CN112424396B - 用于可持续产生氢气的连续方法 - Google Patents

用于可持续产生氢气的连续方法 Download PDF

Info

Publication number
CN112424396B
CN112424396B CN201980047876.2A CN201980047876A CN112424396B CN 112424396 B CN112424396 B CN 112424396B CN 201980047876 A CN201980047876 A CN 201980047876A CN 112424396 B CN112424396 B CN 112424396B
Authority
CN
China
Prior art keywords
zinc
tin
hydroxide
metal
solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201980047876.2A
Other languages
English (en)
Chinese (zh)
Other versions
CN112424396A (zh
Inventor
巴赫曼·阿米尼霍瑞
顾赛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of Surrey
Original Assignee
University of Surrey
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of Surrey filed Critical University of Surrey
Publication of CN112424396A publication Critical patent/CN112424396A/zh
Application granted granted Critical
Publication of CN112424396B publication Critical patent/CN112424396B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen; Reversible storage of hydrogen
    • C01B3/02—Production of hydrogen; Production of gaseous mixtures containing hydrogen
    • C01B3/06—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents
    • C01B3/08—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of inorganic compounds with metals
    • C01B3/10—Production of hydrogen; Production of gaseous mixtures containing hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen with inorganic reducing agents by reaction of inorganic compounds with metals by reaction of water vapour with metals
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/2455—Stationary reactors without moving elements inside provoking a loop type movement of the reactants
    • B01J19/2465—Stationary reactors without moving elements inside provoking a loop type movement of the reactants externally, i.e. the mixture leaving the vessel and subsequently re-entering it
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
    • C01B13/14—Methods for preparing oxides or hydroxides in general
    • C01B13/20—Methods for preparing oxides or hydroxides in general by oxidation of elements in the gaseous state; by oxidation or hydrolysis of compounds in the gaseous state
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
    • C01D1/00—Oxides or hydroxides of sodium, potassium or alkali metals in general
    • C01D1/02—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G1/00—Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general
    • C01G1/02—Oxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00—Compounds of zinc
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G9/00—Compounds of zinc
    • C01G9/02—Oxides; Hydroxides
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/02—Electrodes; Manufacture thereof not otherwise provided for characterised by shape or form
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/14—Electrolytic production, recovery or refining of metals by electrolysis of solutions of tin
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/16—Electrolytic production, recovery or refining of metals by electrolysis of solutions of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Electrochemistry (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
  • Electrolytic Production Of Metals (AREA)
CN201980047876.2A 2018-07-19 2019-07-18 用于可持续产生氢气的连续方法 Active CN112424396B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB1811785.3 2018-07-19
GBGB1811785.3A GB201811785D0 (en) 2018-07-19 2018-07-19 A continuous process for sustainable production of hydrogen
PCT/GB2019/052002 WO2020016580A2 (en) 2018-07-19 2019-07-18 A continuous process for sustainable production of hydrogen

Publications (2)

Publication Number Publication Date
CN112424396A CN112424396A (zh) 2021-02-26
CN112424396B true CN112424396B (zh) 2024-12-24

Family

ID=63364495

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201980047876.2A Active CN112424396B (zh) 2018-07-19 2019-07-18 用于可持续产生氢气的连续方法

Country Status (7)

Country Link
US (1) US12391547B2 (OSRAM)
EP (1) EP3824116A2 (OSRAM)
JP (1) JP7464996B2 (OSRAM)
CN (1) CN112424396B (OSRAM)
CA (1) CA3106028A1 (OSRAM)
GB (1) GB201811785D0 (OSRAM)
WO (1) WO2020016580A2 (OSRAM)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2631304A (en) * 2023-06-27 2025-01-01 Clean Hydrogen Ltd Hydrogen and Battery Storage
GB2632092A (en) * 2023-06-27 2025-01-29 Clean Hydrogen Ltd Multi-phase reactor for hydrogen production
DE102024107523B3 (de) * 2024-03-15 2025-03-06 Forschungszentrum Jülich GmbH Verfahren und eine Anlage zur Wasserstoffgewinnung
WO2025217599A1 (en) * 2024-04-12 2025-10-16 Peregrine Hydrogen Inc. Steam sulfurous material reforming and thermochemical cycles related thereto
EP4711476A1 (en) * 2024-09-16 2026-03-18 Energy 13 GmbH Process for preparing iron metal by reduction of iron oxide with hydrogen and device for implementing this process
WO2026074433A1 (en) 2024-10-01 2026-04-09 Fabio Ruggeri Process and system for producing hydrogen and/or syngas

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101746724A (zh) * 2009-12-25 2010-06-23 昆明理工大学 一种同时制取氢气与氧化锌粉体的方法
WO2013181261A2 (en) * 2012-05-31 2013-12-05 Marine Power Products Incorporated Method of and device for optimizing a hydrogen generating system
CN104919088A (zh) * 2012-09-19 2015-09-16 液体光有限公司 由二氧化碳生产羧酸的综合方法
JP2017190275A (ja) * 2016-04-15 2017-10-19 株式会社Ｋｓｆ 副生水素生成装置

