CN111908572A - Metal substrate carbon nano-film water body purification device - Google Patents

Metal substrate carbon nano-film water body purification device Download PDF

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Publication number
CN111908572A
CN111908572A CN202010934099.8A CN202010934099A CN111908572A CN 111908572 A CN111908572 A CN 111908572A CN 202010934099 A CN202010934099 A CN 202010934099A CN 111908572 A CN111908572 A CN 111908572A
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China
Prior art keywords
metal substrate
power supply
carbon nano
fixed
energy storage
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Pending
Application number
CN202010934099.8A
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Chinese (zh)
Inventor
王亚普
刘铁林
高硕�
欧阳光友
田霆
王海涛
刘红涛
李来喜
赵建泽
繆建峰
黎明
孙福亭
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Hebei Meipulandi Environmental Protection Technology Co ltd
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Hebei Meipulandi Environmental Protection Technology Co ltd
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Application filed by Hebei Meipulandi Environmental Protection Technology Co ltd filed Critical Hebei Meipulandi Environmental Protection Technology Co ltd
Priority to CN202010934099.8A priority Critical patent/CN111908572A/en
Publication of CN111908572A publication Critical patent/CN111908572A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/48Treatment of water, waste water, or sewage with magnetic or electric fields
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/009Apparatus with independent power supply, e.g. solar cells, windpower, fuel cells

Abstract

The invention discloses a metal substrate carbon nano-film water body purification device, which belongs to the field of water pollution control and comprises a core field effect generation mechanism, a multi-waveform low-voltage variable-frequency power supply mechanism, a remote control data acquisition and analysis mechanism, an energy storage mechanism, a buoyancy mechanism, a circulation auxiliary mechanism and a warning mechanism, wherein the core field effect generation mechanism is fixed at the bottom of the buoyancy mechanism, the multi-waveform low-voltage variable-frequency power supply mechanism is fixed at the middle part of the buoyancy mechanism, the multi-waveform low-voltage variable-frequency power supply mechanism is connected with the core field effect generation mechanism, the energy storage mechanism is fixed above the buoyancy mechanism, the energy storage mechanism is connected with the multi-waveform low-voltage variable-frequency power supply mechanism, and the two circulation auxiliary. The metal substrate carbon nano-film water body purification device adopting the structure can catalyze and degrade organic pollutants in water bodies and bottom sludge, reduce harmful indexes of the water bodies, improve the transparency of the water bodies, the dissolved oxygen and the activity of the water bodies, and has a wide action area.

