CN112457696B - 一种基于喹啉类纳米金属-有机框架材料的自修复涂层及其制备方法 - Google Patents
一种基于喹啉类纳米金属-有机框架材料的自修复涂层及其制备方法 Download PDFInfo
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- CN112457696B CN112457696B CN202011177355.XA CN202011177355A CN112457696B CN 112457696 B CN112457696 B CN 112457696B CN 202011177355 A CN202011177355 A CN 202011177355A CN 112457696 B CN112457696 B CN 112457696B
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- quinoline
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- 239000013289 nano-metal-organic framework Substances 0.000 title claims abstract description 100
- 238000000576 coating method Methods 0.000 title claims abstract description 74
- 239000000463 material Substances 0.000 title claims abstract description 69
- 239000011248 coating agent Substances 0.000 title claims abstract description 68
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 239000013105 nano metal-organic framework Substances 0.000 title claims abstract description 25
- 238000002360 preparation method Methods 0.000 title claims description 14
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims abstract description 50
- 229910000165 zinc phosphate Inorganic materials 0.000 claims abstract description 50
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 47
- 238000005260 corrosion Methods 0.000 claims abstract description 21
- 229910000975 Carbon steel Inorganic materials 0.000 claims abstract description 19
- 239000010962 carbon steel Substances 0.000 claims abstract description 19
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 4
- 239000011159 matrix material Substances 0.000 claims abstract description 4
- 239000011572 manganese Substances 0.000 claims description 37
- 229910052748 manganese Inorganic materials 0.000 claims description 20
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 15
- 239000012153 distilled water Substances 0.000 claims description 13
- 239000011268 mixed slurry Substances 0.000 claims description 12
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 11
- 238000005303 weighing Methods 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 239000011259 mixed solution Substances 0.000 claims description 8
- 239000002966 varnish Substances 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 6
- YHUVMHKAHWKQBI-UHFFFAOYSA-N quinoline-2,3-dicarboxylic acid Chemical compound C1=CC=C2N=C(C(O)=O)C(C(=O)O)=CC2=C1 YHUVMHKAHWKQBI-UHFFFAOYSA-N 0.000 claims description 6
- 238000001291 vacuum drying Methods 0.000 claims description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- AFYNADDZULBEJA-UHFFFAOYSA-N bicinchoninic acid Chemical compound C1=CC=CC2=NC(C=3C=C(C4=CC=CC=C4N=3)C(=O)O)=CC(C(O)=O)=C21 AFYNADDZULBEJA-UHFFFAOYSA-N 0.000 claims description 5
- 239000002270 dispersing agent Substances 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000011521 glass Substances 0.000 claims description 5
- 239000012621 metal-organic framework Substances 0.000 claims description 5
- 239000003973 paint Substances 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 239000002244 precipitate Substances 0.000 claims description 3
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical compound C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 claims description 2
- 238000000498 ball milling Methods 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 abstract description 20
- 239000000758 substrate Substances 0.000 abstract description 7
- 230000004044 response Effects 0.000 abstract description 6
- 239000000945 filler Substances 0.000 abstract description 5
- 239000000049 pigment Substances 0.000 abstract description 4
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 abstract description 3
- 239000007864 aqueous solution Substances 0.000 abstract description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 3
- 230000001681 protective effect Effects 0.000 abstract description 3
- 239000003112 inhibitor Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 10
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 9
- 239000000843 powder Substances 0.000 description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 4
- 238000000227 grinding Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 3
- -1 polytetrafluoroethylene Polymers 0.000 description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 3
- 239000004810 polytetrafluoroethylene Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 2