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3928550A (en) * 1974-09-12 1975-12-23 Sun Ventures Inc Process for making hydrogen
US4332650A (en) * 1981-01-21 1982-06-01 Gas Research Institute Thermoelectrochemical process using copper oxide for producing hydrogen and oxygen from water
JP2001270701A (ja) * 2000-03-28 2001-10-02 Yutaka Tamaura 水の分解方法
JP2004529056A (ja) 2001-03-06 2004-09-24 アルケミックス・コーポレーション 水素の製造方法およびその用途
JP2005255505A (ja) 2004-03-15 2005-09-22 Kurita Water Ind Ltd 水素供給方法
JP5124728B2 (ja) * 2005-03-18 2013-01-23 国立大学法人東京工業大学 水素生成装置、レーザ還元装置、エネルギー変換装置、水素生成方法および発電システム
WO2010096392A2 (en) 2009-02-20 2010-08-26 Marine Power Products Corporation Method and apparatus for efficient on-demand production of h2 and o2 from water using waste heat and environmentally safe metals
FR2948654B1 (fr) * 2009-07-30 2015-01-16 Gerkaro Cogeneration d'energie electrique et d'hydrogene
SG193922A1 (en) * 2011-04-05 2013-11-29 Blacklight Power Inc H2o-based electrochemical hydrogen-catalyst power system
CA2841231C (en) 2011-07-08 2016-01-26 Institute Of Chemical Technology (Deemed University) Hydrogen production method by multi-step copper-chlorine thermochemical cycle
US10208384B2 (en) 2011-08-11 2019-02-19 Toyota Motor Engineering & Manufacturing North America, Inc. Efficient water oxidation catalysts and methods of oxygen and hydrogen production by photoelectrolysis
TW201504477A (zh) 2013-07-17 2015-02-01 第諾拉工業公司 電解電池和鹼溶液電解槽以及在電池內之電解方法
ES2643558B1 (es) * 2014-10-28 2018-09-19 Shell Internationale Research Maatschappij B.V. Proceso para producir hidrógeno líquido
JP6040511B2 (ja) 2015-03-31 2016-12-07 株式会社エクォス・リサーチ 太陽光利用システム
ITUB20159792A1 (it) * 2015-12-30 2017-06-30 Federico Longhini Sistema e procedimento per la generazione di idrogeno gassoso a richiesta
JP2017155315A (ja) 2016-03-04 2017-09-07 株式会社東芝 光電気化学反応装置

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101746724A (zh) * 2009-12-25 2010-06-23 昆明理工大学 一种同时制取氢气与氧化锌粉体的方法
WO2013181261A2 (en) * 2012-05-31 2013-12-05 Marine Power Products Incorporated Method of and device for optimizing a hydrogen generating system
CN104919088A (zh) * 2012-09-19 2015-09-16 液体光有限公司 由二氧化碳生产羧酸的综合方法
JP2017190275A (ja) * 2016-04-15 2017-10-19 株式会社Ｋｓｆ 副生水素生成装置

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
A highly efficient hydrogen generation electrolysis system using alkaline zinc hydroxide solution;Bahman Amini Horri et al.;《INTERNATIONAL JOURNAL OF HYDROGEN ENERGY》;第44卷;第72-81页 *

Also Published As

Publication number Publication date
WO2020016580A2 (en) 2020-01-23
US12391547B2 (en) 2025-08-19
JP2021531407A (ja) 2021-11-18
US20210261407A1 (en) 2021-08-26
JP7464996B2 (ja) 2024-04-10
EP3824116A2 (en) 2021-05-26
GB201811785D0 (en) 2018-09-05
CN112424396A (zh) 2021-02-26
WO2020016580A3 (en) 2020-03-12
CA3106028A1 (en) 2020-01-23

Similar Documents

Publication Publication Date Title
JP7464996B2 (ja) 水素の持続可能な生成のための継続的なプロセス
Liu et al. Tuning Sn3O4 for CO2 reduction to formate with ultra-high current density
US11447879B2 (en) Hydrogen generator
Horri et al. A highly efficient hydrogen generation electrolysis system using alkaline zinc hydroxide solution
Wang et al. Cation vacancy engineering in medium-entropy NiFeCoZn layered double hydroxides electrocatalysts for boosting oxygen evolution reaction in water-splitting
Zhang et al. Mechanism investigation of α-Ni (OH) 2 electrodeposition from a NiCl2 solution
CN112501640A (zh) 一种将硝酸盐废水转化为氨的电池系统
CN113355682B (zh) 铁掺杂三氟合钴酸盐析氧电催化材料、其制备方法及应用
Feng et al. Super-Hydrophilic/Aerophobic Co (OH) 2/NiFe Layered Double Hydroxide Heterostructures with Moderate Work Function Difference for Large-Current-Density Electrochemical Ammonia Synthesis
CN102021600A (zh) 一种利用氧阴极无隔膜电解生产碘酸钾的方法及装置
CN114059086A (zh) 一种基于酸性电解质两步电解制氢的装置和方法
Zhao et al. Spin polarization strategy to deploy proton resource over atomic-level metal sites for highly selective CO2 electrolysis
CN113355681B (zh) MNi(1-x)FexF3析氧电催化材料、其制备方法及应用
CN117026262A (zh) Co2电解系统及构建方法
CN113430561B (zh) 基于过渡金属盐的析氧电催化材料、其制备方法及应用
Liu et al. Modulating a1g-b1g-orbital occupied states of planar square-coordinated cobalt single-atom electrocatalyst for oxygen evolution reaction and rechargeable Zn-air batteries
Putri et al. Electrochemical study of nickel-cobalt deposited on boron-doped diamond as working electrodes for urea fuel cells
CN121773232A (zh) 用于产生氢气的多相反应器
CA3068148C (en) Hydrogen generator
JP2019151877A (ja) 二酸化炭素の還元方法および二酸化炭素還元装置
WO2025003670A1 (en) Hydrogen production and battery storage
KR20260072133A (ko) 수산화리튬의 제조방법 및 이를 위한 제조 시스템
CN119020794A (zh) 一种基于纯水体系的电还原co2的装置及方法
Zhaoyang et al. Tuning Interfacial Water Supply and Electron Transfer Enables Industrial-Scale Alkaline Hydrogen Evolution
Kundu Ni-Based Electrocatalysts for Oxygen Evolution Reaction

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant