CN112057412A - Freckle-removing and whitening cosmetic containing anti-black ingredients and preparation process thereof - Google Patents
Freckle-removing and whitening cosmetic containing anti-black ingredients and preparation process thereof Download PDFInfo
- Publication number
- CN112057412A CN112057412A CN202011173645.7A CN202011173645A CN112057412A CN 112057412 A CN112057412 A CN 112057412A CN 202011173645 A CN202011173645 A CN 202011173645A CN 112057412 A CN112057412 A CN 112057412A
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- Prior art keywords
- sliding
- fixedly connected
- freckle
- whitening
- component
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- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/82—Preparation or application process involves sonication or ultrasonication
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Abstract
The invention discloses a freckle-removing and whitening cosmetic containing an anti-black component and a preparation method thereof, wherein the cosmetic comprises the following components in parts by weight: 1-15 parts of whitening and freckle removing component, 1-15 parts of anti-black component and 1-10 parts of auxiliary agent component. The product prepared by the invention can provide nutrition, promote metabolism of skin cells, repair suntan and sunburnt skin, dissolve melanin precipitate, lighten color spots, improve oxidation resistance of the skin, inhibit activity of tyrosinase, and further inhibit generation of melanin, and meanwhile, the nano pearl powder is used as an anti-black component, can effectively shield ultraviolet rays, provides various nutrient substances for the skin, can directly absorb and nourish the skin, and cannot block pores after long-term use. The technical scheme of the invention provides a freckle-removing and whitening cosmetic containing an anti-black component and a preparation method thereof, wherein an ultrasonic dispersion instrument is used in the step of mixing and dispersing raw material components, so that the raw materials are uniformly dispersed, the emulsification and fusion effects are good, and the preparation of uniform products is facilitated.
Description
Technical Field
The invention relates to the technical field of cosmetics, in particular to a freckle-removing and whitening cosmetic containing an anti-black component and a preparation process thereof.
Background
The white is used as the beauty, the Chinese fashion history is spread far away, and the whitening is the fashion topic of the Asian forever fastness. Ultraviolet rays in sunlight have a harmful effect on DNA in human cells, and if ultraviolet rays are irradiated for a long time, skin diseases, skin cancers and the like can be caused, so that gene mutation can be caused seriously, and the gene mutation is malignant generally. The melanin can absorb ultraviolet rays to further protect skin from skin damage caused by excessive ultraviolet irradiation, and after a human body is irradiated by sunlight ultraviolet rays, tyrosinase is stimulated and activated by the ultraviolet rays, the process of synthesizing the melanin by melanocytes is accelerated, and the skin becomes dark. When the metabolism of the body is poor, part of the pigment is left on the surface layer of the skin to form black spots. In addition, in recent years, as the pace of life of people is accelerated, the working pressure is increased, the life is irregular, and the sleeping quality is poor, more and more people are in a sub-health state for a long time, and the phenomena of dull skin, more and more color spots and the like are increasingly aggravated.
In order to whiten and keep the skin healthy, the skin needs to be whitened and protected from the sun. During whitening care, the generated melanin can be slowly eliminated, and the skin can be protected from being damaged by ultraviolet rays by sun protection, the activity of tyrosinase is not stimulated, and the skin can be helped to inhibit new melanin generation.
The ultrasonic dispersion instrument is a process of dispersing and deagglomerating particles in liquid by using liquid as a medium and through the cavitation action of ultrasonic waves in the liquid, and can be used for water treatment, solid-liquid system dispersion, deagglomeration of particles in the liquid, promotion of solid-liquid reaction and other effects.
Disclosure of Invention
In order to solve the problems in the background art, the present invention aims to provide a spot-removing whitening cosmetic containing an anti-black component and a preparation process thereof.
A freckle-removing and whitening cosmetic containing an anti-black component comprises the following components in parts by weight:
1-15 parts of whitening and freckle-removing component
1-15 parts of anti-black component
1-10 parts of auxiliary agent component
The whitening and freckle-removing component is a raw material for promoting metabolism of skin cells, dissolving melanin precipitate and fading freckles; the anti-tanning component is a raw material capable of shielding ultraviolet rays and preventing skin from being tanned and sunburned.
Preferably, the whitening and spot-removing component comprises at least one of shea butter, niacinamide, arbutin, oligopeptides, vitamin E, aloe extract and astaxanthin.
Shea butter is pure natural green plant source solid oil, and has effects of promoting epidermal cell regeneration, providing skin with nutrition function, and repairing sunburn and damaged skin.
Nicotinamide can accelerate metabolism, accelerate exfoliation of keratin containing melanocytes, can be directly absorbed by epidermal cells, stimulate vitality of decayed cells, promote synthesis of collagen, prevent excessive melanin deposition, and achieve whitening effect. In addition, after melanin is produced, the skin is blackened only by being transported to the stratum corneum. The nicotinamide can reduce the transfer of melanin to the horny layer of the skin, reduce the deposition of melanin in the horny layer and avoid the skin from turning black.
Arbutin is extracted from the leaves of bearberry and can inhibit the activity of tyrosinase in vivo and prevent the generation of melanin, thereby reducing skin pigmentation and removing stains and freckles.
Oligopeptide generally consists of 4-10 amino acids, has small molecular weight and easy absorption, can ensure that cells are connected more tightly, accelerate the metabolism speed, promote dead skin to fall off, prevent melanin deposition and make the skin white.
Vitamin E can protect skin from ultraviolet rays and pollution, and reduce scar and pigmentation.
The polysaccharide and the multivitamins contained in the aloe have good nourishing, moistening and whitening effects on human skin, and the polysaccharide is a specific component for activating cells at the bottom layer of the skin and can effectively remove skin pigments.
The astaxanthin has the functions of resisting photoaging damage of ultraviolet rays to skin, resisting oxidation and repairing skin barrier.
Preferably, the anti-black component is nano pearl powder.
The nanometer Margarita powder contains various amino acids and microelements, and has effects of whitening skin, controlling oil, removing acne, removing blackhead, removing speckle, promoting granulation, and preventing sunburn.
Preferably, the auxiliary agent component comprises an emulsifier, a humectant, a fat-endowing agent, a thickener, a preservative, an antioxidant and a complexing agent.
