CN112322061A - Straw composite material degradable lunch box and preparation process thereof - Google Patents

Straw composite material degradable lunch box and preparation process thereof Download PDF

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Publication number
CN112322061A
CN112322061A CN202011032689.8A CN202011032689A CN112322061A CN 112322061 A CN112322061 A CN 112322061A CN 202011032689 A CN202011032689 A CN 202011032689A CN 112322061 A CN112322061 A CN 112322061A
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China
Prior art keywords
parts
straw
lunch box
raw materials
composite
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CN202011032689.8A
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Chinese (zh)
Inventor
胡喜庆
胡国庆
胡庆泉
曹倩倩
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Suzhou Hexin Food Packaging Co ltd
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Suzhou Hexin Food Packaging Co ltd
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Priority to CN202011032689.8A priority Critical patent/CN112322061A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Wrappers (AREA)

Abstract

The invention discloses a straw composite material degradable lunch box and a preparation process thereof, belonging to the technical field of degradable lunch boxes and comprising the following components in parts by weight: 20-30 parts of starch, 30-40 parts of straw, 5-10 parts of silk fibroin fiber, 20-30 parts of composite biochar, 10-20 parts of polyethylene, 10-20 parts of lignocellulose aerogel, 10-20 parts of polylactic acid and 5-8 parts of a coupling agent. The addition of the composite biochar, the starch and the straw can reduce the use of polyethylene, so that the use of raw materials is reduced, and the environment-friendly effect is achieved; the added lignocellulose aerogel can be mixed with the starch and the straws to be wrapped, so that the water and oil leakage is prevented.

