CN112094056A - Preparation process of high-strength glass fiber - Google Patents

Preparation process of high-strength glass fiber Download PDF

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Publication number
CN112094056A
CN112094056A CN202010922346.2A CN202010922346A CN112094056A CN 112094056 A CN112094056 A CN 112094056A CN 202010922346 A CN202010922346 A CN 202010922346A CN 112094056 A CN112094056 A CN 112094056A
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CN
China
Prior art keywords
glass fiber
cleaning
strength glass
raw materials
pool
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010922346.2A
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Chinese (zh)
Inventor
范兴会
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuhe Yongxing Composite Material Co ltd
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Wuhe Yongxing Composite Material Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Wuhe Yongxing Composite Material Co ltd filed Critical Wuhe Yongxing Composite Material Co ltd
Priority to CN202010922346.2A priority Critical patent/CN112094056A/en
Publication of CN112094056A publication Critical patent/CN112094056A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C13/00Fibre or filament compositions
    • C03C13/06Mineral fibres, e.g. slag wool, mineral wool, rock wool
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B37/00Manufacture or treatment of flakes, fibres, or filaments from softened glass, minerals, or slags
    • C03B37/01Manufacture of glass fibres or filaments
    • C03B37/02Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor
    • C03B37/022Manufacture of glass fibres or filaments by drawing or extruding, e.g. direct drawing of molten glass from nozzles; Cooling fins therefor from molten glass in which the resultant product consists of different sorts of glass or is characterised by shape, e.g. hollow fibres, undulated fibres, fibres presenting a rough surface
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/02Pretreated ingredients
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/66Chemical treatment, e.g. leaching, acid or alkali treatment
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/70Cleaning, e.g. for reuse

Abstract

The invention relates to the technical field of glass fiber processing, and particularly discloses a preparation process of high-strength glass fiber, which comprises the following steps: s1, weighing the raw materials according to the proportion of 30-40 parts of pyrophyllite, 12-22 parts of quartz sand, 8-15 parts of dolomite, 10-20 parts of borocalcite and 0.1-0.3 part of coupling agent; s2, placing the raw materials into a cleaning pool, adding water to wash the raw materials, and then drying; s3, adding the raw materials cleaned in the step S2 into a mixer for melting, and drawing the melted materials by using a drawing machine to obtain glass fiber strands; s4, putting the glass fiber strands into the cleaning pool again, adding acid liquor, and carrying out acid cleaning; s5, pumping out acid liquor in the cleaning pool, adding water, soaking the glass fiber precursor, and finally drying to obtain high-strength glass fiber; the glass fiber prepared by the method provided by the invention has the advantages of high strength and high elasticity, and is suitable for being used in more scenes; the method has simple steps, convenient operation for workers and high processing efficiency.

