CN112608536A - 一种强韧耐磨橡塑制品的制备方法 - Google Patents
一种强韧耐磨橡塑制品的制备方法 Download PDFInfo
- Publication number
- CN112608536A CN112608536A CN202011365814.7A CN202011365814A CN112608536A CN 112608536 A CN112608536 A CN 112608536A CN 202011365814 A CN202011365814 A CN 202011365814A CN 112608536 A CN112608536 A CN 112608536A
- Authority
- CN
- China
- Prior art keywords
- parts
- preparation
- wear
- powder
- tough
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920003023 plastic Polymers 0.000 title claims abstract description 39
- 239000004033 plastic Substances 0.000 title claims abstract description 39
- 229920001971 elastomer Polymers 0.000 title claims abstract description 36
- 239000005060 rubber Substances 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 239000000843 powder Substances 0.000 claims abstract description 34
- 239000002699 waste material Substances 0.000 claims abstract description 34
- 238000003756 stirring Methods 0.000 claims abstract description 21
- 238000005187 foaming Methods 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 239000004088 foaming agent Substances 0.000 claims abstract description 9
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 7
- 238000001723 curing Methods 0.000 claims abstract description 6
- 239000004800 polyvinyl chloride Substances 0.000 claims description 41
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- 229920000459 Nitrile rubber Polymers 0.000 claims description 8
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 5
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims description 5
- 229910000013 Ammonium bicarbonate Inorganic materials 0.000 claims description 5
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 5
- 229920002125 Sokalan® Polymers 0.000 claims description 5
- 238000007605 air drying Methods 0.000 claims description 5
- 235000012538 ammonium bicarbonate Nutrition 0.000 claims description 5
- 239000001099 ammonium carbonate Substances 0.000 claims description 5
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 5
- 238000004140 cleaning Methods 0.000 claims description 5
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 229920002681 hypalon Polymers 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 239000012948 isocyanate Substances 0.000 claims description 5
- 150000002513 isocyanates Chemical class 0.000 claims description 5
- OCWMFVJKFWXKNZ-UHFFFAOYSA-L lead(2+);oxygen(2-);sulfate Chemical compound [O-2].[O-2].[O-2].[Pb+2].[Pb+2].[Pb+2].[Pb+2].[O-]S([O-])(=O)=O OCWMFVJKFWXKNZ-UHFFFAOYSA-L 0.000 claims description 5
