CN112482059A - 一种数码印花墨水配方 - Google Patents
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Abstract
本发明公开了一种数码印花墨水配方,涉及数码印花技术领域,数码印花墨水包括如下组分:活性染料、有机溶剂、防腐剂、表面活性剂、pH值调节剂、保湿剂、促染剂、固色剂、消泡剂、杀菌剂、粘度调节剂、助溶剂、去离子水,通过在墨水中加入保湿剂、促染剂、固色剂以及杀菌剂,使得制成的活性墨水具有抗氧化、易着色且着色牢固、抗菌和不变色的特点;采用多种表面活性剂的组合方式,选用具有低接触角及动态表面张力交底的表面活性剂,能够赋予墨水更好的流平性和润湿性;在常温下长期放置,PH值下降不明显,因此,不会因为储存时间过长而导致墨水酸性变强从而腐蚀喷头。
Description
技术领域
本发明涉及数码印花技术领域,具体是一种数码印花墨水配方。
背景技术
数码印花,是用数码技术进行的印花。数码印花技术是随着计算机技术不断发展而逐渐形成的一种集机械、计算机电子信息技术为一体的高新技术产品,这项技术的出现与不断完善,给纺织印染行业带来了一个全新的概念,其先进的生产原理及手段,给纺织印染带来了一个前所未有的发展机遇,数码印花也有着传统印花不可替代的优势,数码印花是将设计好的图案直接通过打印机打印出来,节省成本;数码印花可以满足个性化、小批量、多品种订单的需求,大大简化印前制版等工序,节约生产成本。因此,数码印花技术逐步替代传统的印花技术成为必然。作为数码印花中不可缺少的、决定印花效果的关键因素的印花墨水也要随之发展,作为数码喷墨印花主要耗材之一的印花墨水,也是决定喷墨印花技术成功与否的关键性因素。
但是目前数码喷墨印花所使用的墨水只能用于专属喷头,常用活性墨水因活性染料溶解度低难以配制高浓度活性染料墨水,墨水染料浓度越高稳定性相对越差,且墨水通用性、流畅性能差,仅能用于专用喷头,用于其他喷头就会出现大量断线或喷头堵塞现象,这一问题极大地阻碍了墨水的推广应用。
发明内容
本发明的目的在于提供一种数码印花墨水配方,以解决上述背景技术中提出的墨水染料浓度越高稳定性相对越差,且墨水通用性、流畅性能差的问题。
为实现上述目的,本发明提供如下技术方案:
一种数码印花墨水配方,包括如下重量份的组分:活性染料12-25份、有机溶剂8-24份、防腐剂0.2-0.4份、表面活性剂0.4-2.5份、pH值调节剂0.2-1份、保湿剂4-8份、促染剂4-12份、固色剂1-5份、消泡剂1-3份、杀菌剂1-4份、粘度调节剂2-4份、助溶剂3-7份、去离子水20-40份;
作为本发明进一步的方案:所述活性染料为C.I.活性黑5、活性黑8、活性黑39、C.I.活性黄85、C.I.活性黄95、C.I.活性红24、C.I.活性红141、C.I.活性红195、C.I.活性红218、C.I.活性红245、C.I.活性蓝5、C.I.活性蓝15、C.I.活性蓝49、C.I.活性蓝72、C.I.活性蓝74、C.I.活性橙2、C.I.活性橙5、C.I.活性橙12、C.I.活性橙13、C.I.活性棕19中的至少一种;
作为本发明再进一步的方案:所述粘度调节剂为1,5-戊二醇、1,2-丙二醇、二甲基亚砜、乙二醇苄醚、二甲基乙酰胺、三乙二醇、二乙二醇乙醚、聚乙二醇1000中的一种或几种的混合物;
作为本发明再进一步的方案:所述pH值控制剂为氢氧化钠、碳酸钠、碳酸氢钠、磷酸二氢钠、磷酸氢二钠、磷酸二氢钾、一乙醇胺、乳酸、柠檬酸、硫酸、盐酸中的一种或几种;