Further, the emulsifier is any one of a mixture of tween-20 and span-20, a mixture of tween-40 and span-40, a mixture of tween-60 and span-60, and a mixture of tween-80 and span-80, and the mass percentage of the emulsifier in the cosmetic is 0.1% -2.0%.
Further, the humectant is any one of glycerol, propylene glycol, butanediol, sorbitol, polyethylene glycol 200 and hyaluronic acid, and the content of the humectant in the cosmetic is 0.1-2.0% by mass.
Further, the fatting agent is any one of caprylic triglyceride, capric triglyceride, isopropyl palmitate, cetyl palmitate and cocoglyceride, and the content of the fatting agent in the cosmetic is 1.0-10.0% by mass.
Further, any one of xanthan gum and xanthan gum serving as thickening agents is 0.1-1.0% of the cosmetic by mass.
Further, the preservative is any one of phenoxyethanol, sodium benzoate and potassium sorbate, and the content of the preservative in the cosmetic is 0.05-0.5% by mass.
Further, the antioxidant is any one of ascorbyl palmitate, ethylhexyl glycerol and butyl hydroxy anisol, and the content of the antioxidant in the cosmetic is 0.1-1.0% by mass.
Further, the complexing agent is any one of disodium ethylene diamine tetraacetate and tetrasodium ethylene diamine tetraacetate, and the mass percentage of the complexing agent in the cosmetic is 0.05% -0.5%.
Preferably, the preparation process of the freckle-removing and whitening cosmetic containing the anti-black component comprises the following steps of:
the method comprises the following steps: preparation of nano pearl powder
(1) Selection of raw materials: selecting fresh water pearls without nucleuses;
(2) cleaning and drying: naturally drying at room temperature after cleaning;
(3) coarse crushing: pulverizing air-dried Margarita into coarse powder;
(4) fine powder: blending the pearl coarse powder into 10-20% slurry by using absolute ethyl alcohol, and further pulverizing into pearl fine powder slurry by using a high-shear colloid mill;
(5) nano-grade crushing: pulverizing Margarita fine powder slurry into 50-100nm Margarita nanopowder slurry in a high shear homogenizer,
(6) and (3) drying: drying the nanometer pearl powder slurry in vacuum freeze drying equipment to obtain nanometer pearl powder;
step two: heating and dissolving various auxiliary agent components in deionized water at 50-60 ℃;
step three: and adding the whitening and freckle-removing component and the nano pearl powder into the solution to form a mixed solution, putting the mixed solution into an ultrasonic dispersion instrument, and uniformly dispersing and emulsifying the components in the mixed solution by utilizing ultrasonic vibration to obtain the whitening and freckle-removing product containing the anti-black component.
The technical scheme solves the problems of darkening of human skin caused by ultraviolet irradiation, dark skin and increased color spots caused by irregular life and the like, and can effectively shield ultraviolet rays and inhibit melanin generation. However, in the production process, because solid powder is easy to agglomerate in a liquid phase, the traditional process equipment is difficult to completely disperse the solid-liquid two phases, the liquid-liquid two phases of a water phase and an oil phase can not be completely emulsified and fused, so that the components of a product are not uniform and unstable, the dispersion and emulsification step is carried out by the ultrasonic dispersion instrument, the mixed solution is placed in a liquid storage tank of the ultrasonic dispersion instrument, a dispersion instrument body, namely an ultrasonic generator is started to generate ultrasonic waves, the ultrasonic waves are transmitted to an operating head through a connecting pipe, the height of the liquid storage tank is adjusted through a pushing mechanism, the operating head is inserted into the mixed solution, the strong cavitation effect is excited by the action of ultrasonic vibration energy on the liquid, a large amount of cavitation bubbles are generated in the liquid, solid particles are crushed along with the generation and explosion of the cavitation bubbles, the oil phase components are dispersed into, in addition, the second rotating shaft is extended into the liquid storage tank to stir the mixed liquid through the linkage effect of the motor driving the rotating shaft, so that the dispersion and emulsification effects are improved, and the dispersion and emulsification uniformity of the mixed liquid are realized;
wherein the ultrasonic dispersion instrument comprises an operation shell, the upper surface of the operation shell is clamped with an operation head, the top end of the operation head is communicated with the dispersion instrument body through a connecting pipe, the front side of the operation shell is provided with a bin door, the lower surface of the inner wall of the operation shell is fixedly connected with a first installation block, the upper surface of the first installation block is provided with a third chute, the third chute is in sliding connection with a third sliding block, the back side of the third sliding block is fixedly connected with a pushing mechanism, the upper surface of the third sliding block is hinged with one end of a rotating rod through a first pin shaft, the other end of the rotating rod is hinged with the lower surface of the second installation block through a second pin shaft, the lower surface of the second installation block is fixedly connected with the lower surface of the inner wall of the third chute through a first telescopic rod, the upper surface of the second installation block is provided with a second chute, the second sliding block is in sliding connection, the back of the liquid storage tank is provided with a clamping mechanism, the left side surface and the right side surface of the clamping mechanism are respectively connected with a rotating mechanism in a clamping manner, the rotating mechanisms are fixedly connected with the upper surface of the second mounting block, the clamping mechanism is attached to the outer surface of the liquid storage tank, the back of the operation shell is fixedly connected with a fixed block, the lower surface of the fixed block is provided with a groove, a pushing mechanism is inserted into the groove, the upper surface of the fixed block is fixedly connected with a motor, an output shaft of the motor is fixedly connected with a fourth rotating shaft, the fourth rotating shaft is sleeved in a fourth bearing clamped on the back of the inner wall of the operation shell, the front side surface and the back side surface of the inner wall of the operation shell are respectively connected with a three bearing in a clamping manner, a third rotating shaft is sleeved in the third bearing, the outer surfaces of the third, the worm joint is in the surface of second pivot, and the second pivot cover is established in the second bearing of operation shell inner wall upper surface joint, and two second pivots all extend to in the stock solution jar, each the bottom of second pivot is equidistant to be provided with the flabellum, the top of flabellum is provided with helical blade.
Further, slewing mechanism includes first slider, and first spout has been seted up to the left surface of operation shell inner wall, and sliding connection has first slider in the first spout, the right flank fixedly connected with spliced pole of first slider, two racks of the back fixedly connected with of spliced pole, the upper surface meshing of rack has the gear, the gear joint is at clamping mechanism's surface, the clamping mechanism joint is at the surface of installation shell.
