CN112371690B - Direct and rapid forming device and method for recycling waste aluminum - Google Patents

Direct and rapid forming device and method for recycling waste aluminum Download PDF

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Publication number
CN112371690B
CN112371690B CN202011132254.0A CN202011132254A CN112371690B CN 112371690 B CN112371690 B CN 112371690B CN 202011132254 A CN202011132254 A CN 202011132254A CN 112371690 B CN112371690 B CN 112371690B
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aluminum
liquid
cleaning
waste
wire
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CN112371690A (en
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白培康
袁鑫隆
杨潇
赵占勇
张震
张文达
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North University of China
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B3/00Destroying solid waste or transforming solid waste into something useful or harmless
    • B09B3/40Destroying solid waste or transforming solid waste into something useful or harmless involving thermal treatment, e.g. evaporation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09BDISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
    • B09B5/00Operations not covered by a single other subclass or by a single other group in this subclass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y10/00Processes of additive manufacturing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y30/00Apparatus for additive manufacturing; Details thereof or accessories therefor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

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  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention belongs to the technical field of aluminum scrap recovery, and particularly relates to a direct and rapid molding device and a direct and rapid molding method for aluminum scrap recovery.

Description

Direct and rapid forming device and method for recycling waste aluminum
Technical Field
The invention belongs to the technical field of waste aluminum recovery, and particularly relates to a direct and rapid waste aluminum recovery molding device and method.
Background
Aluminum is the most abundant metal element in the earth crust, and aluminum alloy can be processed into various sectional materials due to low density, high strength and good plasticity, has excellent electrical conductivity, thermal conductivity and corrosion resistance, is widely applied to important fields of aerospace, automobiles, buildings and the like, and is an important raw material for national economic development.
Along with the increase of yield and usage amount, the amount of waste aluminum products is also larger and larger, but a plurality of aluminum products are disposable, the time from product preparation to product loss is short, the waste of a large amount of aluminum products becomes a pollution source, and the recovery and regeneration of waste aluminum becomes a very important work in all countries of the world; at present, a lot of studies on waste aluminum recovery and waste aluminum molding are carried out, but the combination of recovery and molding technologies is less, so that energy consumption and resource waste are caused, the production time is long, the working efficiency is low, the molding quality is poor, and the precision is not high.
Disclosure of Invention
In order to solve the technical problems, the invention provides a waste aluminum recovery direct and fast forming device and a method, which can combine the waste aluminum recovery remelting and laser melting forming technologies into a whole, directly and fast form the waste aluminum into an aluminum product, reduce the energy consumption and the consumption of auxiliary materials, save resources and cost, shorten the production flow period, and improve the forming quality and precision, and adopts the following technical scheme:
the utility model provides a direct rapid prototyping device is retrieved to aluminium scrap, includes preprocessing device, smelts device, aluminium silk forming device and laser melting device, and four devices set gradually and connect.
The pretreatment device comprises a feed inlet, an inclined plate, an electromagnetic iron removal device, an ultrasonic cleaning device and a liquid spraying cleaning device; the electromagnetic iron removing device comprises an electromagnetic iron remover, an external power supply and an iron scrap collecting box; the ultrasonic cleaning device comprises a first liquid inlet, a second liquid inlet, an ultrasonic transducer, a cleaning bin, a lower turning plate, a stainless steel wire filter screen, a first lifting baffle and a waste liquid collecting box; the spray cleaning device comprises a waste gas collecting device, a spray nozzle, an inclined plate, an air heater and a second lifting baffle; the pretreatment device is divided into a left part and a right part, a feed inlet is welded on the left side of the top of the box body, the electromagnetic iron remover is fixed on the wall of the box body through screws and is arranged right below the feed inlet, the electromagnetic iron remover is connected with an external power supply which is adhered on the left side of the box body, an iron scrap collecting box is arranged below the electromagnetic iron remover, the iron scrap collecting box is arranged in a sliding manner, and a waste liquid collecting box is arranged below the iron scrap collecting box; the right side is for wasing the storehouse, the stainless steel wire filter screen of left side welding in washing the storehouse, first liftable baffle is established in stainless steel wire filter screen left side, first liftable baffle passes through the gear shaft setting, the board is turned over under the bottom in washing the storehouse is passed through the gear shaft connection, from the top down welds first inlet in proper order on the wall of washing the storehouse right side, second inlet and ultrasonic transducer, turn over the board below left and right sides wall and weld first swash plate respectively down, hydrojet shower nozzle and exhaust gas collecting device are all being welded to first swash plate below, second liftable baffle is connected through the gear shaft to left side wall bottom, the air heater is established to right side wall bottom, the second swash plate is established in the air heater wind gap.
The smelting device comprises a heat insulation layer, a heat preservation layer, a gas protection device and a battery stirring device, wherein the battery stirring device comprises an electromagnetic stirring device, an external variable frequency power supply, a waste residue collecting box, a discharge hole, a nickel wire filter screen, a partition plate and an infrared heating pipe; smelt device top welding infrared heating pipe, the left side wall skin is the insulating layer, the left side wall inlayer is the heat preservation, the insulating layer links to each other with the heat preservation, welding gas protection device on the left side wall, welding electromagnetic stirring device in the middle of bottom heat preservation and the insulating layer, electromagnetic stirring device connects the external variable frequency power source who welds on the box, gear shaft connection baffle is established on the right side wall the left side, the welding nickel silk filter screen of baffle below, sliding connection's waste residue collecting box is established to nickel silk filter screen left side below.