作为本发明再进一步的方案:所述保湿剂为三乙醇胺和甘油的混合物,所述促染剂为元明粉,所述助溶剂为尿素;
作为本发明再进一步的方案:所述固色剂为丁醚化三聚氰胺树脂和碱性水溶性树脂的混合物,所述助溶抑菌剂为柠檬酸和纳米钛白粉的混合物;
作为本发明再进一步的方案:所述消泡剂为乳化硅油,所述表面活性剂为脂肪醇聚氧乙烯醚硫酸钠;
作为本发明再进一步的方案:所述pH调节剂为三乙醇胺、氢氧化钠、碳酸钠、碳酸氢钠、磷酸二氢钠、二甲基乙醇胺、4-吗啉丙磺酸或氢氧化锂的任一种;
作为本发明再进一步的方案:所述粘度调节剂为丙三醇、二甘醇、丙二醇、二聚丙三醇中的一种或几种;
作为本发明再进一步的方案:所述杀菌剂为5-氯-2-甲基-4-异噻唑啉-3-酮;
作为本发明再进一步的方案:
所述所述促染剂由包含以下重量份的原料制成:
二乙烯三胺:25份;聚环氧氯丙烷二甲胺:50份;水:1000份。
所述数码印花墨水的制备包括以下步骤:步骤(a),配制重量百分含量为25-50%的二乙烯三胺;步骤(b),配制重量百分含量为20-25%的聚环氧氯丙烷-二甲胺;步骤(c),往浸渍缸中加入30-40份水,并将水加热升温至55-65℃;步骤(d),同时往温度为55-65℃的水中加入5-12份重量百分含量为25-50%的二乙烯三胺以及10-20份重量百分含量为20-25%的聚环氧氯丙烷-二甲胺,并保持整个体系的温度在55-65℃混合均匀,即可得到促染剂;
S1:按顺序将去离子水20-40份、活性染料12-25份、有机溶剂8-24份、防腐剂0.2-0.4份、表面活性剂0.4-2.5份、pH值调节剂0.2-1份、保湿剂4-8份、促染剂4-12份、固色剂1-5份、消泡剂1-3份、杀菌剂1-4份、粘度调节剂2-4份、助溶剂3-7份放入容器中搅拌;
S2:过滤,得到墨水。
作为本发明再进一步的方案:高速以400-700rpm的转速搅拌65-75分钟,过滤搅拌后的物料,先使用孔径为0.50μm滤膜过滤,再将滤液用孔径为0.24μm滤膜进行过滤,得到墨水成品。
与现有技术相比,本发明的有益效果是:
1)通过在墨水中加入保湿剂、促染剂、固色剂以及杀菌剂,使得制成的活性墨水具有抗氧化、易着色且着色牢固、抗菌和不变色的特点;
2)采用多种表面活性剂的组合方式,选用具有低接触角及动态表面张力交底的表面活性剂,能够赋予墨水更好的流平性和润湿性;
3)在常温下长期放置,PH值下降不明显,因此,不会因为储存时间过长而导致墨水酸性变强从而腐蚀喷头;并且,在长期储存的过程中不易水解产生一些难容的物质而造成墨水难以过滤而堵塞喷头,从而增加墨水的稳定性。
具体实施方式
下面结合具体实施方式对本发明的技术方案作进一步详细地说明。
为了使本技术领域的人员更好地理解本发明方案,下面将结合本发明实施例中的附图,对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分的实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都应当属于本发明保护的范围。
通过在墨水中加入保湿剂、促染剂、固色剂以及杀菌剂,使得制成的活性墨水具有抗氧化、易着色且着色牢固、抗菌和不变色的特点;采用多种表面活性剂的组合方式,选用具有低接触角及动态表面张力交底的表面活性剂,能够赋予墨水更好的流平性和润湿性,在常温下长期放置,PH值下降不明显,因此,不会因为储存时间过长而导致墨水酸性变强从而腐蚀喷头;并且,在长期储存的过程中不易水解产生一些难容的物质而造成墨水难以过滤而堵塞喷头,从而增加墨水的稳定性。