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 5
- 239000004584 polyacrylic acid Substances 0.000 claims description 5
- 229920001610 polycaprolactone Polymers 0.000 claims description 5
- 239000004632 polycaprolactone Substances 0.000 claims description 5
- 229920000193 polymethacrylate Polymers 0.000 claims description 5
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 5
- 238000012216 screening Methods 0.000 claims description 5
- 229910052708 sodium Inorganic materials 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 5
- VNJISVYSDHJQFR-UHFFFAOYSA-N tert-butyl 4,4-dimethylpentaneperoxoate Chemical compound CC(C)(C)CCC(=O)OOC(C)(C)C VNJISVYSDHJQFR-UHFFFAOYSA-N 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 235000007270 Gaultheria hispida Nutrition 0.000 claims description 4
- 235000009134 Myrica cerifera Nutrition 0.000 claims description 4
- 244000269152 Myrica pensylvanica Species 0.000 claims description 4
- 235000012851 Myrica pensylvanica Nutrition 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 2
- 239000000155 melt Substances 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000008187 granular material Substances 0.000 abstract 2
- 238000000227 grinding Methods 0.000 abstract 1
- 229920002635 polyurethane Polymers 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 abstract 1
- 239000001993 wax Substances 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- GOLXRNDWAUTYKT-UHFFFAOYSA-N 3-(1H-indol-3-yl)propanoic acid Chemical group C1=CC=C2C(CCC(=O)O)=CNC2=C1 GOLXRNDWAUTYKT-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000012179 bayberry wax Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000003889 chemical engineering Methods 0.000 description 1
- 238000012993 chemical processing Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0095—Mixtures of at least two compounding ingredients belonging to different one-dot groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
- C08J2309/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2423/04—Homopolymers or copolymers of ethene
- C08J2423/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2427/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2427/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2427/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2427/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2467/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2467/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
Abstract
