CN112341174A - 一种具有保健功能的功能陶瓷及其制备方法 - Google Patents

一种具有保健功能的功能陶瓷及其制备方法 Download PDF

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CN112341174A
CN112341174A CN202010719938.4A CN202010719938A CN112341174A CN 112341174 A CN112341174 A CN 112341174A CN 202010719938 A CN202010719938 A CN 202010719938A CN 112341174 A CN112341174 A CN 112341174A
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王誉富
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Abstract

本发明公开一种具有保健功能的功能陶瓷,其包括载体陶瓷以及喷涂在载体陶瓷上表面的涂层陶瓷涂料,载体陶瓷包括:麦饭石30‑40,黑竹炭40‑50,二氧化锗15‑20,Fe2O3 15‑20,FeO 15‑20,SnO2 3‑8,电气石20‑30,负离子粉40‑50,黑云母10‑20,钠长石10‑12,粘土10‑12,蒸馏水10‑15;涂层陶瓷涂料包括:二氧化锗3‑8,氧化镁4‑9,胶原蛋白2‑6,粘多糖蛋白2‑6,西藏牦牛脊骨4‑8,黄牛脊骨4‑8,磷酸酯2‑6,陶瓷釉4‑10,蒸馏水适量。本申请的陶瓷具有保健功能。

Description

一种具有保健功能的功能陶瓷及其制备方法
技术领域
本发明涉及陶瓷技术领域,特别涉及一种具有保健功能的功能陶瓷及其制备方法。
背景技术
骨骼是组成脊椎动物内骨骼的坚硬器官,功能是运动、支持和保护身体以及储藏身体重要的矿物质,尤其是钙和磷。
骨是由有机物和无机物组成的,有机物主要是蛋白质,使骨骼具有一定韧度,无机物主义总是钙质和磷质,使骨具有一定的硬度。
骨主要由骨质、骨髓和骨膜三部分构成。骨髓里面有丰富的血管和神经组织。长骨两端和扁骨的骨松质内仍终生保持着造血功能。
骨膜是覆盖在骨表面的结缔组织,里面有丰富的血管和神经,起着营养骨质的作用,同时骨膜内还有成骨细胞,能增生固层,能使受损的骨组织愈合和再生。成骨细胞和破骨细胞在不断反复地进行着建造和破坏骨骼的工作。
发明内容
本发明所要解决的技术问题是提供一种具有保健功能的功能陶瓷以及其制备方法。
本发明所要解决的技术问题是通过以下技术方案来实现的:
一种具有保健功能的功能陶瓷,所述陶瓷包括载体陶瓷以及喷涂在所述载体陶瓷上表面的涂层陶瓷涂料,所述载体陶瓷包括以下重量份组份:麦饭石30-40,黑竹炭40-50,二氧化锗15-20,Fe2O3 15-20,FeO 15-20,SnO2 3-8,电气石20-30,负离子粉40-50,黑云母10-20,钠长石10-12,粘土10-12,蒸馏水10-15;所述涂层陶瓷涂料包括以下重量份组份:二氧化锗3-8,氧化镁4-9,胶原蛋白2-6,粘多糖蛋白2-6,西藏牦牛脊骨4-8,黄牛脊骨4-8,磷酸酯2-6,陶瓷釉4-10,蒸馏水适量。
