CN112090259A - Functional liquid for decomposing TVOC and other peculiar smells by using Korean pine seed and preparation method thereof - Google Patents
Functional liquid for decomposing TVOC and other peculiar smells by using Korean pine seed and preparation method thereof Download PDFInfo
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- CN112090259A CN112090259A CN202010811121.XA CN202010811121A CN112090259A CN 112090259 A CN112090259 A CN 112090259A CN 202010811121 A CN202010811121 A CN 202010811121A CN 112090259 A CN112090259 A CN 112090259A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
- A61L9/013—Deodorant compositions containing animal or plant extracts, or vegetable material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0409—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing Si-atoms
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0427—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing halogen-atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/02—Foam dispersion or prevention
- B01D19/04—Foam dispersion or prevention by addition of chemical substances
- B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
- B01D19/0431—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance containing aromatic rings
- B01D19/0436—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance containing aromatic rings with substituted groups
- B01D19/0459—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance containing aromatic rings with substituted groups which contain halogen-atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/38—Removing components of undefined structure
- B01D53/44—Organic components
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8678—Removing components of undefined structure
- B01D53/8687—Organic components
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2209/00—Aspects relating to disinfection, sterilisation or deodorisation of air
- A61L2209/20—Method-related aspects
- A61L2209/21—Use of chemical compounds for treating air or the like
Abstract
The invention discloses a preparation method of a functional liquid for decomposing peculiar smell of TVOC and the like by a seed product, which comprises the steps of mixing nano-fiber microspheres of the seed product and hyperbranched polymer, adding a proper amount of water and defoamer for stirring, heating to 40-45 ℃, stirring for 10-15min, adding a composite deodorant, a bactericide and an aromatic agent for mixing, mixing and stirring for 2-5min, adding a thickener for mixing and stirring, heating to 60-70 ℃, stirring for 5-10min, standing and cooling to room temperature, mixing the nano-fiber microspheres of the seed product and the hyperbranched polymer to form an emulsion by the catalytic effect of the nano-fiber of the seed product and matching with the hyperbranched polymer, carrying out catalytic decomposition on the compound in the TVOC, mixing the nano-fiber microspheres of the seed product and the hyperbranched polymer by the composite deodorant, the bactericide, the aromatic agent, the defoamer and the thickener to form an emulsion which is suitable for being brushed on indoor walls or objects and is helpful for removing and catalytically decomposing the, and has antibacterial and aromatic effects.
Description
Technical Field
The invention relates to the technical field of TVOC removal and decomposition, in particular to a functional liquid for decomposing TVOC and other peculiar smells by a joss seed product and a preparation method thereof.
Background
Researchers of indoor air quality generally refer to all indoor Organic gaseous substances sampled and analyzed by them as TVOC, which is an abbreviation of the first letter of three words of Volatile Organic Compound, each VOC to be measured is collectively referred to as total Volatile Organic Compound TVOC (total Volatile Organic Compound), TVOC is one of three kinds of pollution seriously influencing indoor air quality, TVOC is an Organic substance with saturated vapor pressure exceeding 133.32 pa at room temperature, the boiling point of the Organic substance is 50 ℃ to 250 ℃, the Organic substance can exist in air in a form of evaporation at room temperature, and the toxicity, irritation, carcinogenicity and special odor of the Organic substance can influence skin and mucous membrane and cause acute damage to human body.
At present, the processing of TVOC adopts natural draft or catalytic decomposition's electrical apparatus to handle usually, and the treatment effect is slow or the energy consumption is high, utilizes pinus koraiensis seed nanofiber's strong catalytic performance can effectively catalytic decomposition peculiar smell gases such as TVOC.
Disclosure of Invention
The present invention aims to provide a functional liquid for solving the above-mentioned problems in the background art, which is a joss seed product for decomposing odor such as TVOC, and a preparation method thereof.
