CN111962292A - 自发热料体及自发热活性炭无纺布发帽 - Google Patents
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Abstract
本发明提供了一种自发热料体及自发热活性炭无纺布发帽,所述自发热料体包括以下重量百分含量的各组分:发热剂1 10%~50%,发热剂2 30%~80%,热感剂0.01%~0.5%,分散剂5%~10%,去离子水0.1%~10%。本发明的自发热活性炭无纺布发帽轻便易携带,使用方便安全,无需在有电源的地方使用;而且本发明的自发热料体通过激发料液从液体变成固体,伴随放热过程,且可以通过吸收来的水气物理发热,从而能够使护发美发类产品如护理发膜,焗油膏等中的营养物质更好的被头发所吸收。
Description
技术领域
本发明涉及高分子材料技术领域,具体涉及一种自发热料体及自发热活性炭无纺布发帽,尤其涉及一种物理吸湿发热自发热材料及其制备的自发热活性炭无纺布发帽。
背景技术
由于人们烫发,染发日益频繁,日常护发美发的需求日益增多,而护发美发类产品如护理发膜,焗油膏等中的营养物质使用时均需加热才能更好的被头发所吸收,市场上经常用电加热的护发帽,不仅产品笨重,加热时必须在有电源的地方,使用空间受到限制,不能随意走动,随着人们生活节奏的加快,要求人们对时间利用效率的加快,电加热的护发帽不便之处日益明显。
现有的自发热材料中,专利文献CN108542589中公开了一种恒温发热组合物,其包含了金属粉、活性炭、发热促进剂、吸水性聚合物、水溶性聚合物、表面活性剂、相变微胶囊和水。其制备的自发热帖发热温度稳定性好。
专利文献CN108283339A中公开了一种自发热袋,其包含有聚合物固体电解质、高纯度铁粉、活性炭、蛭石粉和盐,且记载了聚合物固体电解质采用丙酰溴化钠和聚乙二醇制备,或用脲、硫脲和聚乙二醇制备。
然而,上述专利文献均采用的自发热方式是铁粉氧化发热,涉及化学反应。
发明内容
本发明针对现有技术的不足,提供了一种自发热料体及自发热活性炭无纺布发帽。采用本发明的自发热料体制备的自发热活性炭无纺布发帽相较于传统的电加热发帽,便于携带,使用方便安全,无需在有电源的地方使用,不受使用空间限制。
本发明的目的是通过以下技术方案实现的:
本发明提供了一种自发热料体,其特征在于,包括以下重量百分含量的各组分:
所述发热剂1的加入量过多时,则会导致发帽发热时帽体会变硬,不能很好的贴合头部。
优选地,所述发热剂1为硫代硫酸钠、醋酸钠中的一种或两种。
优选地,所述发热剂2为peg-200、peg-400中的一种或两种。若采用高分子量的PEG,则会导致产品变成半固态或固态。
优选地,所述热感剂为辣椒素、辣椒碱、姜醇、姜烯酚、姜油酮、香草醇丁醚、香草醇异丙基醚、香草醇异丁基醚、香草醇正氨基醚、香草醇异戊基醚、香草醇正己基醚、香草醇甲醚和香草醇乙醚中的一种或几种。其加入可提升使用时的热感,增强热感。
优选地,所述分散剂为异丙醇IPA、丙三醇,丙二醇、山梨醇、乙二醇、硅油中的一种或几种。
优选地,所述自发热料体还含有质量百分含量为0.1%~0.3%的杀菌剂,所述杀菌剂为尼泊酸金酯、苯氧乙醇、馨鲜酮中的一种或几种。
本发明还提供了一种自发热料体的制备方法,包括以下步骤:
A、在去离子水中加入分散剂,热感剂,搅拌均匀,得A料;
B、将发热剂1加入A料中,搅拌至发热剂1完全溶解均后,将发热剂2再加入其中搅拌均匀,即得自发热料体。
本发明专利利用的主要是发热料体通过瞬间激发变成固体状态从而伴随放热的过程,其中的发热剂2在湿度高的情况下就能够溶解放热
而发热剂1从液态变成固态的实现形式可以为:
1、当无纺布直接浸吸发热料体时,可以把激发料体的微粒(硫代硫酸钠颗粒,醋酸钠颗粒,或者铜颗粒,其仅起到激发作用,不发生反应)放在发膜中,当使用者将发帽直接套在涂有发膜(发膜含有激发料体的微粒)的头发上,发帽中的发热剂1被金属微粒激发使自发热料体从液体变成固体,从而放出热量;
