CN112742858A - Method for repairing soil polluted by heavy metal cadmium - Google Patents

Method for repairing soil polluted by heavy metal cadmium Download PDF

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Publication number
CN112742858A
CN112742858A CN202011500432.0A CN202011500432A CN112742858A CN 112742858 A CN112742858 A CN 112742858A CN 202011500432 A CN202011500432 A CN 202011500432A CN 112742858 A CN112742858 A CN 112742858A
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China
Prior art keywords
soil
remediation
cadmium
plants
heavy metal
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Pending
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CN202011500432.0A
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Chinese (zh)
Inventor
王国红
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Suzhou Xiangrun Soil Remediation Technology Research Institute Co ltd
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Suzhou Xiangrun Soil Remediation Technology Research Institute Co ltd
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Priority to CN202011500432.0A priority Critical patent/CN112742858A/en
Publication of CN112742858A publication Critical patent/CN112742858A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/08Reclamation of contaminated soil chemically
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01BSOIL WORKING IN AGRICULTURE OR FORESTRY; PARTS, DETAILS, OR ACCESSORIES OF AGRICULTURAL MACHINES OR IMPLEMENTS, IN GENERAL
    • A01B79/00Methods for working soil
    • A01B79/02Methods for working soil combined with other agricultural processing, e.g. fertilising, planting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/10Reclamation of contaminated soil microbiologically, biologically or by using enzymes
    • B09C1/105Reclamation of contaminated soil microbiologically, biologically or by using enzymes using fungi or plants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C2101/00In situ

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Soil Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Mycology (AREA)
  • Health & Medical Sciences (AREA)
  • Botany (AREA)
  • Biomedical Technology (AREA)
  • Biotechnology (AREA)
  • General Health & Medical Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Mechanical Engineering (AREA)
  • Environmental Sciences (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention relates to the technical field of soil remediation, in particular to a method for remediating heavy metal cadmium polluted soil, which comprises the following steps: s1, ploughing and improving the soil by applying the improving agent; s2, repairing the soil by planting plants in the improved soil; s3, performing animal soil remediation on the soil after the plant improvement; and S4, performing microbial remediation on the soil improved by the animals. The method has the characteristics of economy, convenience and no change of the inherent physicochemical property of soil through animal remediation and microbial remediation modes, the environment polluted by cadmium is remediated by plants, the cost is low, the comprehensive ecological benefit is good, the method is particularly suitable for large-area popularization, and the efficient, stable and green remediation of the cadmium-polluted soil is thoroughly realized by matching the conditioner with animal remediation, microbial remediation and plant remediation, so that the method is the main direction of research.