In order to achieve the purpose, the invention provides the following technical scheme:
a preparation method of a functional liquid for decomposing peculiar smell such as TVOC and the like by using a seed product of Korean pine comprises the following process steps:
s1, mixing the Korean pine seed nanofiber microspheres and the hyperbranched polymer, adding a proper amount of water and a defoaming agent, stirring, heating to 40-45 ℃, and stirring for 10-15 min;
s2, adding the composite deodorant, the bactericide and the aromatic, mixing and stirring for 2-5 min;
s3, adding the thickening agent, mixing and stirring, heating to 60-70 ℃, stirring for 5-10min, standing and cooling to room temperature.
A functional liquid for decomposing peculiar smell of TVOC and the like is prepared from the seed of Korean pine nanofiber microspheres, hyperbranched polymer, composite deodorant, bactericide, aromatic, antifoaming agent, thickening agent and water according to the mass ratio of 50:20:4:3:5:1:1: 1000.
As a further scheme of the invention: the seed product nanofiber microsphere has the sphere diameter of 0.5-2mm, the internal porosity of 30-60%, the pore size of 100-2000nm, and most of the pore sizes are irregular shapes.
As a further scheme of the invention: the hyperbranched polymer is composed of hydroxyl-terminated nitrogen-containing hyperbranched polyphosphate, hydroxyl-terminated hyperbranched polyester and hyperbranched solvent type organic silicon resin according to the mass ratio of 2:1: 3.
As a further scheme of the invention: the composite deodorant is composed of zinc ricinoleate, nano manganese dioxide and nano titanium dioxide according to the mass ratio of 4:2: 3.
As a further scheme of the invention: the aromatic is prepared from the following components in parts by weight: 14-18 parts of aloe, 18-22 parts of ivy, 23-45 parts of elephantopus scaber, 21-36 parts of dysosma versipellis, 9-14 parts of blumea oil and 11-18 parts of citrus essential oil.
As a further scheme of the invention: the bactericide mainly consists of methoxy acrylate.
As a further scheme of the invention: the defoaming agent comprises the following raw materials in parts by weight: 68-88 parts of polydimethylsiloxane, 0.6-0.8 part of chloroplatinic acid-isopropanol solution and 1.3-1.6 parts of hexachloro-p-xylene.
Compared with the prior art, the invention has the beneficial effects that: through joss seed nanofiber's catalytic effect, cooperation hyperbranched polymer carries out catalytic decomposition to the compound in the TVOC, mixes joss seed nanofiber microballon and hyperbranched polymer through compound deodorant, germicide, aromatic, defoaming agent and thickener and forms the emulsion, and suitable brush is on indoor wall or object, helps getting rid of the peculiar smell and catalytic decomposition to indoor TVOC, and possesses the effect of disinfecting and making fragrance.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example one
In the embodiment of the invention, a preparation method of a functional liquid for decomposing peculiar smells such as TVOC and the like by a seed product of Korean pine comprises the following process steps:
s1, mixing the Korean pine seed nanofiber microspheres and the hyperbranched polymer, adding a proper amount of water and a defoaming agent, stirring, heating to 40 ℃, and stirring for 10 min;
s2, adding the composite deodorant, the bactericide and the aromatic, mixing and stirring for 2 min;
and S3, adding the thickening agent, mixing and stirring, heating to 60 ℃, stirring for 5min, standing and cooling to room temperature.
A functional liquid for decomposing peculiar smell of TVOC and the like is prepared from the seed of Korean pine nanofiber microspheres, hyperbranched polymer, composite deodorant, bactericide, aromatic, antifoaming agent, thickening agent and water according to the mass ratio of 50:20:4:3:5:1:1: 1000.
The seed product nanofiber microsphere has the sphere diameter of 0.5-2mm, the internal porosity of 30-60%, the pore size of 100-2000nm, and most of the pore sizes are irregular shapes.
The hyperbranched polymer is composed of hydroxyl-terminated nitrogen-containing hyperbranched polyphosphate, hydroxyl-terminated hyperbranched polyester and hyperbranched solvent type organic silicon resin according to the mass ratio of 2:1: 3.