Description

Metal substrate carbon nano-film water body purification device
Technical Field
The invention relates to the field of water pollution treatment, in particular to a metal substrate carbon nano-film water body purification device.
Background
The enrichment of nutrients such as nitrogen and phosphorus in natural water bodies, artificial lakes and artificial rivers leads to the abnormal proliferation of algae, the generation of water bloom or lake indigo, the reduction of water transparency, the reduction of dissolved oxygen, the serious deterioration of water quality, the pollution of other organic pollutants, the influence on beauty, the damage to ecological balance, the occurrence of certain diseases and the like, and therefore, the water bodies need to be treated.
The physical methods commonly used in water body treatment include aeration, sediment dredging and water-induced scouring. However, the prior art has the defects of slow effect, high cost, narrow action area, easy occurrence of secondary pollution and the like.
Disclosure of Invention
The invention aims to provide a metal substrate carbon nano-film water body purification device which can catalyze and degrade organic pollutants in water bodies and bottom sludge, reduce harmful indexes of the water bodies, improve dissolved oxygen of the water bodies, improve transparency and activity of the water bodies, and has low energy consumption, wide action area and high treatment efficiency.
In order to realize the aim, the invention provides a metal substrate carbon nano-film water body purification device, which comprises a core field effect generation mechanism, a multi-waveform low-voltage variable frequency power supply mechanism, a remote control data acquisition and analysis mechanism, an energy storage mechanism, a buoyancy mechanism, a circulation auxiliary mechanism and a warning mechanism,
the core field effect generating mechanism is fixed at the bottom of the buoyancy mechanism, the multi-waveform low-voltage variable-frequency power supply mechanism is fixed in the middle of the buoyancy mechanism, the multi-waveform low-voltage variable-frequency power supply mechanism is connected with the core field effect generating mechanism, the energy storage mechanism is fixed above the buoyancy mechanism, the energy storage mechanism is connected with the multi-waveform low-voltage variable-frequency power supply mechanism, and the two circulation auxiliary mechanisms are symmetrically fixed at two sides of the buoyancy mechanism.
Preferably, the core field effect generating mechanism includes the metal crate box with a net and set up in the inside core field effect generating unit of metal crate box with a net, the core field effect generating unit is provided with one at least, the core field effect generating unit include central polypropylene punch a hole the board, set up in the first polyethylene net piece of central polypropylene punching a hole board both sides, set up in the metallic copper sheet auxiliary electrode in the first polyethylene net piece outside, set up in the metallic substrate carbon nanomembrane pole piece in the metallic copper sheet auxiliary electrode outside, set up in metallic substrate carbon nanomembrane pole piece outside second polyethylene net piece and set up in the side polypropylene punching a hole board in the second polyethylene net piece outside.
Preferably, the metal substrate carbon nano-film pole piece comprises a porous metal base material and a carbon atom allotrope composite film covering the surface of the porous metal base material.
Preferably, the multi-waveform low-voltage variable frequency power supply mechanism comprises a multi-waveform low-voltage variable frequency power supply and a waterproof distribution box, the multi-waveform low-voltage variable frequency power supply is arranged in the waterproof distribution box, and the multi-waveform low-voltage variable frequency power supply is connected with the core field effect generation mechanism.
Preferably, the buoyancy mechanism comprises a floating platform, a floating platform guardrail support, a solar cell panel support and a camera support, wherein the floating platform guardrail support is fixed on the floating platform, and the solar cell panel support and the camera support are fixed on the floating platform guardrail support.
Preferably, the remote control data acquisition and analysis mechanism comprises a data acquisition device, a power supply detection sensor and a camera, the camera is fixed on the camera support, the camera and the power supply detection sensor are both connected with the data acquisition device, and the data acquisition device is communicated with the cloud platform server.
Preferably, the energy storage mechanism comprises an energy storage battery pack, an energy storage inverter and a solar panel, the solar panel is fixed on the solar panel support, the energy storage inverter is connected with the energy storage battery pack, and the energy storage battery pack is connected with the solar panel.
Preferably, the circulation auxiliary mechanism comprises a flexible fixing support, a fountain water pump fixed at the top end of the flexible support and a safety steel wire rope used for reinforcement, one end of the safety steel wire rope is fixed on the floating platform guardrail support, the other end of the safety steel wire rope is fixed on the flexible fixing support, and the bottom end of the flexible fixing support is fixed on the floating platform guardrail support.
Preferably, the warning mechanism is a warning lamp or a warning board or an underwater color lamp.
Preferably, the porous metal base material is copper foam, copper foam alloy, nickel foam alloy, aluminum foam alloy, stainless steel sintered felt, metal fiber, metal wire mesh or metal wire woven mesh.