The aluminum wire forming device comprises a tundish, a vibration inclined plate, a roller shoe cavity, an extrusion roller, an extrusion die, a material blocking block, a cooling system, a resistance wire heating device, an extrusion wire material and a cooling shoe; a discharge port of the smelting device is welded with a tundish, a vibration inclined plate is arranged at the bottom end of the tundish and is connected with a roller shoe cavity, an extrusion roller is arranged in the roller shoe cavity, an extrusion die is arranged on the right side of the extrusion die, a material blocking block is arranged below the extrusion die, a cooling shoe is arranged on the rear side of the extrusion die, the roller shoe cavity, the extrusion die, the material blocking block and the cooling shoe are welded together, an extruded wire is extruded and prepared by the extrusion die, a cooling system is positioned below the extruded wire and is welded on a shell, resistance wire heating devices are positioned on the upper side and the lower side of the extruded wire and are welded on the shell, and the extruded wire is connected to a laser melting device after being molded;
the laser melting device comprises a gas protection device, a cooling device, a flow control device, a crawler feeding device, a temperature control electromagnetic heating device, a laser, a forming cavity, an infrared temperature and distance measuring instrument, a data acquisition camera, a micro-melting laser and an aluminum substrate; inside being the shaping chamber that is of laser melting device, gaseous protection device is established to the left side wall, aluminium base board is established to the bottom, the data acquisition camera is established to the right side wall, establish the arm of multiaxis connection at the shaping chamber center, bolted connection is in the arm left side for cooling device, the arm mid portion from the top down is welded track material feeding unit, control by temperature change electromagnetic heating device and flow control device in proper order, arm right side welding laser instrument and little melting laser instrument, infrared temperature measurement distancer passes through bolted connection on the arm right side.
Further, the lower turning plate, the first lifting baffle and the second lifting baffle are all made of chromium-molybdenum-vanadium steel.
Furthermore, the heat insulation layer is a ceramic fiber board, and the heat insulation layer is made of ceramic refractory fibers.
Further, the second swash plate inclination angle is 30 °.
A direct and rapid molding method for recovering waste aluminum comprises the following steps:
s1: feeding waste aluminum scraps into a pretreatment device through a feed inlet, falling onto an electromagnetic iron remover and then transmitting the waste aluminum scraps, adsorbing the waste aluminum scraps on the electromagnetic iron remover and collecting the waste aluminum scraps into an iron scrap collecting box, falling into an ultrasonic cleaning device, respectively performing operations of paint removal, oil removal and the like in a cleaning bin under the action of an ultrasonic transducer, introducing a paint remover from a first liquid inlet to perform paint removal treatment, opening a first liftable baffle on the left side after the paint removal treatment is completed, allowing the paint remover to be collected into a waste liquid collecting box through a stainless steel wire filter screen, closing the first liftable baffle, introducing a cleaning liquid from a second liquid inlet to perform oil removal treatment, opening the first liftable baffle on the left side again after the oil removal treatment is completed, allowing the cleaning liquid to be collected into the waste liquid collecting box through the stainless steel wire filter screen, closing the first liftable baffle, and allowing the cleaning liquid to pass through the first liquid inlet, introducing water into the second liquid inlet, cleaning the treated aluminum scraps, opening the first lifting baffle on the left side again after cleaning is finished, allowing the water to pass through the stainless steel wire filter screen and be collected into the waste liquid collecting box, then opening the lower turning plate, allowing the aluminum scraps subjected to ultrasonic cleaning to fall into the liquid spraying cleaning device through the first inclined plate, and closing the lower turning plate after all the aluminum scraps uniformly fall into the second inclined plate in the liquid spraying cleaning device; spraying cleaning liquid through liquid spraying nozzles on two sides, further cleaning the aluminum scrap, then opening the air heater, collecting the cleaning liquid after cleaning the aluminum scrap into a waste gas collecting device in a volatilization mode, drying the aluminum scrap, and after the aluminum scrap after cleaning is dried, opening a second lifting baffle to enable the aluminum scrap to fall into the smelting device through a second inclined plate under the action of the wind power of the air heater;
s2: closing a partition plate below the smelting device, opening a gas protection device, melting waste aluminum scraps under the heating action of an infrared heating pipe under the protection of argon gas, stirring by using an electromagnetic stirring device to prepare liquid slurry with fluidity, then opening the partition plate and a nickel wire filter screen with a telescopic function, filtering the liquid slurry by using the nickel wire filter screen, feeding the liquid slurry into a tundish of a continuous extrusion device, and collecting filtered filter residues into a waste residue collection box;
s3: the method comprises the following steps that refined liquid slurry flows into a tundish firstly, is subjected to primary solidification on a vibration inclined plate, is solidified in a roller shoe cavity through a cooling shoe, is extruded into an aluminum wire through an extrusion die, is subjected to water quenching through a cooling system, is dried through a resistance wire heating device, and is finally connected into a laser melting device;
s4: in the laser melting device, firstly, argon gas is introduced into a forming cavity through a gas protection device, the forming cavity is in an inert gas protection environment, an aluminum wire is heated through a temperature control electromagnetic heating device, after the distance between a spray head and an aluminum substrate or a printed piece is measured through an infrared distance measuring and temperature measuring instrument, the heated aluminum wire is continuously delivered to the substrate or the printed piece through a crawler feeding device, the heated aluminum wire is continuously melted to the aluminum substrate through a laser, the wire feeding is limited by a flow control device after printing of each layer of printed surface is finished, meanwhile, the printed piece is corrected by a micro-melting laser and a cooling device, the whole process works under the monitoring of a data acquisition camera, and the accurate and rapid forming of an aluminum product is guaranteed.
Further, the type of the paint remover is one of JX-817, JX-821 and JX-827;
further, the cleaning solution is an N-acyl glutamate solution prepared by mixing N-acyl glutamate and alcohol at a temperature of 50-60 ℃ according to a ratio of 1:3-5, wherein the N-acyl glutamate is one of N-lauroyl sodium glutamate (LGS-11), V-cocoyl sodium glutamate (CGS-11), N-oleoyl triethanolamine glutamate (CGT-12), N-stearoyl sodium glutamate (HGS11) and NV-oleoyl sodium glutamate (OGS), and the alcohol is one of methanol and N-butanol;
further, the wind speed of the dried hot wind is 13m3/min-18m3The hot air temperature is 220-250 ℃, and the drying time is 60-80 min;
further, the heating temperature of the infrared heating pipe is 800-900 ℃, and the refining time is 60-90 min;
further, the drying temperature of the resistance wire heating device is 60-70 ℃, and the drying time is 30-50 min;
compared with the prior art, the invention has the following beneficial effects:
(1) the device combination realizes the integration of pretreatment and rapid forming of the waste aluminum scraps, so that the recovered waste aluminum scraps are directly formed into aluminum products, the preparation efficiency is improved, and the device has high application value;
(2) the device has the advantages of simple structure, convenient operation, less links, low energy consumption, energy conservation and environmental protection, can greatly improve the recovery and utilization rate of the waste aluminum, and greatly reduces the manufacturing cost of aluminum products;
(3) the problem in the printing process can be monitored, the precision of the formed part can be timely fed back and adjusted, and the rejection rate is reduced.