Description

Preparation process of high-strength glass fiber
Technical Field
The invention relates to the technical field of glass fiber processing, in particular to a preparation process of high-strength glass fiber.
Background
The glass fiber is an inorganic non-metallic material with excellent performance, and has the advantages of good insulativity, strong heat resistance, good corrosion resistance and high mechanical strength. The preparation of the glass fiber needs to be carried out by processes of high-temperature melting, wire drawing, winding, weaving and the like, the diameter of each monofilament ranges from several micrometers to twenty micrometers, the diameter of each monofilament is equivalent to 1/20-1/5 of one hair strand, and each strand of fiber precursor consists of hundreds of monofilaments and even thousands of monofilaments. Glass fibers are commonly used as reinforcing materials in composite materials, electrical and thermal insulation materials, circuit substrates, and other various fields of the national economy.
The existing glass fiber material is low in mechanical strength, and is easy to break in a use scene with high strength requirement, so that the use effect of a product is influenced, and hidden dangers exist in practical application.
Disclosure of Invention
The invention aims to provide a preparation process of high-strength glass fibers, which aims to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: a preparation process of high-strength glass fiber comprises the following steps:
s1, weighing the raw materials according to the proportion of 30-40 parts of pyrophyllite, 12-22 parts of quartz sand, 8-15 parts of dolomite, 10-20 parts of borocalcite and 0.1-0.3 part of coupling agent;
s2, placing the raw materials into a cleaning pool, adding water to wash the raw materials, and then drying;
s3, adding the raw materials cleaned in the step S2 into a mixer for melting, and drawing the melted materials by using a drawing machine to obtain glass fiber strands;
s4, putting the glass fiber strands into the cleaning pool again, adding acid liquor, and carrying out acid cleaning;
s5, pumping out acid liquor in the cleaning pool, adding water again, soaking the glass fiber precursor, and finally drying to obtain high-strength glass fiber;
in the cleaning tank used in the step S2, the whole cleaning tank is of a square structure, the cleaning tank is open, a cleaning tank is arranged in the cleaning tank, a supporting bracket is arranged in the cleaning tank, and a bushing is arranged on the supporting bracket.
Preferably, a liquid inlet and a liquid outlet are arranged on the outer side of the cleaning pool, and a liquid outlet is arranged on the inner side of the cleaning pool; an annular conveying pipeline is arranged along the cleaning pool body, and the liquid inlet and the liquid outlet are communicated with each other through the conveying pipeline.
Preferably, the liquid outlet evenly is provided with a plurality ofly along wasing the pond inner wall, inlet, liquid outlet are close to and wash the setting of pond pool mouth, and the leakage fluid dram is close to and washs the setting of pond bottom of the pool.
Preferably, the whole support bracket is of a frame-shaped structure, a plurality of cross beams are arranged in the frame-shaped groove of the support bracket side by side, the cross beams divide the frame-shaped groove of the support bracket into a plurality of mounting grooves in equal size, and the bushing is correspondingly arranged in the mounting grooves.
Preferably, the bushing plate is provided with a through hole; the frame body of the beam or the supporting bracket is provided with a limit pin, and two sides of the bushing plate are provided with limit grooves.
Preferably, the whole limiting pin is of a trapezoidal structure, and the limiting groove is clamped on the limiting pin in a matching mode.
Preferably, the outside of supporting bracket is provided with the sealing strip, the sealing strip is laminated with the washing tank each other.
Preferably, a hydraulic cylinder is arranged at the bottom of the cleaning pool, a hydraulic rod is arranged in the hydraulic cylinder, and the hydraulic rod is fixedly connected with a support bracket; the hydraulic cylinders are provided with a plurality of groups, and the plurality of groups of hydraulic cylinders are uniformly arranged; the hydraulic cylinder is connected with a controller.
Preferably, stirring equipment is arranged at the bottom of the cleaning pool and comprises a stirring shaft and stirring blades, and the stirring blades are uniformly arranged around the stirring shaft; two ends of the stirring shaft are fixedly connected with the rotary table; the rotary table is installed on the wall of the cleaning pool and is connected with a driving motor which is connected with a controller.
Compared with the prior art, the invention has the beneficial effects that: the glass fiber prepared by the method provided by the invention is prepared and then is subjected to an acid washing process, so that the matching degree of the glass fiber and the coupling agent is increased, and the mechanical strength of the fiber is effectively improved, and the glass fiber is conveniently applied to more scenes; the method has simple steps, convenient operation for workers and high processing efficiency.
Drawings
FIG. 1 is a schematic view of the structure of a cleaning tank according to the present invention;
FIG. 2 is a schematic view of the cleaning tank of the present invention;
FIG. 3 is a schematic view of the support bracket of the present invention;
FIG. 4 is a schematic view of a bushing structure according to the present invention;
reference numbers in the figures: 1. a cleaning tank; 11. a liquid inlet; 12. a liquid outlet; 13. a liquid discharge port; 14. a delivery line; 2. a support bracket; 21. a cross beam; 22. mounting grooves; 23. a spacing pin; 24. a sealing strip; 3. a bushing; 31. a leak hole; 32. a limiting groove; 4. a hydraulic cylinder; 41. a hydraulic lever; 5. a stirring device; 51. a stirring shaft; 52. a stirring blade; 53. a turntable.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it should be noted that the terms "vertical", "upper", "lower", "horizontal", and the like indicate orientations or positional relationships based on those shown in the drawings, and are only for convenience of describing the present invention and simplifying the description, but do not indicate or imply that the referred device or element must have a specific orientation, be constructed in a specific orientation, and be operated, and thus, should not be construed as limiting the present invention.
In the description of the present invention, it should also be noted that, unless otherwise explicitly specified or limited, the terms "disposed," "mounted," "connected," and "connected" are to be construed broadly and may, for example, be fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood by those skilled in the art according to specific situations.