优选地,上述技术方案中,所述载体陶瓷包括以下重量份组份:麦饭石 35-38,黑竹炭44-49,二氧化锗15-20,Fe2O3 15-18,FeO 15-18,SnO2 3-8,电气石25-28,负离子粉45-48,黑云母15-18,钠长石10-12,粘土10-12,蒸馏水10-15;所述涂层陶瓷涂料包括以下重量份组份:二氧化锗4-8,氧化镁5-9,胶原蛋白3-6,粘多糖蛋白3-6,西藏牦牛脊骨4-8,黄牛脊骨4-8,磷酸酯2-6,陶瓷釉6-9,蒸馏水适量。
优选地,上述技术方案中,所述载体陶瓷包括以下重量份组份:麦饭石 35,黑竹炭48,二氧化锗20,Fe2O3 18,FeO 18,SnO2 7,电气石25,负离子粉48,黑云母18,钠长石12,粘土10,蒸馏水10;所述涂层陶瓷涂料包括以下重量份组份:二氧化锗6,氧化镁6,胶原蛋白4,粘多糖蛋白4,西藏牦牛脊骨8,黄牛脊骨8,磷酸酯4,陶瓷釉7,蒸馏水适量。
优选地,上述技术方案中,所述载体陶瓷中各原料的粒度均为10-30μm,所述陶瓷涂料中各原料的粒度均为1-10μm。
一种具有保健功能的功能陶瓷的制备方法,包括以下步骤:
(1)载体陶瓷的制备:
(11)按重量份称取上述载体陶瓷的原料,并将粉末状的原料混合;
(12)将步骤(11)的混合料在球化造粒内机造成粒度为200-300μm 的微粒;
(13)将步骤(12)得到的微粒在50-200℃温度下烘干;
(14)将烘干后的微粒在15000MPa压力机上压制成型;
(15)将压制成型后的载体陶瓷压片体放入马弗炉内,在氮气保护下常压烧结,烧结温度为1000-1300℃,烧结时间1-3小时;
(16)停烧后在炉内自然冷却至室温,取出,待用;
(2)涂层陶瓷涂料的制备:
(21)按重量份称取上述涂层陶瓷的原料,并将粉末状的原料混合;
(22)将(21)中所有原料混合在球化造粒机内造成粒度为200-300μm 的水性涂层陶瓷涂料;
(3)陶瓷的制备:
(31)将步骤(22)制备的涂层陶瓷涂料以刷或喷涂的方式涂在(16) 制备好的载体陶瓷压片体的上表面;
(32)将步骤(31)处理后的载体陶瓷在50-200℃下烘干1-3小时;
(33)将烘干后的载体陶瓷放入马弗炉内,在氮气的保护下常压下烧结,烧结温度500-900℃,烧结时间为1-3小时;
(34)停烧后再炉内自然冷却至室温,取出,得目的陶瓷。
优选地,上述技术方案中,成型体是厚度为5mm的正六边形片状体。
优选地,上述技术方案中,步骤(33)的烧结温度为700℃,烧结时间为 2小时。
麦饭石是一种硅铝酸盐矿石,主要成分包括二氧化硅、三氧化二铝、三氧化二铁、氧化亚铁、氧化镁、氧化钾、二氧化钛、五氧化二磷、氧化锰等。麦饭石有保健功能。麦饭石中的二氧化硅和三氧化二铝是化工催化剂的良好载体,起到吸附催化活性组分,分散活性组分的作用。三氧化二铁、氧化亚铁、氧化镁和氧化钾能活化细胞。
黑竹炭,竹炭是以三年生以上高山毛竹为原料,经近千度高温烧制而成的一种碳。竹炭具有质量坚硬,比表面积大,有疏松多孔结构材料,具有强的吸附性,能把载体陶瓷所有组份均匀吸附其表面,因此能将多种功能陶瓷材料制成强度较高的载体陶瓷。高质量的竹炭还能辐射远红外光能量。本申请优选比表面积大于800m2/g,更优选950m2/g-1000m2/g。
锗原子序数是32,是一种稀有金属半导体材料,是防治细胞疾病最关键材料之一。
Fe2O3、FeO和SnO2三种组分同麦饭石、二氧化锗、电气石、负离子粉等功能陶瓷材料一样,均匀分布于多孔结构的,比表面积大的竹炭中,为细胞供氧,排除二氧化碳。
电气石是一种以含硼为特征的,含铝、钠、铁、镁、锂的硅酸盐矿物,能够释放负离子,防治细胞病。
负离子粉提高载体陶瓷释放负离子浓度。