Therefore, according to the metal substrate carbon nano-film water body purification device adopting the structure, under the action of the multi-waveform low-voltage variable-frequency power supply mechanism, the core field effect generation mechanism enables water molecules to generate atomic oxygen (O) and hydroxyl radicals (& OH), the hydroxyl radicals have extremely high oxidation potential (2.80eV) and extremely high oxidation capacity, and can perform rapid chain reaction with most organic pollutants, so that harmful substances are oxidized into CO2, H2O or mineral salts, secondary pollution is avoided, organic pollutants in water bodies and bottom sludge of the water bodies can be degraded in a catalytic manner to be harmless, the water body value, ammonia nitrogen value, total nitrogen value and total phosphorus value are reduced, indexes such as COD (DO) Dissolved Oxygen (DO) and oxidation reduction potential of the water bodies are improved, the transparency and activity of the water bodies are improved, and the self-cleaning capacity of the water bodies is recovered; meanwhile, the water body is circulated through the circulation auxiliary device, so that the energy consumption is low, the action area is enlarged, and the purification efficiency is improved; the device electric energy is ensured to be supplied uninterruptedly through the energy storage device; the remote control data acquisition and analysis mechanism is used for carrying out operations such as acquisition of corresponding data, remote control and the like, so that the personnel cost is reduced, and the operation is convenient and fast.
The technical solution of the present invention is further described in detail by the accompanying drawings and embodiments.
Drawings
FIG. 1 is a schematic structural diagram of a water purification device with a metal substrate carbon nano-film according to the present invention;
FIG. 2 is a schematic structural diagram of a core field effect generating mechanism according to the present invention;
FIG. 3 is a schematic diagram of a core field effect generating unit according to the present invention;
fig. 4 is a schematic diagram of the circuit of the present invention.
Reference numerals
1. A core field effect generating mechanism; 11. a central polypropylene punching plate; 12. a first polyethylene mesh sheet; 13. a metal copper sheet auxiliary electrode; 14. a metal substrate carbon nanofilm pole piece; 15. a second polyethylene mesh; 16. a polypropylene punching plate; 2. a multi-waveform low-voltage variable-frequency power supply mechanism; 3. an energy storage mechanism; 31. an energy storage inverter; 32. a solar panel; 33. an energy storage battery pack; 4. a circulation assistance mechanism; 41. a flexible fixing support; 42. an insurance wire rope; 43. a fountain pump; 5. a buoyancy mechanism; 51. a floating platform; 52. a floating platform guardrail bracket; 53. a camera mount; 54. a solar panel support; 6. a warning light; 7. remotely controlling a data acquisition and analysis mechanism; 71. a data acquisition device; 72. a power supply detection sensor; 73. a camera.
Detailed Description
Examples
Fig. 1 is a schematic structural diagram of a metal substrate carbon nano-film water body purification device, fig. 2 is a schematic structural diagram of a core field effect generation mechanism of the invention, fig. 3 is a schematic structural diagram of a core field effect generation unit of the invention, and as shown in the figure, the metal substrate carbon nano-film water body purification device comprises a core field effect generation mechanism 1, a multi-waveform low-voltage variable-frequency power supply mechanism 2, a remote control data acquisition and analysis mechanism 7, an energy storage mechanism 3, a buoyancy mechanism 5, a circulation auxiliary mechanism 4 and a warning mechanism.
The buoyancy mechanism 5 comprises a floating platform 51, a floating platform guardrail bracket 52, a solar cell panel bracket 54 and a camera bracket 53, wherein the floating platform guardrail bracket 52 is fixed on the floating platform 51, and the solar cell panel bracket 54 and the camera bracket 53 are fixed on the floating platform guardrail bracket 52.
The core field effect generating mechanism 1 is fixed to the bottom of the floating platform 51 so that it is immersed in water for water treatment. The core field effect generating mechanism 1 comprises a metal frame net cage and a core field effect generating unit arranged inside the metal frame net cage, the metal frame net cage ensures the use safety of the device through insulation treatment, the core field effect generating unit comprises a central polypropylene punching plate 11, first polyethylene net sheets 12 arranged on two sides of the central polypropylene punching plate 11, metal copper sheet auxiliary electrodes 13 arranged on the outer sides of the first polyethylene net sheets 12, metal substrate carbon nano-film pole sheets 14 arranged on the outer sides of the metal copper sheet auxiliary electrodes 13, second polyethylene net sheets 15 arranged on the outer sides of the metal substrate carbon nano-film pole sheets 14 and side polypropylene punching plates 16 arranged on the outer sides of the second polyethylene net sheets 15, so that certain intervals and water permeability are kept among all the parts of the core field effect generating unit, and the effect of isolating all the parts is achieved. At least one core field effect generating unit is arranged, and the number of the core field effect generating units is determined according to actual needs. The metal substrate carbon nano-film pole piece 14 comprises a porous metal base material and a carbon atom allotrope composite film covering the surface of the porous metal base material, wherein the porous metal base material is foamed copper, foamed copper alloy, foamed nickel alloy, foamed aluminum alloy, stainless steel sintered felt, metal fiber, metal wire mesh or metal wire woven mesh. The method adopts a magnetron sputtering assisted chemical vapor deposition coating technology, and a layer of carbon atom allotrope composite film with nano-scale thickness is covered on the surface of a metal base material, and the metal base material carbon nano-film material has various physical and chemical properties such as graphene, graphite alkyne, carbon nano-tube, fullerene, diamond and the like, has excellent electromagnetic, optical and electrochemical properties, and has an ultra-large specific surface area: the thickness is more than 2000m/g, and the contact area is improved. The high-density boundary site of the carbon atom allotrope composite film is used as an active center catalytic proton, water can be efficiently