Drawings
FIG. 1 is a schematic structural view of a direct and rapid molding apparatus for recycling aluminum scrap;
FIG. 2 is a schematic view of the pretreatment apparatus shown in FIG. 1;
FIG. 3 is a schematic structural view of the smelting device in FIG. 1;
FIG. 4 is a schematic structural view of the aluminum wire forming apparatus shown in FIG. 1;
FIG. 5 is a schematic view of the laser melting apparatus of FIG. 1;
1. a pretreatment device; 101. an electromagnetic iron remover; 102. an iron scrap collecting box; 103. a first liquid inlet; 104. a second liquid inlet; 105. an ultrasonic transducer; 106. a lower turning plate; 107. a first inclined plate 108 and an exhaust gas collecting device; 109. a hot air blower; 110. a second swash plate; 111. a second liftable baffle; 112. a liquid spraying nozzle; 113. a waste liquid collection box; 114. a stainless steel wire filter screen; 115. a first liftable baffle; 116. an external power supply; 117. a feed inlet; 2. a smelting device; 201. a thermal insulation layer; 202. a heat-insulating layer; 203. a gas protection device; 204. an electromagnetic stirring device; 205. an external variable frequency power supply; 206. a waste residue collection box; 207. a discharge port; 208. a nickel wire filter screen; 209. a partition plate; 210. an infrared heating pipe; 3. a laser melting device; 3. an aluminum wire forming device; 301. a tundish; 302. a vibrating tilting plate; 303. a roller shoe cavity; 304. a squeeze roll; 305. extruding the die; 306. a material blocking block; 307. a cooling system; 308. a resistance wire heating device; 309. extruding the wire material; 310. a cooling shoe; 4. a laser melting device; 401. a gas protection device; 402. a cooling device; 403. a flow control device; 404. a crawler feeding device; 405. a temperature controlled electromagnetic heating device; 406. a laser; 407. a molding cavity; 408. an infrared temperature and distance measuring instrument; 409. a data acquisition camera; 410. a micro-melting laser; 411. an aluminum substrate.
Detailed Description
The invention will be further described with reference to the accompanying drawings.
Referring to fig. 1, a direct and rapid molding device for recycling aluminum scrap comprises a pretreatment device 1, a smelting device 2, an aluminum wire molding device 3 and a laser melting device 4, wherein the four devices are sequentially arranged and welded;
as shown in fig. 2, the pretreatment device 1 comprises a box body, an electromagnetic iron remover 101, an iron scrap collecting box 102, a first liquid inlet 103, a second liquid inlet 104, an ultrasonic transducer 105, a lower turning plate 106, a first inclined plate 107, a waste gas collecting device 108, an air heater 109, a second inclined plate 110, a second liftable baffle 111, a liquid spray nozzle 112, a waste liquid collecting box 113, a stainless steel wire filter screen 114, a first liftable baffle 115, an external power supply 116 and a feeding port 117, wherein the pretreatment device 1 is divided into a left part and a right part, the feeding port 117 is welded on the left side of the top of the box body, the electromagnetic iron remover 101 is fixed on the wall of the box body through screws and is under the feeding port 117, the electromagnetic iron remover 101 is connected with the external power supply 116 adhered on the left side of the box body, the iron scrap collecting box 102 is arranged below the electromagnetic iron remover 101, the iron scrap collecting box 102 is arranged in a sliding manner, and the waste liquid collecting box 113 is arranged below the iron scrap collecting box 102; the right side is a cleaning bin, the left side of the cleaning bin is welded with a stainless steel wire filter screen 114, the left side of the stainless steel wire filter screen 114 is provided with a first lifting baffle 115, the first lifting baffle 115 is arranged through a gear shaft, the bottom of the cleaning bin is connected with a lower turning plate 106 through the gear shaft, the right side wall of the cleaning bin is sequentially welded with a first liquid inlet 103, a second liquid inlet 104 and an ultrasonic transducer 105 from top to bottom, a first inclined plate 107 is respectively welded in the left side wall and the right side wall below the lower turning plate 106, a liquid spray nozzle 112 and a waste gas collecting device 108 are all welded below the first inclined plate 107, the bottom end of the left side wall below the lower turning plate 106 is connected with a second lifting baffle 111 through the gear shaft, a hot air blower 109 is arranged at the bottom of the right side wall below the lower turning plate 106, and the air opening of the hot air blower 109 is provided with a second inclined plate 110 with an inclination angle of 30 degrees; the waste aluminum scraps are subjected to impurity removal through an electromagnetic iron remover, an iron scrap collecting box, a waste liquid collecting box and a filter screen, and are subjected to oil removal and paint removal through an ultrasonic transducer and a paint remover, so that the forming precision of the waste aluminum is improved; iron fillings collecting box sliding connection conveniently clears up the iron fillings.