本发明公开了一种强韧耐磨橡塑制品的制备方法，该方法按比例将各原料加入到混料机中，搅拌均匀得到混合料；将混合料加入反应釜中混合反应，然后用双螺杆挤出机挤出造粒，得到改性粒料，然后改性粒料研磨成粉料；然后将聚氨酯、粉料、发泡剂、乳化剂混合，投入搅拌机中搅匀后进行加热发泡、固化3‑12h得到强韧耐磨橡塑制品。本发明方法采用回收废旧PVC塑料进行破碎后改性作为生产原料，不仅实现了废旧塑料的无害化和资源化利用，缓解塑料资源紧缺，环保、无污染、无公害、可循环利用，造福社会。同时制备的橡塑制品，阻燃性、耐冲击、耐磨性良好。
Description
技术领域
本发明涉及一种强韧耐磨橡塑制品的制备方法。
背景技术
橡胶行业是我国化学工业的重要组成部分，橡胶行业的基本原材料就是天然橡胶和合成橡胶，为了制造出符合实际使用性能要求的橡胶制品，改善加工工艺性能，必须加入各种化学加工助剂。目前一般生产橡塑制品使用丁腈橡胶和聚氯乙烯树脂为主体材料，添加其他辅助材料高温共混，然后加入硫化剂和发泡剂经过硫化发泡，最终实现橡塑制品的制备。橡塑材料具有柔软，耐曲绕，耐寒，耐热，阻燃，防水，导热系数低，减震，吸音等优良性能，可广泛应用于中央空调、建筑，化工，车辆，电器等行业。聚氯乙烯，英文简称PVC，是氯乙烯单体在过氧化物、偶氮化合物等引发剂；或在光、热作用下按自由基聚合反应机理聚合而成的聚合物。PVC曾是世界上产量最大的通用塑料，应用非常广泛。在建筑材料、工业制品、日用品、包装膜、瓶、发泡材料、密封材料、纤维等方面均有广泛应用。PVC材料的应用广泛导致其废旧物非常低，PVC材料难以降解，通过自然降解处理的方式非常困难，现有技术中少见对其有效的利用。废旧PVC塑料是环境污染的一大公害，但如果变废为宝，既能改变环境污染问题又促进了塑料工业的健康发展，所以本发明中通过对包装箱的配方设计和工艺的结合，提供了一种强韧耐磨橡塑制品的制备方法，将废旧PVC塑料经再生处理后制得原料，经其加工制成的橡塑制品具有优良的机械性能，满足橡塑制品的使用需求。
发明内容
本发明的目的在于提供一种强韧耐磨橡塑制品的制备方法。
为了实现上述目的，本发明提供了一种强韧耐磨橡塑制品的制备方法，该方法包括以下步骤：
步骤1、对PVC废料进行清洗，去除表面的杂质，然后对PVC废料进行晾晒和风干，接着将PVC废料送入破碎机破碎，然后经过分选机筛选收集粉体，然后放入离心机分离水分，再经过热空气干燥，使含水量下降到1％以下，得到PVC废料粉；
步骤2、按重量份计，称取如下原料：PVC废料粉200-300份、聚氯乙烯100-150份、聚己内酯20-30份、丙烯酸甲酯10-20份、三烯丙基异氰酸酯2-8份、杨梅蜡2-3份、乙烯-乙烯醇共聚物4-7份、邻苯二甲酸二甲酐6-9份、三盐基硫酸铅1-4份、聚甲基丙烯酸钠4-5份、双叔丁基过氧异丙基苯3-8份、氯磺化聚乙烯橡胶20-25份、聚乙烯醇缩丁醛2-4份、聚丙烯酸12-14份、碳酸氢铵5-10份、过氧化二异丙苯10-15份、十二烷基苯磺酸钠盐2-6份、过氧化新庚酸叔丁酯4-6份和过硫酸钾1-4份；按比例加入到混料机中，搅拌均匀得到混合料；将混合料加入反应釜中于100-120℃混合10-15min，然后用双螺杆挤出机挤出造粒，得到改性粒料，然后改性粒料研磨成200-300目的粉料；
步骤3、将重量份计，将丁腈橡胶70-80份、粉料60-70份、发泡剂5-10份和乳化剂5-10份混合，投入搅拌机中搅拌20-30min；然后进行加热发泡、固化3-12h得到强韧耐磨橡塑制品。
所述步骤3中，将重量份计，将丁腈橡胶75份、粉料65份、发泡剂8份和乳化剂8份混合投入搅拌机搅拌20-30min。
所述在双螺杆挤出机温度190-210℃，双螺杆挤出机的螺杆转速为60转/min条件下熔融挤出。
所述混料机中搅拌温度为30-40℃，搅拌转速120-150转/min。
所述加热发泡温度为110-130℃、压力为0.01-0.5MPa，时间为10-600s。
有益效果：本发明方法采用回收废旧PVC塑料进行破碎后改性作为生产原料，不仅实现了废旧塑料的无害化和资源化利用，缓解塑料资源紧缺，环保、无污染、无公害、可循环利用，造福社会。同时制备的橡塑制品，阻燃性、耐冲击、耐磨性良好。
具体实施方式
实施例1
一种强韧耐磨橡塑制品的制备方法，该方法包括以下步骤：
步骤1、对PVC废料进行清洗，去除表面的杂质，然后对PVC废料进行晾晒和风干，接着将PVC废料送入破碎机破碎，然后经过分选机筛选收集粉体，然后放入离心机分离水分，再经过热空气干燥，使含水量下降到1％以下，得到PVC废料粉；
步骤2、按重量份计，称取如下原料：PVC废料粉200份、聚氯乙烯100份、聚己内酯20份、丙烯酸甲酯10份、三烯丙基异氰酸酯2份、杨梅蜡2份、乙烯-乙烯醇共聚物4份、邻苯二甲酸二甲酐6份、三盐基硫酸铅1份、聚甲基丙烯酸钠4份、双叔丁基过氧异丙基苯3份、氯磺化聚乙烯橡胶20份、聚乙烯醇缩丁醛2份、聚丙烯酸12份、碳酸氢铵5份、过氧化二异丙苯10份、十二烷基苯磺酸钠盐2份、过氧化新庚酸叔丁酯4份和过硫酸钾1份；按比例加入到混料机中，所述混料机中搅拌温度为30-40℃，搅拌转速120-150转/min，搅拌均匀得到混合料；将混合料加入反应釜中于100-120℃混合10-15min，然后用双螺杆挤出机挤出造粒，双螺杆挤出机温度190-210℃，双螺杆挤出机的螺杆转速为60转/min条件下熔融挤出改性粒料，然后改性粒料研磨成200-300目的粉料；
步骤3、将重量份计，将丁腈橡胶70份、粉料60份、发泡剂5份和乳化剂5份混合，投入搅拌机中搅拌20-30min；然后进行加热发泡、固化3-12h得到强韧耐磨橡塑制品，所述加热发泡温度为110-130℃、压力为0.01-0.5MPa，时间为10-600s。
实施例2
一种强韧耐磨橡塑制品的制备方法，该方法包括以下步骤：
步骤1、对PVC废料进行清洗，去除表面的杂质，然后对PVC废料进行晾晒和风干，接着将PVC废料送入破碎机破碎，然后经过分选机筛选收集粉体，然后放入离心机分离水分，再经过热空气干燥，使含水量下降到1％以下，得到PVC废料粉；