Description

Straw composite material degradable lunch box and preparation process thereof
Technical Field
The invention relates to a degradable lunch box and a preparation process thereof, in particular to a straw composite material degradable lunch box and a preparation process thereof, belonging to the technical field of degradable lunch boxes.
Background
The degradable lunch box is tableware which can generate biochemical reaction under the action of natural environment microorganisms and enzymes to cause the appearance to be mildewed to change to the internal quality and finally form carbon dioxide and water.
The existing degradable lunch box has the following defects: the existing degradable lunch box is easy to leak in the using process, which causes the food to spill.
Disclosure of Invention
The invention mainly aims to solve the defects of the prior art and provides a straw composite material degradable lunch box and a preparation process thereof.
The purpose of the invention can be achieved by adopting the following technical scheme:
a straw composite material degradable lunch box comprises the following components in parts by weight: 20-30 parts of starch, 30-40 parts of straw, 5-10 parts of silk fibroin fiber, 20-30 parts of composite biochar, 10-20 parts of polyethylene, 10-20 parts of lignocellulose aerogel, 10-20 parts of polylactic acid and 5-8 parts of a coupling agent.
Preferably, the composition comprises the following components in parts by weight: 20-25 parts of starch, 30-35 parts of straw, 5-8 parts of silk fibroin fiber, 20-25 parts of composite biochar, 15-20 parts of polyethylene, 10-20 parts of lignocellulose aerogel, 10-15 parts of polylactic acid and 5-8 parts of a coupling agent.
Preferably, the composition comprises the following components in parts by weight: 23 parts of starch, 32 parts of straw, 7 parts of silk fibroin fiber, 24 parts of composite biochar, 18 parts of polyethylene, 18 parts of lignocellulose aerogel, 13 parts of polylactic acid and 7 parts of coupling agent.
Preferably, the silk fibroin fibers are degummed in a sodium carbonate solution for 3-4 times during adding.
Preferably, the composite biochar is a mixture formed by mixing and fermenting wheat straws, seed shells, excrement and sludge.
Preferably, the addition ratio of the lignocellulose aerogel to the polylactic acid is 1: 1.
Preferably, the coupling agent is a titanate or a monoalkoxy titanate.
Preferably, the adding ratio of the starch, the straw and the polyethylene is 2:1: 3.
A preparation method of a straw composite material degradable lunch box comprises the following steps:
step 1: taking raw materials of starch, straws, silk fibroin fibers, composite biochar, polyethylene, lignocellulose aerogel, polylactic acid and a coupling agent;
step 2: pulping and mixing the raw materials, and stirring and mixing the mixed raw materials at 80-120 ℃;
and step 3: and (3) feeding the mixed raw materials into a grinding tool forming machine for film pressing, and pressing and forming at 80-95 ℃.
Preferably, in the step 2, the pulped and mixed raw materials are sieved, and the fineness of the sieved raw materials is 100-150 meshes.
The invention has the beneficial technical effects that: according to the straw composite material degradable lunch box and the preparation process, the composite biochar, the starch and the straw are added to reduce the use of polyethylene, so that the use of raw materials is reduced, and the straw composite material degradable lunch box is green and environment-friendly; the added lignocellulose aerogel can be mixed with the starch and the straws to be wrapped, so that the water and oil leakage is prevented.
Detailed Description
In order to make the technical solutions of the present invention more clear and definite for those skilled in the art, the present invention is further described in detail with reference to the following examples, but the embodiments of the present invention are not limited thereto.
The straw composite material degradable lunch box that this embodiment provided, by weight, includes: 20-30 parts of starch, 30-40 parts of straw, 5-10 parts of silk fibroin fiber, 20-30 parts of composite biochar, 10-20 parts of polyethylene, 10-20 parts of lignocellulose aerogel, 10-20 parts of polylactic acid and 5-8 parts of a coupling agent.
Comprises the following components in parts by weight: 20-25 parts of starch, 30-35 parts of straw, 5-8 parts of silk fibroin fiber, 20-25 parts of composite biochar, 15-20 parts of polyethylene, 10-20 parts of lignocellulose aerogel, 10-15 parts of polylactic acid and 5-8 parts of a coupling agent.
Comprises the following components in parts by weight: 23 parts of starch, 32 parts of straw, 7 parts of silk fibroin fiber, 24 parts of composite biochar, 18 parts of polyethylene, 18 parts of lignocellulose aerogel, 13 parts of polylactic acid and 7 parts of coupling agent.
And degumming the silk fibroin fibers in a sodium carbonate solution for 3-4 times during adding. The composite biochar is a mixture formed by mixing and fermenting wheat straws, seed shells, excrement and sludge. The addition ratio of the lignocellulose aerogel to the polylactic acid is 1: 1. The coupling agent is titanate or mono-alkoxy titanate. The adding proportion of the starch, the straw and the polyethylene is 2:1: 3.
A preparation method of a straw composite material degradable lunch box comprises the following steps:
step 1: taking raw materials of starch, straws, silk fibroin fibers, composite biochar, polyethylene, lignocellulose aerogel, polylactic acid and a coupling agent;
step 2: pulping and mixing the raw materials, and stirring and mixing the mixed raw materials at 80-120 ℃;
and step 3: and (3) feeding the mixed raw materials into a grinding tool forming machine for film pressing, and pressing and forming at 80-95 ℃.
In the step 2, the pulped and mixed raw materials are sieved, and the fineness of the sieved raw materials is 100-150 meshes.
Example 1:
a straw composite material degradable lunch box comprises the following components in parts by weight: 20 parts of starch, 30 parts of straw, 5 parts of silk fibroin fiber, 20 parts of composite biochar, 10 parts of polyethylene, 10 parts of lignocellulose aerogel, 10 parts of polylactic acid and 5 parts of coupling agent.
A preparation method of a straw composite material degradable lunch box comprises the following steps:
step 1: taking raw materials of starch, straws, silk fibroin fibers, composite biochar, polyethylene, lignocellulose aerogel, polylactic acid and a coupling agent;
step 2: pulping and mixing the raw materials, and stirring and mixing the mixed raw materials at 80-120 ℃;
and step 3: and (3) feeding the mixed raw materials into a grinding tool forming machine for film pressing, and pressing and forming at 80-95 ℃.
Example 2:
a straw composite material degradable lunch box comprises the following components in parts by weight: 22 parts of starch, 32 parts of straw, 6 parts of silk fibroin fiber, 22 parts of composite biochar, 12 parts of polyethylene, 12 parts of lignocellulose aerogel, 12 parts of polylactic acid and 5.5 parts of a coupling agent.
A preparation method of a straw composite material degradable lunch box comprises the following steps:
step 1: taking raw materials of starch, straws, silk fibroin fibers, composite biochar, polyethylene, lignocellulose aerogel, polylactic acid and a coupling agent;
step 2: pulping and mixing the raw materials, and stirring and mixing the mixed raw materials at 80-120 ℃;
and step 3: and (3) feeding the mixed raw materials into a grinding tool forming machine for film pressing, and pressing and forming at 80-95 ℃.
Example 3:
a straw composite material degradable lunch box comprises the following components in parts by weight: 24 parts of starch, 34 parts of straw, 6 parts of silk fibroin fiber, 24 parts of composite biochar, 14 parts of polyethylene, 14 parts of lignocellulose aerogel, 14 parts of polylactic acid and 6 parts of coupling agent.
A preparation method of a straw composite material degradable lunch box comprises the following steps:
step 1: starch, straw, silk fibroin fiber, composite biochar, polyethylene, lignocellulose aerogel, polylactic acid and a coupling agent;
step 2: pulping and mixing the raw materials, and stirring and mixing the mixed raw materials at 80-120 ℃;
and step 3: and (3) feeding the mixed raw materials into a grinding tool forming machine for film pressing, and pressing and forming at 80-95 ℃.
Example 4:
a straw composite material degradable lunch box comprises the following components in parts by weight: 23 parts of starch, 32 parts of straw, 7 parts of silk fibroin fiber, 24 parts of composite biochar, 18 parts of polyethylene, 18 parts of lignocellulose aerogel, 13 parts of polylactic acid and 7 parts of coupling agent.
A preparation method of a straw composite material degradable lunch box comprises the following steps:
step 1: taking raw materials of starch, straws, silk fibroin fibers, composite biochar, polyethylene, lignocellulose aerogel, polylactic acid and a coupling agent;
step 2: pulping and mixing the raw materials, and stirring and mixing the mixed raw materials at 80-120 ℃;
and step 3: and (3) feeding the mixed raw materials into a grinding tool forming machine for film pressing, and pressing and forming at 80-95 ℃.
Example 5:
a straw composite material degradable lunch box comprises the following components in parts by weight: 28 parts of starch, 38 parts of straw, 8 parts of silk fibroin fiber, 28 parts of composite biochar, 18 parts of polyethylene, 18 parts of lignocellulose aerogel, 18 parts of polylactic acid and 7 parts of coupling agent.
A preparation method of a straw composite material degradable lunch box comprises the following steps:
step 1: taking raw materials of starch, straws, silk fibroin fibers, composite biochar, polyethylene, lignocellulose aerogel, polylactic acid and a coupling agent;
step 2: pulping and mixing the raw materials, and stirring and mixing the mixed raw materials at 80-120 ℃;
and step 3: and (3) feeding the mixed raw materials into a grinding tool forming machine for film pressing, and pressing and forming at 80-95 ℃.
Example 6:
a straw composite material degradable lunch box comprises the following components in parts by weight: 30 parts of starch, 40 parts of straw, 10 parts of silk fibroin fiber, 30 parts of composite biochar, 20 parts of polyethylene, 20 parts of lignocellulose aerogel, 20 parts of polylactic acid and 8 parts of coupling agent.
A preparation method of a straw composite material degradable lunch box comprises the following steps:
step 1: taking raw materials of starch, straws, silk fibroin fibers, composite biochar, polyethylene, lignocellulose aerogel, polylactic acid and a coupling agent;
step 2: pulping and mixing the raw materials, and stirring and mixing the mixed raw materials at 80-120 ℃;
and step 3: and (3) feeding the mixed raw materials into a grinding tool forming machine for film pressing, and pressing and forming at 80-95 ℃.
In summary, in this embodiment, according to the straw composite degradable lunch box and the preparation process of this embodiment, and the straw composite degradable lunch box and the preparation process of this embodiment, as can be seen from embodiments 1 to 6, the straw composite degradable lunch box prepared in embodiment 4 has the best water-proof and oil-proof effects, and the use of polyethylene can be reduced by adding the composite biochar, starch and straw, which not only reduces the use of raw materials, but also is green and environment-friendly; the added lignocellulose aerogel can be mixed with the starch and the straws to be wrapped, so that the water and oil leakage is prevented.
The above description is only for the purpose of illustrating the present invention and is not intended to limit the scope of the present invention, and any person skilled in the art can substitute or change the technical solution of the present invention and its conception within the scope of the present invention.

