CN112076688A

CN112076688A - Operation method of waste tire pyrolysis carbon black granulation fluidized bed

Info

Publication number: CN112076688A
Application number: CN202011068229.0A
Authority: CN
Inventors: 杨松
Original assignee: Individual
Current assignee: Individual
Priority date: 2020-10-08
Filing date: 2020-10-08
Publication date: 2020-12-15

Abstract

The invention relates to the technical field of environmental protection, in particular to a method for operating a granulation fluidized bed for pyrolysis of carbon black from waste tires. The method is characterized in that: the fluidized inert tail gas carries pyrolytic carbon black particles to enter a fluidized bed body from an inlet of a volute at a high speed, the outlet speed is 20-25 m/s, the pyrolytic carbon black particles are thrown to the wall of the fluidized bed body under the action of centrifugal force and spirally rise along with the wind band of the fluidized inert tail gas, maltodextrin aqueous solution enters an annular flow channel with a narrowed flow channel after passing through a water delivery annular pipe, the flow channel is designed to be annular to prevent the high-speed water flow from scouring and damaging the flow channel, the high-speed water flow is sprayed out from top to bottom through a spray hole and clings to the wall of the fluidized bed body to moisten and scour the wall of the fluidized bed body and clean an adhesion deposition layer in time, the fluidized inert tail gas is separated from the pyrolytic carbon black particles and discharged to a cyclone separator set, the fluidized inert tail gas is separated from.

Description

Operation method of waste tire pyrolysis carbon black granulation fluidized bed

Technical Field

The invention relates to the technical field of environmental protection, in particular to a method for operating a granulation fluidized bed for pyrolysis of carbon black from waste tires.

Background

Waste tires are common solid waste pollutants, people recycle the waste tires through a plurality of ways to realize harmless treatment, wherein the preparation of fuel oil and carbon black through pyrolysis of the waste tires is one of the solutions, solid products after pyrolysis of the waste tires comprise pyrolytic carbon and waste steel wires, and further the pyrolytic carbon needs to be subjected to processes of protection, temperature reduction, iron removal separation, crushing, grinding and the like to prepare the carbon black. The Chinese invention patent (patent application number 201910499620.7, the patent name is a carbon black granulator) discloses a carbon black granulator, which is characterized in that: the device comprises a mixed extrusion section machine body and a rounding drying section machine body which are connected, wherein a pore plate is arranged at the connecting part of the mixed extrusion section machine body and the rounding drying section machine body; a carbon black inlet and a granulation water inlet are arranged on the mixed extrusion section machine body, and a carbon black outlet is arranged on the rolling drying section machine body; a high-speed shaft is arranged in the two sections of machine bodies, a low-speed shaft is arranged on the high-speed shaft in the mixed extrusion section machine body, and stirring teeth and a packing auger are arranged on the low-speed shaft; the high-speed shaft in the rounding drying section machine body is provided with a rounding cylinder, and the end face, facing the pore plate, of the rounding cylinder is provided with a blade. The carbon black granulator can improve the uniformity of carbon black particles, reduce fine powder generated by carbon black granulation, and control the particle size of the carbon black particles. The Chinese patent of the invention (patent application number 201920046303.5, the patent name is a white carbon black granulation device) discloses a white carbon black granulation device, which is characterized in that: the device comprises a feeding hopper (10) and a granulation chamber (20) which are connected through a feeding hole, wherein the top of the granulation chamber (20) is symmetrically provided with two stirring rods (21) of an external motor, the top of the granulation chamber (20) is further symmetrically provided with at least two water mist spray nozzles (23) of an external water tank and a water pump, the spray nozzles (23) face the working direction of the stirring rods (21), the side wall of the upper end of the granulation chamber (20) is symmetrically provided with at least two first hot air inlets (22) of an external fan and a heating device, the first hot air inlets (22) are positioned above the working area of the stirring rods (21), the side wall of the granulation chamber (20) is arranged above the stirring rods (21) and is hinged with two first baffles (24), the first baffles (24) are mutually matched and clamped and form a sealed space above the granulation chamber (20), and one of the side wall of the granulation chamber (20) is arranged below the first baffle (24, a guide plate (26) is arranged in a downward inclined mode, the width of the guide plate (26) is equivalent to that of the granulation chamber (20), a belt conveyor (30) externally connected with a first motor (31) is arranged inside the granulation chamber (20) and below the guide plate (26), the width of the belt conveyor (30) is 4/5-9/10 of the width of the granulation chamber (20), and the feeding tail end of the guide plate (26) is located above the working starting end of the belt conveyor (30); two second baffles (32) which are provided with sieve pores uniformly distributed on the surface and can be matched with each other, clamped and sealed are hinged on the side wall of the granulation chamber (20) and below the belt conveyor (30), and the size of each sieve pore is the same as the preset particle size of the white carbon black; the bottom of the granulating chamber (20) is also provided with a discharge hole (34). Meanwhile, the functions of rapid granulation molding and particle drying are realized; provides a white carbon black granulation device with excellent granulation effect.