Further, clamping mechanism includes first pivot, and the surface joint of first pivot has the gear, and first pivot is established in the first bearing of installation shell left and right sides face joint, and the surface joint of first pivot has the screw thread post, and the surface threaded connection of screw thread post has the screw cap, and the positive fixedly connected with extension rod of screw cap, the front end fixedly connected with splint of extension rod, the extension rod pass the positive spacing hole of seting up of installation shell, and the surface of extension rod and the inner wall laminating in spacing hole.
Furthermore, the extension rod penetrates through a limiting hole formed in the front face of the mounting shell, and the outer surface of the extension rod is attached to the inner wall of the limiting hole.
Furthermore, the number of the clamping plates is two, and the opposite surfaces of the two clamping plates are respectively attached to the left side surface and the right side surface of the liquid storage tank.
Further, the number of the threaded columns is two, and the threads of the two threaded columns are opposite.
Further, pushing mechanism includes the second slide bar, and the back fixedly connected with second slide bar of control shell, the surface sliding connection of second slide bar has the second sliding sleeve, and the upper surface of second sliding sleeve passes through spring and second telescopic link fixedly connected with connecting plate, and the spring housing is established at the surface of second telescopic link, and the last fixed surface of connecting plate is connected with the fixture block, and the fixture block is inserted to in the recess, the lower fixed surface of second sliding sleeve is connected with the gag lever post, how the first slide bar of fixedly connected with of gag lever post, first slide bar sliding connection in the first sliding sleeve of control shell back joint.
Furthermore, the number of the grooves is multiple, and the grooves are uniformly distributed on the lower surface of the fixing block.
Furthermore, a baffle is fixedly connected to the rear end of the second sliding rod.
Furthermore, the number of the second sliding blocks is two, and the two second sliding blocks are uniformly distributed on the upper surface of the second mounting block.
Compared with the prior art, the invention has the following beneficial technical effects:
1. the whitening and freckle-removing component contained in the product can provide nutrition to promote metabolism of skin cells, repair damaged skin and slowly dissolve and remove generated melanin, and can improve the oxidation resistance of the skin, inhibit the activity of tyrosinase and further inhibit the generation of the melanin;
2. the anti-black component of the invention is the nano pearl powder, the dispersibility is good, the ultraviolet ray can be effectively shielded, the fine particles of the nano pearl powder form a uniform barrier layer on the surface of the skin, the ultraviolet ray can be reflected and scattered, the effective physical sun-screening effect is achieved, in addition, the pearl powder is a pure natural nutrient substance, the nano particles can be absorbed by the skin to utilize various nutrient components in the nano pearl powder, so that the skin is nourished, the transparency is good, the problem that pores are blocked by long-term use like zinc oxide, titanium dioxide and the like can not occur, and the using amount is not limited.
3. The pearl powder is prepared by a physical method, does not need a high-temperature treatment process, does not add any other substance, does not destroy any substance, maintains all nutrient components of the pearl, is prepared by absolute ethyl alcohol, and has quick liquid phase volatilization during vacuum freeze drying, thereby greatly improving the drying speed.
4. When the invention carries out dispersion and emulsification treatment on each component of the raw materials in the mixed liquid, the mixed liquid is firstly placed in a liquid storage tank of an ultrasonic disperser, the ultrasonic disperser is provided with a pushing mechanism, a third slide block can be pushed by the pushing mechanism to slide, the third slide block is arranged, the sliding of the third slide block in a third sliding chute can change the angle and the position of a rotating rod, the change of the angle and the position of the rotating rod is utilized to drive a second mounting block to move up and down, then a first telescopic rod is arranged, the second mounting block can be assisted to move up and down by the expansion and contraction of the first telescopic rod, the second mounting block is arranged, the liquid storage tank can move up and down by the up and down movement of the second mounting block, the height of the liquid storage tank is convenient to adjust, and the mixed liquid can be ensured to be contacted with an, the mixed solution is placed in an ultrasonic field, and the dispersion and emulsification of each component in the mixed solution by ultrasonic vibration are realized.
5. Utilize ultrasonic dispersion appearance to when mixing liquid to disperse emulsification treatment, the rotation of motor can drive the fourth pivot and rotate, the transmission that utilizes drive wheel and drive belt is connected, it rotates to drive the third pivot, utilize the cooperation of worm wheel and worm and then drive two second pivots and rotate, the bottom equidistant fan blade that is provided with of second pivot, and the top of fan blade is provided with helical blade, the second pivot is stretched into and can be stirred mixing liquid in the mixed liquid of liquid storage pot, make dispersion appearance body to mix the effect better between each component in the mixed liquid, the effect of dispersion emulsification has been improved.
Drawings
FIG. 1 is a flow chart of the manufacturing process of the present invention;
fig. 2 is a schematic perspective view of a self-suspending elevation type ultrasonic disperser according to the present invention;
FIG. 3 is a schematic side view of a cross-sectional structure of a self-suspending elevation ultrasonic disperser according to the present invention;
FIG. 4 is an enlarged schematic structural view of A in a self-suspending elevation type ultrasonic disperser according to the present invention;
fig. 5 is a schematic front sectional view of a middle mounting shell of the self-suspending elevation type ultrasonic dispersion meter according to the present invention;
fig. 6 is a schematic top view of a second mounting block in the self-suspending elevating ultrasonic disperser according to the present invention;
fig. 7 is a schematic perspective view of a pushing mechanism in a self-suspending elevation type ultrasonic disperser according to the present invention.