步骤2、按重量份计，称取如下原料：PVC废料粉250份、聚氯乙烯120份、聚己内酯25份、丙烯酸甲酯15份、三烯丙基异氰酸酯5份、杨梅蜡2.5份、乙烯-乙烯醇共聚物5份、邻苯二甲酸二甲酐7份、三盐基硫酸铅3份、聚甲基丙烯酸钠4.5份、双叔丁基过氧异丙基苯5份、氯磺化聚乙烯橡胶23份、聚乙烯醇缩丁醛3份、聚丙烯酸13份、碳酸氢铵7份、过氧化二异丙苯13份、十二烷基苯磺酸钠盐4份、过氧化新庚酸叔丁酯5份和过硫酸钾3份；按比例加入到混料机中，所述混料机中搅拌温度为30-40℃，搅拌转速120-150转/min，搅拌均匀得到混合料；将混合料加入反应釜中于100-120℃混合10-15min，然后用双螺杆挤出机挤出造粒，双螺杆挤出机温度190-210℃，双螺杆挤出机的螺杆转速为60转/min条件下熔融挤出改性粒料，然后改性粒料研磨成200-300目的粉料；
步骤3、将重量份计，将丁腈橡胶75份、粉料65份、发泡剂8份和乳化剂8份混合投入搅拌机搅拌20-30min。然后进行加热发泡、固化3-12h得到强韧耐磨橡塑制品，所述加热发泡温度为110-130℃、压力为0.01-0.5MPa，时间为10-600s。
实施例3
一种强韧耐磨橡塑制品的制备方法，该方法包括以下步骤：
步骤1、对PVC废料进行清洗，去除表面的杂质，然后对PVC废料进行晾晒和风干，接着将PVC废料送入破碎机破碎，然后经过分选机筛选收集粉体，然后放入离心机分离水分，再经过热空气干燥，使含水量下降到1％以下，得到PVC废料粉；
步骤2、按重量份计，称取如下原料：PVC废料粉300份、聚氯乙烯150份、聚己内酯30份、丙烯酸甲酯20份、三烯丙基异氰酸酯8份、杨梅蜡3份、乙烯-乙烯醇共聚物7份、邻苯二甲酸二甲酐9份、三盐基硫酸铅4份、聚甲基丙烯酸钠5份、双叔丁基过氧异丙基苯8份、氯磺化聚乙烯橡胶25份、聚乙烯醇缩丁醛4份、聚丙烯酸14份、碳酸氢铵10份、过氧化二异丙苯15份、十二烷基苯磺酸钠盐6份、过氧化新庚酸叔丁酯6份和过硫酸钾4份；按比例加入到混料机中，所述混料机中搅拌温度为30-40℃，搅拌转速120-150转/min，搅拌均匀得到混合料；将混合料加入反应釜中于100-120℃混合10-15min，然后用双螺杆挤出机挤出造粒，双螺杆挤出机温度190-210℃，双螺杆挤出机的螺杆转速为60转/min条件下熔融挤出改性粒料，然后改性粒料研磨成200-300目的粉料；
步骤3、将重量份计，将丁腈橡胶80份、粉料70份、发泡剂10份和乳化剂10份混合，投入搅拌机中搅拌20-30min；然后进行加热发泡、固化3-12h得到强韧耐磨橡塑制品，所述加热发泡温度为110-130℃、压力为0.01-0.5MPa，时间为10-600s。
Claims (5)
1.一种强韧耐磨橡塑制品的制备方法，其特征在于该方法包括以下步骤：
步骤1、对PVC废料进行清洗，去除表面的杂质，然后对PVC废料进行晾晒和风干，接着将PVC废料送入破碎机破碎，然后经过分选机筛选收集粉体，然后放入离心机分离水分，再经过热空气干燥，使含水量下降到1％以下，得到PVC废料粉；
步骤2、按重量份计，称取如下原料：PVC废料粉200-300份、聚氯乙烯100-150份、聚己内酯20-30份、丙烯酸甲酯10-20份、三烯丙基异氰酸酯2-8份、杨梅蜡2-3份、乙烯-乙烯醇共聚物4-7份、邻苯二甲酸二甲酐6-9份、三盐基硫酸铅1-4份、聚甲基丙烯酸钠4-5份、双叔丁基过氧异丙基苯3-8份、氯磺化聚乙烯橡胶20-25份、聚乙烯醇缩丁醛2-4份、聚丙烯酸12-14份、碳酸氢铵5-10份、过氧化二异丙苯10-15份、十二烷基苯磺酸钠盐2-6份、过氧化新庚酸叔丁酯4-6份和过硫酸钾1-4份；按比例加入到混料机中，搅拌均匀得到混合料；将混合料加入反应釜中于100-120℃混合10-15min，然后用双螺杆挤出机挤出造粒，得到改性粒料，然后改性粒料研磨成200-300目的粉料；
步骤3、将重量份计，将丁腈橡胶70-80份、粉料60-70份、发泡剂5-10份和乳化剂5-10份混合，投入搅拌机中搅拌20-30min；然后进行加热发泡、固化3-12h得到强韧耐磨橡塑制品。
2.根据权利要求1所述的一种强韧耐磨橡塑制品的制备方法，其特征在于：所述步骤3中，将重量份计，将丁腈橡胶75份、粉料65份、发泡剂8份和乳化剂8份混合投入搅拌机搅拌20-30min。
3.根据权利要求1所述的一种强韧耐磨橡塑制品的制备方法，其特征在于：所述在双螺杆挤出机温度190-210℃，双螺杆挤出机的螺杆转速为60转/min条件下熔融挤出。
4.根据权利要求1所述的一种强韧耐磨橡塑制品的制备方法，其特征在于：所述混料机中搅拌温度为30-40℃，搅拌转速120-150转/min。
5.根据权利要求1所述的一种强韧耐磨橡塑制品的制备方法，其特征在于：所述加热发泡温度为110-130℃、压力为0.01-0.5MPa，时间为10-600s。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011365814.7A CN112608536A (zh) | 2020-11-29 | 2020-11-29 | 一种强韧耐磨橡塑制品的制备方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202011365814.7A CN112608536A (zh) | 2020-11-29 | 2020-11-29 | 一种强韧耐磨橡塑制品的制备方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN112608536A true CN112608536A (zh) | 2021-04-06 |
Family
ID=75228044
