CN112300454A - High-strength heat-resistant PET (polyethylene terephthalate) decorative film for building decoration - Google Patents

High-strength heat-resistant PET (polyethylene terephthalate) decorative film for building decoration Download PDF

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CN112300454A
CN112300454A CN202011234570.9A CN202011234570A CN112300454A CN 112300454 A CN112300454 A CN 112300454A CN 202011234570 A CN202011234570 A CN 202011234570A CN 112300454 A CN112300454 A CN 112300454A
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parts
weight
pet
zinc oxide
decorative film
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张正辉
张翔
韩璐槿
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Jiangsu Himei New Material Co ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2455/00Characterised by the use of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08J2423/00 - C08J2453/00
    • C08J2455/02Acrylonitrile-Butadiene-Styrene [ABS] polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2467/00Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
    • C08J2467/02Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/02Organic and inorganic ingredients
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/002Physical properties
    • C08K2201/003Additives being defined by their diameter
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/04Oxygen-containing compounds
    • C08K5/10Esters; Ether-esters
    • C08K5/101Esters; Ether-esters of monocarboxylic acids
    • C08K5/103Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/17Amines; Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/541Silicon-containing compounds containing oxygen
    • C08K5/5415Silicon-containing compounds containing oxygen containing at least one Si—O bond
    • C08K5/5419Silicon-containing compounds containing oxygen containing at least one Si—O bond containing at least one Si—C bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/54Silicon-containing compounds
    • C08K5/541Silicon-containing compounds containing oxygen
    • C08K5/5425Silicon-containing compounds containing oxygen containing at least one C=C bond

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

A high-strength heat-resistant PET decorative film for building decoration comprises: the high-strength heat-resistant PET decorative film for building decoration comprises the following ingredients: 4-22 parts of pet, 4-28 parts of zinc oxide, 4-22 parts of ABS resin, 18-34 parts of polyisoprene, 28-46 parts of N-dodecyl dimethylamine, 28-46 parts of glyceryl tristearate, 24-34 parts of dimethyl siloxane and 16-46 parts of gamma-methacryloxypropyl trimethoxysilane. The defects that the pet decorative film for building decoration in the prior art is insufficient in heat resistance, often melted, very low in melting point and insufficient in tensile strength are effectively overcome.