In the prior art, the stirring teeth and the auger are adopted for rounding, drying and granulating, so that the problems that the carbon black particles are difficult to be uniformly wetted by the binder water, and part of carbon black and fine powder cannot be recycled and granulated are solved. The second prior art discloses a carbon black stirring granulation and drying process, and still has the problems that the binder water is difficult to uniformly wet carbon black particles, and part of carbon black and fine powder cannot be recycled and granulated.

Disclosure of Invention

In view of the above problems, the present invention provides a method for operating a granulation fluidized bed for pyrolysis of carbon black from waste tires, which is characterized in that:

step one, blowing a cyclone separator group and a fluidized bed body by using fluidized inert tail gas, checking that a Y-shaped material returning device has no channeling, blowing a drying chamber by using dry inert tail gas, modulating the inert tail gas obtained by a steam jet pump according to the requirement of working gas required by the granulation of the pyrolytic carbon black, and dispersing the conveyed fluidized inert tail gas because the pyrolytic carbon black powder is not easy to flow: the oxygen content is lower than 3%, the temperature is 82-85 ℃, and the working pressure is 4000-8000 Pa; due to the limitation of water content in the product standard, the drying inert tail gas of the dried pyrolytic carbon black particles is required: oxygen content less than 3%, and water content less than 0.3g/m³The temperature is 250-280 ℃; the pyrolytic carbon black granulation adhesive is prepared by selecting water, adding 1-1.5% by mass of maltodextrin dissolved in the water to serve as the pyrolytic carbon black granulation adhesive, so that the intensity of pyrolytic carbon black particles is enhanced, the mixing amount of the pyrolytic carbon black and the maltodextrin aqueous solution is 1: 1-1.2 by mass, and the temperature of the maltodextrin aqueous solution is 82-85 ℃.

Secondly, the fluidized inert tail gas carries pyrolytic carbon black particles to enter the fluidized bed body from an inlet of the volute at a high speed, the outlet speed is 20-25 m/s, under the action of centrifugal force, the pyrolytic carbon black particles are thrown to the wall of the fluidized bed body and spirally rise along with the wind band of the fluidized inert tail gas, the wall flow device comprises an annular flow passage, spray holes and a water delivery ring pipe, maltodextrin water solution enters the annular flow passage with the narrowed flow passage after passing through the water delivery ring pipe, the flow speed is increased rapidly, in order to prevent the flow passage from being damaged by high-speed water flow scouring, the flow passage is designed into an annular shape, the high-speed water flow is sprayed out from top to bottom and clinging to the wall of the fluidized bed body through the spray holes, the wall of the fluidized bed body is wetted and scoured to clean an adhesion deposition layer in time, the pyrolytic carbon black particles are wetted and aggregated, the fluidization inert tail gas flow forms the characteristics of high peripheral flow velocity, low central flow velocity and high peripheral pressure compared with the central pressure, the continuously growing and rounded pyrolytic carbon black particles are driven to lose kinetic energy and gather towards the center in friction collision, the fluidization inert tail gas and the pyrolytic carbon black particles are separated and discharged to a cyclone separator group, the fluidization inert tail gas and the pyrolytic carbon black fine powder are separated again, the fluidization inert tail gas is discharged through a gas collection chamber, and the fine powder returns to a fluidization bed body through a Y-shaped material returning device to be continuously granulated.

