CN112694847A - Film with anti-dazzle, subtract reflection and prevent fingerprint - Google Patents
Film with anti-dazzle, subtract reflection and prevent fingerprint Download PDFInfo
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- CN112694847A CN112694847A CN202011436676.7A CN202011436676A CN112694847A CN 112694847 A CN112694847 A CN 112694847A CN 202011436676 A CN202011436676 A CN 202011436676A CN 112694847 A CN112694847 A CN 112694847A
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Abstract
The invention discloses a film with anti-glare, anti-reflection and anti-fingerprint functions, which comprises: the film comprises a film base layer, an adhesive layer, a release film, an anti-glare layer, an anti-reflection layer and an anti-fingerprint layer; one side of the film base layer is sequentially provided with an adhesive layer and a release film from inside to outside; the other side is provided with an anti-glare layer, an anti-reflection layer and an anti-fingerprint layer from inside to outside in sequence; the anti-dazzle layer is prepared on the film base layer through curing resin and UV transfer printing; the anti-reflection layer is formed by alternately laminating a first preset number of high-refractive-index film layers and a second preset number of low-refractive-index film layers on the anti-glare layer in sequence; the anti-fingerprint layer is coated on the anti-reflection layer. The anti-glare layer formed by the UV transfer printing mode is stable, the anti-reflection effect of the anti-reflection layer obtained by alternately laminating the high-refractive-index film layer and the low-refractive-index film layer is good, the anti-fingerprint effect is good, the high-hardness wear resistance is good, the anti-explosion performance of the glass can be enhanced by laminating the anti-reflection layer and the substrate through the laminating process, and the anti-fingerprint anti-abrasion film is environment-friendly, low in cost and high in production.
Description
Technical Field
The invention belongs to the field of optical films, and relates to a film with anti-glare, anti-reflection and anti-fingerprint functions.
Background
Along with the popularization of wearable electronic product, pen electric product and on-vehicle electronic display screen, the visual effect of screen and practicality are more and more influenced to the anti-dazzle, subtract reflection and antifouling nature of display screen, and the product that has anti-dazzle, subtract reflection and prevent the fingerprint is more and more liked by the consumer. At present, most of glass is directly processed on the surface of glass to realize the functionality of products, but the glass has poor self-explosion resistance and low production yield, so that the production cost is high, and actual products cannot meet the use requirements.
Disclosure of Invention
The invention aims to: the film with the anti-glare, anti-reflection and anti-fingerprint functions is attached to the base materials such as glass or composite plates through the attaching process, the anti-explosion performance of the glass can be enhanced, and the film has the advantages of being environment-friendly, low in cost and high in production yield.
The technical scheme of the invention is as follows: a film with anti-glare, anti-reflection, and anti-fingerprint properties, comprising: the film comprises a film base layer, an adhesive layer, a release film, an anti-glare layer, an anti-reflection layer and an anti-fingerprint layer;
the adhesive layer and the release film are sequentially arranged on one side of the film base layer from inside to outside; the anti-glare layer, the anti-reflection layer and the anti-fingerprint layer are sequentially arranged on the other side of the film base layer from inside to outside;
the anti-glare layer is prepared on the film base layer through curing resin and UV transfer printing;
the anti-reflection layer is formed by alternately laminating a first preset number of high-refractive-index film layers and a second preset number of low-refractive-index film layers on the anti-glare layer in sequence;
the anti-fingerprint layer is coated on the antireflection layer.
The further technical scheme is as follows: the refractive index of the high refractive index film layer is 1.9-3.0, and the refractive index of the low refractive index film layer is 1.2-1.8.
The further technical scheme is as follows: the low-refractive-index film layer is an SiO2 film layer; the high-refractive-index film layer is one of a Nb2O5 film layer, a TiO2 film layer or a Si3N4 film layer.
The further technical scheme is as follows: the first preset layer number is 2, the second preset layer number is 3, and the first low-refractive-index film layer, the first high-refractive-index film layer, the second low-refractive-index film layer, the second high-refractive-index film layer and the third low-refractive-index film layer are sequentially stacked on the antireflection layer from inside to outside.
The further technical scheme is as follows: the thickness of the first low refractive index film layer is 85-100 nm, the thickness of the first high refractive index film layer is 100-120 nm, the thickness of the second low refractive index film layer is 35-50 nm, the thickness of the second high refractive index film layer is 8-16 nm, and the thickness of the third low refractive index film layer is 35-55 nm.
