CN112647298A - 一种去除胶带痕迹的纤维材料及其制备方法 - Google Patents
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- B08B1/00—Cleaning by methods involving the use of tools
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B1/00—Cleaning by methods involving the use of tools
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Abstract
本发明涉及清洁材料领域,具体为一种去除胶带痕迹的纤维材料及其制备方法。所述纤维材料的组成分为为:聚苯乙烯、有机溶剂、聚丙烯纤维,其制作方法为先将聚苯乙烯颗粒溶于有机溶剂中,搅拌形成均一溶液A;后将聚丙烯纤维浸入溶液A中,浸泡;最后将带有溶液A的聚丙烯纤维取出,晾晒干燥,制备成为表面改性的聚丙烯纤维复合材料。本发明采用易得的化学原材料,经过简单的工艺,制备了一种可以高效去除胶带痕迹的纤维材料。该材料的应用克服了目前机械或者有机溶剂去除胶带痕迹等方法的缺点。
Description
技术领域
本发明涉及清洁材料领域,具体为一种去除胶带痕迹的纤维材料及其制备方法。
背景技术
透明胶带、包装胶带、双面胶带、自粘标签已经成为最常用的固定方法。使用一段时间后,胶带的粘接层材料会逐渐与表面结合,当需要去除或更换时,胶带上的粘接层材料往往会与胶带基材分离,进而残存在被粘接的基材表面,这种现象在硬质基材,例如玻璃、瓷砖、金属表面、塑料、木材或人工板材的表面尤其明显,难以去除;很多带有标签的工艺品、容器、玩具表面也会发生这种现象。目前常用的方法是利用刮刀等工具清除,但是容易损伤被黏附的表面,影响外观;或者利用有机溶剂,例如乙醇或去甲油、香蕉水等溶剂去除,容易带来健康问题,当需要处理的样品较多时,还会带来安全问题。
CN108714582公布了一种基于缩放旋转的钢化玻璃胶带痕迹去除装置,有十几个组件构成,制造复杂。CN201710701891.7公布了一种含松油醇类化合物的清洁剂及其制备方法,其组成成份包括松油醇类化合物、乳化剂、水溶性有机溶剂和水。将松油醇类化合物与乳化剂溶解在有机溶剂中作为油相,然后将油相与水相通过在微腔体内高速射流混合而制得尺寸随时间稳定的纳米水乳液。CN201310543643.6公开了一种用植物油、矿物油和泥沙制备的清洁泥,在光滑表面使用时容易划伤表面。
胶带的粘接层大多是由丙烯酸酯化合物制成的压敏胶,属于有极性的化合物。该类化合物与基材的粘接,主要是依靠范德华力作用。但是该类化合物并不溶解于水中,因此去除丙烯酸酯的方法是增加接触面积,利用毛糙表面,增加清洁材料与胶带粘接物质的范德华作用力。
发明内容
本发明提供了一种去除胶带痕迹的纤维材料及其制备方法,通过引入聚苯乙烯的目的是为了增加苯乙烯中苯环与丙烯酸酯的亲和性,达到快速、高效的去除胶带痕迹的目的。
为实现上述目的,本发明采用的技术方案具体如下:
本发明的目的之一是提供一种去除胶带痕迹的纤维材料,其特征在于:所述纤维材料的组成分为为:聚苯乙烯、有机溶剂、聚丙烯纤维,聚苯乙烯与有机溶剂的质量比例是1∶50-1∶200,聚丙烯纤维与聚苯乙烯颗粒的质量比为10∶1-1∶5。
本发明的另一目的是一种去除胶带痕迹的纤维材料制作方法,其特征在于:包括以下步骤:
S1、将聚苯乙烯颗粒溶于有机溶剂中,搅拌形成均一溶液A;
S2、将聚丙烯纤维浸入溶液A中,浸泡;
S3、将带有溶液A的聚丙烯纤维取出,晾晒干燥,制备成为表面改性的聚丙烯纤维复合材料。
所述聚丙烯纤维材料是熔喷PP无纺布纤维材料。
所述有机溶剂使用的溶剂为氯仿、二氯甲烷,丙酮、甲乙酮、乙酸乙酯、乙酸丁酯和乙酸甲酯中一种。
所述溶液A是分子量处于20000-50000的悬浮聚合制备的聚苯乙烯颗粒。
本发明的有益效果为:本发明采用易得的化学原材料,经过简单的工艺,制备了一种可以高效去除胶带痕迹的纤维材料。该材料的应用克服了目前机械或者有机溶剂去除胶带痕迹等方法的缺点。
附图说明
图1是产品B的电子显微镜照片;
图2是产品B擦拭完胶带痕迹的显微镜照片;
图3是产品B的纤维的细部结构;
图4是产品B擦拭完胶带痕迹后的胶带成分在纤维上的形貌图。
具体实施方式
下面结合附图并通过具体的实施例进一步的说明本发明的技术方案:
实施例1
本发明利用聚丙烯无纺布纤维材料表面改性的方法,制备了一种符合纤维材料,可以高效去除由各类胶带引起的痕迹。
