CN111748225A - Negative oxygen ion ecological coating - Google Patents

Negative oxygen ion ecological coating Download PDF

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Publication number
CN111748225A
CN111748225A CN201910230862.6A CN201910230862A CN111748225A CN 111748225 A CN111748225 A CN 111748225A CN 201910230862 A CN201910230862 A CN 201910230862A CN 111748225 A CN111748225 A CN 111748225A
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ecological
parts
negative oxygen
oxygen ion
stirring
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陈承祥
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Guangdong Shanyuan Health Investment Co ltd
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Guangdong Shanyuan Health Investment Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular

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Abstract

The invention discloses an oxygen anion ecological coating, which relates to the technical field of ecological coatings, and comprises the following components in parts by weight: the ecological environment-friendly water-based paint comprises 25-40 parts of ecological essence liquid, 40-50 parts of ecological environment-friendly mud, 5-15 parts of algae, 8-20 parts of retarder, 20-25 parts of calcium-containing inorganic matrix, 10-25 parts of fluorosilicone resin and the balance of deionized and energized water. The ecological coating can release high-concentration negative oxygen ions permanently, is ecological, environment-friendly, healthy and effective permanently, and enables a room to have a long-term healthy microenvironment, and the ecological coating comprises three using modes: the ecological essence can be directly sprayed on indoor buildings, releases high-concentration negative oxygen ions for a long time after film forming, and can also be implanted into all kinds of building materials to form healthy green building materials; the ecological environment-friendly mud can be directly used for indoor buildings, and is particularly suitable for newly-decorated buildings; the ecological essence and the ecological environment-friendly mud are mixed for use, and the high-quality negative oxygen ion coating can be produced.

Description

Negative oxygen ion ecological coating
Technical Field
The invention relates to the technical field of ecological coatings, in particular to an oxygen anion ecological coating.
Background
At present, with the continuous progress and development of the environment in China, the problem of environmental pollution caused by continuous progress and development is very prominent, especially the urban atmospheric pollution is very serious, and industrial fire coal releases a large amount of harmful gases such as sulfur dioxide, carbon monoxide and the like, and simultaneously with the high-speed development of the automobile industry, the air pollution of large and medium cities is serious because of the emission of a large amount of nitrides and carbon monoxide from automobile tail gas; many interior materials and furniture slowly release small molecule harmful organic substances such as aldehydes, phenols, alcohols, etc., and the central air conditioner also generates an unpleasant smell and spreads pathogenic microorganisms.
In order to reduce pollution and protect the environment, the photocatalytic ecological building material with the function of degrading pollutants is a main product of the building material industry in the century. In recent years, reports on photocatalysis coatings are increasing, nano materials such as nano TiO2 and ZnO are added into the coatings, although the brushing resistance, the aging resistance and the stain resistance of the coatings are enhanced, the effects are not obvious, the effects are obviously reduced after long-time use along with the passage of time, and most of ecological coatings on the market are not perfect in mildew-proof effect and antibacterial effect and insufficient in durability when used for indoor decoration, meanwhile, the release amount of the ecological coatings on the market is not obvious enough for the release amount of negative oxygen ions, the release amount is greatly reduced after long-time use, the ecological coatings lose the release performance of the negative oxygen ions, and how to ensure that the ecological coatings can keep the sufficient release amount of the negative oxygen ions, the lasting performance of mildew resistance and the antibacterial performance for a long time is a big problem to be solved by the current decoration coatings, accordingly, those skilled in the art have provided an ecological coating of negative oxygen ions to solve the problems set forth in the background art described above.
Disclosure of Invention
The invention aims to provide a negative oxygen ion ecological coating to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: the negative oxygen ion ecological coating comprises the following components in parts by weight: the ecological environment-friendly coating comprises 25-40 parts of ecological essence liquid, 40-50 parts of ecological environment-friendly mud, 5-15 parts of algae, 8-20 parts of retarder, 20-25 parts of calcium-containing inorganic matrix, 10-25 parts of fluorosilicone resin and the balance of deionized and energized water;
the ecological essence comprises the following components in parts by weight: 40-60 parts of pure plant stock solution, 20-35 parts of mineral substances, 8-12 parts of nano photocatalyst materials, 12-30 parts of biological enzymes and 5-10 parts of film forming agents;
the ecological environment-friendly mud comprises the following components in parts by weight: 30-50 parts of sticky mud, 8-12 parts of pigment and filler and 20-30 parts of glutinous rice glue.