Description

High-strength heat-resistant PET (polyethylene terephthalate) decorative film for building decoration
Technical Field
The invention relates to the technical field of decorative films, in particular to a high-strength heat-resistant PET decorative film for building decoration.
Background
After the pet decorative film is used for the building, the building can be beautified perfectly, so that the whole visual perception is brand-new. And according to different colors, a quite poetic appearance can be created, and a great imagination space is provided for many design masters. The artistic beauty is increased, and meanwhile, the safety protection function is also realized.
After the pet decorative film is used indoors, the monotonous feeling in the room can be changed, and the interior becomes beautiful and elegant. And the surface is smooth and clean after the film is pasted, and the cleaning is easy. Has the characteristic of high strength, and meets the requirement of protecting personal safety.
The pet decorative film for building decoration in the prior art has insufficient heat resistance, often has melting point which is very low, usually between 65 ℃ and 92 ℃, and also has insufficient tensile strength.
Disclosure of Invention
In order to solve the problems, the invention provides a high-strength heat-resistant PET decorative film for building decoration, which effectively overcomes the defects that the PET decorative film for building decoration in the prior art is not enough in heat resistance, often melts, has a very low melting point and is not enough in tensile strength.
In order to overcome the defects in the prior art, the invention provides a solution for a high-strength heat-resistant PET decorative film for building decoration, which comprises the following specific steps:
a high-strength heat-resistant PET decorative film for building decoration comprises:
the high-strength heat-resistant PET decorative film for building decoration comprises the following ingredients:
4-22 parts of pet, 4-28 parts of zinc oxide, 4-22 parts of ABS resin, 18-34 parts of polyisoprene, 28-46 parts of N-dodecyl dimethylamine, 28-46 parts of glyceryl tristearate, 24-34 parts of dimethyl siloxane and 16-46 parts of gamma-methacryloxypropyl trimethoxysilane.
Preferably, the ingredients of the high-strength heat-resistant PET decorative film for building decoration comprise:
13 parts by weight of pet, 15 parts by weight of zinc oxide, 16 parts by weight of ABS resin, 24 parts by weight of polyisoprene, 36 parts by weight of N-dodecyldimethylamine, 37 parts by weight of glyceryl tristearate, 28 parts by weight of dimethylsiloxane and 26 parts by weight of gamma-methacryloxypropyltrimethoxysilane.
Preferably, the pet is an engineering plastic grade pet.
Preferably, the zinc oxide comprises first zinc oxide particles with the diameter size of 0.006 mm-0.008 mm and second zinc oxide particles with the diameter size of 0.026 mm-0.098 mm, and the weight parts of the first zinc oxide particles with the diameter size of 0.006 mm-0.008 mm and the second zinc oxide particles with the diameter size of 0.026 mm-0.098 mm are the same.
The manufacturing method of the high-strength heat-resistant PET decorative film for building decoration comprises the following steps:
uniformly mixing 4-22 parts by weight of PET, 4-28 parts by weight of zinc oxide, 4-22 parts by weight of ABS resin, 18-34 parts by weight of polyisoprene, 28-46 parts by weight of N-dodecyl dimethylamine, 28-46 parts by weight of glyceryl tristearate, 24-34 parts by weight of dimethyl siloxane and 16-46 parts by weight of gamma-methacryloxypropyl trimethoxysilane, putting into an injection molding machine, melting, filling into a calender and calendering to obtain the high-strength heat-resistant PET decorative film for building decoration; the melting period was also oscillated via a magnetic oscillator connected to the injection molding machine.
Preferably, 13 parts by weight of PET, 15 parts by weight of zinc oxide, 16 parts by weight of ABS resin, 24 parts by weight of polyisoprene, 36 parts by weight of N-dodecyl dimethylamine, 37 parts by weight of glyceryl tristearate, 28 parts by weight of dimethyl siloxane and 26 parts by weight of gamma-methacryloxypropyl trimethoxysilane are uniformly stirred, placed into an injection molding machine, melted and filled into a rolling machine to be rolled into the high-strength heat-resistant PET decorative film for building decoration; the zinc oxide comprises a first zinc oxide particle with the diameter of 0.006 mm-0.008 mm and a second zinc oxide particle with the diameter of 0.026 mm-0.098 mm, and the weight parts of the first zinc oxide particle with the diameter of 0.006 mm-0.008 mm and the second zinc oxide particle with the diameter of 0.026 mm-0.098 mm are the same.
The invention has the beneficial effects that:
the invention improves the heat resistance of pet decorative film for building decoration, the melting point and the tensile strength of pet decorative film for building decoration, and the injection molding machine can better perform injection molding by oscillating the pet decorative film through a magnetic oscillator connected with the injection molding machine during the melting period. The defects that the pet decorative film for building decoration in the prior art is insufficient in heat resistance, often melted, very low in melting point and insufficient in tensile strength are effectively overcome.
Detailed Description
The present invention will be further described with reference to the following examples.
Example 1
High strength heat-resistant type PET decorating film for building decoration includes:
the high-strength heat-resistant PET decorative film for building decoration comprises the following ingredients:
4 parts by weight of pet, 4 parts by weight of zinc oxide, 4 parts by weight of ABS resin, 18 parts by weight of polyisoprene, 28 parts by weight of N-dodecyldimethylamine, 28 parts by weight of glyceryl tristearate, 24 parts by weight of dimethylsiloxane and 16 parts by weight of gamma-methacryloxypropyltrimethoxysilane.
