown in Figure 7, the left side of Figure 7 is the columnar sample before elution, and the right side is the columnar sample after elution. It is obvious that the dirty layer that produces black odor at the bottom of the water is isolated with the elution layer, and it can be used under ideal conditions. Remove all contamination layers.
经过以上底泥处理后,可使泥-水界限清晰,即使进行再次挠动也很快澄清,迅速消除底泥厌氧上泛和水体黑臭。洗脱后污染物和藻细胞量显著减少,采用以下表格进行效果对比。After the above sediment treatment, the mud-water boundary can be made clear, even if it is shaken again, it will be clarified quickly, and the anaerobic upwashing of the sediment and the black odor of the water body can be quickly eliminated. After elution, the amount of pollutants and algae cells is significantly reduced, and the following table is used for comparison.
关于水体水质提升:上述提升方法提到微纳米气泡增氧,以及采用EM菌培养和水下森林建设。本实施例中,是先采用微纳米气泡增氧的方式,与此同时进行浮上型混凝剂的投放。通过微纳米曝气装置的改造,利用负压区的形成原理,在曝气同时投放浮上型混凝剂。由于上述提到,曝气时会将水下分成周边液体带和中心气体带,当微纳米小气泡在水底散发时,同时带动浮上型混凝剂一起进入水中,这样可以免去搅拌的操作。Regarding the improvement of water quality: the above-mentioned improvement method refers to the oxygenation of micro-nano bubbles, as well as the use of EM bacteria culture and underwater forest construction. In this embodiment, the method of increasing oxygen by micro-nano bubbles is firstly used, and at the same time, the floating-type coagulant is added. Through the transformation of the micro-nano aeration device, using the formation principle of the negative pressure zone, the floating coagulant is put in at the same time as the aeration. As mentioned above, during aeration, the underwater will be divided into a peripheral liquid zone and a central gas zone. When the micro-nano bubbles are dispersed at the bottom of the water, they will drive the floating coagulant into the water together, which can avoid the operation of stirring.
本实施例中,浮上型混凝剂按质量份计,含有壳聚糖20-30份,聚合硫酸铁20-35,高锰酸盐20-30份,磺化木质素盐30-40份。其中,In this embodiment, the floating coagulant contains 20-30 parts by mass of chitosan, 20-35 parts of polyferric sulfate, 20-30 parts of permanganate, and 30-40 parts of sulfonated lignin salt. in,
聚合硫酸铁是一种由铁盐预制的中间水解产物,属于水溶性无机高分子物质,溶于水后产生大量的高电荷聚合阳离子,如Fe2(OH)3+3,Fe2(OH)4+2,Fe3(OH)5+4等羟基桥联形成的各级多核络合铁离子。因此具有很强的中和悬浮颗粒上的电荷能力,使之脱稳并生成较大颗粒的絮凝体,同时也因其具有很大的比表面积和很强的吸附能力,对污水中乳化油有良好的破乳效果,对重金属、臭味和色素有较强的吸附能力,使用时显示出其独特的优越性。Polyferric sulfate is an intermediate hydrolyzate prefabricated by iron salt, which belongs to water-soluble inorganic macromolecular substances. 2, Fe3(OH)5+4 and other hydroxyl bridges formed by all levels of multi-nuclear complex iron ions. Therefore, it has a strong ability to neutralize the charge on the suspended particles, make it destabilized and generate larger particle flocs, and because of its large specific surface area and strong adsorption capacity, it is effective for emulsified oil in sewage. Good demulsification effect, strong adsorption capacity for heavy metals, odors and pigments, showing its unique advantages when used.