Referring to fig. 1-4, the present invention provides a technical solution: a preparation process of high-strength glass fiber comprises the following steps:
s1, weighing the raw materials according to the proportion of 30-40 parts of pyrophyllite, 12-22 parts of quartz sand, 8-15 parts of dolomite, 10-20 parts of borocalcite and 0.1-0.3 part of coupling agent;
s2, placing the raw materials into a cleaning pool 1, adding water to wash the raw materials, and then drying the raw materials;
s3, adding the raw materials cleaned in the step S2 into a mixer for melting, and drawing the melted materials by using a drawing machine to obtain glass fiber strands;
s4, putting the glass fiber strands into the cleaning pool 1 again, adding acid liquor, and carrying out acid cleaning;
s5, pumping out the acid liquor in the cleaning tank 1, adding water again, soaking the glass fiber precursor, and finally drying to obtain high-strength glass fiber;
in the cleaning tank 1 used in the step S2, the whole cleaning tank 1 is of a square structure, the cleaning tank 1 is open, a cleaning tank is arranged in the cleaning tank, a support bracket 2 is arranged in the cleaning tank, and a bushing 3 is arranged on the support bracket 2.
Further, a liquid inlet 11 and a liquid outlet 13 are arranged on the outer side of the cleaning pool 1, and a liquid outlet 12 is arranged on the inner side of the cleaning pool 1; an annular conveying pipeline 14 is arranged along the cleaning tank 1, and the liquid inlet 11 and the liquid outlet 12 are communicated with each other through the conveying pipeline 14.
Further, liquid outlet 12 evenly is provided with a plurality ofly along wasing 1 inner walls in pond, inlet 11, liquid outlet 12 are close to and wash 1 pool mouth setting in pond, and leakage fluid dram 13 is close to and washs 1 bottom of the pool setting.
Further, the whole support bracket 2 is of a frame structure, a plurality of cross beams 21 are arranged in frame-shaped grooves of the support bracket 2 side by side, the cross beams 21 divide the frame-shaped grooves of the support bracket 2 into a plurality of mounting grooves 22 in equal size, and the bushing 3 is correspondingly arranged in the mounting grooves 22.
Furthermore, the bushing 3 is provided with a leak hole 31, and the leak hole 31 is a through hole; the cross beam 21 or the support body of the support bracket 2 is provided with a limit pin 23, and two sides of the bushing 3 are provided with limit grooves 32.
Further, the whole limiting pin 23 is of a trapezoidal structure, and the limiting groove 32 is clamped on the limiting pin 23 in a matching manner.
Further, the outside of supporting bracket 2 is provided with sealing strip 24, sealing strip 24 and washing tank are laminated each other.
Further, a hydraulic cylinder 4 is arranged at the bottom of the cleaning pool 1, a hydraulic rod 41 is arranged in the hydraulic cylinder 4, and the hydraulic rod 41 is fixedly connected with the support bracket 2; the hydraulic cylinders 4 are provided with a plurality of groups, and the hydraulic cylinders 4 are uniformly arranged; the hydraulic cylinder 4 is connected with a controller.
Further, stirring equipment 5 is arranged at the bottom of the cleaning pool 1, the stirring equipment 5 comprises a stirring shaft 51 and stirring blades 52, and the stirring blades 52 are uniformly arranged around the stirring shaft 51; the two ends of the stirring shaft 51 are fixedly connected with the rotating disc 53; the turntable 53 is installed on the wall of the cleaning pool 1, the turntable 53 is connected with a driving motor, and the driving motor is connected with a controller.
The working principle is as follows: after the raw materials are obtained in proportion, the raw materials are cleaned in a cleaning tank 1, impurities are washed off, the purity of the raw materials is ensured, and the quality of finished fibers is further ensured; then melting the mixture by a mixer, and drawing the molten liquid by a drawing machine to obtain fiber precursor; and (3) pickling the fiber protofilament by using a cleaning pool 1, and finally soaking by using water to prepare the final high-strength glass fiber.
Liquid, which can be acid liquor or water, is added into the annular conveying pipeline 14 through the liquid inlet 11, and is selected according to the process requirements. The liquid is fed into the cleaning tank 1 through the liquid outlet 13 by the conveying pipeline 14, and the raw materials or the fibers in the tank are cleaned or soaked. After the corresponding steps are finished, the liquid in the cleaning pool 1 is discharged through the liquid outlet 13 so as to be added with the liquid again for use. A plurality of liquid outlets 12 are uniformly arranged along the inner wall of the cleaning pool 1, and liquid is uniformly added into the cleaning pool; liquid inlet 11, liquid outlet 12 are close to and wash 1 pool mouth setting in pond, and drain outlet 13 is close to and washs 1 bottom of the pool setting, and this kind of mode of setting makes things convenient for the joining and the discharge of liquid.
The frame-shaped support bracket 2 is divided into a plurality of mounting grooves 22 through a cross beam 21, and the bushing 3 is clamped and arranged in the mounting grooves 22 through a limiting pin 23 and a limiting groove 32; the limiting pin 23 is of a trapezoidal structure, a pin groove of the trapezoidal structure is convenient to place, the bushing 3 is convenient to take and place, and the work difficulty of replacing the bushing 3 is reduced; the nozzle plate 3 can be taken and placed for replacement, so that the nozzle holes 31 with different specifications are selected to adapt to cleaning of different raw materials or fibers, and cleaning materials are prevented from leaking from the nozzle holes 31. The sealing strip 24 is arranged on the outer side of the supporting bracket 2, the sealing strip 24 is mutually attached to the cleaning tank, and cleaning substances are prevented from leaking from the gap.
The hydraulic cylinder 4 is controlled by the controller, and the hydraulic rod 41 is controlled by the controller to stretch up and down, so that the support bracket 2 is driven to move up and down, and the material placed on the support bracket 2 is conveniently taken and placed. The hydraulic cylinders 4 are arranged in multiple groups and used synchronously, so that the workload of each hydraulic cylinder is reduced, and the service life of each hydraulic cylinder is prolonged. The motor connected with the turntable 53 is controlled by the controller to work, and the stirring shaft 51 is driven to rotate, so that the stirring blades 52 stir liquid, the liquid flows, the cleaning materials are cleaned, and the cleaning effect is better.
It is worth noting that: the whole device realizes control over the device through the master control button, and the device matched with the control button is common equipment, belongs to the existing mature technology, and is not repeated for the electrical connection relation and the specific circuit structure.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (9)