electro-catalytically decomposed under the conditions of non-doping and no loading of a cocatalyst, and the rich high-density boundary tip site of the carbon nano film enables the carbon nano film to have high catalytic performance. When light (natural light can be used without adding a lighting device) and a special electric field are applied to the metal substrate carbon nano-film material, the metal substrate carbon nano-film material has a very strong catalytic effect on water molecules: atomic oxygen (O) and hydroxyl radical (. OH) are generated. The hydroxyl free radical has extremely high oxidation potential (2.80eV) and extremely high oxidation capacity, can generate rapid chain reaction with most organic pollutants, oxidizes harmful substances into CO2, H2O or mineral salts, and has no secondary pollution. When the core field effect generating mechanism 1 applies illumination (natural light can be used without adding an illumination device on another day) and a special electric field, the core field effect generating mechanism 1 can efficiently catalyze and degrade organic pollutants in the water body and sludge at the bottom of the water body to make the organic pollutants harmless, reduce the COD (chemical oxygen demand) value, the ammonia nitrogen value, the total nitrogen value and the total phosphorus value of the water body, improve indexes such as Dissolved Oxygen (DO) and oxidation-reduction potential of the water body, improve the transparency and activity of the water body, recover the self-purification capacity of the water body, and has low energy consumption and wide action area.
The multi-waveform low-voltage variable frequency power supply mechanism 2 comprises a multi-waveform low-voltage variable frequency power supply and a waterproof distribution box, the multi-waveform low-voltage variable frequency power supply is arranged in the waterproof distribution box, the waterproof distribution box is internally fixed on a floating platform guardrail support 52, electronic devices are prevented from being damaged, the multi-waveform low-voltage variable frequency power supply is connected with a core field effect generating mechanism, different waveforms (such as sine, square wave, triangular wave and the like), amplitude (precision 0.001) and frequency are provided for the core field effect generating mechanism 1 so as to form a special electric field and a special magnetic field, and the core field effect generating mechanism 1 can adjust working parameters of different water bodies pertinently and improve the working efficiency and.
The energy storage mechanism 3 comprises an energy storage battery pack 33, an energy storage inverter 31 and a solar cell panel 32, wherein the solar cell panel 32 is fixed on a solar cell panel bracket 54, and the energy storage inverter 31 and the energy storage battery pack 33 are fixed on a floating platform guardrail bracket 52. The energy storage inverter 31 is connected with the energy storage battery pack 33, the energy storage battery pack 33 is connected with the solar cell panel 32, the energy storage inverter 31 can supply electric energy by using distributed energy (wind power generation, photovoltaic power generation, a power grid and the like), and the electric energy can be supplied through the energy storage battery pack 33 and the solar cell panel 32 when the power grid is powered off.
The remote control data acquisition and analysis mechanism 7 comprises a data acquisition device 71, a power supply detection sensor 72 and a camera 73, wherein the power supply detection sensor 72 is used for detecting whether the working voltage, current and frequency of the core field effect generation mechanism 1 are normal or not, the camera 73 is fixed on a camera support 53, both the camera 73 and the power supply detection sensor 73 are connected with the data acquisition device 71, the data acquisition device 71 is communicated with a cloud platform server, the data acquisition device 71 and the power supply detection sensor 73 are fixed in a waterproof distribution box in the embodiment, the data acquisition device 71 is used for transmitting data and control instructions with the cloud platform server through an intelligent gateway, the cloud platform server is internally provided with server platform software for facilitating data checking and control instruction inputting of workers, and the data acquisition device 71 is connected with a corresponding switch through an I/O controller, for remotely controlling the opening and closing of the switch.
The two circulation auxiliary mechanisms 4 are symmetrically fixed on two sides of the buoyancy mechanism 5. The circulation auxiliary mechanism 4 comprises a flexible fixing support 41, a fountain water pump 43 fixed at the top end of the flexible support 41 and a safety steel wire rope 42 for reinforcement, one end of the safety steel wire rope 42 is fixed on the floating platform guardrail support 52, the other end of the safety steel wire rope 42 is fixed on the flexible fixing support 41, the bottom end of the flexible fixing support 41 is fixed on the floating platform guardrail support 52, and the circulation auxiliary mechanism 4 accelerates water circulation and improves treatment efficiency.
Warning mechanism is warning light or warning sign or color lamp under water, and the warning light is adopted to this embodiment, plays the warning effect, avoids colliding, plays the effect of beautifying the environment simultaneously.
Therefore, the metal substrate carbon nano-film water body purification device adopting the structure can catalyze and degrade organic pollutants in water bodies and bottom sludge, reduce harmful indexes of the water bodies, improve dissolved oxygen of the water bodies, improve transparency and activity of the water bodies, and has the advantages of low energy consumption, wide action area and high treatment efficiency.
Finally, it should be noted that: the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting the same, and although the present invention is described in detail with reference to the preferred embodiments, those of ordinary skill in the art should understand that: modifications and equivalents may be made to the invention without departing from the spirit and scope of the invention.