实施例1
取活性染料12份、有机溶剂8份、防腐剂0.2份、表面活性剂0.4份、pH值调节剂0.2份、保湿剂4份、固色剂1份、消泡剂1份、杀菌剂1份、粘度调节剂2份、助溶剂3份、去离子水20份;往浸渍缸中加入30份水,并将水加热升温至55℃,同时往温度为55℃的水中加入5份重量百分含量为25%的二乙烯三胺以及10份重量百分含量为20%的聚环氧氯丙烷-二甲胺,并保持整个体系的温度在55℃混合均匀,得到促染剂,按顺序将去离子水20份、活性染料12份、有机溶剂8份、防腐剂0.2份、表面活性剂0.4份、pH值调节剂0.2份、保湿剂4份、促染剂4份、固色剂1份、消泡剂1份、杀菌剂1份、粘度调节剂2份、助溶剂3份放入容器中搅拌,高速以400rpm的转速搅拌65分钟,过滤搅拌后的物料,先使用孔径为0.50μm滤膜过滤,再将滤液用孔径为0.24μm滤膜进行过滤,得到墨水成品。
实施例2
取活性染料14份、有机溶剂10份、防腐剂0.3份、表面活性剂0.6份、pH值调节剂0.4份、保湿剂5份、固色剂2份、消泡剂1.5份、杀菌剂1.5份、粘度调节剂2.5份、助溶剂4份、去离子水25份;往浸渍缸中加入30份水,并将水加热升温至60℃,同时往温度为60℃的水中加入7份重量百分含量为30%的二乙烯三胺以及12份重量百分含量为22%的聚环氧氯丙烷-二甲胺,并保持整个体系的温度在60℃混合均匀,得到促染剂,按顺序将去离子水25份、活性染料14份、有机溶剂8份、防腐剂0.3份、表面活性剂0.6份、pH值调节剂0.4份、保湿剂5份、固色剂2份、消泡剂1.5份、杀菌剂1.5份、粘度调节剂2.5份、助溶剂4份放入容器中搅拌,高速以450rpm的转速搅拌70分钟,过滤搅拌后的物料,先使用孔径为0.50μm滤膜过滤,再将滤液用孔径为0.24μm滤膜进行过滤,得到墨水成品。
实施例3
取活性染料18份、有机溶剂15份、防腐剂0.4份、表面活性剂1份、pH值调节剂0.6份、保湿剂6份、固色剂3份、消泡剂2份、杀菌剂2.5份、粘度调节剂3份、助溶剂4份、去离子水30份;往浸渍缸中加入35份水,并将水加热升温至65℃,同时往温度为65℃的水中加入9份重量百分含量为35%的二乙烯三胺以及15份重量百分含量为23%的聚环氧氯丙烷-二甲胺,并保持整个体系的温度在65℃混合均匀,得到促染剂,按顺序将去离子水30份、活性染料18份、有机溶剂15份、防腐剂0.4份、表面活性剂1份、pH值调节剂0.6份、保湿剂6份、固色剂3份、消泡剂2份、杀菌剂2.5份、粘度调节剂3份、助溶剂4份放入容器中搅拌,高速以500rpm的转速搅拌75分钟,过滤搅拌后的物料,先使用孔径为0.50μm滤膜过滤,再将滤液用孔径为0.24μm滤膜进行过滤,得到墨水成品。
实施例4
取活性染料20份、有机溶剂17份、防腐剂0.4份、表面活性剂1.5份、pH值调节剂0.8份、保湿剂7份、固色剂4份、消泡剂3份、杀菌剂3份、粘度调节剂3.5份、助溶剂5份、去离子水35份;往浸渍缸中加入40份水,并将水加热升温至65℃,同时往温度为65℃的水中加入10份重量百分含量为40%的二乙烯三胺以及18份重量百分含量为24%的聚环氧氯丙烷-二甲胺,并保持整个体系的温度在65℃混合均匀,得到促染剂,按顺序将去离子水35份、活性染料20份、有机溶剂17份、防腐剂0.4份、表面活性剂1.5份、pH值调节剂0.8份、保湿剂7份、固色剂4份、消泡剂3份、杀菌剂3份、粘度调节剂3.5份、助溶剂5份放入容器中搅拌,高速以600rpm的转速搅拌75分钟,过滤搅拌后的物料,先使用孔径为0.50μm滤膜过滤,再将滤液用孔径为0.24μm滤膜进行过滤,得到墨水成品。