As shown in fig. 3, the smelting device 2 comprises a heat insulation layer 201, a heat insulation layer 202, a gas protection device 203 and a battery stirring device, wherein the battery stirring device comprises an electromagnetic stirring device 204, an external variable frequency power supply 205, a waste residue collection box 206, a discharge hole 207, a nickel wire filter screen 208, a partition 209 and an infrared heating pipe 210; an infrared heating pipe 210 is welded on the top of the smelting device 2, the outer layer of the left side wall is a heat insulation layer 201, the inner layer of the left side wall is a heat insulation layer 202, the heat insulation layer 201 is connected with the heat insulation layer 202, a gas protection device 203 is welded on the left side wall, an electromagnetic stirring device 204 is welded between the heat insulation layer and the bottom heat insulation layer, the electromagnetic stirring device 204 is connected with an external variable frequency power supply 205 welded on a box body, a gear shaft is arranged on the left side of the right side wall and connected with a partition plate 209, a nickel wire filter screen 208 is welded below the partition plate 209, and a waste residue collection box 206 in sliding connection is arranged below the left side of the nickel wire filter screen 208; the device is insulated through the insulating layer and the heat insulating layer, so that the loss of heat is reduced; the waste aluminum scraps are melted in the inert gas environment through the gas protection device, and impurities generated by oxidation are avoided.
As shown in fig. 4, the aluminum wire forming device 3 comprises a tundish 301, a vibration inclined plate 302, a roller shoe cavity 303, a pressing roller 304, a pressing die 305, a material blocking block 306, a cooling system 307, a resistance wire heating device 308, a pressed wire 309 and a cooling shoe 310; a discharge port 207 of a smelting device is welded with a tundish 301, a vibrating inclined plate 302 is arranged at the bottom end of the tundish 301, the vibrating inclined plate 302 is connected with a roller shoe cavity 303, an extrusion roller 304 is arranged in the roller shoe cavity 303, an extrusion die 305 is arranged on the right side, a material blocking block 306 is arranged below the extrusion die 305, a cooling shoe 310 is arranged on the rear side of the extrusion die 305, the roller shoe cavity 303, the extrusion die 305, the material blocking block 306 and the cooling shoe 310 are welded together, an extruded wire 309 is extruded and prepared by the extrusion die 305, a cooling system 307 is positioned below the extruded wire 309 and welded on a shell, resistance wire heating devices 308 are positioned on the upper side and the lower side of the extruded wire 309 and welded on the shell, and the extruded wire 309 is connected to a laser smelting device 4 after being molded; the liquid slurry is solidified through the roller shoe cavity, so that the extrusion forming is convenient; drying the water-quenched extruded wires by a resistance wire heating device to remove water stains on the surface.
As shown in fig. 5, the laser melting device 4 comprises a gas protection device 401, a cooling device 402, a flow control device 403, a crawler feeding device 404, a temperature-controlled electromagnetic heating device 405, a laser 406, a molding cavity 407, an infrared temperature and distance measuring instrument 408, a data acquisition camera 409, a micro-melting laser 410 and an aluminum substrate 411; the laser melting device 4 is internally provided with a forming cavity 407, the left side wall of the laser melting device is provided with a gas protection device 401, the bottom of the laser melting device is provided with an aluminum substrate 411, the right side wall of the laser melting device is provided with a data acquisition camera 409, the center of the forming cavity 407 is provided with a multi-shaft connected mechanical arm, a cooling device 402 is connected to the left side of the mechanical arm through bolts, the middle part of the mechanical arm is sequentially provided with a welded crawler feeding device 404, a temperature control electromagnetic heating device 405 and a flow control device 403 from top to bottom, the right side of the mechanical arm is welded with a laser 406 and a micro-melting laser 410, and an infrared temperature measuring and ranging instrument 408 is connected to the right side of the mechanical arm through bolts; the aluminum wire is continuously heated through the crawler feeding device, so that the molding precision is prevented from being influenced by uneven heating; the aluminum wire is continuously melted by the laser, so that the forming efficiency is improved; the wire feeding is limited by the flow control device, so that the adjustment is convenient, and the forming quality is improved; the formed part is corrected through the micro-melting laser and the cooling device, and the forming accuracy is improved.
A method for directly and quickly forming recovered waste aluminum comprises the following specific steps:
example one
S1: the waste aluminum scraps are fed into the pre-treatment furnace through the feed inlet 117In the treatment device 1, the waste scrap iron falls on the electromagnetic iron remover 101 and is driven along with the electromagnetic iron remover 101, the waste scrap iron is adsorbed on the electromagnetic iron remover 101 and is collected in the scrap iron collecting box 102, the waste aluminum scrap falls into the ultrasonic cleaning device, paint removal and oil removal are respectively carried out in the cleaning bin under the action of the ultrasonic transducer 105, paint remover is introduced from the first liquid inlet 103 for paint removal treatment, the paint remover is soaked in the paint remover for 4min for paint removal treatment, and the type of the paint remover is JX-817 paint remover; after depainting, opening the first lifting baffle 115 at the left side, allowing a depainting agent to be collected into the waste liquid collecting box 113 through the stainless steel wire filter screen 114, then closing the first lifting baffle 115, introducing a cleaning liquid from the second liquid inlet 104 for removing oil, wherein the cleaning liquid is an N-acyl glutamate solution prepared by N-stearyl sodium glutamate (HGS11) and methanol at a temperature of 55 ℃ according to a ratio of 1: 4; the first liftable baffle 115 at the left side is opened again, so that the cleaning solution is collected into the waste liquid collection tank 113 through the stainless steel wire filter screen 114, the first lifting baffle 115 is closed, after the cleaning solution is cleaned, the cleaning solution is discharged, water is introduced from the first liquid inlet 103 and the second liquid inlet 104, the treated aluminum scraps are cleaned, after the cleaning is finished, the first lifting baffle 115 at the left side is opened again, water is collected into the waste liquid collecting box 113 through the stainless steel wire filter screen 114, then, the lower turning plate 106 is opened, the waste aluminum scraps after ultrasonic cleaning fall into a liquid spraying cleaning device through a first inclined plate 107 for liquid spraying cleaning, the liquid spraying is sprayed out through liquid spraying nozzles 112 on two sides, the liquid spraying is a fluorocarbon organic solvent with the density of 1.7g/ml and the model of FC-4430, and the waste aluminum scraps all uniformly fall into a second inclined plate 110 in the liquid spraying cleaning device, and the lower turning plate 106 is closed; opening the hot air blower 109, collecting the cleaning liquid after cleaning the waste aluminum scraps into the waste gas collecting device 108 in a volatilization mode, and drying the waste aluminum scraps, wherein the wind speed of the dried hot air is 18m3The temperature of hot air is 230 ℃, the drying time is 70min, and after the drying is finished, a second lifting baffle is opened, so that the aluminum scraps are made to fall into the smelting device 2 under the action of the wind power of the hot air blower 109 through a second inclined plate 110;