黑云母是一种填充材料。
钠长石是架状硅酸盐结构,主要作用是降低陶瓷的烧结温度。
粘土是一种硅铝酸盐,能够增加载体功能陶瓷成型强度。
蒸馏水是一种挥发性液体,因表面张力大,增加各种原料粉末颗粒间亲和力。
二氧化锗活化细胞;氧化镁能保持和调节细胞内外离子平衡;胶原蛋白、粘多糖蛋白、牦牛脊骨、黄牛脊骨和磷酸酯能为骨骼、脊髓提供能量,促进骨骼骨髓生长发育。
陶瓷釉是一种陶瓷粘合剂,会使涂层陶瓷涂料的配方成分粘合一起喷涂在载体功能陶瓷压片体的上表面,经烘干,烧结后形成功能陶瓷。
本发明上述技术方案,具有如下有益效果:
本申请的功能陶瓷具有保健功能。
附图说明
图1为本发明的功能陶瓷、参考资料与人体所发射的红外光谱的示意图。
具体实施方式
下面对本发明的具体实施例进行详细描述,以便于进一步理解本发明。以下实施例中所有使用的实验方法如无特殊说明,均为常规方法。以下实施例中所用的材料、试剂等,如无特殊说明,均可通过商业途径获得。
实施例1
一种具有保健功能的功能陶瓷,该陶瓷包括载体陶瓷以及喷涂在载体陶瓷表面的涂层陶瓷。
该载体陶瓷包括以下重量份(kg):麦饭石35,黑竹炭48,二氧化锗20, Fe2O3 18,FeO 18,SnO2 7,电气石25,负离子粉48,钠长石12,黑云母 18,粘土10,蒸馏水10;
该涂层陶瓷包括以下重量份(kg):二氧化锗6,氧化镁6,胶原蛋白4,粘多糖蛋白4,西藏牦牛脊骨8,黄牛脊骨8,磷酸酯4,陶瓷釉7,蒸馏水适量。
该功能陶瓷的制备方法,包括以下步骤:
(1)载体陶瓷的制备:
(11)按重量份称取上述载体陶瓷的原料,并将粉末状的原料混合;
(12)将步骤(11)的混合料在球化造粒内机造成粒度为200-300μm 的微粒;
(13)将步骤(12)得到的微粒在200℃温度下烘干2小时;
(14)将烘干后的微粒在15000MPa压力机上压制成型;
(15)将压制成型后的载体陶瓷压片体放入马弗炉内,在氮气保护下常压烧结,烧结温度为1200℃,烧结时间2小时;
(16)停烧后在炉内自然冷却至室温,取出,待用;
(2)涂层陶瓷涂料的制备:
(21)按重量份称取上述涂层陶瓷的原料,并将粉末状的原料混合;
(22)将(21)中所有原料混合在球化造粒机内造成粒度为200-300μm 的水性涂层陶瓷涂料;
(3)功能陶瓷的制备:
(31)将步骤(22)制备的涂层陶瓷涂料以刷或喷涂的方式涂在(16) 制备好的载体陶瓷压片体的上表面;
(32)将步骤(31)处理后的载体陶瓷在200℃下烘干2小时;
(33)将烘干后的载体陶瓷放入马弗炉内,在氮气的保护下常压下烧结,烧结温度900℃,烧结时间为2小时;
(34)停烧后再炉内自然冷却至室温,取出,得目的陶瓷。
性能指标测定:
负离子释放浓度70400个/分·cm2
极近红外光、近红外光和中红外光辐射强度为0.81-0.83。
实施例2
一种具有保健功能的功能陶瓷,该陶瓷包括载体陶瓷以及喷涂在载体陶瓷表面的涂层陶瓷。
该载体陶瓷包括以下重量份(kg):麦饭石35,黑竹炭49,二氧化锗20, Fe2O3 18,FeO 18,SnO2 8,电气石25,负离子粉48,钠长石12,黑云母 18,粘土10,蒸馏水10;
该涂层陶瓷包括以下重量份(kg):二氧化锗8,氧化镁9,胶原蛋白6,粘多糖蛋白6,西藏牦牛脊骨10,黄牛脊骨10,磷酸酯4,陶瓷釉7,蒸馏水适量。
该功能陶瓷的制备方法与实施例1相似,不同之处在于涂层陶瓷的烧结温度为500℃。
性能指标测定:
负离子释放浓度56200个/分·cm2