In the figure: 1. a dispersion meter body; 2. a connecting pipe; 3. an operating shell; 4. a bin gate; 5. a rotating mechanism; 51. a first slider; 52. connecting columns; 53. a gear; 54. mounting a shell; 55. a rack; 6. a clamping mechanism; 61. a first rotating shaft; 62. a threaded cap; 63. an extension pole; 64. a threaded post; 65. a splint; 7. a pushing mechanism; 71. a clamping block; 72. a connecting plate; 73. a baffle plate; 74. a spring; 75. a sliding sleeve; 76. a limiting rod; 77. a first slide bar; 78. a second slide bar; 8. an operating head; 9. a second rotating shaft; 10. a worm; 11. a worm gear; 12. a transmission belt; 13. a driving wheel; 14. a motor; 15. a fixed block; 16. a third rotating shaft; 17. a second slider; 18. a first mounting block; 19. a first telescopic rod; 20. a second mounting block; 21. a third slider; 22. a liquid storage tank; 23. a fourth rotating shaft; 24. a fan blade; 25. a helical blade.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1
The freckle-removing and whitening cosmetic containing the anti-black component comprises the following components in parts by weight:
whitening and freckle removing component 8 parts
6 portions of auxiliary agent component
Wherein the whitening and freckle-removing component comprises shea butter and vitamin E, the shea butter and the vitamin E respectively account for 50 percent of 8 parts by weight, the anti-black component comprises nano pearl powder, the emulsifier in the auxiliary component is a mixture of Tween-60 and span-60, the dosage of the humectant in the cosmetic is 1.0 percent by weight, the humectant in the auxiliary component is glycerin, the dosage of the humectant in the cosmetic is 1.0 percent by weight, the fatting agent in the auxiliary component is coco glyceride, the dosage of the fatting agent in the cosmetic is 5 percent by weight, the thickener in the auxiliary component is xanthan gum, the dosage of the thickener in the cosmetic is 0.5 percent by weight, the preservative in the auxiliary component is potassium sorbate, the dosage of the preservative in the cosmetic is 0.1 percent by weight, the antioxidant in the auxiliary component is ascorbyl palmitate, and the dosage of the antioxidant in the cosmetic is 0.5 percent by weight, the complexing agent in the auxiliary agent component is disodium ethylene diamine tetraacetate, the mass percentage of the dosage in the cosmetic is 0.2%, and the balance is deionized water.
Preparing nano pearl powder:
(1) selection of raw materials: selecting fresh water pearls without nucleuses;
(2) cleaning and drying: naturally drying at room temperature after cleaning;
(3) coarse crushing: pulverizing air-dried Margarita into coarse powder;
(4) fine powder: blending the pearl coarse powder into 15% slurry by using absolute ethyl alcohol, and further pulverizing into pearl fine powder slurry by using a high-shear colloid mill;
(5) nano-grade crushing: pulverizing Margarita fine powder slurry into nanometer Margarita powder slurry of about 60nm in a high shear homogenizer,
(6) and (3) drying: drying the nanometer pearl powder slurry in vacuum freeze drying equipment to obtain nanometer pearl powder;
the preparation of the freckle-removing and whitening cosmetic containing the anti-black component comprises the following steps:
heating and dissolving various auxiliary components in deionized water at 55 ℃;
and adding the whitening and freckle-removing component and the nano pearl powder into the solution to form a mixed solution, putting the mixed solution into an ultrasonic dispersion instrument, and uniformly dispersing and emulsifying the components in the mixed solution by utilizing ultrasonic vibration to obtain the whitening and freckle-removing product containing the anti-black component.
Example 2
The freckle-removing and whitening cosmetic containing the anti-black component comprises the following components in parts by weight:
whitening and freckle removing component 5 parts
Wherein the whitening and freckle-removing component comprises niacinamide and arbutin, the niacinamide accounts for 40 weight parts of 5 weight parts, the arbutin accounts for 60 weight parts of 5 weight parts, the anti-black component comprises nano pearl powder, the emulsifier in the auxiliary component is a mixture of tween-20 and span-20, the using amount of the emulsifier in the auxiliary component is 0.5 weight percent of the cosmetic, the humectant in the auxiliary component is butanediol, the using amount of the humectant in the cosmetic is 0.5 weight percent of the cosmetic, the fat-imparting agent in the auxiliary component is isopropyl palmitate, the using amount of the emulsifier in the cosmetic is 3 weight percent, the thickener in the auxiliary component is xanthan gum, the using amount of the thickener in the cosmetic is 0.4 weight percent, the preservative in the auxiliary component is phenoxyethanol, the using amount of the preservative in the cosmetic is 0.2 weight percent, and the antioxidant in the auxiliary component is butyl hydroxy anisole, the mass percentage of the usage amount in the cosmetics is 0.2 percent, the complexing agent in the auxiliary agent component is ethylenediaminetetraacetic acid tetrasodium salt, the mass percentage of the usage amount in the cosmetics is 0.1 percent,
the preparation of nano pearl powder is the same as example 1.
The preparation of the freckle-removing and whitening cosmetic containing the anti-black component comprises the following steps:
heating and dissolving various auxiliary components in deionized water at 50 ℃;
and adding the whitening and freckle-removing component and the nano pearl powder into the solution to form a mixed solution, putting the mixed solution into an ultrasonic dispersion instrument, and uniformly dispersing and emulsifying the components in the mixed solution by utilizing ultrasonic vibration to obtain the whitening and freckle-removing product containing the anti-black component.
Example 3
The freckle-removing and whitening cosmetic containing the anti-black component comprises the following components in parts by weight:
14 parts of whitening and freckle-removing component
9 portions of auxiliary agent component
Wherein the whitening and freckle-removing component comprises aloe extract and astaxanthin, the aloe extract accounts for 14 weight parts, 70% of astaxanthin accounts for 30 weight parts of 14 weight parts, the anti-black component comprises nano pearl powder, the emulsifier in the auxiliary component is a mixture of tween-80 and span-80, the using amount of the emulsifier in the auxiliary component is 1.5% by mass in the cosmetic, the humectant in the auxiliary component is hyaluronic acid, the using amount of the humectant in the cosmetic is 1.5% by mass, the fat-imparting agent in the auxiliary component is cetyl palmitate, the using amount of the fat-imparting agent in the cosmetic is 8% by mass, the thickener in the auxiliary component is xanthan gum, the using amount of the thickener in the cosmetic is 0.6% by mass, the preservative in the auxiliary component is sodium benzoate, the using amount of the preservative in the cosmetic is 0.3% by mass, and the antioxidant in the auxiliary component is ethylhexyl glycerol, the mass percentage of the usage amount in the cosmetics is 0.8 percent, the complexing agent in the auxiliary agent component is disodium ethylene diamine tetraacetate, the mass percentage of the usage amount in the cosmetics is 0.4 percent,
the preparation of nano pearl powder is the same as example 1.