- 238000013270 controlled release Methods 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000013005 self healing agent Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- HYFPVPNWNRFTMP-UHFFFAOYSA-N formic acid;manganese Chemical compound [Mn].OC=O HYFPVPNWNRFTMP-UHFFFAOYSA-N 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 230000004043 responsiveness Effects 0.000 description 1
- 238000004729 solvothermal method Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G83/00—Macromolecular compounds not provided for in groups C08G2/00 - C08G81/00
- C08G83/008—Supramolecular polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2150/00—Compositions for coatings
- C08G2150/90—Compositions for anticorrosive coatings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/328—Phosphates of heavy metals
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
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CN202011177355.XA CN112457696B (zh) | 2020-10-28 | 2020-10-28 | 一种基于喹啉类纳米金属-有机框架材料的自修复涂层及其制备方法 |
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CN114196031A (zh) * | 2021-09-04 | 2022-03-18 | 桂林理工大学 | 一种基于噻吩类MOFs的POTS超疏水改性材料的制备方法及应用 |
Citations (8)
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CN104861822A (zh) * | 2015-05-05 | 2015-08-26 | 沈阳化工大学 | 一种金属有机骨架/水性防腐涂料的制备方法 |
CN107417921A (zh) * | 2017-04-27 | 2017-12-01 | 桂林理工大学 | 一种金属有机框架化合物的合成及应用 |
CN107698625A (zh) * | 2017-09-25 | 2018-02-16 | 桂林理工大学 | 基于噻吩‑2,5‑二羧酸和邻菲啰啉构筑的金属有机框架化合物的合成及应用 |
CN109825866A (zh) * | 2019-04-15 | 2019-05-31 | 东北大学 | 一种合金自修复耐蚀微弧氧化涂层的制备方法 |
CN110079140A (zh) * | 2019-04-30 | 2019-08-02 | 中山大学 | 一种智能响应自修复防腐涂层材料和制备方法 |
CN110105843A (zh) * | 2019-04-30 | 2019-08-09 | 中山大学 | 一种刺激响应型自修复防腐涂层材料和制备方法 |
CN111234566A (zh) * | 2020-01-22 | 2020-06-05 | 湖南大学 | 一种酸碱双响应中空介孔二氧化硅复合纳米容器和自修复防腐蚀涂料及其制备方法 |
CN111518451A (zh) * | 2020-06-12 | 2020-08-11 | 浙江中泓新材料科技有限公司 | 一种环氧云铁中间漆 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7579049B2 (en) * | 2004-07-06 | 2009-08-25 | The Boeing Company | Nano-structured inorganic zinc phosphate corrosion protective coating for metal alloys |
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2020
- 2020-10-28 CN CN202011177355.XA patent/CN112457696B/zh active Active
Patent Citations (8)
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CN104861822A (zh) * | 2015-05-05 | 2015-08-26 | 沈阳化工大学 | 一种金属有机骨架/水性防腐涂料的制备方法 |
CN107417921A (zh) * | 2017-04-27 | 2017-12-01 | 桂林理工大学 | 一种金属有机框架化合物的合成及应用 |
CN107698625A (zh) * | 2017-09-25 | 2018-02-16 | 桂林理工大学 | 基于噻吩‑2,5‑二羧酸和邻菲啰啉构筑的金属有机框架化合物的合成及应用 |
CN109825866A (zh) * | 2019-04-15 | 2019-05-31 | 东北大学 | 一种合金自修复耐蚀微弧氧化涂层的制备方法 |
CN110079140A (zh) * | 2019-04-30 | 2019-08-02 | 中山大学 | 一种智能响应自修复防腐涂层材料和制备方法 |
CN110105843A (zh) * | 2019-04-30 | 2019-08-09 | 中山大学 | 一种刺激响应型自修复防腐涂层材料和制备方法 |
CN111234566A (zh) * | 2020-01-22 | 2020-06-05 | 湖南大学 | 一种酸碱双响应中空介孔二氧化硅复合纳米容器和自修复防腐蚀涂料及其制备方法 |
CN111518451A (zh) * | 2020-06-12 | 2020-08-11 | 浙江中泓新材料科技有限公司 | 一种环氧云铁中间漆 |
Non-Patent Citations (3)
Title |
---|
Recent Advances in Polymeric Nanocomposites of Metal-Organic Frameworks(MOFs);jun zhong,et al.;《polymers》;20191009(第11期);全文 * |
Synthesis of Mn-MOFs loaded zinc phosphate composite for water-based acrylic coatings with durable anticorrosion performance on mild steel;zesheng Chen,et al.;《RSC Advances》;20210115(第11期);全文 * |
基于金属有机框架材料的pH-响应型自修复防腐涂层研究;王杰;《中国优秀硕士学位论文全文数据库 工程科技I辑》;20190715;第42、49页 * |
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Application publication date: 20210309 Assignee: Nanning Richong Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980045033 Denomination of invention: A self-healing coating based on quinoline type nano metal organic framework material and its preparation method Granted publication date: 20220322 License type: Common License Record date: 20231101 Application publication date: 20210309 Assignee: GUANGXI SHENGWEI ENERGY TECHNOLOGY Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980045025 Denomination of invention: A self-healing coating based on quinoline type nano metal organic framework material and its preparation method Granted publication date: 20220322 License type: Common License Record date: 20231101 |
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Application publication date: 20210309 Assignee: Guilin Juge Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2023980044685 Denomination of invention: A self-healing coating based on quinoline type nano metal organic framework material and its preparation method Granted publication date: 20220322 License type: Common License Record date: 20231030 |
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