2、当无纺布发帽是中空结构时,可以在灌入发热料体的腔体1附近增加一个腔体2,腔体2中灌入激发料体的微粒(硫代硫酸钠颗粒,醋酸钠颗粒,或者铜颗粒,其仅起到激发作用,不与发热剂1发生反应),在使用时将腔体2的微粒挤入腔体1,腔体1的料体中的发热剂1即可以立即被激发反应使自发热料体由液体变成固体,伴随放热过程。
本发明还提供了一种自发热料体在制备自发热产品中的应用。
本发明还提供了一种自发热帽,其特征在于,包括帽体和前述的自发热料体,所述帽体为具有中空结构的无纺布帽体或无中空结构的无纺布帽体,所述自发热料体设置在无纺布帽体的中空结构内或无中空结构的无纺布帽体直接浸吸发热料体。
优选地,所述帽体采用活性炭无纺布制备。
本发明还提供了一种自发热帽的制备方法,包括以下步骤:
将自发热料体灌入帽体的中空结构内或无中空结构的无纺布帽体直接浸吸发热料体,然后封装,即得。
本发明制备的自发热活性炭无纺布发帽在进行发膜护发,焗油美发等需要加热操作时,其接触人体后能自发热升温3-7℃左右,从而能对头发起到一个加热作用,让营养物质更好地被头发吸收。
本发明将活性炭无纺布制作成待束带的帽体形状,将制备的自发热料体均匀浸入帽体,形成能自发热的活性炭发帽,并且该自发热料体对皮肤无刺激性,使用方便,轻便易携,环保卫生,不需要插电,不受使用位置空间限制,使用时可随意走动,且使用时不妨碍正常工作生活,能够高效利用时间。
现有技术相比,本发明具有如下的有益效果:
1、本发明的自发热活性炭无纺布发帽轻便易携带,使用方便安全,无需在有电源的地方使用。
2、本发明的自发热料体通过吸收来的水气物理发热,从而能够使护发美发类产品如护理发膜,焗油膏等中的营养物质更好的被头发所吸收。
3、本发明的整个发热过程不涉及化学反应,瞬间激发,发热迅速,发热料体通过瞬间激发变成固体状态从而伴随放热的过程,且发热剂2是在湿度高的情况下溶解放热。
附图说明
通过阅读参照以下附图对非限制性实施例所作的详细描述,本发明的其它特征、目的和优点将会变得更明显:
图1为实施例1制备的具有发热料体自发热功能的活性炭无纺布发帽的帽体升温结果;
图2为实施例2制备的具有发热料体自发热功能的活性炭无纺布发帽的帽体升温结果;
图3为实施例3制备的具有发热料体自发热功能的活性炭无纺布发帽的帽体升温结果;
图4为实施例4制备的具有发热料体自发热功能的活性炭无纺布发帽的帽体升温结果;
图5为实施例1制备的具有自发热功能的活性炭无纺布发帽结构图;
图6为实施例1制备的具有自发热功能的活性炭无纺布发帽俯视图。
具体实施方式
下面结合具体实施例对本发明进行详细说明。以下实施例将有助于本领域的技术人员进一步理解本发明,但不以任何形式限制本发明。应当指出的是,对本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进。这些都属于本发明的保护范围。
实施例1
按各原料的重量百分比,称取3%的去离子水,加入0.3%的香兰基丁醚,0.1%馨鲜酮,10%丙三醇搅拌均匀的溶液A。再称取50%的硫代硫酸钠,36.6%的PEG400加入溶液A中,然后混合液在70℃水浴锅中搅拌均匀。待混合液冷却至室温后即得自发热料体。
将自发热料体按照50克标准灌装在帽体的腔体1中,帽体的腔体2中装有激发微粒硫代硫酸钠颗粒,使用时需将腔体2中的激发微粒挤入腔体1,即成具有自发热功能的活性炭无纺布发帽,如图5和图6所示。所述发帽的帽体升温结果如图1所示。
实施例2
按各原料的重量百分比,称取5%的去离子水,加入0.5%的香兰基丁醚,0.2%苯氧乙醇,8%丙三醇搅拌均匀的溶液A。再称取30%的硫代硫酸钠,56.3%的PEG400加入溶液A,然后混合液在70℃水浴锅中搅拌均匀。待混合液冷却至室温后即得自发热料体。
将无纺布发帽浸吸自发热料体50克后封入袋中,消费者使用时,需要配合使用加有激发微粒的发膜,所述加有激发微粒的发膜为在现有的常规发膜中添加入1%的激发微粒硫代硫酸钠颗粒,混合均匀后得到。述发帽的帽体升温结果如图2所示。
实施例3