The preparation of the freckle-removing and whitening cosmetic containing the anti-black component comprises the following steps:
heating and dissolving various auxiliary components in deionized water at 60 ℃;
and adding the whitening and freckle-removing component and the nano pearl powder into the solution to form a mixed solution, putting the mixed solution into an ultrasonic dispersion instrument, and uniformly dispersing and emulsifying the components in the mixed solution by utilizing ultrasonic vibration to obtain the whitening and freckle-removing product containing the anti-black component.
Example 4
As shown in fig. 2-7, the ultrasonic dispersion apparatus used in step three includes an operation housing 3, an operation head 8 is clamped on an upper surface of the operation housing 3, a top end of the operation head 8 is communicated with the dispersion apparatus body 1 through a connection pipe 2, a door 4 is arranged on a front surface of the operation housing 3, a first installation block 18 is fixedly connected to a lower surface of an inner wall of the operation housing 3, a third sliding groove is arranged on an upper surface of the first installation block 18, a third sliding block 21 is slidably connected in the third sliding groove, a pushing mechanism 7 is fixedly connected to a back surface of the third sliding block 21, the pushing mechanism 7 includes a second sliding rod 78, a second sliding rod 78 is fixedly connected to a back surface of the operation housing 3, a baffle 73 is fixedly connected to a back end of the second sliding rod 78, the second sliding sleeve 75 can be blocked by setting the baffle 73, the second sliding sleeve 75 is prevented from sliding out of the second sliding rod 78, thereby affecting operation of, the outer surface of the second sliding rod 78 is slidably connected with a second sliding sleeve 75, the upper surface of the second sliding sleeve 75 is fixedly connected with a connecting plate 72 through a spring 74 and a second telescopic rod, the spring 74 is sleeved on the outer surface of the second telescopic rod, the upper surface of the connecting plate 72 is fixedly connected with a fixture block 71, the fixture block 71 is inserted into a plurality of grooves, the plurality of grooves are uniformly distributed on the lower surface of the fixing block 15, and the fixture block 71 can be inserted into different positions through the plurality of grooves by arranging the plurality of grooves, so that the sliding sleeve 75 can be moved to different positions, and the adjustment of different positions of the liquid storage tank 22 is realized;
the lower surface of the second sliding sleeve 75 is fixedly connected with a limiting rod 76, how the limiting rod 76 is fixedly connected with a first sliding rod 77, the first sliding rod 77 is connected in the first sliding sleeve 75 clamped on the back surface of the operating shell 3 in a sliding manner, through the arrangement of the second sliding sleeve 75, the sliding of the second sliding sleeve 75 in the second sliding rod 78 can drive the limiting rod 76 to push the first sliding rod 77 to move back and forth, so that the third sliding block 21 can move back and forth by the back and forth movement of the first sliding rod 77, the up and down movement of the second mounting block 20 is realized, and the up and down position of the liquid storage tank 22 can be adjusted conveniently by people;
the upper surface of the third sliding block 21 is hinged to one end of the rotating rod through a first pin shaft, the other end of the rotating rod is hinged to the lower surface of the second mounting block 20 through a second pin shaft, the lower surface of the second mounting block 20 is fixedly connected to the lower surface of the inner wall of the third sliding groove through a first telescopic rod 19, a second sliding groove is formed in the upper surface of the second mounting block 20, the second sliding grooves are connected with the second sliding blocks 17 in a sliding mode, the number of the second sliding blocks 17 is two, the two second sliding blocks 17 are uniformly distributed on the upper surface of the second mounting block 20, and the liquid storage tank 22 can smoothly enter the operating shell 3 by means of sliding of the second sliding blocks 17 in the second sliding grooves through the arrangement of the two second sliding blocks 17; the bottom end of each second rotating shaft 9 is provided with fan blades 24 at equal intervals, the top end of each fan blade 24 is provided with a spiral blade 25, the second rotating shaft 9 rotates to drive the fan blades 24 at the bottom end to rotate, mixed liquid is stirred, the mixed liquid around the operating head 8 flows, the activity of the mixed liquid around the operating head 8 is improved, the top end of each fan blade 24 is provided with a spiral blade 25, the bottom end of each second rotating shaft 9 extends into the raw materials, the spiral blades 25 rotate to push the mixed liquid to the bottom, and fluctuation of the mixed liquid when the surface of the mixed liquid is stirred is reduced;
the upper surface of the second sliding block 17 is attached with the liquid storage tank 22, the back of the liquid storage tank 22 is provided with a clamping mechanism 6, the clamping mechanism 6 comprises a first rotating shaft 61, the outer surface of the first rotating shaft 61 is connected with a gear 53 in a clamped manner, the first rotating shaft 61 is sleeved in a first bearing which is clamped and connected with the left side surface and the right side surface of the installation shell 54, the outer surface of the first rotating shaft 61 is connected with two threaded columns 64 in a clamped manner, the number of the threaded columns 64 is two, the threads of the two threaded columns 64 are opposite, the two threaded columns 64 are arranged, the two threaded caps 62 can drive the two clamping plates 65 to move in opposite directions by utilizing the simultaneous rotation of the two threaded columns 64, so that the liquid storage tank 22 is clamped by the clamping plates 65, the shaking of the liquid storage tank 22 is avoided, the outer surface of the threaded columns 64 is connected with the threaded caps 62 in a threaded manner, the front of, the outer surface of the extension rod 63 is attached to the inner wall of the limiting hole, the number of the clamping plates 65 is two, the opposite surfaces of the two clamping plates 65 are respectively attached to the left side surface and the right side surface of the liquid storage tank 22, the liquid storage tank 22 can be fixed more firmly by the two clamping plates 65 by arranging the two clamping plates 65, shaking of the liquid storage tank 22 is avoided, mixed liquid in the liquid storage tank 22 can be processed smoothly, the rotation of the screw cap 62 can be limited by the limiting hole, so that the screw cap 62 can only move horizontally, the clamping plates 65 are fixedly connected to the front end of the extension rod 63, the extension rod 63 penetrates through the limiting hole formed in the front surface of the mounting shell 54, the outer surface of the extension rod 63 is attached to the inner wall of the limiting hole, the two screw posts 64 can rotate by the rotation of the first rotating shaft 61 by arranging the first rotating shaft 61, and the two screw caps 62 can move by the rotation of the, thereby driving the two clamping plates 65 to approach, thereby realizing the fixation of the liquid storage tank 22 and avoiding the toppling of the liquid storage tank 22;