And step three, rolling the diameter of the pyrolytic carbon black particles to grow until the sedimentation velocity exceeds the through-flow velocity of the fluidized inert tail gas, allowing the pyrolytic carbon black particles to fall into a drying chamber through a discharge elbow under the action of gravity, allowing the dry inert tail gas to enter a side branch pipe at the bottom of the drying chamber to heat and dry the pyrolytic carbon black particles, wherein the pyrolytic carbon black finished product particles in the discharge elbow form a material seal, so that the dry inert tail gas cannot escape through the discharge elbow to influence the air flow movement environment of a fluidized bed body, mixing the dry inert tail gas discharged in the drying process and the fluidized inert tail gas discharged by a gas collection chamber together and discharging the mixture to a pulse bag dust collector, heating the fluidized inert tail gas by using the waste heat of the dry inert tail gas to prevent the blockage of condensed water and carbon black, keeping the working temperature of the pulse bag dust collector above 110 ℃, and.

The inventor finds that the tire consists of an outer tire, an inner tire and a cushion belt, the outer tire consists of three main parts, namely a tire body, a tire tread and a tire bead, the tire body is formed by attaching a plurality of layers of rubberized cord fabrics according to a certain angle, and the cord fabrics are usually made of high-strength steel wires and synthetic fiber rubberized fabrics; the tread contacts with the ground and is made of heat-resistant and shear-resistant rubber materials; the tyre bead is used for tightly fixing the tyre on a wheel rim, and mainly comprises a steel wire ring, triangular filling rubber and steel wire ring wrapping cloth. The pneumatic tire can be classified into a car tire, a truck tire, an agricultural tire, an engineering tire, a special vehicle tire, an aircraft tire, a motorcycle tire and a bicycle tire according to the application of the pneumatic tire, and the recycled waste tire is generally a car tire, a truck tire, an agricultural tire, a motorcycle tire and a bicycle tire, and the structure of the waste tire is generally an oblique tire and a radial tire. The recovered waste tires are used for building fillers, highway fillers, regenerated rubber preparation, fuel oil and carbon black preparation by pyrolysis and the like.

The inventor finds that the process for preparing fuel oil and carbon black by pyrolyzing waste tires requires the processes to be carried out in a vacuum, inert gas protection and anaerobic closed environment, and the process is currently put into industrial production methods such as reaction kettle pyrolysis, rotary reaction furnace pyrolysis, vertical tower pyrolysis and the like. Although the pyrolysis method of the reaction kettle has the advantage that the whole material is fed without being crushed, the pyrolysis method has high energy consumption and low finished product yield and is difficult to popularize due to the reason that continuous production cannot be realized; the rotary reaction furnace pyrolysis method is difficult to popularize due to the reasons that feeding and discharging are difficult, pollutants are easy to leak through high-temperature dynamic sealing and the like; the vertical tower pyrolysis method has the advantages from the thermodynamic point of view undoubtedly compared with the first two methods, the power of the material from top to bottom is provided by gravity, the hot air completes heat exchange with the material from bottom to top, the feeding and discharging and the heat exchange are easy to implement, the vertical tower is static equipment, and the high-temperature sealing problem is easy to solve, but the technical problem that a discharge channel is blocked by a rubber jelly and a steel wire ball which are reformed after long chain breakage of rubber exists in the pyrolysis process of the waste tires, the surface of the waste tires is further pyrolyzed to generate pyrolytic carbon crust and the interior of the waste tires is prevented from being pyrolyzed continuously, and the technical problem that the pyrolysis efficiency is low due to the low thermal conductivity of the waste.