s2: closing a partition 209 below the smelting device 2, opening a gas protection device 203, heating the waste aluminum scraps in an infrared heating pipe 210 with 380V voltage and 45KW power to 900 ℃ to smelt for 60min under the protection of argon gas, stirring by using an electromagnetic stirring device 204 with the frequency of 9Hz to prepare liquid slurry with fluidity, then opening the partition 209, filtering the liquid slurry by a nickel wire filter screen 208 with a telescopic function, feeding the liquid slurry into a tundish 301 of a continuous extrusion device, and collecting filtered filter residues in a waste residue collection box 206;
s3: casting the refined liquid slurry in an aluminum wire forming device 3 with the temperature of 700 ℃, solidifying the liquid slurry in a roller shoe cavity 303 of the device, and extruding the liquid slurry into aluminum wires with the diameter of 1.9mm through an extrusion die 305, wherein the rotating speed of an extrusion roller 304 is 6 rpm; water quenching is carried out through a cooling system 307, and the flow rate of water is 12L/min; drying the prepared aluminum wire by a resistance wire heating device 308 at 70 ℃ for 30 min;
s4: in the laser melting device 4, firstly, argon gas is introduced into the molding cavity 407 through the gas protection device 401, the molding cavity 407 is in the protection environment of inert gas, the aluminum wire is heated to 300-500 ℃ through the temperature control electromagnetic heating device 405, after the distance between the nozzle and the printed piece is measured through the infrared distance measuring thermometer 408, the caterpillar feeding device 404 continuously delivers the heated aluminum wires to an aluminum substrate with a thickness of 25mm, the laser 406 with power of 280W continuously melts the heated aluminum wires to the aluminum substrate 411, after printing of each layer of printing surface is finished, the flow control device limits wire feeding, the extrusion speed of the aluminum wire is 45mm/s, the forming speed is 40mm/s, the layering thickness is 0.15mm, meanwhile, the micro-melting laser 410 and the cooling device 402 correct the printed piece, and the whole process works under the monitoring of the data acquisition camera 409, so that the aluminum product is accurately and quickly molded.
Example two
S1: waste aluminum scraps enter the pretreatment device 1 through the feed inlet 117, fall on the electromagnetic iron remover 101 and are transmitted along with the electromagnetic iron remover, the waste aluminum scraps are adsorbed on the electromagnetic iron remover 101 and are collected in the scrap iron collecting box 102, the waste aluminum scraps fall into the ultrasonic cleaning device, under the action of the ultrasonic transducer 105, paint and oil are respectively removed in the cleaning bin, and paint remover is introduced from the first liquid inlet 103 to remove paintTreating, namely soaking the paint remover in the paint remover for 4min for paint removing treatment, wherein the type of the paint remover is JX-817; after depainting, opening the first lifting baffle 115 at the left side, allowing a depainting agent to be collected into the waste liquid collecting box 113 through the stainless steel wire filter screen 114, then closing the first lifting baffle 115, introducing a cleaning liquid from the second liquid inlet 104 for removing oil, wherein the cleaning liquid is an N-acyl glutamate solution prepared by N-stearyl sodium glutamate (HGS11) and methanol at a temperature of 55 ℃ according to a ratio of 1: 4; the first liftable baffle 115 at the left side is opened again, so that the cleaning solution is collected into the waste liquid collection tank 113 through the stainless steel wire filter screen 114, the first lifting baffle 115 is closed, after the cleaning solution is cleaned, the cleaning solution is discharged, water is introduced from the first liquid inlet 103 and the second liquid inlet 104, the treated aluminum scraps are cleaned, after the cleaning is finished, the first lifting baffle 115 at the left side is opened again, water is collected into the waste liquid collecting box 113 through the stainless steel wire filter screen 114, then, the lower turning plate 106 is opened, the waste aluminum scraps after ultrasonic cleaning fall into a liquid spraying cleaning device through a first inclined plate 107 for liquid spraying cleaning, the liquid spraying is sprayed out through liquid spraying nozzles 112 on two sides, the liquid spraying is a fluorocarbon organic solvent with the density of 1.7g/ml and the model of FC-4430, and the waste aluminum scraps all uniformly fall into a second inclined plate 110 in the liquid spraying cleaning device, and the lower turning plate 106 is closed; opening the hot air blower 109, collecting the cleaning liquid after cleaning the waste aluminum scraps into the waste gas collecting device 108 in a volatilization mode, and drying the waste aluminum scraps, wherein the wind speed of the dried hot air is 17m3The temperature of hot air is 235 ℃, the drying time is 70min, and after the drying is finished, a second lifting baffle is opened, so that the aluminum scraps are made to fall into the smelting device 2 under the action of the wind power of the hot air blower 109 through a second inclined plate 110;
s2: closing a partition 209 below the smelting device 2, opening a gas protection device 203, heating the waste aluminum scraps in an infrared heating pipe 210 with 380V voltage and 45KW power to 900 ℃ to smelt for 60min under the protection of argon gas, stirring by using an electromagnetic stirring device 204 with the frequency of 9Hz to prepare liquid slurry with fluidity, then opening the partition 209, filtering the liquid slurry by a nickel wire filter screen 208 with a telescopic function, feeding the liquid slurry into a tundish 301 of a continuous extrusion device, and collecting filtered filter residues in a waste residue collection box 206;
s3: casting the refined liquid slurry in an aluminum wire forming device 3 with the temperature of 700 ℃, solidifying the liquid slurry in a roller shoe cavity 303 of the device, and extruding the liquid slurry into aluminum wires with the diameter of 1.9mm through an extrusion die 305, wherein the rotating speed of an extrusion roller 304 is 6 rpm; water quenching is carried out through a cooling system 307, and the flow rate of water is 12L/min; drying the prepared aluminum wire by a resistance wire heating device 308 at 70 ℃ for 30 min;
s4: in the laser melting device 4, firstly, argon gas is introduced into the molding cavity 407 through the gas protection device 401, the molding cavity 407 is in the protection environment of inert gas, the aluminum wire is heated to 400-500 ℃ through the temperature control electromagnetic heating device 405, after the distance between the nozzle and the printed piece is measured through the infrared distance measuring thermometer 408, the caterpillar feeding device 404 continuously delivers the heated aluminum wires to an aluminum substrate with a thickness of 25mm, the laser 406 with power of 270W continuously melts the heated aluminum wires to the aluminum substrate 411, after printing of each layer of printing surface is finished, the flow control device limits wire feeding, the extrusion speed of the aluminum wire is 45mm/s, the forming speed is 40mm/s, the layering thickness is 0.19mm, meanwhile, the micro-melting laser 410 and the cooling device 402 correct the printed piece, and the whole process works under the monitoring of the data acquisition camera 409, so that the aluminum product is accurately and quickly molded.