The further technical scheme is as follows: the reflectivity of the antireflection layer is less than 0.7%.
The further technical scheme is as follows: the haze of the anti-glare layer is 0.3-15.
The further technical scheme is as follows: the water drop angle of the anti-fingerprint layer is larger than 110 degrees.
The further technical scheme is as follows: the film base layer at least comprises one of PET, TAC and SRF.
The invention has the advantages that:
the anti-dazzle structure is directly formed on the surface of the film base layer by combining the high-strength curing resin with a transfer printing mode, the anti-dazzle structure is subjected to anti-reflection coating or coating on the surface, finally, an anti-fingerprint scratch-resistant layer is formed on the surface through coating, an anti-dazzle layer formed by the UV transfer printing mode is stable, the anti-reflection effect of the anti-reflection layer obtained by alternately stacking the high-refractive-index film layer and the low-refractive-index film layer is good, the anti-fingerprint effect is good, the high-hardness wear resistance is good, the anti-explosion performance of glass can be enhanced through the laminating process and the laminating of glass or composite plates and other base materials.
Drawings
The invention is further described with reference to the following figures and examples:
FIG. 1 is a schematic structural view of a film with anti-glare, anti-reflection, and anti-fingerprint properties provided herein;
fig. 2 is a schematic structural diagram of an antireflection layer provided in the present application.
Wherein: 1. a film base layer; 2. an adhesive layer; 3. a release film; 4. an anti-glare layer; 5. an anti-reflective layer; 51. a first low refractive index film layer; 52. a first high refractive index film layer; 53. a second low refractive index film layer; 54. a second high refractive index film layer; 55. a third low refractive index film layer; 6. an anti-fingerprint layer.
Detailed Description
Example (b): the present application provides a film with Anti-glare (AG), Anti-Reflection (AR) and Anti-fingerprint (AF), which includes, in conjunction with fig. 1 and 2: the film comprises a film base layer 1, an adhesive layer 2, a release film 3, an anti-glare layer 4, an anti-reflection layer 5 and an anti-fingerprint layer 6.
One side of the film base layer 1 is sequentially provided with an adhesive layer 2 and a release film 3 from inside to outside; the other side of the film base layer 1 is provided with an anti-glare layer 4, an anti-reflection layer 5 and an anti-fingerprint layer 6 from inside to outside in sequence. The anti-glare layer 4 is prepared on the film base layer 1 by combining cured resin and UV transfer printing; the antireflection layer 5 is formed by alternately laminating a first preset number of high-refractive-index film layers and a second preset number of low-refractive-index film layers on the antiglare layer 4 in sequence; the anti-fingerprint layer 6 is coated on the anti-reflection layer 4.
The Adhesive layer 2 may be optical Adhesive (OCA). In practical application, the release film can be removed, the adhesive layer 2 is attached to the glass or the composite board and other substrates through the attaching process, the explosion resistance of the glass can be enhanced, and the glass is environment-friendly, low in cost and high in production yield.
The positive reflection (specular reflection) is large, the penetration light is greatly reduced, and the dazzling optical fiber and the light of the mapping are reflected light generated by the positive reflection, so that the dazzling and the mapping can be prevented by controlling the positive reflection. For the anti-glare layer 4, usually, AG glass is subjected to etching treatment on the glass surface, so that the reflective surface (flat mirror surface) of the glass becomes a non-reflective matte surface (rough surface), and UV transfer printing is performed by using AG glass as a mold and dispensing (UV glue), pressing, curing and film-separating to obtain an AG film on the surface of the film base layer 1. The anti-glare layer 4 has excellent characteristics of anti-glare, high hardness, friction resistance and the like, and compared with an anti-glare layer prepared in an additive mode, the anti-glare layer 4 prepared in a UV transfer mode has lower roughness and smoother hand feeling under the same haze, and the anti-glare effect of the anti-glare layer 4 realized in the transfer mode is more stable.
Optionally, the haze of the anti-glare layer 4 is 0.3-15.
The principle of antireflection is that light is reflected at the boundary between substances having different refractive indices, and the interference of the reflected light produces an effect of increasing and decreasing the reflection. For the antireflection layer 5, the refractive index of the high-refractive-index film layer is 1.9-3.0, and the refractive index of the low-refractive-index film layer is 1.2-1.8.
Optionally, the low refractive index film layer is a SiO2 film layer; the high-refractive-index film layer is one of a Nb2O5 film layer, a TiO2 film layer or a Si3N4 film layer.