Claims (10)

1. The straw composite material degradable lunch box is characterized by comprising the following components in parts by weight: 20-30 parts of starch, 30-40 parts of straw, 5-10 parts of silk fibroin fiber, 20-30 parts of composite biochar, 10-20 parts of polyethylene, 10-20 parts of lignocellulose aerogel, 10-20 parts of polylactic acid and 5-8 parts of a coupling agent.
2. The straw composite degradable lunch box of claim 1, comprising the following components in parts by weight: 20-25 parts of starch, 30-35 parts of straw, 5-8 parts of silk fibroin fiber, 20-25 parts of composite biochar, 15-20 parts of polyethylene, 10-20 parts of lignocellulose aerogel, 10-15 parts of polylactic acid and 5-8 parts of a coupling agent.
3. The straw composite degradable lunch box of claim 1, comprising the following components in parts by weight: 23 parts of starch, 32 parts of straw, 7 parts of silk fibroin fiber, 24 parts of composite biochar, 18 parts of polyethylene, 18 parts of lignocellulose aerogel, 13 parts of polylactic acid and 7 parts of coupling agent.
4. The straw composite material degradable lunch box according to claim 1, wherein the silk fibroin fiber is firstly degummed in a sodium carbonate solution for 3-4 times when being added.
5. The straw composite material degradable lunch box of claim 1, wherein the composite biochar is a mixture formed by mixing and fermenting wheat straws, seed shells, excrement and sludge.
6. The straw composite degradable lunch box of claim 1, wherein the addition ratio of the lignocellulose aerogel to the polylactic acid is 1: 1.
7. The straw composite degradable lunch box of claim 1, wherein the coupling agent is titanate or mono-alkoxy titanate.
8. The straw composite degradable lunch box of claim 1, wherein the starch, the straw and the polyethylene are added in a ratio of 2:1: 3.
9. A preparation method of a straw composite material degradable lunch box is characterized by comprising the following steps:
step 1: taking raw materials of starch, straws, silk fibroin fibers, composite biochar, polyethylene, lignocellulose aerogel, polylactic acid and a coupling agent;
step 2: pulping and mixing the raw materials, and stirring and mixing the mixed raw materials at 80-120 ℃;
and step 3: and (3) feeding the mixed raw materials into a grinding tool forming machine for film pressing, and pressing and forming at 80-95 ℃.
10. The preparation method of the straw composite degradable lunch box according to claim 9, wherein in the step 2, the pulped and mixed raw materials are sieved, and the fineness of the sieved raw materials is 100-150 meshes.
CN202011032689.8A 2020-09-27 2020-09-27 Straw composite material degradable lunch box and preparation process thereof Pending CN112322061A (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113388163A (en) * 2021-06-16 2021-09-14 贵州海跃食品包装有限责任公司 Starch-based degradable lunch box and forming method thereof
CN113603938A (en) * 2021-07-30 2021-11-05 宁夏禾易源生物科技有限公司 Starch-based degradable safe and environment-friendly packaging box and preparation method thereof
CN117004094A (en) * 2023-09-01 2023-11-07 河南奥尼斯帝新材料有限公司 Starch-based foaming composition, starch-based foaming product and preparation method thereof

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CN102229750A (en) * 2011-06-28 2011-11-02 刘立文 Modified polypropylene composite material and preparation technology thereof
CN102417687A (en) * 2011-06-21 2012-04-18 刘立文 Modified impact-resistant polystyrene composite material and preparation technique thereof
CN104592558A (en) * 2015-02-04 2015-05-06 哈尔滨绿环生物降解制品开发有限公司 Comprehensive resource utilization type photo-biodegradable environment-friendly material and preparation method thereof
CN107118434A (en) * 2017-05-05 2017-09-01 周瑾 The process of degradable dinner set is made in a kind of stalk and plastic cement
CN107254095A (en) * 2017-08-02 2017-10-17 合肥市大卓电力有限责任公司 Degradable Novel environment-friendlymaterial material of a kind of high mechanical strength and preparation method thereof
CN107603174A (en) * 2017-08-08 2018-01-19 安徽泰诺塑胶有限公司 A kind of degradable once plastic cup

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Publication number Priority date Publication date Assignee Title
CN102417687A (en) * 2011-06-21 2012-04-18 刘立文 Modified impact-resistant polystyrene composite material and preparation technique thereof
CN102229750A (en) * 2011-06-28 2011-11-02 刘立文 Modified polypropylene composite material and preparation technology thereof
CN104592558A (en) * 2015-02-04 2015-05-06 哈尔滨绿环生物降解制品开发有限公司 Comprehensive resource utilization type photo-biodegradable environment-friendly material and preparation method thereof
CN107118434A (en) * 2017-05-05 2017-09-01 周瑾 The process of degradable dinner set is made in a kind of stalk and plastic cement
CN107254095A (en) * 2017-08-02 2017-10-17 合肥市大卓电力有限责任公司 Degradable Novel environment-friendlymaterial material of a kind of high mechanical strength and preparation method thereof
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113388163A (en) * 2021-06-16 2021-09-14 贵州海跃食品包装有限责任公司 Starch-based degradable lunch box and forming method thereof
CN113603938A (en) * 2021-07-30 2021-11-05 宁夏禾易源生物科技有限公司 Starch-based degradable safe and environment-friendly packaging box and preparation method thereof
CN117004094A (en) * 2023-09-01 2023-11-07 河南奥尼斯帝新材料有限公司 Starch-based foaming composition, starch-based foaming product and preparation method thereof

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