CN111777829A - 一种用于电缆料的绝缘pvc材料及其制备方法 - Google Patents
一种用于电缆料的绝缘pvc材料及其制备方法 Download PDFInfo
- Publication number
- CN111777829A CN111777829A CN202010625939.2A CN202010625939A CN111777829A CN 111777829 A CN111777829 A CN 111777829A CN 202010625939 A CN202010625939 A CN 202010625939A CN 111777829 A CN111777829 A CN 111777829A
- Authority
- CN
- China
- Prior art keywords
- cable
- nano
- filler
- insulating
- pvc
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 89
- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- 239000000945 filler Substances 0.000 claims abstract description 47
- 239000002105 nanoparticle Substances 0.000 claims abstract description 38
- 239000004014 plasticizer Substances 0.000 claims abstract description 34
- 239000011347 resin Substances 0.000 claims abstract description 25
- 229920005989 resin Polymers 0.000 claims abstract description 25
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 19
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 19
- 239000003063 flame retardant Substances 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000003381 stabilizer Substances 0.000 claims abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 60
- 238000002156 mixing Methods 0.000 claims description 27
- 239000012188 paraffin wax Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 26
- 238000001035 drying Methods 0.000 claims description 22
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 20
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 18
- 235000019441 ethanol Nutrition 0.000 claims description 18
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 12
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 12
- 239000000395 magnesium oxide Substances 0.000 claims description 12
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 12
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 12
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 12
- 239000004033 plastic Substances 0.000 claims description 11
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 10
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 10
- 238000007598 dipping method Methods 0.000 claims description 10
- 238000003756 stirring Methods 0.000 claims description 10
- 238000010438 heat treatment Methods 0.000 claims description 9
- 239000004593 Epoxy Substances 0.000 claims description 8
- 238000001354 calcination Methods 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 8
- 238000007872 degassing Methods 0.000 claims description 8
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims description 8
- 238000000605 extraction Methods 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 6
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 6
- NBOMNTLFRHMDEZ-UHFFFAOYSA-N thiosalicylic acid Chemical compound OC(=O)C1=CC=CC=C1S NBOMNTLFRHMDEZ-UHFFFAOYSA-N 0.000 claims description 6
- 229940103494 thiosalicylic acid Drugs 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 239000000440 bentonite Substances 0.000 claims description 4
- 229910000278 bentonite Inorganic materials 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 4
- RCWIWCRIXGJJED-UHFFFAOYSA-M SC(C(=O)[O-])S.C(CCCCC(C)C)[Sn+](CCCCCCCC)CCCCCCCC Chemical compound SC(C(=O)[O-])S.C(CCCCC(C)C)[Sn+](CCCCCCCC)CCCCCCCC RCWIWCRIXGJJED-UHFFFAOYSA-M 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- 239000005909 Kieselgur Substances 0.000 claims 1
- 230000005540 biological transmission Effects 0.000 abstract description 5
- 230000015556 catabolic process Effects 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000010276 construction Methods 0.000 abstract description 2
- 238000009825 accumulation Methods 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 230000005684 electric field Effects 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- YAHBZWSDRFSFOO-UHFFFAOYSA-L dimethyltin(2+);2-(2-ethylhexoxy)-2-oxoethanethiolate Chemical compound CCCCC(CC)COC(=O)CS[Sn](C)(C)SCC(=O)OCC(CC)CCCC YAHBZWSDRFSFOO-UHFFFAOYSA-L 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000001291 vacuum drying Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- IRCSIGNHSFZBRR-UHFFFAOYSA-N dioctyltin 6-methylheptyl 2,2-bis(sulfanyl)acetate Chemical compound C(CCCCCCC)[Sn]CCCCCCCC.SC(C(=O)OCCCCCC(C)C)S IRCSIGNHSFZBRR-UHFFFAOYSA-N 0.000 description 1