Description

Method for repairing soil polluted by heavy metal cadmium
Technical Field
The invention relates to the technical field of soil remediation, in particular to a method for remediating heavy metal cadmium polluted soil.
Background
Cadmium is one of heavy metal elements with the strongest toxicity in the environment, is positioned in the second subgroup of the periodic table of elements, has the characteristics of strong biological mobility and easy absorption and accumulation by plants, can generate toxic action on animals, plants and human bodies, and even can cause diseases such as osteodynia, hypertension, renal dysfunction, liver damage, pulmonary edema and the like in serious cases; according to statistics, agricultural products and animals with cadmium content exceeding the standard produced in China every year cause accumulated toxic products of 146 ten thousand concave, the farmland area polluted by cadmium is over 28 ten thousand hm2, the agricultural products with cadmium exceeding the standard produced in China every year reach 150 ten thousand state, about 10% of common rice sold in the market in China has cadmium exceeding the standard, and great hidden danger is caused to environmental economy and human health.
The existing chemical remediation only changes the form of cadmium in soil, does not really remove cadmium pollution, has the possibility of reactivation damage, and is not a permanent remediation measure; therefore, a method for repairing soil polluted by heavy metal cadmium.
Disclosure of Invention
The invention aims to provide a method for repairing soil polluted by heavy metal cadmium, which aims to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme:
a method for repairing soil polluted by heavy metal cadmium comprises the following steps:
s1, ploughing and improving the soil by applying the improving agent;
s2, repairing the soil by planting plants in the improved soil;
s3, performing animal soil remediation on the soil after the plant improvement;
and S4, performing microbial remediation on the soil improved by the animals.
Preferably, the S1 is used for improving the soil by applying the improving agent, and the plowing depth is 10-15 cm.
Preferably, the S1 is used for improving the soil by applying the conditioner: chemical modifying agents are added into the polluted soil , heavy metals are subjected to fixed conversion, dissolution extraction and extraction separation, so that the content of the heavy metals in the polluted soil is reduced, the environmental conditions of the soil are changed, and the active cadmium and the stable cadmium in the soil can be mutually converted, wherein the modifying agents are alkaline modifying agents (lime, calcium magnesium phosphate fertilizer and the like), clay minerals (zeolite, sepiolite and the like), antagonistic substances (zinc sulfate, rare earth lanthanum and the like) and organic matters (peat, organic compost and the like) cadmium pollution remediation chemical materials.
Preferably, the S2 repairs the soil by planting plants in the improved soil: the method is characterized in that toxic and harmful pollutants in soil, sediment, sludge or ground surface and underground water are absorbed, decomposed, transformed or fixed by plants, and the method comprises plant extraction, plant volatilization, plant degradation, plant root filtration and rhizosphere microbial degradation, wherein cruciferae is more, and is mainly concentrated in Brassica, Brassica and Thalassia, and the hyperaccumulator plants with good cadmium polluted soil repairing effect comprise more than 10 families of plants including Brassica and Gramineae; some ornamental plants, farmland weeds and woody plants are also cadmium-contaminated soil remediation super-accumulative plants.
Preferably, the S3 is used for animal remediation of soil after plant improvement: some lower animals such as earthworms and rats in the soil can absorb heavy metals in the soil, so that the content of the heavy metals in the soil is reduced to a certain extent; the earthworms are inoculated in the heavy metal contaminated soil to find that the earthworms have stronger enrichment capacity on cadmium, and the enrichment amount is gradually increased along with the prolonging of the culture time of the earthworms.
Preferably, the S4 is used for microbial remediation of soil improved by animals: the remediation of the polluted soil is realized mainly by changing the activity of heavy metal ions in the soil, adsorbing and enriching heavy metals by microbial cells and promoting the absorption of heavy metals by hyper-enriched plants; the antagonistic bacterium WS34 can greatly improve the cadmium and lead enriching capability of Indian mustard and rape, and the AM fungus can increase the cadmium tolerance of plants and promote heavy metals such as cadmium to be transferred from the underground part to the overground part of the plants; the microbes for cadmium contaminated soil remediation encompass bacteria (Citrobacter, Pseudomonas, etc.), fungi (Rhizopus, Penicillium, Trichoderma, etc.), and certain small algae (Chlorella, Sargassum, etc.).
Compared with the prior art, the invention has the beneficial effects that:
according to the invention, the method has the characteristics of economy, convenience and no change of the inherent physicochemical property of soil through animal restoration and microbial restoration, the environment polluted by cadmium is restored by using plants, the cost is low, the comprehensive ecological benefit is good, the method is particularly suitable for large-area popularization, and the efficient, stable and green restoration of the cadmium polluted soil is thoroughly realized by matching the modifying agent with animal restoration, microbial restoration and plant restoration.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments, and all other embodiments obtained by a person of ordinary skill in the art without creative efforts based on the embodiments of the present invention belong to the protection scope of the present invention.
The invention provides a technical scheme that:
a method for repairing soil polluted by heavy metal cadmium comprises the following steps:
s1, ploughing and improving the soil by applying the improving agent;
s2, repairing the soil by planting plants in the improved soil;
s3, performing animal soil remediation on the soil after the plant improvement;
and S4, performing microbial remediation on the soil improved by the animals.
And S1, the soil is ploughed and improved by applying the conditioner, and the ploughing depth is 10-15 cm.