Illustratively, as shown in fig. 2, the first predetermined number of layers is 2, the second predetermined number of layers is 3, and the antireflection layer 5 is formed by sequentially stacking a first low refractive index film layer 51, a first high refractive index film layer 52, a second low refractive index film layer 53, a second high refractive index film layer 54, and a third low refractive index film layer 55 from inside to outside.
Since the outer layer is made of a material having a high refractive index, most of light is reflected when the light is incident from the uppermost surface, and thus antireflection cannot be achieved, the innermost layer and the outermost layer of the antireflection layer 5 are low refractive index film layers. By alternately laminating the high-refractive-index film layers and the low-refractive-index film layers, light can be reflected from the low-refractive-index material to the high-refractive-index material at the contact interface, and multiple reflections realize surface antireflection extinction.
Optionally, the thickness of the first low refractive index film layer 51 is 85 to 100nm, the thickness of the first high refractive index film layer 52 is 100 to 120nm, the thickness of the second low refractive index film layer 53 is 35 to 50nm, the thickness of the second high refractive index film layer 54 is 8 to 16nm, and the thickness of the third low refractive index film layer 55 is 35 to 55 nm. The reflection of the antireflection layer is less than 0.7%. The film layers can be alternately laminated in sequence by means of coating or coating.
The anti-fingerprint coating film simulates the lotus leaf effect, and the AF material is a fluorine-containing coating, has extremely low surface tension, can improve the performances of hydrophobicity, oil drainage, pollution prevention and the like of a screen, and also has the characteristics of wear resistance, high light transmittance and the like. For the anti-fingerprint layer 6, the anti-fingerprint layer 6 prepared on the anti-reflection layer 5 in a coating mode enables the surface of a product not to generate fingerprints easily and has good wear resistance according to the strong hydrophobic, anti-fingerprint and anti-oil stain capabilities of Europe.
Optionally, the water drop angle of the anti-fingerprint layer 6 is greater than 110 °.
Optionally, the film base layer 1 includes at least one of PET, TAC, and SRF.
To sum up, the film that has anti-dazzle, subtract reflection and prevent fingerprint that this application provided, the solidification resin that combines the rendition mode through high strength directly forms anti-dazzle structure at film basic unit surface, and subtract reflection coating film or coating on the surface, form on the surface through the coating at last and prevent fingerprint scratch-resistant layer, anti-dazzle layer through the formation of UV rendition mode is more stable, the anti-reflection effect of the antireflection layer that high refracting index rete and low refracting index rete range upon range of in turn obtained is good, prevent that the fingerprint is effectual, high rigidity wearability is good, can laminate through substrate laminating such as laminating technology and glass or composite sheet, can strengthen glass's explosion-proof nature, the environmental protection, low cost and production yield are high.
The terms "first" and "second" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance or implying a number of the indicated technical features. Thus, a defined feature of "first", "second", may explicitly or implicitly include one or more of that feature. In the description of the present application, "a plurality" means two or more unless otherwise specified.
The above-mentioned serial numbers of the embodiments of the present application are merely for description and do not represent the merits of the embodiments.
The above description is only exemplary of the present application and should not be taken as limiting the present application, as any modification, equivalent replacement, or improvement made within the spirit and principle of the present application should be included in the protection scope of the present application.
Claims (9)
1. A film with anti-glare, anti-reflection, and anti-fingerprint properties, comprising: the film comprises a film base layer, an adhesive layer, a release film, an anti-glare layer, an anti-reflection layer and an anti-fingerprint layer;
the adhesive layer and the release film are sequentially arranged on one side of the film base layer from inside to outside; the anti-glare layer, the anti-reflection layer and the anti-fingerprint layer are sequentially arranged on the other side of the film base layer from inside to outside;
the anti-glare layer is prepared on the film base layer through curing resin and UV transfer printing;
the anti-reflection layer is formed by alternately laminating a first preset number of high-refractive-index film layers and a second preset number of low-refractive-index film layers on the anti-glare layer in sequence;
the anti-fingerprint layer is coated on the antireflection layer.
2. The film with anti-glare, anti-reflection and anti-fingerprint effects of claim 1, wherein the high refractive index film layer has a refractive index of 1.9-3.0, and the low refractive index film layer has a refractive index of 1.2-1.8.
3. The film having anti-glare, anti-reflection, and anti-fingerprint properties of claim 2, wherein the low refractive index film layer is a SiO2 film layer; the high-refractive-index film layer is one of a Nb2O5 film layer, a TiO2 film layer or a Si3N4 film layer.