the rotating mechanisms 5 are clamped on the left side surface and the right side surface of the clamping mechanism 6, each rotating mechanism 5 comprises a first sliding block 51, a first sliding groove is formed in the left side surface of the inner wall of the operating shell 3, the first sliding block 51 is connected in the first sliding groove in a sliding mode, a connecting column 52 is fixedly connected to the right side surface of the first sliding block 51, two racks 55 are fixedly connected to the back surface of the connecting column 52, a gear 53 is meshed on the upper surface of each rack 55, the gear 53 is clamped on the outer surface of the clamping mechanism 6, the clamping mechanism 6 is clamped on the outer surface of the mounting shell 54, by arranging the first slider 51, the rack 55 can move back and forth by the sliding of the first slider 51 in the first sliding groove, the gear 53 can be driven to rotate by the back and forth movement of the rack 55, and the first rotating shaft 61 can be rotated by the rotation of the gear 53, so that the clamping plate 65 can fix the liquid storage tank 22;
the rotating mechanism 5 is fixedly connected to the upper surface of the second mounting block 20, the clamping mechanism 6 is attached to the outer surface of the liquid storage tank 22, the back surface of the operating shell 3 is fixedly connected with a fixed block 15, a groove is formed in the lower surface of the fixed block 15, a pushing mechanism 7 is inserted into the groove, the upper surface of the fixed block 15 is fixedly connected with a motor 14, an output shaft of the motor 14 is fixedly connected with a fourth rotating shaft 23, the fourth rotating shaft 23 is sleeved in a fourth bearing clamped on the back surface of the inner wall of the operating shell 3, three bearings are clamped on the front side surface and the back side surface of the inner wall of the operating shell 3, a third rotating shaft 16 is sleeved in the third bearing, transmission wheels 13 are clamped on the outer surfaces of the third rotating shaft 16 and the fourth rotating shaft 23, the two transmission wheels 13 are in transmission connection through a transmission belt 12, two worm wheels 11 are clamped on the outer surface of the third rotating, the second rotating shafts 9 are sleeved in second bearings clamped on the upper surface of the inner wall of the operating shell 3, and the two second rotating shafts 9 extend into the liquid storage tank 22;
the clamping mechanism 6 comprises a first rotating shaft 61, a gear 53 is clamped on the outer surface of the first rotating shaft 61, the first rotating shaft 61 is sleeved in a first bearing clamped on the left side surface and the right side surface of the mounting shell 54, a threaded column 64 is clamped on the outer surface of the first rotating shaft 61, a threaded cap 62 is connected on the outer surface of the threaded column 64 in a threaded manner, an extension rod 63 is fixedly connected on the front surface of the threaded cap 62, a clamping plate 65 is fixedly connected on the front end of the extension rod 63, the extension rod 63 penetrates through a limiting hole formed in the front surface of the mounting shell 54, and the outer surface of the extension rod 63 is attached to, by providing the first rotating shaft 61, the two threaded posts 64 can be rotated by the rotation of the first rotating shaft 61, the two threaded caps 62 can be moved by the rotation of the two threaded posts 64, thereby driving the two clamping plates 65 to approach each other, thereby realizing the fixation of the liquid storage tank 22 and avoiding the toppling of the liquid storage tank 22.
When the ultrasonic dispersion instrument is used for dispersing and emulsifying the mixed liquid, the mixed liquid to be processed is put into the liquid storage tank 22, the bin gate 4 is opened, the liquid storage tank 22 is put on the second slide block 17 and the liquid storage tank 22 is pushed to enter the operation shell 3, the bin gate 4 is closed, the connecting plate 72 is pressed downwards to enable the clamping block 71 to be separated from the groove, so that the sliding sleeve 75 is driven to move forwards, the limiting rod 76 drives the first slide rod 77 to move, the third slide block 21 is driven to move forwards, the angle and position of the rotating rod are changed, so that the second mounting block 20 drives the liquid storage tank 22 to change the position, the connecting rod 52 is pulled and the connecting rod 52 is pushed backwards, the rack 55 drives the gear 53 to rotate, the two threaded columns 64 drive the two threaded caps 62 to move by utilizing the rotation of the gear 53, so that the two clamping plates 65 are close to the liquid storage tank 22 to, and simultaneously, the motor 14 is started, the fourth rotating shaft 23 is driven to rotate by the rotation of the motor 14, so that the third rotating shaft 16 is driven to rotate by the driving wheel 13 and the driving belt 12, and the two second rotating shafts 9 are driven to rotate by the rotation of the third rotating shaft 16 through the matching of the worm wheel 11 and the worm 10 and the mixed liquid in the liquid storage tank 22 is stirred.
The freckle-removing and whitening cosmetic containing the anti-blackening component prepared in the embodiments 1-3 is rich in whitening freckle-removing components and anti-blackening components, various effective auxiliary agents are added, and the product is uniform and fine through dispersing and emulsifying treatment by an ultrasonic disperser, so that the product can provide nutrition, promote metabolism of skin cells, repair suntan and sunburned skin, dissolve melanin sediment, fade color spots, improve the oxidation resistance of the skin, inhibit the activity of tyrosinase, and further inhibit the generation of melanin, and meanwhile, the nano pearl powder is used as the anti-blackening component, so that the ultraviolet rays can be effectively shielded, various nutrient substances are provided for the skin, and the nano pearl powder can be directly absorbed and nourish the skin, and pores cannot be blocked after long-term use.
In the embodiment 4, when the ultrasonic dispersion instrument is used to perform dispersion and emulsification treatment on each component of the raw material in the mixed liquid, the mixed liquid is first placed in the liquid storage tank of the ultrasonic dispersion instrument, the ultrasonic dispersion instrument is provided with the pushing mechanism, the third slider can be pushed by the pushing mechanism to slide, the third slider is arranged, the third slider can slide in the third sliding groove to change the angle and the position of the rotating rod, the second mounting block is driven to move up and down by the change of the angle and the position of the rotating rod, the second mounting block can be assisted to move up and down by the extension and contraction of the first telescopic rod by the arrangement of the third slider, the liquid storage tank can move up and down by the up and down movement of the second mounting block by the arrangement of the second mounting block, the height of the liquid storage tank can be conveniently adjusted, and the mixed liquid can be ensured to be contacted with the operating, the mixed solution is placed in an ultrasonic field, and the dispersion and emulsification of each component in the mixed solution by ultrasonic vibration are realized.