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202011365814.7A Pending CN112608536A (zh) | 2020-11-29 | 2020-11-29 | 一种强韧耐磨橡塑制品的制备方法 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN112608536A (zh) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107418139A (zh) * | 2017-08-31 | 2017-12-01 | 苏州仲勉装饰有限公司 | 一种阻燃保温材料的制备方法 |
| KR20180035409A (ko) * | 2016-09-29 | 2018-04-06 | (주)엘지하우시스 | 폴리염화비닐 함유 가교 고무 폼 시트, 융착 적층체 및 폴리염화비닐 함유 가교 고무 폼 시트의 제조 방법 |
| CN108192242A (zh) * | 2018-01-08 | 2018-06-22 | 安徽以诺木塑板材科技有限公司 | 一种环保pvc木塑发泡板材及其制备方法 |
| CN108752670A (zh) * | 2018-05-31 | 2018-11-06 | 河北神州保温建材集团有限公司 | 一种橡塑共混发泡材料及其制备方法 |
-
2020
- 2020-11-29 CN CN202011365814.7A patent/CN112608536A/zh active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20180035409A (ko) * | 2016-09-29 | 2018-04-06 | (주)엘지하우시스 | 폴리염화비닐 함유 가교 고무 폼 시트, 융착 적층체 및 폴리염화비닐 함유 가교 고무 폼 시트의 제조 방법 |
| CN107418139A (zh) * | 2017-08-31 | 2017-12-01 | 苏州仲勉装饰有限公司 | 一种阻燃保温材料的制备方法 |
| CN108192242A (zh) * | 2018-01-08 | 2018-06-22 | 安徽以诺木塑板材科技有限公司 | 一种环保pvc木塑发泡板材及其制备方法 |
| CN108752670A (zh) * | 2018-05-31 | 2018-11-06 | 河北神州保温建材集团有限公司 | 一种橡塑共混发泡材料及其制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101580615B (zh) | 一种环保型瓷塑高分子复合材料配方及其制备方法 | |
| CN102382406B (zh) | 聚乙烯醇缩丁醛发泡材料 | |
| CN103992590B (zh) | 一种废旧塑料资源再生利用生产木塑材料的配方及其制备方法 | |
| CN109593163A (zh) | 一种聚丙烯基接枝物及其制备方法 | |
| CN102492213B (zh) | 一种滚塑级交联聚乙烯耐磨复合材料及其制备方法 | |
| CN106751095B (zh) | 含有l-poss交联剂的同质异构改性回收ps及其制备方法 | |
| CN112143125A (zh) | 一种聚氯乙烯材料及其制备方法 | |
| CN112608536A (zh) | 一种强韧耐磨橡塑制品的制备方法 | |
| CN112608589A (zh) | 一种环保保温橡塑制品的制备方法 | |
| CN112622087A (zh) | 一种湿法锂电池隔膜边角料回收造粒方法 | |
| CN113717439B (zh) | 一种改性风积沙增强增韧热塑性树脂建筑模板组合物及其制备方法 | |
| CN105440382A (zh) | 一种耐高温抗老化再生橡胶密封圈及其制备方法 | |
| CN112608567A (zh) | 一种耐老化耐腐橡塑制品的制备方法 | |
| CN112480597A (zh) | 一种防霉抗菌橡塑制品的制备方法 | |
| CN104817772A (zh) | 一种废旧发泡聚苯乙烯回收利用的新方法 | |
| CN108059782A (zh) | 一种聚氯乙烯塑料颗粒及其制备方法 | |
| CN114106481A (zh) | 一种增韧聚苯乙烯填充母料及其制备方法 | |
| EP1598164B1 (en) | Polymeric foam extrusion process | |
| CN113861515A (zh) | 一种可水溶性淀粉基包装缓冲填充物及其制备方法 | |
| CN102849985A (zh) | 环保石头纸及其制备方法 | |
| CN112299790A (zh) | 一种环保高性能混凝土及其制备方法 | |
| US9631766B2 (en) | Use of inorganic materials for producing composites | |
| CN112250950A (zh) | 一种聚丙烯再生塑料颗粒的制备方法 | |
| US3644576A (en) | Impact-resistant resinous blends containing vinyl chloride polymer and method of making same | |
| CN106496769B (zh) | 一种含有l-poss交联剂的同质异构交联法改性回收pp及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20210406 |
|
| RJ01 | Rejection of invention patent application after publication |