聚合硫酸铁又称碱式硫酸铁,它是一种高效新型水处理剂,广泛用于饮用水、工业废水、城市污水的处理。聚合硫酸铁(PFS)在水中存在着多种形态的铁络合离子,如[Fe(OH)2]+、[Fe(OH)]2+、[Fe2-(OH)2]4+等。它们以─OH架桥形成多核络合离子,这些多核络合离子能与水以任意比例互溶,发挥电性中和、吸附架桥作用。聚合硫酸铁絮凝剂实质上是硫酸铁在水体中水解2络合2聚合2胶凝2沉淀等转化过程的中间产物。Fe(Ⅲ)水解的基本反应式可写为:Fe(H2O)3+6+nH2O=[Fe(OH)n(H2O)6-n](3-n)++nH3O+当溶液的pH值升高后,单核羟基络离子就会生成羟基桥联的多核络合物,基本反应式可写成[Fe(OH)+2]n+Fe3++2H2O=[Fe(OH)+2]n+1+2H+生成羟基桥联的多核络合物会部分较缓慢的发生反应[Fe(OH)+2]n=[FeO(OH)]n+nH+。Polymerized ferric sulfate, also known as basic ferric sulfate, is a new type of efficient water treatment agent, widely used in the treatment of drinking water, industrial wastewater, and urban sewage. Polyferric sulfate (PFS) has various forms of iron complex ions in water, such as [Fe(OH)2]+, [Fe(OH)]2+, [Fe2-(OH)2]4+, etc. They form multinuclear complex ions with ─OH bridging. These multinuclear complex ions can be miscible with water in any proportion, and play the role of electrical neutralization and adsorption bridging. Polymerized ferric sulfate flocculant is essentially an intermediate product in the transformation process of ferric sulfate in water, such as hydrolysis, complexation, polymerization, gelation, and precipitation. The basic reaction formula of Fe(Ⅲ) hydrolysis can be written as: Fe(H2O)3+6+nH2O=[Fe(OH)n(H2O)6-n](3-n)++nH3O+ when the pH value of the solution rises When the concentration is high, the mononuclear hydroxyl complex ion will generate a hydroxyl bridged multinuclear complex, and the basic reaction formula can be written as [Fe(OH)+2]n+Fe3++2H2O=[Fe(OH)+2]n+ 1+2H+ generates hydroxyl-bridged polynuclear complexes, which will partially react [Fe(OH)+2]n=[FeO(OH)]n+nH+ more slowly.
壳聚糖Chitosan
壳聚糖甲壳素脱乙酰基的产物,在自然界来源非常丰富,酸性介质中可表现出阳离子聚合电解质性质,且无毒、易生物降解。通过壳聚糖与聚合硫酸铁复合协同作用能够提高絮凝能力。壳聚糖分子链上带正电荷、可通过与聚合硫酸铁的正电荷叠加作用增强电性的中和能力。另外,壳聚糖分子每个单元都有一个氨基,可以与聚合硫酸铁的金属离子发生螯合过吸附作用和网捕架桥作用命名用机高分子的分子链在已经脱稳的颗粒物之间架桥,增强对水中微小颗粒的去除能力。Chitosan, the product of deacetylation of chitin, is very rich in natural sources, can exhibit cationic polyelectrolyte properties in acidic media, and is non-toxic and easily biodegradable. The flocculation ability can be improved through the synergistic effect of chitosan and polyferric sulfate. The chitosan molecular chain is positively charged, which can enhance the neutralization ability of electricity through the superposition of positive charges with polyferric sulfate. In addition, each unit of chitosan molecule has an amino group, which can chelate with the metal ion of polyferric sulfate, over-adsorb, and net catch and bridging. The molecular chain of the organic polymer is named between the particles that have been destabilized. Build bridges to enhance the ability to remove tiny particles in water.