The rotation of motor can drive the fourth pivot and rotate, the transmission that utilizes drive wheel and drive belt is connected, it rotates to drive the third pivot, the cooperation of recycling worm wheel and worm and then drive two second pivots and rotate, the equidistant flabellum that is provided with in bottom of second pivot, and the top of flabellum is provided with helical blade, the second pivot is stretched into and can be stirred mixed liquid in the mixed liquid of liquid storage pot, make the dispersion appearance body to mix the effect better between each component in the mixed liquid, the emulsified effect of dispersion has been improved.
The ultrasonic wave dispersion instrument is provided with the rotating mechanism, the clamping mechanism can be close to the liquid storage tank by utilizing the rotation of the rotating mechanism, so that the liquid storage tank is clamped tightly, the liquid storage tank is prevented from being toppled by violent vibration generated by the dispersion instrument body in the machining process, and the liquid storage tank is prevented from being broken and the mixed liquid in the liquid storage tank is prevented from being lost and wasted.
Ultrasonic dispersion appearance is provided with the fixed block, utilizes the fixed block to make the motor by fixed mounting more stable, has guaranteed the stability of motor operation to utilize the motor to make the mixed liquid in the liquid storage pot can be by more stable of stirring, and utilize the recess of fixed block lower surface to play limiting displacement to pushing mechanism, thereby make the height of liquid storage pot can be by stable change, made things convenient for the mixed liquid dispersion emulsification in the liquid storage pot.
The above description is only a preferred embodiment of the present invention, and the protection scope of the present invention is not limited to the above embodiments, and all technical solutions belonging to the idea of the present invention belong to the protection scope of the present invention. It should be noted that modifications and embellishments within the scope of the invention may occur to those skilled in the art without departing from the principle of the invention, and are considered to be within the scope of the invention.
Claims (9)
1. The freckle-removing and whitening cosmetic containing the anti-black component is characterized by comprising the following components in parts by weight:
1-15 parts of whitening and freckle-removing component
1-15 parts of anti-black component
1-10 parts of auxiliary agent component
Wherein the whitening and freckle-removing component is a raw material for promoting skin cell metabolism, dissolving melanin precipitate and fading freckles; the anti-tanning component is a raw material which can shield ultraviolet rays and prevent the skin from being tanned and sunburned.
2. The spot-removing whitening cosmetic containing an anti-black ingredient according to claim 1, wherein the spot-removing whitening component comprises at least one of shea butter, niacinamide, arbutin, oligopeptide, vitamin E, aloe vera extract and astaxanthin.
3. The spot-removing whitening cosmetic containing an anti-black component according to claim 1, wherein the anti-black component is nano pearl powder.
4. The spot-removing whitening cosmetic containing an anti-black component according to claim 1, wherein the auxiliary agent comprises an emulsifier, a humectant, a fat-imparting agent, a thickener, a preservative, an antioxidant, and a complexing agent;
the emulsifier is any one of a mixture of Tween-20 and span-20, a mixture of Tween-40 and span-40, a mixture of Tween-60 and span-60 and a mixture of Tween-80 and span-80, and the mass percentage content of the emulsifier in the cosmetic is 0.1-2.0%;
the humectant is any one of glycerol, propylene glycol, butanediol, sorbitol, polyethylene glycol 200 and hyaluronic acid, and the content of the humectant in the cosmetic is 0.1-2.0% by mass;
the fatting agent is any one of caprylic triglyceride, capric triglyceride, isopropyl palmitate, cetyl palmitate and cocoglyceride, and the mass percentage of the fatting agent in the cosmetic is 1.0% -10.0%;
any one of xanthan gum and xanthan gum serving as thickening agents is 0.1-1.0% of the cosmetic by mass percentage;
the preservative is any one of phenoxyethanol, sodium benzoate and potassium sorbate, and the mass percentage of the preservative in the cosmetic is 0.05-0.5%;
the antioxidant is any one of ascorbyl palmitate, ethylhexyl glycerol and butyl hydroxy anisol, and the mass percentage of the antioxidant in the cosmetic is 0.1-1.0%;
the complexing agent is any one of disodium ethylene diamine tetraacetate and tetrasodium ethylene diamine tetraacetate, and the mass percentage content of the complexing agent in the cosmetic is 0.05-0.5%.
5. A preparation method of a freckle-removing and whitening cosmetic containing an anti-black component is characterized by comprising the following steps:
the method comprises the following steps: preparing nano pearl powder:
(1) selection of raw materials: selecting fresh water pearls without nucleuses;
(2) cleaning and drying: naturally drying at room temperature after cleaning;
(3) coarse crushing: pulverizing air-dried Margarita into coarse powder;
(4) fine powder: blending the pearl coarse powder into 10-20% slurry by using absolute ethyl alcohol, and further crushing the pearl coarse powder into pearl fine powder slurry by using a high-shear colloid mill;
(5) nano-grade crushing: pulverizing Margarita fine powder slurry into 50-100nm Margarita nanopowder slurry in a high shear homogenizer;
(6) and (3) drying: drying the nanometer pearl powder slurry in vacuum freeze drying equipment to obtain nanometer pearl powder;
step two: heating and dissolving various auxiliary agent components in deionized water at 50-60 ℃;
step three: and adding the whitening and freckle-removing component and the nano pearl powder into the solution to form a mixed solution, putting the mixed solution into an ultrasonic dispersion instrument, and uniformly dispersing and emulsifying the components in the mixed solution by utilizing ultrasonic vibration to obtain the whitening and freckle-removing product containing the anti-black component.