1. A preparation process of high-strength glass fiber is characterized by comprising the following steps: the method comprises the following steps:
s1, weighing the raw materials according to the proportion of 30-40 parts of pyrophyllite, 12-22 parts of quartz sand, 8-15 parts of dolomite, 10-20 parts of borocalcite and 0.1-0.3 part of coupling agent;
s2, placing the raw materials into a cleaning pool (1), adding water to wash the raw materials, and then drying;
s3, adding the raw materials cleaned in the step S2 into a mixer for melting, and drawing the melted materials by using a drawing machine to obtain glass fiber strands;
s4, putting the glass fiber strands into the cleaning pool (1) again, adding acid liquor, and carrying out acid cleaning;
s5, pumping out the acid liquor in the cleaning pool (1), adding water again, soaking the glass fiber precursor, and finally drying to obtain high-strength glass fiber;
in the cleaning tank (1) used in the step S2, the whole cleaning tank (1) is of a square structure, the cleaning tank (1) is arranged with an opening, a cleaning tank is arranged in the cleaning tank, a support bracket (2) is arranged in the cleaning tank, and a bushing (3) is arranged on the support bracket (2).
2. The process for preparing a high strength glass fiber according to claim 1, wherein: a liquid inlet (11) and a liquid outlet (13) are arranged on the outer side of the cleaning pool (1), and a liquid outlet (12) is arranged on the inner side of the cleaning pool (1); an annular conveying pipeline (14) is arranged along the tank body of the cleaning tank (1), and the liquid inlet (11) and the liquid outlet (12) are communicated with each other through the conveying pipeline (14).
3. The process for preparing a high strength glass fiber according to claim 2, wherein: liquid outlet (12) evenly are provided with a plurality ofly along wasing pond (1) inner wall, inlet (11), liquid outlet (12) are close to and wash pond (1) pool mouth setting, and leakage fluid dram (13) are close to and wash pond (1) bottom of the pool setting.
4. The process for preparing a high strength glass fiber according to claim 1, wherein: the support bracket (2) is integrally of a frame-shaped structure, a plurality of cross beams (21) are arranged in the frame-shaped grooves of the support bracket (2) side by side, the cross beams (21) divide the frame-shaped grooves of the support bracket (2) into a plurality of mounting grooves (22) in an equal size mode, and the bushing (3) is correspondingly arranged in the mounting grooves (22).
5. The process for preparing a high strength glass fiber according to claim 4, wherein: the bushing plate (3) is provided with a leakage hole (31), and the leakage hole (31) is a through hole; limiting pins (23) are arranged on the cross beam (21) or the support body of the support bracket (2), and limiting grooves (32) are arranged on two sides of the bushing (3).
6. The process for preparing a high strength glass fiber according to claim 5, wherein: the whole limiting pin (23) is of a trapezoidal structure, and the limiting groove (32) is clamped on the limiting pin (23) in a matching mode.
7. The process for preparing a high strength glass fiber according to claim 1, wherein: the outside of supporting bracket (2) is provided with sealing strip (24), sealing strip (24) and washing tank are laminated each other.
8. The process for preparing a high strength glass fiber according to claim 1, wherein: the bottom of the cleaning pool (1) is provided with a hydraulic cylinder (4), a hydraulic rod (41) is arranged in the hydraulic cylinder (4), and the hydraulic rod (41) is fixedly connected with the support bracket (2); the hydraulic cylinders (4) are provided with a plurality of groups, and the hydraulic cylinders (4) are uniformly arranged; the hydraulic cylinder (4) is connected with a controller.
9. The process for preparing a high strength glass fiber according to claim 1, wherein: the bottom of the cleaning pool (1) is provided with stirring equipment (5), the stirring equipment (5) comprises a stirring shaft (51) and stirring blades (52), and the stirring blades (52) are uniformly arranged around the stirring shaft (51); the two ends of the stirring shaft (51) are fixedly connected with the turntable (53); the rotary table (53) is installed on the wall of the cleaning pool (1), the rotary table (53) is connected with a driving motor, and the driving motor is connected with a controller.
CN202010922346.2A 2020-09-04 2020-09-04 Preparation process of high-strength glass fiber Pending CN112094056A (en)