实施例5
取活性染料20份、有机溶剂17份、防腐剂0.4份、表面活性剂1.5份、pH值调节剂0.8份、保湿剂7份、固色剂4份、消泡剂3份、杀菌剂3份、粘度调节剂3.5份、助溶剂5份、去离子水35份;往浸渍缸中加入40份水,并将水加热升温至65℃,同时往温度为65℃的水中加入10份重量百分含量为40%的二乙烯三胺以及18份重量百分含量为24%的聚环氧氯丙烷-二甲胺,并保持整个体系的温度在65℃混合均匀,得到促染剂,按顺序将去离子水35份、活性染料20份、有机溶剂17份、防腐剂0.4份、表面活性剂1.5份、pH值调节剂0.8份、保湿剂7份、固色剂4份、消泡剂3份、杀菌剂3份、粘度调节剂3.5份、助溶剂5份放入容器中搅拌,高速以600rpm的转速搅拌75分钟,过滤搅拌后的物料,先使用孔径为0.50μm滤膜过滤,再将滤液用孔径为0.24μm滤膜进行过滤,得到墨水成品。
实施例6
取活性染料25份、有机溶剂24份、防腐剂0.4份、表面活性剂2.5份、pH值调节剂1份、保湿剂8份、固色剂5份、消泡剂3份、杀菌剂4份、粘度调节剂4份、助溶剂7份、去离子水40份;往浸渍缸中加入40份水,并将水加热升温至65℃,同时往温度为65℃的水中加入12份重量百分含量为50%的二乙烯三胺以及20份重量百分含量为25%的聚环氧氯丙烷-二甲胺,并保持整个体系的温度在65℃混合均匀,得到促染剂,按顺序将去离子水40份、活性染料25份、有机溶剂24份、防腐剂0.4份、表面活性剂2.5份、pH值调节剂1份、保湿剂8份、固色剂5份、消泡剂3份、杀菌剂4份、粘度调节剂4份、助溶剂7份放入容器中搅拌,高速以700rpm的转速搅拌75分钟,过滤搅拌后的物料,先使用孔径为0.50μm滤膜过滤,再将滤液用孔径为0.24μm滤膜进行过滤,得到墨水成品。
实施例7
取活性染料20份、有机溶剂17份、防腐剂0.4份、表面活性剂1.5份、pH值调节剂0.8份、保湿剂7份、固色剂4份、消泡剂3份、杀菌剂3份、粘度调节剂3.5份、助溶剂5份、去离子水35份;往浸渍缸中加入30份水,并将水加热升温至55℃,同时往温度为55℃的水中加入5份重量百分含量为25%的二乙烯三胺以及10份重量百分含量为20%的聚环氧氯丙烷-二甲胺,并保持整个体系的温度在55℃混合均匀,得到促染剂,按顺序将去离子水35份、活性染料20份、有机溶剂17份、防腐剂0.4份、表面活性剂1.5份、pH值调节剂0.8份、保湿剂7份、固色剂4份、消泡剂3份、杀菌剂3份、粘度调节剂3.5份、助溶剂5份放入容器中搅拌,高速以600rpm的转速搅拌75分钟,过滤搅拌后的物料,先使用孔径为0.50μm滤膜过滤,再将滤液用孔径为0.24μm滤膜进行过滤,得到墨水成品。
实施例8
取活性染料13份、有机溶剂9份、防腐剂0.3份、表面活性剂0.6份、pH值调节剂0.4份、保湿剂4份、固色剂1.5份、消泡剂1.5份、杀菌剂1.5份、粘度调节剂2.5份、助溶剂4份、去离子水25份;往浸渍缸中加入40份水,并将水加热升温至65℃,同时往温度为65℃的水中加入10份重量百分含量为40%的二乙烯三胺以及18份重量百分含量为24%的聚环氧氯丙烷-二甲胺,并保持整个体系的温度在65℃混合均匀,得到促染剂,按顺序将去离子水25份、活性染料13份、有机溶剂9份、防腐剂0.3份、表面活性剂0.6份、pH值调节剂0.4份、保湿剂4份、固色剂1.5份、消泡剂1.5份、杀菌剂1.5份、粘度调节剂2.5份、助溶剂4份放入容器中搅拌,高速以600rpm的转速搅拌75分钟,过滤搅拌后的物料,先使用孔径为0.50μm滤膜过滤,再将滤液用孔径为0.24μm滤膜进行过滤,得到墨水成品。