The inventor finds that pyrolysis of waste tires is mainly used for recovering pyrolysis oil and pyrolysis carbon, and further preparing products such as fuel oil, carbon black and the like, and the pyrolysis gas is uneconomical if the pyrolysis gas is used as a main productBecause the yield of the pyrolysis gas is improved, the pyrolysis oil chain hydrocarbon with larger molecular weight can be fractured to generate the pyrolysis gas mainly containing methane, ethane, ethylene, propylene and other components with smaller molecular weight only by higher pyrolysis temperature (550-600 ℃), a part of energy is wasted on the damaged molecular chain due to the higher pyrolysis temperature, and the pyrolysis gas generated by degrading the pyrolysis oil is flammable and explosive and is difficult to store and transport; in order to reduce the manufacturing cost of the pyrolysis reaction furnace and meet the requirements of mechanical processing, Q345R steel is selected as a furnace body material, the allowable stress requirement of the Q345R steel at high temperature is considered, namely the steel is used at the temperature of not more than 475 ℃, the comprehensive consideration of the factors is taken, the pyrolysis process temperature of the waste tires is designed to be 350-400 ℃, the heat source for pyrolyzing the waste tires is high-temperature flue gas generated by recycling pyrolysis gas, the pyrolysis gas is non-condensable combustible gas after pyrolysis oil is condensed at normal temperature, and the low-grade heat value is 17-54 MJ/Nm³. Due to the requirements of heat transfer efficiency and heat transfer temperature difference, the temperature of flue gas from the outlet of the waste tire pyrolysis gas combustion kiln to the jacket of the vertical pyrolysis tower body and the inlet of the rotary rake roller is controlled to be 550-560 ℃, the temperature of flue gas after heat exchange of the vertical pyrolysis tower body and the rotary rake roller is 410-420 ℃, and the average temperature difference of heat transfer is 140 ℃, so that the pyrolysis gas combustion kiln can regulate and control the temperature of high-temperature flue gas generated by pyrolysis gas combustion, a cold source is required to be introduced to be mixed with the high-temperature flue gas, and the temperature required by a pyrolysis process is achieved by regulating the component ratio of.

The inventor finds that in the waste tire pyrolysis process, the requirements of material balance, water (steam) balance and energy balance and the total targets of saving energy, reducing emission and recycling, the oxygen content of the exhaust gas after the high-temperature flue gas output by the pyrolysis gas combustion kiln is subjected to heat exchange through the vertical pyrolysis tower body and the rotary rake roller is reduced to be less than 3%, the temperature is 410-420 ℃, the pressure bearing of the rotary rake roller under the dynamic seal high-temperature working condition is limited, and the designed absolute pressure is not more than 105kPa, so that the pressure index of the exhaust gas is lower than the pressure requirements of a secondary air inlet of a combustor and a cold source at an inlet of the pyrolysis gas combustion kiln of 112-118 kPa, and the exhaust gas cannot be directly recycled. According to the operating principle of turbocharging, considering that the pressure of the discharged waste gas is low, selecting an axial air inlet and vertical upward exhaust mode with small pressure loss at the air inlet end, and using a cantilever type rotor structure, the discharged waste gas is expanded through a static blade grid and a movable blade wheel to do work, the heat energy is converted into mechanical energy for rotating the movable blade wheel, the movable blade wheel drives a planetary speed increaser to drive the air turbine, the air turbine pumps the air to pressurize and enter a combustor, a blower required by premixed air conveyed by the combustor is replaced, but the absolute pressure of an inlet of the discharged waste gas is 105kPa, an outlet of the discharged waste gas is directly communicated with a chimney, namely, the backpressure of a waste gas turbine is 101 kPa, the pressure difference of the inlet and the outlet is not enough to overcome the pressure loss of a flow passage of the static blade grid and the movable blade wheel to cause the rotation, the outlet pressure of the discharged waste gas is reduced to 50-55 kPa, the pressure difference between the inlet and the outlet of the waste gas turbine reaches 52-57 kPa, and the movable impeller can work reliably. The steam source of the steam jet pump is saturated steam generated by condensation of pyrolysis oil, the pressure is 0.35-0.4 MPa, the exhaust gas and steam mixed gas at the outlet of the steam jet pump are sent to an expansion tank, non-condensable gas in the expansion tank is inert tail gas, the inert tail gas has three purposes, one of the inert tail gas serves as a cold source for adjusting the temperature of the pyrolysis gas combustion kiln, the other inert tail gas serves as an air source for adjusting the coefficient of excess air of a pyrolysis gas combustor, and the third inert tail gas serves as inert protective gas required by purging of a middle-section bell jar storage bin.