As a further scheme of the invention: the ecological essence liquid accounts for 35% of the total proportion of the ecological paint, and the ecological environment-friendly mud accounts for 45% of the total proportion of the ecological paint.
As a still further scheme of the invention: the nano photocatalyst material adopts a plurality of oxide sulfide semiconductors such as titanium dioxide, zinc oxide, tin oxide, zirconium dioxide, cadmium sulfide and the like, and preferably selects nano titanium dioxide.
As a still further scheme of the invention: the pure plant stock solution adopts the extract liquor of tea tree leaves, camphor tree leaves, coleus blumei, common lophatherum herb, common chlorophytum herb, cold water flowers after soaking leaves, crassula argentea, aloe and other plants.
As a still further scheme of the invention: the mineral substance is Xinjiang Altai mountain tourmaline and other mineral substances, and the film forming agent is one or a mixture of a plurality of compounds of styrene resin, isooctyl acrylate, C9 petroleum resin, urea resin, methyl cellulose, triethyl borate and ethylene glycol dimethacrylate.
As a still further scheme of the invention: the calcium-containing inorganic matrix is one or more of natural calcium sulfate hemihydrate, shell calcium carbonate and shell calcium oxide.
As a still further scheme of the invention: the algae is white diatom powder which is subjected to titanium dioxide loading or bleaching treatment and then ground.
As a still further scheme of the invention: the preparation method of the ecological essence comprises the following steps:
a1, grinding a certain amount of mineral substances into powder by using a grinder, then putting the ground mineral substances into a stirring tank, adding the nano photocatalyst material and pure plant stock solution into the stirring tank, adding a certain amount of deionized energized water, and uniformly stirring for 15min at the rotating speed of 2000-3000 r/min;
and A2, sequentially adding the biological enzyme and the film-forming agent into the stirring tank after the stirring is finished, continuously stirring for 15min, and uniformly stirring to obtain the ecological essence.
As a still further scheme of the invention: the preparation method of the negative oxygen ion ecological coating comprises the following steps:
s1, putting a certain amount of sticky mud, pigment and filler and sticky rice glue into a stirrer, adding a certain amount of deionized and energetic water, and uniformly stirring for 5min at the rotating speed of 1000-2000 r/min to obtain sticky ecological environment-friendly mud;
s2, putting a certain amount of powdery algae and a calcium-containing inorganic matrix into the stirrer, continuously stirring, keeping the temperature condition at 50-70 ℃ during stirring for 10min, then adding a certain amount of fluorosilicone resin and a retarder, and uniformly stirring for 15min to obtain a viscous mixture;
and S3, uniformly mixing and stirring the viscous mixture prepared in the step S2 and the ecological essence, adding the rest deionized and energetic water, and continuously stirring for 30min at the rotating speed of 2500-3500 r/min until the mixture is uniformly stirred to obtain the negative oxygen ion ecological paint.
Compared with the prior art, the invention has the beneficial effects that: the invention designs a negative oxygen ion ecological coating which is prepared by mixing a negative oxygen ion raw material,
1. the ecological coating comprises ecological environment-friendly mud and ecological essence, the ecological environment-friendly mud and the ecological essence can be used in a mixed manner, the ecological coating can have the capability of persistently releasing high-concentration negative oxygen ions by adding the ecological essence into the ecological environment-friendly mud, is ecological, environment-friendly, healthy and lasting, can have a long-term healthy microenvironment indoors, has good breathing and humidity regulation performance of high-quality negative oxygen ions, does not need to worry about rainy humid weather, has strong antibacterial and mildew-proof effects, has an antibacterial rate of 99.9 percent and a mildew-proof grade of 0, can be added with any color according to the needs of users, and is green, environment-friendly and pollution-free; the ecological essence can be used independently, is uniformly sprayed on a home or furniture through a spray gun, is naturally filmed after being naturally dried, naturally generates a photoelectric effect through light, naturally generates a thermoelectric effect through heat, generates a piezoelectric effect through wind blowing, combines electrons and oxygen, can generate more than 1 ten thousand per cubic centimeter and can release negative oxygen ions permanently, and has the effects of ecology, environmental protection and health; the ecological essence can also be implanted into almost all kinds of building materials to make the ecological essence become healthy green building materials; the ecological environment-friendly mud can be independently used, and ecological, environment-friendly and healthy indoor environment is deduced in a colorful and colorful mode through modern decoration technology.