EXAMPLE III
S1: waste aluminum scraps enter the pretreatment device 1 through a feed inlet 117, fall on the electromagnetic iron remover 101 and are transmitted along with the electromagnetic iron remover, the waste aluminum scraps are adsorbed on the electromagnetic iron remover 101 and are collected in the scrap iron collecting box 102, the waste aluminum scraps fall into an ultrasonic cleaning device, paint and oil are respectively removed in a cleaning bin under the action of an ultrasonic transducer 105, a paint remover is introduced from a first liquid inlet 103 for paint removal treatment, the waste aluminum scraps are soaked in the paint remover for 3min for paint removal treatment, and the type of the paint remover is JX-821; after paint removal, the first lifting baffle 115 at the left side is opened, the paint remover is collected into the waste liquid collecting box 113 through the stainless steel wire filter screen 114, then the first lifting baffle 115 is closed, cleaning liquid is introduced from the second liquid inlet 104 to remove oil, and the cleaning liquidIs N-acyl glutamic acid salt solution prepared by N-lauroyl sodium glutamate (LGS-11) and methanol at a temperature of 50 ℃ according to a ratio of 1: 3; the first liftable baffle 115 at the left side is opened again, so that the cleaning solution is collected into the waste liquid collection tank 113 through the stainless steel wire filter screen 114, the first lifting baffle 115 is closed, after the cleaning solution is cleaned, the cleaning solution is discharged, water is introduced from the first liquid inlet 103 and the second liquid inlet 104, the treated aluminum scraps are cleaned, after the cleaning is finished, the first lifting baffle 115 at the left side is opened again, water is collected into the waste liquid collecting box 113 through the stainless steel wire filter screen 114, then, the lower turning plate 106 is opened, the aluminum scraps after ultrasonic cleaning fall into a liquid spraying cleaning device through a first inclined plate 107 to be sprayed and cleaned, the sprayed liquid is sprayed out through liquid spraying nozzles 112 on two sides, the sprayed liquid is a fluorocarbon organic solvent with the density of 1.76/ml and the model of HCFC-l4lb, and the lower turning plate 106 is closed when all the aluminum scraps uniformly fall into a second inclined plate 110 in the liquid spraying cleaning device; the hot air blower 109 is opened, the cleaning liquid which has cleaned the waste aluminum scraps is collected into the waste gas collecting device 108 in a volatilization mode and the waste aluminum scraps are dried, and the wind speed of the dried hot air is 15m3The temperature of hot air is 220 ℃, the drying time is 80min, and after the drying is finished, a second lifting baffle is opened, so that the aluminum scraps are made to fall into the smelting device 2 under the action of the wind power of the hot air blower 109 through a second inclined plate 110;
s2: closing a partition 209 below the smelting device 2, opening a gas protection device 203, heating the waste aluminum scraps in an infrared heating pipe 210 with 380V voltage and 45KW power to 800 ℃ to smelt for 90min under the protection of argon gas, stirring by using an electromagnetic stirring device 204 with the frequency of 8Hz to prepare liquid slurry with fluidity, then opening the partition 209, filtering the liquid slurry by a nickel wire filter screen 208 with a telescopic function, feeding the liquid slurry into a tundish 301 of a continuous extrusion device, and collecting filtered filter residues in a waste residue collection box 206;
s3: casting the refined liquid slurry in an aluminum wire forming device 3 with the temperature of 730 ℃, solidifying the liquid slurry in a roller shoe cavity 303 of the device, and extruding the liquid slurry into aluminum wires with the diameter of 1.8mm through an extrusion die 305, wherein the rotating speed of an extrusion roller 304 is 7 rpm; water quenching is carried out through a cooling system 307, and the flow rate of water is 12L/min; heating device 308 via resistance wire
Drying the prepared aluminum wire at 60 ℃ for 50 min;
s4: in the laser melting device 4, firstly, argon gas is introduced into the molding cavity 407 through the gas protection device 401, the molding cavity 407 is in the protection environment of inert gas, the aluminum wire is heated to 300-500 ℃ through the temperature control electromagnetic heating device 405, after the distance between the nozzle and the printed piece is measured through the infrared distance measuring thermometer 408, the caterpillar feeding device 404 continuously delivers the heated aluminum wire to the aluminum substrate with the thickness of 20mm, the laser 406 with the power of 220W continuously melts the heated aluminum wire to the aluminum substrate 411, after printing of each layer of printing surface is finished, the flow control device limits wire feeding, the extrusion speed of the aluminum wire is 45mm/s, the forming speed is 50mm/s, the layering thickness is 0.2mm, meanwhile, the micro-melting laser 410 and the cooling device 402 correct the printed piece, and the whole process works under the monitoring of the data acquisition camera 409, so that the aluminum product is accurately and quickly molded.
The above description is only for the purpose of illustrating the preferred embodiments of the present invention and is not to be construed as limiting the invention, and any modifications, equivalents and improvements made within the spirit and principles of the present invention are intended to be included therein.