The inventors have found that the inert tail gas obtained by the steam jet pump is adjusted according to the requirements of the working gas required for granulation of the pyrolytic carbon black, and since the pyrolytic carbon black powder does not flow easily, the fluidized inert tail gas to be conveyed in a dispersed manner is required: the oxygen content is lower than 3%, the temperature is 82-85 ℃, and the working pressure is 4000-8000 Pa; due to the limitation of water content in the product standard, the drying inert tail gas of the dried pyrolytic carbon black particles is required: oxygen content less than 3%, and water content less than 0.3g/m³And the temperature is 250-280 ℃. The pyrolytic carbon black granulation adhesive is prepared by selecting water, adding 1-1.5% by mass of maltodextrin dissolved in the water to serve as the pyrolytic carbon black granulation adhesive, so that the intensity of pyrolytic carbon black particles is enhanced, the mixing amount of the pyrolytic carbon black and the maltodextrin aqueous solution is 1: 1-1.2 by mass, and the temperature of the maltodextrin aqueous solution is 82-85 ℃.

The inventor finds that the granulation fluidized bed comprises a gas collection chamber, a cyclone separator group, a fluidized bed body, a Y-shaped return feeder, a volute inlet, a discharge elbow, a drying chamber, a pulse bag dust collector and a wall flow device, fluidized inert tail gas carries pyrolytic carbon black particles to enter the fluidized bed body from the volute inlet at a high speed, the outlet speed is 20-25 m/s, the pyrolytic carbon black particles are thrown to the wall of the fluidized bed under the action of centrifugal force and rise spirally along with the fluidized inert tail gas wind belt, the wall flow device comprises an annular flow passage, a spray hole and a water conveying ring pipe, maltodextrin aqueous solution enters the annular flow passage with the narrowed flow passage after passing through the water conveying ring pipe, the flow speed is increased rapidly, the flow passage is designed to be annular, the high-speed water flows from top to bottom and is sprayed out to be close to the wall of the fluidized bed through the spray hole, the fluidized bed wall is wetted and washed, the deposited layer is cleaned and adhered The fluidized inert tail gas flow forms the characteristics of high peripheral flow velocity, low central flow velocity and high peripheral pressure than the central pressure, the continuous growth and the loss of kinetic energy of the rounded pyrolytic carbon black particles are driven to gather to the center in the friction collision, the fluidized inert tail gas and the pyrolytic carbon black particles are separated and discharged to a cyclone separator group, the fluidized inert tail gas and the pyrolytic carbon black fine powder are separated again, the fluidized inert tail gas is discharged through a gas collecting chamber, the fine powder returns to a fluidized bed body through a Y-shaped returning device to continue granulation, the rolling diameter of the pyrolytic carbon black particles grows until the sedimentation velocity exceeds the through-flow velocity of the fluidized inert tail gas flow, the particles fall into a drying chamber through a discharge elbow pipe under the action of gravity, and the dried inert tail gas enters a branch pipe at the bottom of the drying chamber to heat and dry the pyrolytic carbon black particles, because the pyrolysis carbon black finished product particles in the discharge elbow form a material seal, dry inert tail gas cannot be blown out through the discharge elbow to influence the air flow movement environment of a fluidized bed body, the dry inert tail gas discharged in the drying process is mixed with the fluidized inert tail gas discharged by the gas collection chamber and discharged to the pulse bag dust collector together, in order to prevent condensed water and carbon black from blocking a cloth bag, the waste heat of the dry inert tail gas is used for heating the fluidized inert tail gas, the working temperature of the pulse bag dust collector is kept above 110 ℃, and carbon black fine powder collected by the pulse bag dust collector is recycled.

Compared with the prior art, the invention at least has the following advantages: the inert tail gas obtained by the steam jet pump is modulated according to the requirements of working gas required by the granulation of the pyrolytic carbon black, so that the requirements of material balance, water (steam) balance and energy balance in the pyrolytic process of the waste tires are met, and the total targets of saving energy, reducing emission and recycling are achieved.

Drawings

FIG. 1 is a schematic structural view of the operation method of a granulation fluidized bed for pyrolysis of carbon black from waste tires according to the present invention.

FIG. 2 is a schematic view of the structure of the A direction of the operation method of the granulation fluidized bed for pyrolysis of carbon black from waste tires.

Fig. 3 is a partial enlarged structural schematic diagram of a B operation method of the granulation fluidized bed for pyrolysis of carbon black from junked tires according to the present invention.

Fig. 4 is a partial enlarged structural schematic diagram of a part C of the operation method of the granulation fluidized bed for pyrolysis of carbon black from junked tires according to the present invention.