2. Meanwhile, natural plant essence and natural mineral materials are added into the raw materials, the materials are ground and stirred and then are mixed with the ecological environment-friendly mud to form the designed ecological coating, and the ecological coating is coated on the surface of a carrier, so that indoor heat can be absorbed, and the effect of converting heat energy into electronic energy and combining the electronic energy with oxygen in air into negative oxygen ions is realized;
3. meanwhile, algae and an inorganic calcium-containing matrix are fully utilized in the raw materials, so that the ecological performances of the ecological paint, such as formaldehyde purification, negative oxygen ion bionics, self-humidifying and the like, are further improved, the nano titanium dioxide is dispersed in the fluorosilicone resin by utilizing the good compatibility of the nano titanium dioxide and the fluorosilicone resin, and a nano rough structure is further formed on the surface of the fluorosilicone resin, so that a super-hydrophobic structure is formed, the contact area with water in a humid environment is reduced, the adhesion force of ice is further reduced, the hydrophobicity and the excellent ice covering prevention capability of the ecological paint are realized, and meanwhile, the ecological paint has a certain self-cleaning capability.
Drawings
FIG. 1 is a composition diagram of a negative oxygen ion ecological paint;
FIG. 2 is a schematic diagram showing comparison of experimental results of examples 1-3 and comparative example 1 in a negative oxygen ion ecological coating.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Referring to fig. 1-2, in the embodiment of the present invention,
example 1
The negative oxygen ion ecological coating comprises the following components in parts by weight: the ecological environment-friendly water-based paint comprises 25 parts of ecological essence liquid and 40 parts of ecological environment-friendly mud, and also comprises 5 parts of algae, 8 parts of retarder, 20 parts of calcium-containing inorganic matrix, 25 parts of fluorosilicone resin and the balance of deionized and energized water;
the ecological essence comprises the following components in parts by weight: 40 parts of pure plant stock solution, 20 parts of mineral substances, 8 parts of nano photocatalyst materials, 12 parts of biological enzyme and 5 parts of film forming agents;
the ecological environment-friendly mud comprises the following components in parts by weight: 30 parts of sticky mud, 8 parts of pigment and filler and 20 parts of glutinous rice glue.
Wherein the ecological essence liquid accounts for 35% of the total proportion of the ecological paint, and the ecological environment-friendly mud accounts for 45% of the total proportion of the ecological paint.
Furthermore, the nano photocatalyst material adopts various oxide sulfide semiconductors such as titanium dioxide, zinc oxide, tin oxide, zirconium dioxide, cadmium sulfide and the like, and preferably nano titanium dioxide.
Further, the pure plant stock solution is the extract of tea tree leaves, camphor tree leaves, coleus blumei, common sasanqua, chlorophytum comosum, cold water flowers, crassula argentea, aloe and other plants.
Furthermore, the mineral substance is Xinjiang Altai mountain tourmaline and other mineral substances, and the film forming agent is one or a mixture of a plurality of compounds of styrene resin, isooctyl acrylate, C9 petroleum resin, urea resin, methyl cellulose, triethyl borate and ethylene glycol dimethacrylate.
Furthermore, the calcium-containing inorganic matrix is one or more of natural calcium sulfate hemihydrate, shell calcium carbonate and shell calcium oxide.
Further, the algae is white diatom powder which is carried by titanium dioxide or bleached and then ground.
Still further, the preparation method of the ecological essence comprises the following steps:
a1, grinding a certain amount of mineral substances into powder by using a grinder, then putting the ground mineral substances into a stirring tank, adding the nano photocatalyst material and pure plant stock solution into the stirring tank, adding a certain amount of deionized energized water, and uniformly stirring for 15min at the rotating speed of 2000-3000 r/min;
and A2, sequentially adding the biological enzyme and the film-forming agent into the stirring tank after the stirring is finished, continuously stirring for 15min, and uniformly stirring to obtain the ecological essence.
Still further, the preparation method of the negative oxygen ion ecological coating comprises the following steps:
s1, putting a certain amount of sticky mud, pigment and filler and sticky rice glue into a stirrer, adding a certain amount of deionized and energetic water, and uniformly stirring for 5min at the rotating speed of 1000-2000 r/min to obtain sticky ecological environment-friendly mud;
s2, putting a certain amount of powdery algae and a calcium-containing inorganic matrix into the stirrer, continuously stirring, keeping the temperature condition at 50-70 ℃ during stirring for 10min, then adding a certain amount of fluorosilicone resin and a retarder, and uniformly stirring for 15min to obtain a viscous mixture;
and S3, uniformly mixing and stirring the viscous mixture prepared in the step S2 and the ecological essence, adding the rest deionized and energetic water, and continuously stirring for 30min at the rotating speed of 2500-3500 r/min until the mixture is uniformly stirred to obtain the negative oxygen ion ecological paint.