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Cited By (4)

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Publication number Priority date Publication date Assignee Title
CN112679099A (en) * 2021-03-12 2021-04-20 山东墨匠新材料科技有限公司 High-strength high-modulus glass fiber composition
CN113354292A (en) * 2021-06-25 2021-09-07 五河信达新材料有限公司 Preparation method of high-strength glass fiber
CN113461323A (en) * 2021-06-07 2021-10-01 句容市百事特复合材料有限公司 Production method and processing equipment of silver-plated high-strength antistatic long glass fiber
CN115260741A (en) * 2022-09-02 2022-11-01 润德浩远环保科技(北京)有限公司 Fiber-reinforced polyurethane polymer composite material

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112679099A (en) * 2021-03-12 2021-04-20 山东墨匠新材料科技有限公司 High-strength high-modulus glass fiber composition
CN112679099B (en) * 2021-03-12 2021-05-28 山东墨匠新材料科技有限公司 High-strength high-modulus glass fiber composition
CN113461323A (en) * 2021-06-07 2021-10-01 句容市百事特复合材料有限公司 Production method and processing equipment of silver-plated high-strength antistatic long glass fiber
CN113354292A (en) * 2021-06-25 2021-09-07 五河信达新材料有限公司 Preparation method of high-strength glass fiber
CN115260741A (en) * 2022-09-02 2022-11-01 润德浩远环保科技(北京)有限公司 Fiber-reinforced polyurethane polymer composite material

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Application publication date: 20201218