1-gas collection chamber 2-cyclone separator group 3-fluidized bed body 4-Y type material returning device

5-volute inlet 6-discharge elbow 7-drying chamber 8-pulse cloth bag dust collector

9-annular flow channel 10-spray hole 11-water delivery ring pipe 12-wall flow device.

Detailed Description

The invention is further described with reference to the following detailed description of embodiments and drawings.

As shown in fig. 1, 2, 3 and 4, the operation method of the granulation fluidized bed for pyrolysis of carbon black from waste tires is characterized in that: step one, blowing a cyclone separator group 2 and a fluidized bed body 3 by using fluidized inert tail gas, checking that a Y-shaped material returning device 4 has no cross flow, blowing a drying chamber 7 by using dry inert tail gas, and modulating the inert tail gas obtained by a steam jet pump according to the requirement of working gas required by the granulation of the pyrolytic carbon black, wherein the fluidized inert tail gas to be conveyed needs to be dispersed because the pyrolytic carbon black powder does not flow easily: oxygen content less than 3%, temperature 82 ℃At 85 ℃, the working pressure is 4000-8000 Pa; due to the limitation of water content in the product standard, the drying inert tail gas of the dried pyrolytic carbon black particles is required: oxygen content less than 3%, and water content less than 0.3g/m³The temperature is 250-280 ℃; the pyrolytic carbon black granulation adhesive is prepared by selecting water, adding 1-1.5% by mass of maltodextrin dissolved in the water to serve as the pyrolytic carbon black granulation adhesive, so that the intensity of pyrolytic carbon black particles is enhanced, the mixing amount of the pyrolytic carbon black and the maltodextrin aqueous solution is 1: 1-1.2 by mass, and the temperature of the maltodextrin aqueous solution is 82-85 ℃.

Secondly, the fluidized inert tail gas carries pyrolytic carbon black particles to enter the fluidized bed body 3 from the volute inlet 5 at a high speed, the outlet speed is 20-25 m/s, the pyrolytic carbon black particles are thrown to the wall of the fluidized bed body 3 under the action of centrifugal force and spirally ascend along with the fluidized inert tail gas wind band, the wall flow device 12 comprises an annular flow passage 9, a spray hole 10 and a water delivery ring pipe 11, a maltodextrin aqueous solution enters the annular flow passage 9 with the narrowed flow passage after passing through the water delivery ring pipe 11, the flow speed is sharply increased, in order to prevent the high-speed water flow from scouring and damaging the flow passage, the flow passage is designed to be annular, the high-speed water flow is sprayed out from top to bottom by the spray hole 10 and clings to the wall of the fluidized bed body 3 to moisten and scour the wall of the fluidized bed body 3, an adhesion deposition layer is timely cleaned, the pyrolytic carbon black particles are wetted and agglomerated by, observed from the cross section of the fluidization inert tail gas flow, the fluidization inert tail gas flow forms the characteristics of high peripheral flow velocity, low central flow velocity and high peripheral pressure compared with the central pressure, and drives the continuously growing and rounded pyrolytic carbon black particles to lose kinetic energy and gather towards the center in friction collision, the fluidization inert tail gas and the pyrolytic carbon black particles are separated and discharged to the cyclone separator group 2, the fluidization inert tail gas and the pyrolytic carbon black fine powder are separated again, the fluidization inert tail gas is discharged through the gas collection chamber 1, and the fine powder returns to the fluidization bed body 3 through the Y-shaped return feeder 4 to be continuously granulated.

Step three, after the rolling diameter of the pyrolytic carbon black particles grows until the sedimentation velocity exceeds the flow velocity of the fluidized inert tail gas, falls into a drying chamber 7 through a discharge bent pipe 6 under the action of gravity, dry inert tail gas enters from a side branch pipe at the bottom of the drying chamber 7 to heat and dry pyrolytic carbon black particles, because the pyrolytic carbon black finished product particles in the discharge elbow 6 form a material seal, dry inert tail gas cannot be blown out through the discharge elbow 6 to influence the airflow movement environment of the fluidized bed body 3, the dry inert tail gas discharged in the drying process is mixed with the fluidized inert tail gas discharged by the gas collection chamber 1 and discharged to the pulse bag dust collector 8 together, in order to prevent condensed water and carbon black from blocking a cloth bag, the waste heat of the dry inert tail gas is used for heating the fluidized inert tail gas, the working temperature of the pulse bag dust collector 8 is kept above 110 ℃, and carbon black fine powder collected by the pulse bag dust collector 8 is recycled.