Example 2
The negative oxygen ion ecological coating comprises the following components in parts by weight: the ecological environment-friendly water-based paint comprises 28 parts of ecological essence liquid, 42 parts of ecological environment-friendly mud, 15 parts of algae, 20 parts of retarder, 25 parts of calcium-containing inorganic matrix, 10 parts of fluorosilicone resin and the balance of deionized and energized water;
the ecological essence comprises the following components in parts by weight: 60 parts of pure plant stock solution, 35 parts of mineral substances, 12 parts of nano photocatalyst materials, 30 parts of biological enzyme and 10 parts of film forming agents;
the ecological environment-friendly mud comprises the following components in parts by weight: 50 parts of sticky mud, 12 parts of pigment and filler and 30 parts of glutinous rice glue.
Wherein the ecological essence liquid accounts for 35% of the total proportion of the ecological paint, and the ecological environment-friendly mud accounts for 45% of the total proportion of the ecological paint.
Furthermore, the nano photocatalyst material adopts various oxide sulfide semiconductors such as titanium dioxide, zinc oxide, tin oxide, zirconium dioxide, cadmium sulfide and the like, and preferably nano titanium dioxide.
Further, the pure plant stock solution is the extract of tea tree leaves, camphor tree leaves, coleus blumei, common sasanqua, chlorophytum comosum, cold water flowers, crassula argentea, aloe and other plants.
Furthermore, the mineral substance is Xinjiang Altai mountain tourmaline and other mineral substances, and the film forming agent is one or a mixture of a plurality of compounds of styrene resin, isooctyl acrylate, C9 petroleum resin, urea resin, methyl cellulose, triethyl borate and ethylene glycol dimethacrylate.
Furthermore, the calcium-containing inorganic matrix is one or more of natural calcium sulfate hemihydrate, shell calcium carbonate and shell calcium oxide.
Further, the algae is white diatom powder which is carried by titanium dioxide or bleached and then ground.
Still further, the preparation method of the ecological essence comprises the following steps:
a1, grinding a certain amount of mineral substances into powder by using a grinder, then putting the ground mineral substances into a stirring tank, adding the nano photocatalyst material and pure plant stock solution into the stirring tank, adding a certain amount of deionized energized water, and uniformly stirring for 15min at the rotating speed of 2000-3000 r/min;
and A2, sequentially adding the biological enzyme and the film-forming agent into the stirring tank after the stirring is finished, continuously stirring for 15min, and uniformly stirring to obtain the ecological essence.
Still further, the preparation method of the negative oxygen ion ecological coating comprises the following steps:
s1, putting a certain amount of sticky mud, pigment and filler and sticky rice glue into a stirrer, adding a certain amount of deionized and energetic water, and uniformly stirring for 5min at the rotating speed of 1000-2000 r/min to obtain sticky ecological environment-friendly mud;
s2, putting a certain amount of powdery algae and a calcium-containing inorganic matrix into the stirrer, continuously stirring, keeping the temperature condition at 50-70 ℃ during stirring for 10min, then adding a certain amount of fluorosilicone resin and a retarder, and uniformly stirring for 15min to obtain a viscous mixture;
and S3, uniformly mixing and stirring the viscous mixture prepared in the step S2 and the ecological essence, adding the rest deionized and energetic water, and continuously stirring for 30min at the rotating speed of 2500-3500 r/min until the mixture is uniformly stirred to obtain the negative oxygen ion ecological paint.
Example 3
The negative oxygen ion ecological coating comprises the following components in parts by weight: the ecological environment-friendly water-based paint comprises 35 parts of ecological essence liquid, 45 parts of ecological environment-friendly mud, 10 parts of algae, 12 parts of retarder, 22 parts of calcium-containing inorganic matrix, 18 parts of fluorosilicone resin and the balance of deionized and energized water;
the ecological essence comprises the following components in parts by weight: 50 parts of pure plant stock solution, 30 parts of mineral substances, 10 parts of nano photocatalyst materials, 20 parts of biological enzyme and 7 parts of film forming agents;
the ecological environment-friendly mud comprises the following components in parts by weight: 40 parts of sticky mud, 9 parts of pigment and filler and 25 parts of glutinous rice glue.
Wherein the ecological essence liquid accounts for 35% of the total proportion of the ecological paint, and the ecological environment-friendly mud accounts for 45% of the total proportion of the ecological paint.
Furthermore, the nano photocatalyst material adopts various oxide sulfide semiconductors such as titanium dioxide, zinc oxide, tin oxide, zirconium dioxide, cadmium sulfide and the like, and preferably nano titanium dioxide.