Claims (10)

1. A direct and rapid forming device for aluminum scrap recovery comprises a pretreatment device (1), a smelting device (2), an aluminum wire forming device (3) and a laser melting device (4), and is characterized in that the pretreatment device (1) comprises a feed inlet (117), an electromagnetic iron removal device, an ultrasonic cleaning device and a spray liquid cleaning device; the electromagnetic iron removal device comprises an electromagnetic iron remover (101), an external power supply (116) and an iron scrap collecting box (102); the ultrasonic cleaning device comprises a first liquid inlet (103), a second liquid inlet (104), an ultrasonic transducer (105), a cleaning bin, a lower turning plate (106), a stainless steel wire filter screen (114), a first lifting baffle (115) and a waste liquid collecting box (113); the spray cleaning device comprises an exhaust gas collecting device (108), a spray nozzle (112), a first inclined plate (107), a second inclined plate (110), a hot air blower (109) and a second lifting baffle (111); the pretreatment device (1) is divided into a left part and a right part, a feed inlet (117) is welded on the left side of the top of the box body, the electromagnetic iron remover (101) is fixed on the wall of the box body through screws and is arranged right below the feed inlet (117), the electromagnetic iron remover (101) is connected with an external power supply (116) adhered to the left side of the box body, an iron scrap collecting box (102) is arranged below the electromagnetic iron remover (101), the iron scrap collecting box (102) is arranged in a sliding mode, and a waste liquid collecting box (113) is arranged below the iron scrap collecting box (102); the right side is a cleaning bin, a stainless steel wire filter screen (114) is welded on the left side of the cleaning bin, a first lifting baffle (115) is arranged on the left side of the stainless steel wire filter screen (114), the first lifting baffle (115) is arranged through a gear shaft, the bottom of the cleaning bin is connected with a lower turning plate (106) through the gear shaft, a first liquid inlet (103) is sequentially welded on the right side wall of the cleaning bin from top to bottom, a second liquid inlet (104) and an ultrasonic transducer (105), wherein a first inclined plate (107) is respectively welded in the left side wall and the right side wall below the lower turning plate (106), a liquid spray nozzle (112) and a waste gas collecting device (108) are respectively welded below the first inclined plates (107) on both sides, the bottom end of the left side wall below the lower turning plate (106) is connected with a second lifting baffle (111) through a gear shaft, a hot air blower (109) is arranged at the bottom of the right side wall below the lower turning plate (106), and a second inclined plate (110) is arranged at an air opening of the hot air blower (109);
the smelting device (2) comprises a heat insulation layer (201), a heat insulation layer (202), a gas protection device (203) and a battery stirring device, wherein the battery stirring device comprises an electromagnetic stirring device (204), an external variable frequency power supply (205), a waste residue collection box (206), a discharge hole (207), a nickel wire filter screen (208), a partition plate (209) and an infrared heating pipe (210); an infrared heating pipe (210) is welded at the top of the smelting device (2), a heat insulation layer (201) is arranged on the outer layer of the left side wall, a heat insulation layer (202) is arranged on the inner layer of the left side wall, the heat insulation layer (201) is connected with the heat insulation layer (202), a gas protection device (203) is welded on the left side wall, an electromagnetic stirring device (204) is welded between the heat insulation layer and the heat insulation layer, the electromagnetic stirring device (204) is connected with an external variable frequency power supply (205) welded on the box body, a gear shaft is arranged on the left side of the right side wall and connected with a partition plate (209), a nickel wire filter screen (208) is welded below the partition plate (209), and a waste residue collecting box (206) in sliding connection is arranged below the left side of the nickel wire filter screen (208);
the aluminum wire forming device (3) comprises a tundish (301), a vibration inclined plate (302), a roller shoe cavity (303), an extrusion roller (304), an extrusion die (305), a material blocking block (306), a cooling system (307), a resistance wire heating device (308), an extrusion wire (309) and a cooling shoe (310); a discharge port (207) of a smelting device is welded with a tundish (301), a vibration inclined plate (302) is arranged at the bottom end of the tundish (301), the vibration inclined plate (302) is connected with a roller shoe cavity (303), an extrusion roller (304) is arranged in the roller shoe cavity (303), an extrusion die (305) is arranged on the right side, a material blocking block (306) is arranged below the extrusion die (305), a cooling shoe (310) is arranged on the rear side of the extrusion die (305), the roller shoe cavity (303), the extrusion die (305), the material blocking block (306) and the cooling shoe (310) are welded together, an extruded wire (309) is extruded and prepared by the extrusion die (305), a cooling system (307) is positioned below the extruded wire (309) and welded on the shell, resistance wire heating devices (308) are positioned on the upper side and the lower side of the extruded wire (309) and welded on the shell, and the extruded wire (309) is connected to a laser smelting device (4) after being molded;
the laser melting device (4) comprises a gas protection device (401), a cooling device (402), a flow control device (403), a crawler feeding device (404), a temperature control electromagnetic heating device (405), a laser (406), a molding cavity (407), an infrared temperature measurement range finder (408), a data acquisition camera (409), a micro-melting laser (410) and an aluminum substrate (411); the laser melting device (4) is internally provided with a forming cavity (407), the left side wall is provided with a gas protection device (401), the bottom of the laser melting device is provided with an aluminum substrate (411), the right side wall is provided with a data acquisition camera (409), the center of the forming cavity (407) is provided with a multi-shaft connected mechanical arm, a cooling device (402) is connected to the left side of the mechanical arm by bolts, the middle part of the mechanical arm is sequentially provided with a welded crawler feeding device (404), a temperature control electromagnetic heating device (405) and a flow control device (403) from top to bottom, the right side of the mechanical arm is welded with a laser (406) and a micro-melting laser (410), and an infrared temperature and distance measuring instrument (408) is connected to the right side of the mechanical arm by bolts;
the pretreatment device (1), the smelting device (2), the aluminum wire forming device (3) and the laser melting device (4) are sequentially arranged.
2. The direct and rapid molding device for aluminum scrap recovery according to claim 1, wherein the lower turning plate (106), the first liftable baffle (115) and the second liftable baffle (111) are all made of chrome molybdenum vanadium steel.