Variations and modifications to the above-described embodiments may occur to those skilled in the art, which fall within the scope and spirit of the above description. Therefore, the present invention is not limited to the specific embodiments disclosed and described above, and some modifications and variations of the present invention should fall within the scope of the claims of the present invention. Furthermore, although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.

Claims

1. The operation method of the waste tire pyrolysis carbon black granulation fluidized bed is characterized in that: step one, blowing a cyclone separator set and a fluidized bed body by using fluidized inert tail gas, checking that a Y-shaped material returning device has no cross flow, and blowing a drying chamber by using dry inert tail gas; secondly, the fluidized inert tail gas carries pyrolytic carbon black particles to enter the fluidized bed body from the inlet of the volute at a high speed, the outlet speed is 20-25 m/s, the pyrolytic carbon black particles are thrown to the wall of the fluidized bed body under the action of centrifugal force, and spirally rises along with the fluidized inert tail gas wind band, the wall flow device comprises an annular flow channel, spray holes and a water delivery annular pipe, maltodextrin water solution enters the annular flow channel with the narrowed flow channel after passing through the water delivery annular pipe, the flow speed is rapidly increased, in order to prevent the flow channel from being washed and damaged by high-speed water flow, the flow channel is designed into an annular shape, the high-speed water flow is sprayed out from top to bottom by the spray holes and clings to the wall of the fluidized bed to wet and wash the wall of the fluidized bed, an adhered deposition layer is timely cleaned, the fluidized inert tail gas and pyrolytic carbon, the fluidization inert tail gas is separated from the pyrolytic carbon black fine powder again, the fluidization inert tail gas is discharged through a gas collecting chamber, and the fine powder returns to the fluidized bed body through a Y-shaped material returning device to continue granulation; and step three, rolling the diameter of the pyrolytic carbon black particles to grow until the sedimentation velocity exceeds the through-flow velocity of the fluidized inert tail gas, allowing the pyrolytic carbon black particles to fall into a drying chamber through a discharge elbow under the action of gravity, allowing the dry inert tail gas to enter a side branch pipe at the bottom of the drying chamber to heat and dry the pyrolytic carbon black particles, wherein the pyrolytic carbon black finished product particles in the discharge elbow form a material seal, so that the dry inert tail gas cannot escape through the discharge elbow to influence the air flow movement environment of a fluidized bed body, mixing the dry inert tail gas discharged in the drying process and the fluidized inert tail gas discharged by a gas collection chamber together and discharging the mixture to a pulse bag dust collector, heating the fluidized inert tail gas by using the waste heat of the dry inert tail gas to prevent the blockage of condensed water and carbon black, keeping the working temperature of the pulse bag dust collector above 110 ℃, and.

2. The method for operating the fluidized bed for granulation of carbon black from waste tires according to claim 1, wherein the method comprises the following steps: the inert tail gas obtained by the steam jet pump is modulated according to the requirement of working gas required by the granulation of the pyrolytic carbon black, and because the pyrolytic carbon black powder is not easy to flow, the fluidized inert tail gas which needs to be dispersed and conveyed: the oxygen content is lower than 3%, the temperature is 82-85 ℃, and the working pressure is 4000-8000 Pa; due to the limitation of water content in the product standard, the drying inert tail gas of the dried pyrolytic carbon black particles is required: oxygen content less than 3%, and water content less than 0.3g/m³And the temperature is 250-280 ℃.

3. The method for operating the fluidized bed for granulation of carbon black from waste tires according to claim 1, wherein the method comprises the following steps: the pyrolytic carbon black granulation adhesive is prepared by selecting water, adding 1-1.5% by mass of maltodextrin dissolved in the water to serve as the pyrolytic carbon black granulation adhesive, so that the intensity of pyrolytic carbon black particles is enhanced, the mixing amount of the pyrolytic carbon black and the maltodextrin aqueous solution is 1: 1-1.2 by mass, and the temperature of the maltodextrin aqueous solution is 82-85 ℃.