The S1 ploughing and improving the soil by applying the improving agent: chemical modifying agents are added into the polluted soil , heavy metals are subjected to fixed conversion, dissolution extraction and extraction separation, so that the content of the heavy metals in the polluted soil is reduced, the environmental conditions of the soil are changed, and the active cadmium and the stable cadmium in the soil can be mutually converted, wherein the modifying agents are alkaline modifying agents (lime, calcium magnesium phosphate fertilizer and the like), clay minerals (zeolite, sepiolite and the like), antagonistic substances (zinc sulfate, rare earth lanthanum and the like) and organic matters (peat, organic compost and the like) cadmium pollution remediation chemical materials.
And S2, repairing the soil by planting plants in the improved soil: the method is characterized in that toxic and harmful pollutants in soil, sediment, sludge or ground surface and underground water are absorbed, decomposed, transformed or fixed by plants, and the method comprises plant extraction, plant volatilization, plant degradation, plant root filtration and rhizosphere microbial degradation, wherein cruciferae is more, and is mainly concentrated in Brassica, Brassica and Thalassia, and the hyperaccumulator plants with good cadmium polluted soil repairing effect comprise more than 10 families of plants including Brassica and Gramineae; some ornamental plants, farmland weeds and woody plants are also cadmium-contaminated soil remediation super-accumulative plants.
And S3, performing animal remediation on the soil after the plant improvement: some lower animals such as earthworms and rats in the soil can absorb heavy metals in the soil, so that the content of the heavy metals in the soil is reduced to a certain extent; the earthworms are inoculated in the heavy metal contaminated soil to find that the earthworms have stronger enrichment capacity on cadmium, and the enrichment amount is gradually increased along with the prolonging of the culture time of the earthworms.
And S4, carrying out microbial remediation on the soil improved by the animals: the remediation of the polluted soil is realized mainly by changing the activity of heavy metal ions in the soil, adsorbing and enriching heavy metals by microbial cells and promoting the absorption of heavy metals by hyper-enriched plants; the antagonistic bacterium WS34 can greatly improve the cadmium and lead enriching capability of Indian mustard and rape, and the AM fungus can increase the cadmium tolerance of plants and promote heavy metals such as cadmium to be transferred from the underground part to the overground part of the plants; the microbes for cadmium contaminated soil remediation encompass bacteria (Citrobacter, Pseudomonas, etc.), fungi (Rhizopus, Penicillium, Trichoderma, etc.), and certain small algae (Chlorella, Sargassum, etc.).
The method has the characteristics of economy, convenience and no change of the inherent physicochemical property of soil through animal remediation and microbial remediation modes, the environment polluted by cadmium is remediated by plants, the cost is low, the comprehensive ecological benefit is good, the method is particularly suitable for large-area popularization, and the efficient, stable and green remediation of the cadmium-polluted soil is thoroughly realized by matching the conditioner with animal remediation, microbial remediation and plant remediation, so that the method is the main direction of research.
Example (b): the soil is ploughed and improved by applying the modifying agent, and the ploughing depth is 10-15 cm; and (3) ploughing and improving the soil by applying the conditioner: chemical modifying agents are put into the polluted soil , heavy metals are subjected to fixed conversion, dissolution extraction and extraction separation, so that the content of the heavy metals in the polluted soil is reduced, the environmental conditions of the soil are changed, and the active cadmium and the stable cadmium in the soil can be mutually converted, wherein the modifying agents are alkaline modifying agents (lime, calcium magnesium phosphate fertilizer and the like), clay minerals (zeolite, sepiolite and the like), antagonistic substances (zinc sulfate, rare earth lanthanum and the like) and organic matters (peat, organic compost and the like) cadmium pollution remediation chemical materials; and (3) repairing the soil by planting plants in the improved soil: the method is characterized in that toxic and harmful pollutants in soil, sediment, sludge or ground surface and underground water are absorbed, decomposed, transformed or fixed by plants, and the method comprises plant extraction, plant volatilization, plant degradation, plant root filtration and rhizosphere microbial degradation, wherein cruciferae is more, and is mainly concentrated in Brassica, Brassica and Thalassia, and the hyperaccumulator plants with good cadmium polluted soil repairing effect comprise more than 10 families of plants including Brassica and Gramineae; some ornamental plants, farmland weeds and woody plants are also cadmium-contaminated soil remediation hyperaccumulator plants; carrying out animal remediation on the soil after plant improvement: some lower animals such as earthworms and rats in the soil can absorb heavy metals in the soil, so that the content of the heavy metals in the soil is reduced to a certain extent; the earthworms are inoculated in the heavy metal contaminated soil to find that the earthworms have stronger enrichment capacity on cadmium, and the enrichment amount is gradually increased along with the prolonging of the culture time of the earthworms; carrying out microbial remediation on the soil improved by the animals: the remediation of the polluted soil is realized mainly by changing the activity of heavy metal ions in the soil, adsorbing and enriching heavy metals by microbial cells and promoting the absorption of heavy metals by hyper-enriched plants; the antagonistic bacterium WS34 can greatly improve the cadmium and lead enriching capability of Indian mustard and rape, and the AM fungus can increase the cadmium tolerance of plants and promote heavy metals such as cadmium to be transferred from the underground part to the overground part of the plants; the microbes for repairing the cadmium-polluted soil cover bacteria (such as bacillus citrate and pseudomonas), fungi (such as rhizopus, penicillium and trichoderma) and certain small algae (such as chlorella and gulfweed), the animal repairing and microbial repairing modes have the characteristics of economy, convenience and no change of the inherent physicochemical properties of the soil, the environment polluted by cadmium is repaired by plants, the cost is low, the comprehensive ecological benefits are good, the application is particularly suitable for large-area popularization, and the improvement agent is matched with the animal repairing, microbial repairing and plant repairing, so that the high efficiency, stability and greenness of the cadmium-polluted soil repairing are thoroughly realized, and the main direction of research is provided.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (6)