The pet is an engineering plastic grade pet.
The zinc oxide comprises first zinc oxide particles with the diameter size of 0.006 mm and second zinc oxide particles with the diameter size of 0.026 mm, and the weight parts of the first zinc oxide particles with the diameter size of 0.006 mm and the second zinc oxide particles with the diameter size of 0.026 mm are the same.
The manufacturing method of the high-strength heat-resistant PET decorative film for building decoration comprises the following steps:
uniformly stirring 4 parts by weight of PET, 4 parts by weight of zinc oxide, 4 parts by weight of ABS resin, 18 parts by weight of polyisoprene, 28 parts by weight of N-dodecyl dimethylamine, 28 parts by weight of glyceryl tristearate, 24 parts by weight of dimethyl siloxane and 16 parts by weight of gamma-methacryloxypropyl trimethoxy silane, putting into an injection molding machine, melting, filling into a calender and calendering to obtain the high-strength heat-resistant PET decorative film for building decoration; the melting period was also oscillated via a magnetic oscillator connected to the injection molding machine.
Example 2
High strength heat-resistant type PET decorating film for building decoration includes:
the high-strength heat-resistant PET decorative film for building decoration comprises the following ingredients:
13 parts by weight of pet, 16 parts by weight of zinc oxide, 13 parts by weight of ABS resin, 26 parts by weight of polyisoprene, 37 parts by weight of N-dodecyldimethylamine, 37 parts by weight of glyceryl tristearate, 29 parts by weight of dimethylsiloxane and 31 parts by weight of gamma-methacryloxypropyltrimethoxysilane.
The pet is an engineering plastic grade pet.
The zinc oxide comprises first zinc oxide particles with the diameter size of 0.007 millimeters and second zinc oxide particles with the diameter size of 0.057 millimeters, and the first zinc oxide particles with the diameter size of 0.007 millimeters and the second zinc oxide particles with the diameter size of 0.057 millimeters are the same in parts by weight.
The manufacturing method of the high-strength heat-resistant PET decorative film for building decoration comprises the following steps:
13 parts of PET, 16 parts of zinc oxide, 13 parts of ABS resin, 26 parts of polyisoprene, 37 parts of N-dodecyl dimethylamine, 37 parts of glyceryl tristearate, 29 parts of dimethyl siloxane and 31 parts of gamma-methacryloxypropyl trimethoxysilane are uniformly mixed, put into an injection molding machine, melted and poured into a calender to be calendered into the high-strength heat-resistant PET decorative film for building decoration; the melting period was also oscillated via a magnetic oscillator connected to the injection molding machine.
Example 3
High strength heat-resistant type PET decorating film for building decoration includes:
the high-strength heat-resistant PET decorative film for building decoration comprises the following ingredients:
22 parts by weight of pet, 28 parts by weight of zinc oxide, 22 parts by weight of ABS resin, 34 parts by weight of polyisoprene, 46 parts by weight of N-dodecyldimethylamine, 46 parts by weight of glyceryl tristearate, 34 parts by weight of dimethylsiloxane and 46 parts by weight of gamma-methacryloxypropyltrimethoxysilane.
The pet is an engineering plastic grade pet.
The zinc oxide comprises first zinc oxide particles with the diameter size of 0.008 mm and second zinc oxide particles with the diameter size of 0.098 mm, and the weight parts of the first zinc oxide particles with the diameter size of 0.008 mm and the second zinc oxide particles with the diameter size of 0.098 mm are the same.
The manufacturing method of the high-strength heat-resistant PET decorative film for building decoration comprises the following steps:
22 parts of PET, 28 parts of zinc oxide, 22 parts of ABS resin, 34 parts of polyisoprene, 46 parts of N-dodecyl dimethylamine, 46 parts of glyceryl tristearate, 34 parts of dimethyl siloxane and 46 parts of gamma-methacryloxypropyl trimethoxysilane are uniformly stirred, put into an injection molding machine, melted and poured into a calender to be calendered into the high-strength heat-resistant PET decorative film for building decoration; the melting period was also oscillated via a magnetic oscillator connected to the injection molding machine.
The high-strength heat-resistant PET decorative films for building decoration obtained in examples 1 to 3 were tested with the PET decorative film for building decoration of the prior art to obtain the test results shown in table 1:
TABLE 1
Figure BDA0002766350210000061
As can be seen from Table 1, the high-strength heat-resistant PET decorative film for building decoration obtained in the embodiment of the invention has the advantages that compared with the PET decorative film for building decoration in the prior art, the tensile strength, the melting point and the specific heat capacity of the PET decorative film for building decoration are obviously improved in a double mode, the heat resistance of the PET decorative film for building decoration is improved, the melting point of the PET decorative film is also improved, the tensile strength of the PET decorative film for building decoration is also improved, and the PET decorative film for building decoration can be better subjected to injection molding by an injection molding machine through oscillation of a magnetic oscillator connected with the injection molding machine during melting. The defects that the pet decorative film for building decoration in the prior art is insufficient in heat resistance, often melted, very low in melting point and insufficient in tensile strength are effectively overcome.
The present invention has been described in an illustrative manner by the embodiments, and it should be understood by those skilled in the art that the present disclosure is not limited to the embodiments described above, but is capable of various changes, modifications and substitutions without departing from the scope of the present invention.