Claims (10)

1. A metal substrate carbon nano-film water purification device is characterized in that: comprises a core field effect generating mechanism, a multi-waveform low-voltage variable frequency power supply mechanism, a remote control data acquisition and analysis mechanism, an energy storage mechanism, a buoyancy mechanism, a circulation auxiliary mechanism and a warning mechanism,
the core field effect generating mechanism is fixed at the bottom of the buoyancy mechanism, the multi-waveform low-voltage variable-frequency power supply mechanism is fixed in the middle of the buoyancy mechanism, the multi-waveform low-voltage variable-frequency power supply mechanism is connected with the core field effect generating mechanism, the energy storage mechanism is fixed above the buoyancy mechanism, the energy storage mechanism is connected with the multi-waveform low-voltage variable-frequency power supply mechanism, and the two circulation auxiliary mechanisms are symmetrically fixed at two sides of the buoyancy mechanism.
2. The metal substrate carbon nano-film water body purification device according to claim 1, wherein: the core field effect generating mechanism comprises a metal frame net cage and a core field effect generating unit arranged inside the metal frame net cage, wherein the core field effect generating unit is at least provided with one, the core field effect generating unit comprises a central polypropylene punching plate, a first polyethylene net piece arranged on two sides of the central polypropylene punching plate, a metal copper sheet auxiliary electrode arranged on the outer side of the first polyethylene net piece, a metal substrate carbon nanometer film pole piece arranged on the outer side of the metal copper sheet auxiliary electrode, a second polyethylene net piece arranged on the outer side of the metal substrate carbon nanometer film pole piece and a side polypropylene punching plate arranged on the outer side of the second polyethylene net piece.
3. The metal substrate carbon nano-film water body purification device according to claim 2, wherein: the metal substrate carbon nano-film pole piece comprises a porous metal base material and a carbon atom allotrope composite film covering the surface of the porous metal base material.
4. The metal substrate carbon nano-film water body purification device according to claim 1, wherein: the multi-waveform low-voltage variable frequency power supply mechanism comprises a multi-waveform low-voltage variable frequency power supply and a waterproof distribution box, wherein the multi-waveform low-voltage variable frequency power supply is arranged in the waterproof distribution box, and the multi-waveform low-voltage variable frequency power supply is connected with the core field effect generation mechanism.
5. The metal substrate carbon nano-film water body purification device according to claim 4, wherein: the buoyancy mechanism comprises a floating platform, a floating platform guardrail support, a solar cell panel support and a camera support, wherein the floating platform guardrail support is fixed on the floating platform, and the solar cell panel support and the camera support are fixed on the floating platform guardrail support.
6. The metal substrate carbon nano-film water body purification device according to claim 5, wherein: the remote control data acquisition and analysis mechanism comprises a data acquisition device, a power supply detection sensor and a camera, the camera is fixed on the camera support, the camera and the power supply detection sensor are both connected with the data acquisition device, and the data acquisition device is communicated with the cloud platform server.
7. The metal substrate carbon nano-film water body purification device according to claim 5, wherein: the energy storage mechanism comprises an energy storage battery pack, an energy storage inverter and a solar panel, the solar panel is fixed on the solar panel support, the energy storage inverter is connected with the energy storage battery pack, and the energy storage battery pack is connected with the solar panel.
8. The metal substrate carbon nano-film water body purification device according to claim 5, wherein: the circulation auxiliary mechanism comprises a flexible fixing support, a fountain water pump and a safety steel wire rope, wherein the fountain water pump is fixed to the top end of the flexible support, the safety steel wire rope is used for reinforcing, one end of the safety steel wire rope is fixed to the floating platform guardrail support, the other end of the safety steel wire rope is fixed to the flexible fixing support, and the bottom end of the flexible fixing support is fixed to the floating platform guardrail support.
9. The metal substrate carbon nano-film water body purification device according to claim 5, wherein: the warning mechanism is a warning lamp or a warning board or an underwater colored lamp.
10. The metal substrate carbon nano-film water body purification device according to claim 3, wherein: the porous metal base material is foamed copper, foamed copper alloy, foamed nickel alloy, foamed aluminum alloy, stainless steel sintered felt, metal fiber, metal wire mesh or metal wire woven mesh.
CN202010934099.8A 2020-09-08 2020-09-08 Metal substrate carbon nano-film water body purification device Pending CN111908572A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114349152A (en) * 2021-12-30 2022-04-15 水利部交通运输部国家能源局南京水利科学研究院 Water treatment process based on photoelectric-magnetic-biological synergistic effect of nano germanium material

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114349152A (en) * 2021-12-30 2022-04-15 水利部交通运输部国家能源局南京水利科学研究院 Water treatment process based on photoelectric-magnetic-biological synergistic effect of nano germanium material
CN114349152B (en) * 2021-12-30 2023-02-28 水利部交通运输部国家能源局南京水利科学研究院 Water treatment process based on photoelectric-magnetic-biological synergistic effect of nano germanium material

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