极近红外光、近红外光和中红外光辐射强度为0.74-0.77。
实施例3
一种具有保健功能的功能陶瓷,该陶瓷包括载体陶瓷以及喷涂在载体陶瓷表面的涂层陶瓷。
该载体陶瓷包括以下重量份(kg):麦饭石38,黑竹炭44,二氧化锗20, Fe2O3 15,FeO 15,SnO2 3,电气石28,负离子粉45,钠长石10,黑云母 15,粘土12,蒸馏水10;
该涂层陶瓷包括以下重量份(kg):二氧化锗6,氧化镁6,胶原蛋白4,粘多糖蛋白4,西藏牦牛脊骨8,黄牛脊骨8,磷酸酯6,陶瓷釉7,蒸馏水适量。
该功能陶瓷的制备方法与实施例1相似,不同之处在于涂层陶瓷的烧结温度为700℃。性能指标测定:
负离子释放浓度71300个/分·cm2
极近红外光、近红外光和中红外光辐射强度为0.84-0.93。
实施例4
一种具有保健功能的功能陶瓷,该陶瓷包括载体陶瓷以及喷涂在载体陶瓷表面的涂层陶瓷。
该载体陶瓷包括以下重量份(kg):麦饭石30,黑竹炭50,二氧化锗20, Fe2O3 15,FeO 20,SnO2 6,电气石20,负离子粉50,钠长石12,黑云母 10,粘土10,蒸馏水10;
该涂层陶瓷包括以下重量份(kg):二氧化锗6,氧化镁6,胶原蛋白4,粘多糖蛋白4,西藏牦牛脊骨8,黄牛脊骨8,磷酸酯4,陶瓷釉9,蒸馏水适量。
该功能陶瓷的制备方法与实施例1相似,不同之处在于造粒粒度为 100-200μm。
性能指标测定:
负离子释放浓度71400个/分·cm2
极近红外光、近红外光和中红外光辐射强度为0.80-0.83。
实施例5
一种具有保健功能的功能陶瓷,该陶瓷包括载体陶瓷以及喷涂在载体陶瓷表面的涂层陶瓷。
该载体陶瓷包括以下重量份(kg):麦饭石40,黑竹炭40,二氧化锗20, Fe2O3 20,FeO 15,SnO2 3,电气石30,负离子粉40,钠长石10,黑云母 20,粘土12,蒸馏水10;
该涂层陶瓷包括以下重量份(kg):二氧化锗6,氧化镁6,胶原蛋白4,粘多糖蛋白4,西藏牦牛脊骨8,黄牛脊骨8,磷酸酯4,陶瓷釉9,蒸馏水适量。
该功能陶瓷的制备方法与实施例1相似,不同之处在于造粒粒度为 100-200μm。
性能指标测定:
负离子释放浓度72300个/分·cm2
极近红外光、近红外光和中红外光辐射强度为0.84-0.92。
比较例1
该功能陶瓷包括载体陶瓷和喷涂在载体陶瓷上表面的涂层陶瓷。
载体陶瓷和涂层陶瓷的组份均与实施例1相同。
该功能陶瓷的制备方法与实施例1相似,不同之处在于涂层陶瓷的球化造粒的粒度为100-200μm。
性能指标测定:
负离子释放浓度56900个/分·cm2
极近红外光、近红外光和中红外光辐射强度为0.77-0.83。
比较例2
该功能陶瓷包括载体陶瓷和喷涂在载体陶瓷上表面的涂层陶瓷。
载体陶瓷和涂层陶瓷的组份均与实施例1相同。
该功能陶瓷的制备方法与实施例1相似,不同之处在于涂层陶瓷的球化造粒的粒度为300-400μm。
性能指标测定:
负离子释放浓度56400个/分·cm2
极近红外光、近红外光和中红外光辐射强度为0.75-0.78。
通过上述实施例和对比例之间的对比发现,本申请中涂层陶瓷的制备,最佳优选的球化造粒的粒度为200-300μm最优选的烧结温度为700℃。
虽然本发明已以实施例公开如上,然其并非用于限定本发明,任何本领域技术人员,在不脱离本发明的精神和范围内,均可作各种不同的选择和修改,因此本发明的保护范围由权利要求书及其等同形式所限定。

Claims (7)