The composite deodorant is composed of zinc ricinoleate, nano manganese dioxide and nano titanium dioxide according to the mass ratio of 4:2: 3.
The aromatic is prepared from the following components in parts by weight: 14 parts of aloe, 18 parts of ivy, 23 parts of elephantopus scaber, 21 parts of dysosma versipellis, 9 parts of blumea oil and 11 parts of citrus essential oil.
The bactericide mainly consists of methoxy acrylate.
The defoaming agent comprises the following raw materials in parts by weight: 68 parts of polydimethylsiloxane, 0.6 part of chloroplatinic acid-isopropanol solution and 1.3 parts of hexachloro-p-xylene.
Example two
A preparation method of a functional liquid for decomposing peculiar smell such as TVOC and the like by using a seed product of Korean pine comprises the following process steps:
s1, mixing the Korean pine seed nanofiber microspheres and the hyperbranched polymer, adding a proper amount of water and a defoaming agent, stirring, heating to 43 ℃, and stirring for 13 min;
s2, adding the composite deodorant, the bactericide and the aromatic, mixing and stirring for 4 min;
and S3, adding the thickening agent, mixing and stirring, heating to 65 ℃, stirring for 7min, standing and cooling to room temperature.
The difference between the functional liquid for decomposing TVOC and other peculiar smells by the seed product of Korean pine and the embodiment I is that the aromatic is prepared from the following components in parts by weight: 16 parts of aloe, 20 parts of ivy, 32 parts of elephantopus scaber, 28 parts of dysosma versipellis, 12 parts of blumea oil and 15 parts of citrus essential oil.
The defoaming agent comprises the following raw materials in parts by weight: 74 parts of polydimethylsiloxane, 0.7 part of chloroplatinic acid-isopropanol solution and 1.4 parts of hexachloro-p-xylene.
EXAMPLE III
A preparation method of a functional liquid for decomposing peculiar smell such as TVOC and the like by using a seed product of Korean pine comprises the following process steps:
s1, mixing the Korean pine seed nanofiber microspheres and the hyperbranched polymer, adding a proper amount of water and a defoaming agent, stirring, heating to 45 ℃, and stirring for 15 min;
s2, adding the composite deodorant, the bactericide and the aromatic, mixing and stirring for 5 min;
s3, adding the thickening agent, mixing and stirring, heating to 70 ℃, stirring for 10min, standing and cooling to room temperature.
The difference between the functional liquid for decomposing TVOC and other peculiar smells by the seed product of Korean pine and the embodiment I is that the aromatic is prepared from the following components in parts by weight: 18 parts of aloe, 22 parts of ivy, 45 parts of elephantopus scaber, 36 parts of dysosma versipellis, 14 parts of blumea oil and 18 parts of citrus essential oil.
The defoaming agent comprises the following raw materials in parts by weight: 88 parts of polydimethylsiloxane, 0.8 part of chloroplatinic acid-isopropanol solution and 1.6 parts of hexachloro-p-xylene.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Claims (8)
1. A preparation method of a functional liquid for decomposing peculiar smells such as TVOC and the like by a seed product of Korean pine is characterized by comprising the following process steps:
s1, mixing the Korean pine seed nanofiber microspheres and the hyperbranched polymer, adding a proper amount of water and a defoaming agent, stirring, heating to 40-45 ℃, and stirring for 10-15 min;
s2, adding the composite deodorant, the bactericide and the aromatic, mixing and stirring for 2-5 min;
s3, adding the thickening agent, mixing and stirring, heating to 60-70 ℃, stirring for 5-10min, standing and cooling to room temperature.
2. The functional liquid for decomposing peculiar smell of TVOC and the like is characterized by comprising the seed product of Korean pine nano-fiber microspheres, hyperbranched polymer, composite deodorant, bactericide, aromatic, defoamer, thickener and water according to the mass ratio of 50:20:4:3:5:1:1: 1000.