实施例9
取活性染料23份、有机溶剂21份、防腐剂0.3份、表面活性剂2.2份、pH值调节剂0.8份、保湿剂8份、固色剂4份、消泡剂2.5份、杀菌剂3.5份、粘度调节剂3份、助溶剂6份、去离子水38份;往浸渍缸中加入40份水,并将水加热升温至65℃,同时往温度为65℃的水中加入12份重量百分含量为50%的二乙烯三胺以及20份重量百分含量为25%的聚环氧氯丙烷-二甲胺,并保持整个体系的温度在65℃混合均匀,得到促染剂,按顺序将去离子水38份、活性染料23份、有机溶剂21份、防腐剂0.3份、表面活性剂2.2份、pH值调节剂0.8份、保湿剂8份、固色剂4份、消泡剂2.5份、杀菌剂3.5份、粘度调节剂3份、助溶剂6份放入容器中搅拌,高速以700rpm的转速搅拌75分钟,过滤搅拌后的物料,先使用孔径为0.50μm滤膜过滤,再将滤液用孔径为0.24μm滤膜进行过滤,得到墨水成品。
本发明中提供的数码印花喷墨墨水,可应用到微压电、热发泡打印机;品质稳定可长时间储存,符合中华人民共和国轻工行业标准QB/T 2730-2005,本发明实施例1~9制备的产品评价结果列于表1:
表1
对比例1
对比例1与实施例5的不同之处在于,对比例1中不含促染剂,其余与实施例5相同;
对比例2
对比例2与实施例5的不同之处在于,对比例2中不含固色剂,其余与实施例5相同;
对比例3
对比例3与实施例5的不同之处在于,对比例3中不含促染剂和固色剂,其余与实施例5相同;
本发明对比例1~3制备的产品评价结果列于表2:
表2
综上所述,参照对比实施例1-9以及对比例1-3的实验数据,可知,通过在墨水中加入保湿剂、促染剂、固色剂以及杀菌剂,使得制成的活性墨水具有抗氧化、易着色且着色牢固、抗菌和不变色的特点;采用多种表面活性剂的组合方式,选用具有低接触角及动态表面张力交底的表面活性剂,能够赋予墨水更好的流平性和润湿性;在常温下长期放置,PH值下降不明显,因此,不会因为储存时间过长而导致墨水酸性变强从而腐蚀喷头;并且,在长期储存的过程中不易水解产生一些难容的物质而造成墨水难以过滤而堵塞喷头,从而增加墨水的稳定性。
上面对本发明的较佳实施方式作了详细说明,但是本发明并不限于上述实施方式,在本领域的普通技术人员所具备的知识范围内,还可以在不脱离本发明宗旨的前提下作出各种变化。
Claims (10)
1.一种数码印花墨水配方,其特征在于,包括如下重量份的组分:活性染料12-25份、有机溶剂8-24份、防腐剂0.2-0.4份、表面活性剂0.4-2.5份、pH值调节剂0.2-1份、保湿剂4-8份、促染剂4-12份、固色剂1-5份、消泡剂1-3份、杀菌剂1-4份、粘度调节剂2-4份、助溶剂3-7份、去离子水20-40份。
2.根据权利要求1所述的一种数码印花墨水配方,其特征在于,所述活性染料为C.I.活性黑5、活性黑8、活性黑39、C.I.活性黄85、C.I.活性黄95、C.I.活性红24、C.I.活性红141、C.I.活性红195、C.I.活性红218、C.I.活性红245、C.I.活性蓝5、C.I.活性蓝15、C.I.活性蓝49、C.I.活性蓝72、C.I.活性蓝74、C.I.活性橙2、C.I.活性橙5、C.I.活性橙12、C.I.活性橙13、C.I.活性棕19中的至少一种。