- PIRIAZVDIOKRIR-UHFFFAOYSA-N dioctyltin;6-methylheptyl 2-hydroxyethanedithioate Chemical compound CC(C)CCCCCSC(=S)CO.CCCCCCCC[Sn]CCCCCCCC PIRIAZVDIOKRIR-UHFFFAOYSA-N 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 238000005036 potential barrier Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G73/00—Recovery or refining of mineral waxes, e.g. montan wax
- C10G73/38—Chemical modification of petroleum
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Medicinal Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
Description
Claims (9)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010625939.2A CN111777829B (zh) | 2020-07-02 | 2020-07-02 | 一种用于电缆料的绝缘pvc材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN202010625939.2A CN111777829B (zh) | 2020-07-02 | 2020-07-02 | 一种用于电缆料的绝缘pvc材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN111777829A true CN111777829A (zh) | 2020-10-16 |
CN111777829B CN111777829B (zh) | 2022-08-19 |
Family
ID=72757936
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN202010625939.2A Active CN111777829B (zh) | 2020-07-02 | 2020-07-02 | 一种用于电缆料的绝缘pvc材料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN111777829B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114957883A (zh) * | 2022-06-06 | 2022-08-30 | 安徽蒙特尔电缆集团有限公司 | 一种防护性能高的耐火型电缆 |
CN116925427A (zh) * | 2023-07-18 | 2023-10-24 | 沧州兴达化工有限责任公司 | 一种环保防水增塑剂及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03265641A (ja) * | 1990-03-14 | 1991-11-26 | Fujikura Ltd | 難燃性樹脂組成物 |
CN106117893A (zh) * | 2016-07-21 | 2016-11-16 | 安徽华源电缆集团有限公司 | 一种用于热电偶补偿电缆的护套料 |
CN106496728A (zh) * | 2016-10-06 | 2017-03-15 | 常州市鼎升环保科技有限公司 | 一种高压电缆绝缘材料的制备方法 |
CN110144242A (zh) * | 2019-05-21 | 2019-08-20 | 安徽星鑫化工科技有限公司 | 一种改性氯化石蜡及其制备方法、应用 |
CN110483920A (zh) * | 2019-09-11 | 2019-11-22 | 江苏枫润线缆材料有限公司 | 一种环保型电缆绝缘料及其制备方法 |
-
2020
- 2020-07-02 CN CN202010625939.2A patent/CN111777829B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03265641A (ja) * | 1990-03-14 | 1991-11-26 | Fujikura Ltd | 難燃性樹脂組成物 |
CN106117893A (zh) * | 2016-07-21 | 2016-11-16 | 安徽华源电缆集团有限公司 | 一种用于热电偶补偿电缆的护套料 |
CN106496728A (zh) * | 2016-10-06 | 2017-03-15 | 常州市鼎升环保科技有限公司 | 一种高压电缆绝缘材料的制备方法 |
CN110144242A (zh) * | 2019-05-21 | 2019-08-20 | 安徽星鑫化工科技有限公司 | 一种改性氯化石蜡及其制备方法、应用 |
CN110483920A (zh) * | 2019-09-11 | 2019-11-22 | 江苏枫润线缆材料有限公司 | 一种环保型电缆绝缘料及其制备方法 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114957883A (zh) * | 2022-06-06 | 2022-08-30 | 安徽蒙特尔电缆集团有限公司 | 一种防护性能高的耐火型电缆 |
CN116925427A (zh) * | 2023-07-18 | 2023-10-24 | 沧州兴达化工有限责任公司 | 一种环保防水增塑剂及其制备方法 |
CN116925427B (zh) * | 2023-07-18 | 2024-01-19 | 沧州兴达化工有限责任公司 | 一种环保防水增塑剂及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN111777829B (zh) | 2022-08-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN111777829B (zh) | 一种用于电缆料的绝缘pvc材料及其制备方法 | |
CA2641266C (en) | Semiconductive compositions | |
CN103642178A (zh) | 一种无卤阻燃热塑性聚酯弹性体纳米复合材料及其制备方法 | |
CN104115239A (zh) | 用于制备交联的聚烯烃的组合物和方法 | |
WO2011156442A1 (en) | Thiobis phenolic antioxidant/polyethylene glycol blends | |
CN115044143A (zh) | 一种耐挤压抗开裂电力电缆 | |
CN107556661A (zh) | 一种耐磨电缆料及其制备方法 | |
CN109762275B (zh) | 一种氟化导电粒子/pvdf基复合介电薄膜的制备方法 | |
TW201007774A (en) | Improved method for degassing cables | |
WO2012162019A1 (en) | Thiobis phenolic antioxidant/polyethylene glycol blends | |
CN105255017A (zh) | 中压电力电缆用乙丙绝缘料及其制备方法 | |
CN110964298A (zh) | 一种生物降解改性材料及其制备方法 | |
KR100545354B1 (ko) | 다이아몬드를 이용한 전계방출소자의 에미터 조성물, 그 제조 방법 및 에미터 조성물을 이용한 전계방출소자 | |
CN103214751A (zh) | 一种pvc/农用废弃物复合材料及其制备方法和应用 | |
CN108395610A (zh) | 一种碳纳米管半导体屏蔽料及其制备方法 | |
CN111607165B (zh) | 高扩张绝缘乙丙胶冷缩材料、其制备方法和应用 | |
KR20200009158A (ko) | 코팅된 고온내성 난연재 및 그 제조 방법 | |
CN113698723A (zh) | 一种用于环保型电缆的聚丙烯基热塑型半导电屏蔽料及制备方法 | |
CN106397935A (zh) | 一种添加纳米膨润土改性沥青的复合电缆料 | |
CN107629288B (zh) | 聚乙烯/金属氢氧化物/科琴黑阻燃材料及其制备方法 | |
CN111234345A (zh) | 一种改性陶瓷/低密度聚乙烯复合材料及其制备方法和应用 | |
CN106519378A (zh) | 一种添加稀土氧化物复配聚甲基丙烯酸乙酯的复合电缆料 | |
CN109651658B (zh) | 一种导热缓冲混胶套及其制备方法与应用 | |
CN115594978B (zh) | 一种耐高压绝缘橡胶板及其制备方法 | |
CN115806645B (zh) | 一种耐高电压绝缘材料及其制备方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: An insulating PVC material for cable material and its preparation method Effective date of registration: 20230529 Granted publication date: 20220819 Pledgee: Tianchang vibration financing Company limited by guarantee Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2023980041963 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20220819 Pledgee: Tianchang vibration financing Company limited by guarantee Pledgor: ANHUI CABLE Co.,Ltd. Registration number: Y2023980041963 |