按各原料的重量百分比,称取3.9%的去离子水,加入0.8%的姜烯酚,0.3%馨鲜酮,5%山梨醇搅拌均匀的溶液A。再称取30%的醋酸钠,60%的PEG200加入溶液A,然后混合液在70℃水浴锅中搅拌均匀。待混合液冷却至室温后即得自发热料体。由此将本实施例制备的自发热料体按实施例1的相同方法制备的发帽使用时升温结果如图3。
实施例4
按各原料的重量百分比,称取0.1%的去离子水,加入0.1%的辣椒素,0.2%馨鲜酮,10%乙二醇搅拌均匀的溶液A。再称取10%的硫代硫酸钠,79.6%的PEG200加入溶液A,然后混合液在70℃水浴锅中搅拌均匀。待混合液冷却至室温后即得自发热料体。由此将本实施例制备的自发热料体按实施例1的相同方法制备的发帽使用时升温效果如图4。
对比例1
本对比例与实施例1相比,各组分及含量基本相同,不同之处仅在于:本对比例不添加PEG400,硫代硫酸钠的质量百分含量为86.6%。由此制备的发帽使用时不具备吸湿发热的功能,如果只添加硫代硫酸钠,不加PEG-400发热时发帽变硬,不能很好的贴合头部,从而达不到较好的加热效果。
对比例2
本对比例与实施例1相比,各组分及含量基本相同,不同之处仅在于:本对比例不添加硫代硫酸钠,PEG400的质量百分含量为86.6%。由此制备的发帽使用时发热缓慢,且微量,不足以达到加热的效果。
对比例3
本对比例与实施例2相比,各组分及含量基本相同,不同之处仅在于:本对比例采用PEG800代替PEG400。由此制备的发帽使用时吸湿性能不明显,无法产生足够热量,且料体由于太稠,无法均匀分散在发帽上。
对比例4
本对比例与实施例4相比,各组分及含量基本相同,不同之处仅在于:本对比例添加硫代硫酸钠的质量百分含量为5%,PEG400的质量百分含量为84.6%。由此制备的发帽使用时发热缓慢,发热热量不足以达到合适较热的效果。
对比例5
本对比例与实施例1相比,各组分及含量基本相同,不同之处仅在于:本对比例添加硫代硫酸钠的质量百分含量为60%,PEG400的质量百分含量为26.6%。由此制备的发帽使用时发帽变硬,不能很好地贴合头部,且产品的吸湿效果不明显。
本发明具体应用途径很多,以上所述仅是本发明的优选实施方式。应当指出,以上实施例仅用于说明本发明,而并不用于限制本发明的保护范围。对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进,这些改进也应视为本发明的保护范围。
Claims (10)
2.根据权利要求1所述的自发热料体,其特征在于,所述发热剂1为硫代硫酸钠、醋酸钠中的一种或两种。
3.根据权利要求1所述的自发热料体,其特征在于,所述发热剂2为peg-200、peg-400中的一种或两种。
4.根据权利要求1所述的自发热料体,其特征在于,所述热感剂为辣椒素、辣椒碱、姜醇、姜烯酚、姜油酮、香草醇丁醚、香草醇异丙基醚、香草醇异丁基醚、香草醇正氨基醚、香草醇异戊基醚、香草醇正己基醚、香草醇甲醚和香草醇乙醚中的一种或几种。
5.根据权利要求1所述的自发热料体,其特征在于,所述分散剂为异丙醇IPA、丙三醇,丙二醇、山梨醇、乙二醇、硅油中的一种或几种。
6.根据权利要求1所述的自发热料体,其特征在于,所述自发热料体还含有质量百分含量为0.1%~0.3%的杀菌剂,所述杀菌剂为尼泊酸金酯、苯氧乙醇、馨鲜酮中的一种或几种。
7.一种如权利要求1所述的自发热料体的制备方法,其特征在于,包括以下步骤:
A、在去离子水中加入分散剂,热感剂,搅拌均匀,得A料;
B、将发热剂1加入A料中,搅拌至发热剂1完全溶解均后,将发热剂2再加入其中搅拌均匀,即得自发热料体。
8.一种如权利要求1所述的自发热料体在制备自发热产品中的应用。
9.一种自发热帽,其特征在于,包括帽体和权利要求1所述的自发热料体,所述帽体为具有中空结构的无纺布帽体或无中空结构的无纺布帽体,所述自发热料体设置在无纺布帽体的中空结构内或无中空结构的无纺布帽体直接浸吸发热料体。
10.一种根据权利要求8所述自发热帽的制备方法,其特征在于,包括以下步骤:
将自发热料体灌入帽体的中空结构内或无中空结构的无纺布帽体直接浸吸发热料体,然后封装,即得。
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