1. A method for repairing soil polluted by heavy metal cadmium is characterized by comprising the following steps:
s1, ploughing and improving the soil by applying the improving agent;
s2, repairing the soil by planting plants in the improved soil;
s3, performing animal soil remediation on the soil after the plant improvement;
and S4, performing microbial remediation on the soil improved by the animals.
2. The method for remediating the soil contaminated by heavy metal cadmium as claimed in claim 1, wherein S1 is used for improving the soil by applying an improver, and the plowing depth is 10-15 cm.
3. The method for soil remediation of heavy metal cadmium pollution as recited in claim 1, wherein said S1 is used for improving the soil by applying an improving agent: chemical modifying agents are added into the polluted soil , heavy metals are subjected to fixed conversion, dissolution extraction and extraction separation, so that the content of the heavy metals in the polluted soil is reduced, the environmental conditions of the soil are changed, and the active cadmium and the stable cadmium in the soil can be mutually converted, wherein the modifying agents are alkaline modifying agents (lime, calcium magnesium phosphate fertilizer and the like), clay minerals (zeolite, sepiolite and the like), antagonistic substances (zinc sulfate, rare earth lanthanum and the like) and organic matters (peat, organic compost and the like) cadmium pollution remediation chemical materials.
4. The method for soil remediation of heavy metal cadmium pollution as recited in claim 1, wherein said S2 is applied to the improved soil for plant cultivation, and the soil remediation is performed: the method is characterized in that toxic and harmful pollutants in soil, sediment, sludge or ground surface and underground water are absorbed, decomposed, transformed or fixed by plants, and the method comprises plant extraction, plant volatilization, plant degradation, plant root filtration and rhizosphere microbial degradation, wherein cruciferae is more, and is mainly concentrated in Brassica, Brassica and Thalassia, and the hyperaccumulator plants with good cadmium polluted soil repairing effect comprise more than 10 families of plants including Brassica and Gramineae; some ornamental plants, farmland weeds and woody plants are also cadmium-contaminated soil remediation super-accumulative plants.
5. The method for soil remediation of heavy metal cadmium contaminated soil as recited in claim 1, wherein said S3 is performed on the plant-improved soil by animal remediation of the soil: some lower animals such as earthworms and rats in the soil can absorb heavy metals in the soil, so that the content of the heavy metals in the soil is reduced to a certain extent; the earthworms are inoculated in the heavy metal contaminated soil to find that the earthworms have stronger enrichment capacity on cadmium, and the enrichment amount is gradually increased along with the prolonging of the culture time of the earthworms.
6. The method for soil remediation of heavy metal cadmium pollution as recited in claim 1, wherein said S4 is used for microbial remediation of animal-modified soil: the remediation of the polluted soil is realized mainly by changing the activity of heavy metal ions in the soil, adsorbing and enriching heavy metals by microbial cells and promoting the absorption of heavy metals by hyper-enriched plants; the antagonistic bacterium WS34 can greatly improve the cadmium and lead enriching capability of Indian mustard and rape, and the AM fungus can increase the cadmium tolerance of plants and promote heavy metals such as cadmium to be transferred from the underground part to the overground part of the plants; the microbes for cadmium contaminated soil remediation encompass bacteria (Citrobacter, Pseudomonas, etc.), fungi (Rhizopus, Penicillium, Trichoderma, etc.), and certain small algae (Chlorella, Sargassum, etc.).
CN202011500432.0A 2020-12-17 2020-12-17 Method for repairing soil polluted by heavy metal cadmium Pending CN112742858A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114015599A (en) * 2021-11-08 2022-02-08 广东省科学院动物研究所 Lead-resistant bacterium and application thereof
CN115228918A (en) * 2022-07-29 2022-10-25 中冶集团武汉勘察研究院有限公司 Soil extractant and method for repairing heavy metal contaminated soil by using same
CN115532809A (en) * 2022-09-27 2022-12-30 西南科技大学 Process for treating heavy metal pollution of soil

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114015599A (en) * 2021-11-08 2022-02-08 广东省科学院动物研究所 Lead-resistant bacterium and application thereof
CN114015599B (en) * 2021-11-08 2022-08-19 广东省科学院动物研究所 Lead-resistant bacterium and application thereof
CN115228918A (en) * 2022-07-29 2022-10-25 中冶集团武汉勘察研究院有限公司 Soil extractant and method for repairing heavy metal contaminated soil by using same
CN115532809A (en) * 2022-09-27 2022-12-30 西南科技大学 Process for treating heavy metal pollution of soil

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Application publication date: 20210504