3. The direct rapid prototyping apparatus of aluminum scrap recycling according to claim 1 wherein the angle of inclination of the second inclined plate (110) is 30 °.
4. The direct and rapid prototyping device for aluminum scrap recycling according to claim 1, wherein the heat insulation layer (201) is a ceramic fiber board, the heat insulation layer (202) is a ceramic refractory fiber, and the partition plate (209) is made of chromium molybdenum vanadium steel.
5. A direct and rapid molding method for recycling waste aluminum is characterized by comprising the following steps:
s1: waste aluminum scraps enter a pretreatment device through a feed inlet (117), fall onto an electromagnetic iron remover (101) and are transmitted along with the electromagnetic iron remover, the waste iron scraps are adsorbed on the electromagnetic iron remover (101) and are collected in an iron scrap collecting box (102), the waste aluminum scraps fall into an ultrasonic cleaning device, paint and oil are respectively removed in a cleaning bin under the action of an ultrasonic transducer (105), paint remover is introduced from a first liquid inlet (103) for paint removal, after the paint removal treatment is finished, a first lifting baffle (115) on the left side is opened, the paint remover is collected in a waste liquid collecting box (113) through a stainless steel wire filter screen (114), then the first lifting baffle (115) on the left side is closed, cleaning liquid is introduced from a second liquid inlet (104) for oil removal, the first lifting baffle (115) on the left side is opened, and cleaning liquid is collected in the waste liquid collecting box (113) through the stainless steel wire filter screen (114), closing the first lifting baffle (115), introducing water from the first liquid inlet (103) and the second liquid inlet (104), cleaning the treated aluminum scraps, opening the first lifting baffle (115) on the left side again after the cleaning is finished, collecting the water into a waste liquid collecting box (113) through a stainless steel wire filter screen (114), opening the lower turning plate (106), enabling the aluminum scraps subjected to ultrasonic cleaning to fall into the spray liquid cleaning device through a first inclined plate (107), and closing the lower turning plate (106) after all the aluminum scraps uniformly fall into a second inclined plate (110) in the spray liquid cleaning device; cleaning liquid is sprayed out through liquid spraying nozzles (112) on two sides to further clean the aluminum scrap, then an air heater (109) is opened, the cleaning liquid which cleans the aluminum scrap is collected into a waste gas collecting device (108) in a volatilization mode and dries the aluminum scrap, and after the cleaned aluminum scrap is dried, a second lifting baffle is opened to allow the aluminum scrap to fall into a smelting device (2) under the wind force of the air heater (109) through a second inclined plate (110);
s2: closing a partition plate (209) below the smelting device (2), opening a gas protection device (203), melting waste aluminum scraps under the heating action of an infrared heating pipe (210) under the protection of argon gas, stirring by using an electromagnetic stirring device (204) to prepare liquid slurry with fluidity, then opening the partition plate (209), filtering the liquid slurry by using a flexible nickel wire filter screen (208), feeding the liquid slurry into a tundish (301) of an aluminum wire forming device (3), and collecting filtered filter residues into a waste residue collecting box (206);
s3: the method comprises the following steps that refined liquid slurry flows into a tundish (301), primary solidification is carried out in a vibration inclined plate (302), the primarily solidified liquid slurry is solidified in a roller shoe cavity (303) through a cooling shoe (310), extruded into aluminum wires through an extrusion die (305), water quenching is carried out through a cooling system (307), the prepared aluminum wires are dried through a resistance wire heating device (308), and finally the aluminum wires are connected into a laser melting device (4);
s4: in the laser melting device (4), argon gas is introduced into a forming cavity (407) through a gas protection device (401), the forming cavity (407) is made to be in an inert gas protection environment, an aluminum wire is heated through a temperature control electromagnetic heating device (405), after the distance between a spray head and an aluminum substrate or a printed piece is measured through an infrared temperature measurement range finder (408), the heated aluminum wire is continuously delivered to the aluminum substrate (411) or the printed piece through a crawler feeding device (404), the heated aluminum wire is continuously melted onto the aluminum substrate (411) through a laser (406), the flow control device limits wire feeding after printing of each layer of printed surface is finished, meanwhile, a micro-melting laser (410) and a cooling device (402) correct the printed piece, the whole process works under the monitoring of a data acquisition camera (409), and accurate and rapid forming of an aluminum product is guaranteed.
6. The direct and rapid prototyping method for aluminum scrap recycling according to claim 5, wherein the type of the paint remover is one of JX-817, JX-821 and JX-827.
7. The direct and rapid prototyping method for aluminum scrap recycling according to claim 5, wherein said cleaning solution is an N-acyl glutamate solution prepared by mixing N-acyl glutamate and alcohols at a temperature of 50 ℃ to 60 ℃ in proportion; the N-acyl glutamate is one of N-lauroyl sodium glutamate, N-oleoyl triethanolamine glutamate and N-stearoyl sodium glutamate; the alcohol is one of methanol and n-butanol.
8. The direct and rapid prototyping method for aluminum scrap recycling according to claim 5, wherein the drying hot wind speed is 13m3/min-18m3The hot air temperature is 220-250 ℃, and the drying time is 60-80 min.
9. The direct and rapid molding method for aluminum scrap recovery according to claim 5, wherein the heating temperature of the infrared heating pipe is 800-900 ℃, and the refining time is 60-90 min.
10. The direct and rapid molding method for aluminum scrap recovery according to claim 5, wherein the drying temperature of the resistance wire heating device is 60 ℃ to 70 ℃, and the drying time is 30min to 50 min.
CN202011132254.0A 2020-10-21 2020-10-21 Direct and rapid forming device and method for recycling waste aluminum Active CN112371690B (en)

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CN110835697A (en) * 2019-11-29 2020-02-25 中北大学 Method for directly preparing aluminum alloy refiner by recycling waste aluminum
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CN205341471U (en) * 2015-12-16 2016-06-29 重庆奥博铝材制造有限公司 Old and useless aluminium washs recovery unit
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