3.根据权利要求2所述的一种数码印花墨水配方,其特征在于,所述粘度调节剂为1,5-戊二醇、1,2-丙二醇、二甲基亚砜、乙二醇苄醚、二甲基乙酰胺、三乙二醇、二乙二醇乙醚、聚乙二醇1000中的一种或几种的混合物。
4.根据权利要求3所述的一种数码印花墨水配方,其特征在于,所述pH值控制剂为氢氧化钠、 碳酸钠、 碳酸氢钠、 磷酸二氢钠、 磷酸氢二钠、 磷酸二氢钾、一乙醇胺、 乳酸、 柠檬酸、 硫酸、 盐酸中的一种或几种;所述保湿剂为三乙醇胺和甘油的混合物,所述促染剂为元明粉,所述助溶剂为尿素。
5.根据权利要求4所述的一种数码印花墨水配方,其特征在于,所述固色剂为丁醚化三聚氰胺树脂和碱性水溶性树脂的混合物,所述助溶抑菌剂为柠檬酸和纳米钛白粉的混合物。
6.根据权利要求5所述的一种数码印花墨水配方,其特征在于,所述消泡剂为乳化硅油,所述表面活性剂为脂肪醇聚氧乙烯醚硫酸钠。
7.根据权利要求6所述的一种数码印花墨水配方,其特征在于,所述pH调节剂为三乙醇胺、氢氧化钠、 碳酸钠、 碳酸氢钠、 磷酸二氢钠、二甲基乙醇胺、4-吗啉丙磺酸或氢氧化锂的任一种;所述粘度调节剂为丙三醇、二甘醇、丙二醇、二聚丙三醇中的一种或几种。
8.根据权利要求7所述的一种数码印花墨水配方,其特征在于,所述杀菌剂为5-氯-2-甲基-4-异噻唑啉-3-酮。
9.根据权利要求8所述的一种数码印花墨水配方,其特征在于,所述促染剂由包含以下重量份的原料制成:
二乙烯三胺:25份;聚环氧氯丙烷二甲胺:50份;水:1000份;
所述促染剂的制备包括以下步骤:步骤(a),配制重量百分含量为25-50%的二乙烯三胺;步骤(b),配制重量百分含量为20-25%的聚环氧氯丙烷-二甲胺;步骤(c),往浸渍缸中加入30-40份水,并将水加热升温至55-65°C;步骤(d),同时往温度为55-65°C的水中加入5-12份重量百分含量为25-50%的二乙烯三胺以及10-20份重量百分含量为20-25%的聚环氧氯丙烷-二甲胺,并保持整个体系的温度在55-65°C混合均匀,即可得到促染剂。
10.根据权利要求1-9任一所述的一种数码印花墨水配方,其特征在于,所述的数码印花墨水的制备方法,包括以下步骤:
S1:按顺序将去离子水20-40份、活性染料12-25份、有机溶剂8-24份、防腐剂0.2-0.4份、表面活性剂0.4-2.5份、pH值调节剂0.2-1份、保湿剂4-8份、促染剂4-12份、固色剂1-5份、消泡剂1-3份、杀菌剂1-4份、粘度调节剂2-4份、助溶剂3-7份放入容器中搅拌,高速以400-700rpm的转速搅拌65-75分钟;
S2:过滤搅拌后的物料,先使用孔径为0.50μm滤膜过滤,再将滤液用孔径为0.24μm滤膜进行过滤,得到墨水成品。
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Publication number | Priority date | Publication date | Assignee | Title |
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CN114134733A (zh) * | 2021-12-30 | 2022-03-04 | 江苏德旺数码科技有限公司 | 一种水性染料墨水及其应用 |
CN115260833A (zh) * | 2022-07-19 | 2022-11-01 | 苏州大学 | 一种直喷型印花墨水及其制备方法与应用 |
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