具体的方法如下:将聚苯乙烯颗粒溶于有机溶剂中,搅拌形成均一溶液A,后将熔喷PP无纺布浸渍与上述溶液中,停留1-2分钟后,取出,晾干或通风干燥,制备成为表面改性的聚丙烯纤维复合材料。
有机溶剂采用的溶剂为乙酸乙酯、乙酸丁酯或丙酮三种的一种。
使用方法:将聚丙烯纤维复合材料剪成小块,然后蘸取少量水,在胶带痕迹地方轻轻擦拭,胶带痕迹便慢慢粘附到聚丙烯纤维材料上,表面被清理干净。
实施例2
取1g聚苯乙烯颗粒,溶解于100mL乙酸乙酯中,搅拌均匀后,备用。取熔喷PP无纺布100mm×100mm薄膜,浸渍于聚苯乙烯的乙酸乙酯溶液中3-5秒后,取出。在通风橱中,挥发溶剂至干。得到产品B。
去除实验:
将透明胶带在玻璃表面粘接,放置1-2月后,慢慢揭掉胶带,发现玻璃表面留下明显的胶带痕迹。将产品B蘸取少量清水后,用产品B在胶带痕迹表面轻轻擦拭,胶带痕迹便被轻松去除
对于本领域技术人员而言,显然本发明不限于上述示范性实施例的细节,而且在不背离本发明的精神或基本特征的情况下,能够以其他的具体形式实现本发明。因此,无论从哪一点来看,均应将实施例看作是示范性的,而且是非限制性的,本发明的范围由所附权利要求而不是上述说明限定,因此旨在将落在权利要求的等同要件的含义和范围内的所有变化囊括在本发明内。不应将权利要求中的任何附图标记视为限制所涉及的权利要求。
此外,应当理解,虽然本说明书按照实施方式加以描述,但并非每个实施方式仅包含一个独立的技术方案,说明书的这种叙述方式仅仅是为清楚起见,本领域技术人员应当将说明书作为一个整体,各实施例中的技术方案也可以经适当组合,形成本领域技术人员可以理解的其他实施方式。
Claims (5)
1.一种去除胶带痕迹的纤维材料,其特征在于:所述纤维材料的组成分为为:聚苯乙烯、有机溶剂、聚丙烯纤维,聚苯乙烯与有机溶剂的质量比例是1∶50-1∶200,聚丙烯纤维与聚苯乙烯颗粒的质量比为10∶1-1∶5。
2.一种去除胶带痕迹的纤维材料制作方法,其特征在于:包括以下步骤:
S1、将聚苯乙烯颗粒溶于有机溶剂中,搅拌形成均一溶液A;
S2、将聚丙烯纤维浸入溶液A中,浸泡;
S3、将带有溶液A的聚丙烯纤维取出,晾晒干燥,制备成为表面改性的聚丙烯纤维复合材料。
3.根据权利要求1所述的一种去除胶带痕迹的纤维材料,其特征在于:所述聚丙烯纤维材料是熔喷PP无纺布纤维材料。
4.根据权利要求1所述的一种去除胶带痕迹的纤维材料,其特征在于:所述有机溶剂使用的溶剂为氯仿、二氯甲烷,丙酮、甲乙酮、乙酸乙酯、乙酸丁酯和乙酸甲酯中一种。
5.根据权利要求2所述的一种去除胶带痕迹的纤维材料制作方法,其特征在于:所述溶液A是分子量处于20000-50000的悬浮聚合制备的聚苯乙烯颗粒。
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Citations (3)
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CN102010544A (zh) * | 2010-06-07 | 2011-04-13 | 李美香 | 一种塑料复合纸 |
CN103242774A (zh) * | 2013-05-31 | 2013-08-14 | 苏州华周胶带有限公司 | 一种以玻璃布为基材的胶带 |
CN110947602A (zh) * | 2018-09-27 | 2020-04-03 | 国家纳米科学中心 | 一种基于纤维阵列的耐刮擦超疏水材料及其制备方法 |
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Patent Citations (3)
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CN102010544A (zh) * | 2010-06-07 | 2011-04-13 | 李美香 | 一种塑料复合纸 |
CN103242774A (zh) * | 2013-05-31 | 2013-08-14 | 苏州华周胶带有限公司 | 一种以玻璃布为基材的胶带 |
CN110947602A (zh) * | 2018-09-27 | 2020-04-03 | 国家纳米科学中心 | 一种基于纤维阵列的耐刮擦超疏水材料及其制备方法 |
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Title |
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崔建华等: "《基础化学》", 31 August 2014, 广西人民出版社 * |
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