6. The method for preparing a freckle-removing and whitening cosmetic containing an anti-black component according to claim 7, wherein the three steps of dispersing and emulsifying are carried out by using an ultrasonic disperser, the mixed solution is placed in a liquid storage tank of the ultrasonic disperser, a body of the disperser, namely an ultrasonic generator, is started to generate ultrasonic waves, the ultrasonic waves are transmitted to the operating head through a connecting pipe, the operating head is inserted into the mixed solution by adjusting the height of the liquid storage tank through a pushing mechanism, and the ultrasonic vibration energy enables the two phases of solid and liquid to be uniformly dispersed and the two phases of liquid and liquid to be emulsified and fused, so that the uniform dispersion and emulsification of the mixed solution is realized;
wherein the ultrasonic dispersion instrument comprises an operation shell (3) and is characterized in that the upper surface of the operation shell (3) is clamped with an operation head (8), the top end of the operation head (8) is communicated with a dispersion instrument body (1) through a connecting pipe (2), the front surface of the operation shell (3) is provided with a bin door (4), the lower surface of the inner wall of the operation shell (3) is fixedly connected with a first installation block (18), the upper surface of the first installation block (18) is provided with a third sliding chute, the third sliding chute is internally and slidably connected with a third sliding block (21), the back surface of the third sliding block (21) is fixedly connected with a pushing mechanism (7), the upper surface of the third sliding block (21) is hinged with one end of a rotating rod through a first pin shaft, the other end of the rotating rod is hinged with the lower surface of a second installation block (20) through a second pin shaft, the lower surface of the second installation block (20) is fixedly connected with the lower surface of the inner wall of, a second chute is formed in the upper surface of the second mounting block (20), a second sliding block (17) is connected in the second chute in a sliding mode, a liquid storage tank (22) is attached to the upper surface of the second sliding block (17), a clamping mechanism (6) is arranged on the back surface of the liquid storage tank (22), rotating mechanisms (5) are connected to the left side surface and the right side surface of the clamping mechanism (6) in a clamping mode, the rotating mechanisms (5) are fixedly connected to the upper surface of the second mounting block (20), the clamping mechanism (6) is attached to the outer surface of the liquid storage tank (22), a fixing block (15) is fixedly connected to the back surface of the operating shell (3), a groove is formed in the lower surface of the fixing block (15), a pushing mechanism (7) is inserted into the groove, a motor (14) is fixedly connected to the upper surface of the fixing block (15), a fourth rotating shaft (23) is fixedly connected to an output shaft of the motor (14), and the, the equal joint of front and back both sides face of operation shell (3) inner wall has three bearings, the third bearing endotheca is equipped with third pivot (16), the equal joint of surface of third pivot (16) and fourth pivot (23) has drive wheel (13), two drive wheels (13) are connected through drive belt (12) transmission, the surface joint of third pivot (16) has two worm wheel (11), the surface meshing of worm wheel (11) has worm (10), worm (10) joint is at the surface of second pivot (9), second pivot (9) cover is established in the second bearing of operation shell (3) inner wall upper surface joint, two second pivot (9) all extend to liquid storage pot (22) in, each the bottom of second pivot (9) is equidistant to be provided with flabellum (24), the top of flabellum (24) is provided with helical blade (25).
7. The method for preparing a freckle-removing and whitening cosmetic containing an anti-black component according to claim 6, wherein the rotating mechanism (5) in the ultrasonic dispersion instrument comprises a first slider (51), a first sliding groove is formed in the left side surface of the inner wall of the operating shell (3), the first slider (51) is slidably connected in the first sliding groove, a connecting column (52) is fixedly connected to the right side surface of the first slider (51), two racks (55) are fixedly connected to the back surface of the connecting column (52), a gear (53) is meshed with the upper surface of each rack (55), the gear (53) is clamped on the outer surface of the clamping mechanism (6), and the clamping mechanism (6) is clamped on the outer surface of the mounting shell (54);
the clamping mechanism (6) comprises a first rotating shaft (61), a gear (53) is clamped on the outer surface of the first rotating shaft (61), the first rotating shaft (61) is sleeved in a first bearing clamped on the left side surface and the right side surface of the installation shell (54), a threaded column (64) is clamped on the outer surface of the first rotating shaft (61), a threaded cap (62) is connected on the outer surface of the threaded column (64) in a threaded manner, an extension rod (63) is fixedly connected on the front surface of the threaded cap (62), a clamping plate (65) is fixedly connected on the front end of the extension rod (63), the extension rod (63) penetrates through a limiting hole formed in the front surface of the installation shell (54), the outer surface of the extension rod (63) is attached to the inner wall of the limiting hole, the number of the clamping plates (65) is two, the opposite surfaces of the two clamping plates (65) are respectively attached to the left side surface and the right side surface of the liquid storage tank (22), the number of the threaded columns (64) is two, and the threads of the two threaded columns (64) are opposite.
8. The method for preparing a spot-removing whitening cosmetic containing an anti-black ingredient according to claim 7, it is characterized in that the pushing mechanism (7) in the ultrasonic dispersion instrument comprises a second sliding rod (78), the back of the operating shell (3) is fixedly connected with the second sliding rod (78), the outer surface of the second sliding rod (78) is connected with a second sliding sleeve (75) in a sliding manner, the upper surface of the second sliding sleeve (75) is fixedly connected with a connecting plate (72) through a spring (74) and a second telescopic rod, the spring (74) is sleeved on the outer surface of the second telescopic rod, the upper surface of the connecting plate (72) is fixedly connected with a clamping block (71), the clamping block (71) is inserted into the groove, the lower surface fixedly connected with gag lever post (76) of second sliding sleeve (75), how fixedly connected with first slide bar (77) of gag lever post (76), first slide bar (77) sliding connection is in first sliding sleeve (75) of operation shell (3) back joint.
9. The method for preparing a spot-removing whitening cosmetic containing an anti-black ingredient according to claim 8, wherein the ultrasonic dispersion instrument has a plurality of grooves which are uniformly distributed on the lower surface of the fixing block (15);
the rear end of the second sliding rod (78) is fixedly connected with a baffle, the number of the second sliding blocks (17) is two, and the two second sliding blocks (17) are uniformly distributed on the upper surface of the second mounting block (20).
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| CN202011173645.7A CN112057412B (en) | 2020-10-28 | 2020-10-28 | Freckle-removing and whitening cosmetic containing anti-black ingredients and preparation process thereof |
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| CN112057412B (en) | 2021-04-13 |
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