4. The film of any one of claims 1 to 3, wherein the first predetermined number of layers is 2, the second predetermined number of layers is 3, and the antireflection layer is formed by sequentially stacking a first low refractive index film layer, a first high refractive index film layer, a second low refractive index film layer, a second high refractive index film layer, and a third low refractive index film layer from inside to outside.
5. The film with anti-glare, anti-reflection and anti-fingerprint effects of claim 4, wherein the first low refractive index film layer has a thickness of 85 to 100nm, the first high refractive index film layer has a thickness of 100 to 120nm, the second low refractive index film layer has a thickness of 35 to 50nm, the second high refractive index film layer has a thickness of 8 to 16nm, and the third low refractive index film layer has a thickness of 35 to 55 nm.
6. The film of claim 5 having anti-glare, anti-reflection, and anti-fingerprint properties, wherein the anti-reflection layer has a reflectivity of less than 0.7%.
7. The film with anti-glare, anti-reflection and anti-fingerprint effects of claim 1, wherein the anti-glare layer has a haze of 0.3 to 15.
8. The film of claim 1 having anti-glare, anti-reflection, and anti-fingerprint properties, wherein the anti-fingerprint layer has a water drop angle of greater than 110 °.
9. The film of claim 1, wherein the film base layer comprises at least one of PET, TAC, and SRF.
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Cited By (8)
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CN113504587A (en) * | 2021-07-01 | 2021-10-15 | 安徽胜利精密制造科技有限公司 | Integrated diaphragm with black display effect |
CN113552657A (en) * | 2021-07-01 | 2021-10-26 | 安徽胜利精密制造科技有限公司 | Preparation method of anti-glare ultralow-reflection film |
CN113652641A (en) * | 2021-06-18 | 2021-11-16 | 浙江三海微纳科技有限公司 | Antireflection film and production process thereof |
CN113820762A (en) * | 2021-07-30 | 2021-12-21 | 信利光电股份有限公司 | Anti-dazzle ultralow reflectivity apron |
CN113956809A (en) * | 2021-10-11 | 2022-01-21 | 安徽胜利精密制造科技有限公司 | Preparation method of integrated near-colorless low-reflection film |
CN114395340A (en) * | 2021-11-28 | 2022-04-26 | 凯盛科技股份有限公司蚌埠华益分公司 | Antireflection functional film for vehicle-mounted display screen and preparation method thereof |
CN114740553A (en) * | 2022-05-25 | 2022-07-12 | 江苏日久光电股份有限公司 | Large-viewing-angle anti-reflection composite film, display assembly and display device |
CN116559984A (en) * | 2023-05-06 | 2023-08-08 | 佛山纳诺特科技有限公司 | Inorganic wear-resistant homogeneous refractive index change antireflection film and preparation method and application thereof |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113652641A (en) * | 2021-06-18 | 2021-11-16 | 浙江三海微纳科技有限公司 | Antireflection film and production process thereof |
CN113652641B (en) * | 2021-06-18 | 2023-06-02 | 浙江三海微纳科技有限公司 | Antireflection film and production process thereof |
CN113504587A (en) * | 2021-07-01 | 2021-10-15 | 安徽胜利精密制造科技有限公司 | Integrated diaphragm with black display effect |
CN113552657A (en) * | 2021-07-01 | 2021-10-26 | 安徽胜利精密制造科技有限公司 | Preparation method of anti-glare ultralow-reflection film |
CN113820762A (en) * | 2021-07-30 | 2021-12-21 | 信利光电股份有限公司 | Anti-dazzle ultralow reflectivity apron |
CN113956809A (en) * | 2021-10-11 | 2022-01-21 | 安徽胜利精密制造科技有限公司 | Preparation method of integrated near-colorless low-reflection film |
CN114395340A (en) * | 2021-11-28 | 2022-04-26 | 凯盛科技股份有限公司蚌埠华益分公司 | Antireflection functional film for vehicle-mounted display screen and preparation method thereof |
CN114740553A (en) * | 2022-05-25 | 2022-07-12 | 江苏日久光电股份有限公司 | Large-viewing-angle anti-reflection composite film, display assembly and display device |
CN116559984A (en) * | 2023-05-06 | 2023-08-08 | 佛山纳诺特科技有限公司 | Inorganic wear-resistant homogeneous refractive index change antireflection film and preparation method and application thereof |
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