Claims (6)

1. The utility model provides a PET decorating film is used to heat-resisting type building decoration that excels in which includes:
the high-strength heat-resistant PET decorative film for building decoration comprises the following ingredients:
4-22 parts of pet, 4-28 parts of zinc oxide, 4-22 parts of ABS resin, 18-34 parts of polyisoprene, 28-46 parts of N-dodecyl dimethylamine, 28-46 parts of glyceryl tristearate, 24-34 parts of dimethyl siloxane and 16-46 parts of gamma-methacryloxypropyl trimethoxysilane.
2. The high strength heat resistant PET decorative film for building decoration according to claim 1, wherein the ingredients of the high strength heat resistant PET decorative film for building decoration comprise:
13 parts by weight of pet, 15 parts by weight of zinc oxide, 16 parts by weight of ABS resin, 24 parts by weight of polyisoprene, 36 parts by weight of N-dodecyldimethylamine, 37 parts by weight of glyceryl tristearate, 28 parts by weight of dimethylsiloxane and 26 parts by weight of gamma-methacryloxypropyltrimethoxysilane.
3. The high strength, heat resistant PET decorative film for building finishing as claimed in claim 1, wherein the PET is engineering plastic grade PET.
4. The PET decorative film for high-strength heat-resistant building decoration according to claim 1, wherein the zinc oxide includes a first zinc oxide particle having a diameter of 0.006 mm to 0.008 mm and a second zinc oxide particle having a diameter of 0.026 mm to 0.098 mm, and the first zinc oxide particle having a diameter of 0.006 mm to 0.008 mm and the second zinc oxide particle having a diameter of 0.026 mm to 0.098 mm are the same in parts by weight.
5. The PET decorative film for high-strength heat-resistant building decoration according to claim 1, wherein the PET decorative film for high-strength heat-resistant building decoration is prepared by a method comprising the following steps:
uniformly mixing 4-22 parts by weight of PET, 4-28 parts by weight of zinc oxide, 4-22 parts by weight of ABS resin, 18-34 parts by weight of polyisoprene, 28-46 parts by weight of N-dodecyl dimethylamine, 28-46 parts by weight of glyceryl tristearate, 24-34 parts by weight of dimethyl siloxane and 16-46 parts by weight of gamma-methacryloxypropyl trimethoxysilane, putting into an injection molding machine, melting, filling into a calender and calendering to obtain the high-strength heat-resistant PET decorative film for building decoration; the melting period was also oscillated via a magnetic oscillator connected to the injection molding machine.
6. The PET decorative film for high-strength heat-resistant building decoration according to claim 5, wherein 13 parts by weight of PET, 15 parts by weight of zinc oxide, 16 parts by weight of ABS resin, 24 parts by weight of polyisoprene, 36 parts by weight of N-dodecyl dimethylamine, 37 parts by weight of glyceryl tristearate, 28 parts by weight of dimethyl siloxane and 26 parts by weight of gamma-methacryloxypropyl trimethoxysilane are uniformly mixed, put into an injection molding machine, melted and poured into a calender to be calendered into the PET decorative film for high-strength heat-resistant building decoration; the zinc oxide comprises a first zinc oxide particle with the diameter of 0.006 mm-0.008 mm and a second zinc oxide particle with the diameter of 0.026 mm-0.098 mm, and the weight parts of the first zinc oxide particle with the diameter of 0.006 mm-0.008 mm and the second zinc oxide particle with the diameter of 0.026 mm-0.098 mm are the same.
CN202011234570.9A 2020-11-07 2020-11-07 High-strength heat-resistant PET (polyethylene terephthalate) decorative film for building decoration Pending CN112300454A (en)

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CN202011234570.9A CN112300454A (en) 2020-11-07 2020-11-07 High-strength heat-resistant PET (polyethylene terephthalate) decorative film for building decoration

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CN202011234570.9A CN112300454A (en) 2020-11-07 2020-11-07 High-strength heat-resistant PET (polyethylene terephthalate) decorative film for building decoration

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005105055A (en) * 2003-09-29 2005-04-21 Daicel Polymer Ltd Recycled pet resin composition, composition for modifying recycled pet resin and molded product of recycled pet resin
CN103772880A (en) * 2012-10-25 2014-05-07 合肥杰事杰新材料股份有限公司 ABS/PET material for extrusion process and preparation method of ABS/PET material
CN106009478A (en) * 2016-08-10 2016-10-12 安徽省宁国天成电工有限公司 Glass fiber-reinforced PET heater housing material
CN110343562A (en) * 2019-07-09 2019-10-18 广州市君禾实业有限公司 A kind of water base extraordinary fatty amine highly-efficient lubricant

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005105055A (en) * 2003-09-29 2005-04-21 Daicel Polymer Ltd Recycled pet resin composition, composition for modifying recycled pet resin and molded product of recycled pet resin
CN103772880A (en) * 2012-10-25 2014-05-07 合肥杰事杰新材料股份有限公司 ABS/PET material for extrusion process and preparation method of ABS/PET material
CN106009478A (en) * 2016-08-10 2016-10-12 安徽省宁国天成电工有限公司 Glass fiber-reinforced PET heater housing material
CN110343562A (en) * 2019-07-09 2019-10-18 广州市君禾实业有限公司 A kind of water base extraordinary fatty amine highly-efficient lubricant

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