高锰酸盐permanganate
高锰酸钾是一种强氧化剂,它可以与聚合硫酸铁的吸附进行联合,对于河或湖中的藻和臭味具有很好的去除功能,快速使水体变清。在此基础上,还增加了一种磺化木质素盐作为加气剂,由于所述磺化木质素盐为木质素磺酸钠或木质素磺酸镁,均为天然产物,性能稳定无毒无害。作为一种加气剂使得絮凝的物质漂浮到水面,再用捞渣机进行收集,从河/湖去除水中的这些污染物。Potassium permanganate is a strong oxidant, which can be combined with the adsorption of polyferric sulfate. It has a good function of removing algae and odor in rivers or lakes, and quickly clears the water body. On this basis, a sulfonated lignin salt is added as an air-entraining agent. Since the sulfonated lignin salt is sodium lignosulfonate or magnesium lignosulfonate, which are both natural products, the performance is stable and non-toxic harmless. As an air-entraining agent, the flocculated material floats to the surface of the water and is collected by a slag machine to remove these pollutants from the river/lake water.
通过以上的处理之后,河底污泥去除,河水中悬浮物基本去除,清水变清。再投入EM菌和藻类。所述EM菌是微生物菌剂,包括光合细菌、乳酸菌、酵母菌、放线菌等。在修复过程还可以引入一些食藻虫、水生动物、水蚯蚓等,以及引入藻类。然后开始水下森林的建设。After the above treatment, the sludge at the bottom of the river is removed, the suspended solids in the river water are basically removed, and the clear water becomes clear. Add EM bacteria and algae again. The EM bacteria are microbial agents, including photosynthetic bacteria, lactic acid bacteria, yeast, actinomycetes and the like. In the restoration process, some algae-eating insects, aquatic animals, water earthworms, etc., as well as algae can also be introduced. Then start the construction of the underwater forest.
应用例1:宿州市三八沟黑臭水体治理Application example 1: Treatment of black and odorous water body in Sanbagou, Suzhou City
如图5所示,针对沟里水体的污染,分别从水体表面、水底淤泥和水体本身三个层面进行处理。对水体表面悬浮物、藻类、油污等,通过投加浮上型混凝剂将污染物浮上水面,浮上型混凝剂的重量比为:聚糖20份,聚合硫酸铁35,高锰酸盐30份,磺化木质素盐40份。再通过水面捞渣机40将表面污染物收集抽送到微纳米气泡气浮设备进行处理,清水返回水体,污染物转移处置。对于水底淤泥,通过底泥洗脱技术进行处理,洗脱底泥中轻质、有机的胶体污染物,消除底泥污染物对水体水质的影响。对于水体,通过投加EM菌和水下森林措施,构建水体生态系统,维持水质的长效达标。污水处理后的效果可参见下表:As shown in Figure 5, the pollution of the water body in the ditch is dealt with from three levels: the surface of the water body, the bottom silt, and the water body itself. For suspended solids, algae, oil, etc. on the surface of the water body, the pollutants are floated to the water surface by adding a floating coagulant. The weight ratio of the floating coagulant is: 20 parts of polysaccharide, 35 parts of polyferric sulfate, and 30 parts of permanganate Parts, 40 parts of sulfonated lignin salt. Then the surface pollutants are collected and pumped to the micro-nano bubble air flotation equipment through the water surface
应用例2:东莞市茅洲河黑臭水体治理Application example 2: Treatment of black and odorous water body in Maozhou River, Dongguan City
处理方式与上述案例1相同,浮上型混凝剂的重量比有差别,投入量是:聚糖30份,聚合硫酸铁25,高锰酸盐40份,磺化木质素盐30份。污水处理后的效果可参见下表:The treatment method is the same as the above case 1, but the weight ratio of the floating coagulant is different. The input amount is: 30 parts of polysaccharide, 25 parts of polyferric sulfate, 40 parts of permanganate, and 30 parts of sulfonated lignin salt. The effect after sewage treatment can be seen in the table below:
以上所述,仅是本发明的较佳实施例而已,并非对本发明的技术范围作任何限制,故凡是依据本发明的技术实质对以上实施例所作的任何细微修改、等同变化与修饰,均仍属于本发明技术方案的范围内。The above descriptions are only preferred embodiments of the present invention, and do not limit the technical scope of the present invention in any way, so any minor modifications, equivalent changes and modifications made to the above embodiments according to the technical essence of the present invention are still valid. It belongs to the scope of the technical solutions of the present invention.
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