1.一种具有保健功能的功能陶瓷,其特征在于,所述陶瓷包括载体陶瓷以及喷涂在所述载体陶瓷上表面的涂层陶瓷涂料,所述载体陶瓷包括以下重量份组份:麦饭石30-40,黑竹炭40-50,二氧化锗15-20,Fe2O3 15-20,FeO 15-20,SnO2 3-8,电气石20-30,负离子粉40-50,黑云母10-20,钠长石10-12,粘土10-12,蒸馏水10-15;所述涂层陶瓷涂料包括以下重量份组份:二氧化锗3-8,氧化镁4-9,胶原蛋白2-6,粘多糖蛋白2-6,西藏牦牛脊骨4-8,黄牛脊骨4-8,磷酸酯2-6,陶瓷釉4-10,蒸馏水适量。
2.根据权利要求1所述的一种具有保健功能的功能陶瓷,其特征在于,所述载体陶瓷包括以下重量份组份:麦饭石35-38,黑竹炭44-49,二氧化锗15-20,Fe2O3 15-18,FeO 15-18,SnO2 3-8,电气石25-28,负离子粉45-48,黑云母15-18,钠长石10-12,粘土10-12,蒸馏水10-15;所述涂层陶瓷涂料包括以下重量份组份:二氧化锗4-8,氧化镁5-9,胶原蛋白3-6,粘多糖蛋白3-6,西藏牦牛脊骨4-8,黄牛脊骨4-8,磷酸酯2-6,陶瓷釉6-9,蒸馏水适量。
3.根据权利要求2所述的一种具有保健功能的功能陶瓷,其特征在于,所述载体陶瓷包括以下重量份组份:麦饭石35,黑竹炭48,二氧化锗20,Fe2O3 18,FeO 18,SnO2 7,电气石25,负离子粉48,黑云母18,钠长石12,粘土10,蒸馏水10;所述涂层陶瓷涂料包括以下重量份组份:二氧化锗6,氧化镁6,胶原蛋白4,粘多糖蛋白4,西藏牦牛脊骨8,黄牛脊骨8,磷酸酯4,陶瓷釉7,蒸馏水适量。
4.根据权利要求3所述的一种具有保健功能的功能陶瓷,其特征在于,所述载体陶瓷中各原料的粒度均为10-30μm,所述陶瓷涂料中各原料的粒度均为1-10μm。
5.根据权利要求1-4任一所述的一种具有保健功能的功能陶瓷的制备方法,其特征在于,包括以下步骤:
(1)载体陶瓷的制备:
(11)按重量份称取上述载体陶瓷的原料,并将粉末状的原料混合;
(12)将步骤(11)的混合料在球化造粒内机造成粒度为200-300μm的微粒;
(13)将步骤(12)得到的微粒在50-200℃温度下烘干;
(14)将烘干后的微粒在15000MPa压力机上压制成型;
(15)将压制成型后的载体陶瓷压片体放入马弗炉内,在氮气保护下常压烧结,烧结温度为1000-1300℃,烧结时间1-3小时;
(16)停烧后在炉内自然冷却至室温,取出,待用;
(2)涂层陶瓷涂料的制备:
(21)按重量份称取上述涂层陶瓷的原料,并将粉末状的原料混合;
(22)将(21)中所有原料混合在球化造粒机内造成粒度为200-300μm的水性涂层陶瓷涂料;
(3)陶瓷的制备:
(31)将步骤(22)制备的涂层陶瓷涂料以刷或喷涂的方式涂在(16)制备好的载体陶瓷压片体的上表面;
(32)将步骤(31)处理后的载体陶瓷在50-200℃下烘干1-3小时;
(33)将烘干后的载体陶瓷放入马弗炉内,在氮气的保护下常压下烧结,烧结温度500-900℃,烧结时间为1-3小时;
(34)停烧后再炉内自然冷却至室温,取出,得目的陶瓷。
6.根据权利要求5所述的一种的健康具有保健功能的功能陶瓷的制备方法,其特征在于,成型体是厚度为5mm的正六边形片状体。
7.根据权利要求5所述的一种具有保健功能的功能陶瓷的制备方法,其特征在于,步骤(33)的烧结温度为700℃,烧结时间为2小时。
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