3. The functional liquid for relieving off-flavor of TVOC and the like according to claim 2, wherein the seed nano fiber microspheres of Korean pine have a sphere diameter of 0.5-2mm, an internal porosity of 30% -60%, a pore size of 100-2000nm, and most of the pore sizes are irregular shapes.
4. The functional liquid for dissolving an odor of TVOC and the like of the seed product of the Korean pine according to claim 2, wherein the hyperbranched polymer is composed of a hydroxyl-terminated nitrogen-containing hyperbranched polyphosphate, a hydroxyl-terminated hyperbranched polyester and a hyperbranched solvent-based silicone resin in a mass ratio of 2:1: 3.
5. The functional liquid for relieving an odor of TVOC and the like of claim 2, wherein the compound deodorant comprises zinc ricinoleate, nano manganese dioxide, nano titanium dioxide in a mass ratio of 4:2: 3.
6. The functional liquid for relieving an odor of TVOC and the like according to claim 2, wherein the aromatic agent is prepared from the following components in parts by weight: 14-18 parts of aloe, 18-22 parts of ivy, 23-45 parts of elephantopus scaber, 21-36 parts of dysosma versipellis, 9-14 parts of blumea oil and 11-18 parts of citrus essential oil.
7. The functional liquid for relieving an odor of TVOC and the like according to claim 2, wherein said bactericide is mainly composed of methoxyacrylate.
8. The functional liquid for relieving an odor of TVOC and the like according to claim 2, wherein the antifoaming agent comprises the following raw materials in parts by weight: 68-88 parts of polydimethylsiloxane, 0.6-0.8 part of chloroplatinic acid-isopropanol solution and 1.3-1.6 parts of hexachloro-p-xylene.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010811121.XA CN112090259A (en) | 2020-08-13 | 2020-08-13 | Functional liquid for decomposing TVOC and other peculiar smells by using Korean pine seed and preparation method thereof |
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| CN202010811121.XA CN112090259A (en) | 2020-08-13 | 2020-08-13 | Functional liquid for decomposing TVOC and other peculiar smells by using Korean pine seed and preparation method thereof |
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Citations (6)
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| US20170239836A1 (en) * | 2016-02-24 | 2017-08-24 | Dehua Tb New Decoration Material Co., Ltd. | Method For Preparing Functional Engineered Wood |
| CN108786415A (en) * | 2018-05-29 | 2018-11-13 | 安徽省银锂子生物科技发展有限公司 | A kind of environmentally protective sterilization methanal scavenger |
| CN109385745A (en) * | 2018-10-22 | 2019-02-26 | 成都新柯力化工科技有限公司 | A kind of automobile ceiling selfdecomposition VOC non-woven fabrics and preparation method |
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2020
- 2020-08-13 CN CN202010811121.XA patent/CN112090259A/en active Pending
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| CN104356920A (en) * | 2014-10-12 | 2015-02-18 | 宁波格瑞特涂料科技有限公司 | Environmental-friendly water paint and preparation method thereof |
| CN105816986A (en) * | 2015-01-05 | 2016-08-03 | 刘林 | Preparation method of pure plant household formaldehyde scavenger |
| US20170239836A1 (en) * | 2016-02-24 | 2017-08-24 | Dehua Tb New Decoration Material Co., Ltd. | Method For Preparing Functional Engineered Wood |
| CN106474653A (en) * | 2016-08-31 | 2017-03-08 | 杭州风铃草环保科技有限公司 | Furniture formaldehyde scavenger and preparation method that a kind of percdation top layer persistently catches |
| CN108786415A (en) * | 2018-05-29 | 2018-11-13 | 安徽省银锂子生物科技发展有限公司 | A kind of environmentally protective sterilization methanal scavenger |
| CN109385745A (en) * | 2018-10-22 | 2019-02-26 | 成都新柯力化工科技有限公司 | A kind of automobile ceiling selfdecomposition VOC non-woven fabrics and preparation method |
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Application publication date: 20201218 |