Further, the pure plant stock solution is the extract of tea tree leaves, camphor tree leaves, coleus blumei, common sasanqua, chlorophytum comosum, cold water flowers, crassula argentea, aloe and other plants.
Furthermore, the mineral substance is Xinjiang Altai mountain tourmaline and other mineral substances, and the film forming agent is one or a mixture of a plurality of compounds of styrene resin, isooctyl acrylate, C9 petroleum resin, urea resin, methyl cellulose, triethyl borate and ethylene glycol dimethacrylate.
Furthermore, the calcium-containing inorganic matrix is one or more of natural calcium sulfate hemihydrate, shell calcium carbonate and shell calcium oxide.
Further, the algae is white diatom powder which is carried by titanium dioxide or bleached and then ground.
Still further, the preparation method of the ecological essence comprises the following steps:
a1, grinding a certain amount of mineral substances into powder by using a grinder, then putting the ground mineral substances into a stirring tank, adding the nano photocatalyst material and pure plant stock solution into the stirring tank, adding a certain amount of deionized energized water, and uniformly stirring for 15min at the rotating speed of 2000-3000 r/min;
and A2, sequentially adding the biological enzyme and the film-forming agent into the stirring tank after the stirring is finished, continuously stirring for 15min, and uniformly stirring to obtain the ecological essence.
Still further, the preparation method of the negative oxygen ion ecological coating comprises the following steps:
s1, putting a certain amount of sticky mud, pigment and filler and sticky rice glue into a stirrer, adding a certain amount of deionized and energetic water, and uniformly stirring for 5min at the rotating speed of 1000-2000 r/min to obtain sticky ecological environment-friendly mud;
s2, putting a certain amount of powdery algae and a calcium-containing inorganic matrix into the stirrer, continuously stirring, keeping the temperature condition at 50-70 ℃ during stirring for 10min, then adding a certain amount of fluorosilicone resin and a retarder, and uniformly stirring for 15min to obtain a viscous mixture;
and S3, uniformly mixing and stirring the viscous mixture prepared in the step S2 and the ecological essence, adding the rest deionized and energetic water, and continuously stirring for 30min at the rotating speed of 2500-3500 r/min until the mixture is uniformly stirred to obtain the negative oxygen ion ecological paint.
Comparative example 1
Selects the ecological paint produced by the current market process.
The experimental conditions are as follows:
taking one part (same weight) of the ecological paint prepared in the examples 1-3 and the ecological paint produced in the comparative example 1, and selecting four same carriers;
secondly, coating the ecological coating taken out from the examples 1-3 and the comparative example 1 on the surfaces of four same carriers respectively;
under the third condition, after four same carriers are placed for 15 days in a humid environment, observing the mildew-proof effect and the antibacterial effect of the surfaces of the carriers, and detecting the negative oxygen ion release index of the surfaces of the carriers by using negative oxygen ion detection equipment;
fourthly, under a humid environment, after four same carriers are placed for 30 days, observing the mildew-proof effect and the antibacterial effect of the surfaces of the carriers, and detecting the negative oxygen ion release index of the surfaces of the carriers by using negative oxygen ion detection equipment;
the specific experimental data comparison results are shown in fig. 2.
In conclusion, the negative oxygen ion ecological coating designed by the invention can persistently release high-concentration negative oxygen ions, is ecological, environment-friendly, healthy and effective, and enables a room to have a long-term healthy microenvironment, the ecological coating comprises ecological environment-friendly mud and ecological essence, the ecological environment-friendly mud and the ecological essence can be used in a mixed manner, the ecological coating can have the capacity of persistently releasing the high-concentration negative oxygen ions by adding the ecological essence into the ecological environment-friendly mud, the room can have a long-term healthy microenvironment, the breathing and humidity-adjusting performance of the high-quality negative oxygen ions is good, the worries about the rainy weather are avoided, meanwhile, the ecological coating has a strong antibacterial and mildew-proof effect, the antibacterial rate reaches 99.9%, the mildew-proof grade is 0, any color can be added according to the needs of users, and the ecological coating is green and pollution-free; the ecological essence can be used independently, is uniformly sprayed on a home or furniture through a spray gun, is naturally filmed after being naturally dried, naturally generates a photoelectric effect through light, naturally generates a thermoelectric effect through heat, generates a piezoelectric effect through wind blowing, combines electrons and oxygen, can generate more than 1 ten thousand per cubic centimeter and can release negative oxygen ions permanently, and has the effects of ecology, environmental protection and health; the ecological essence can also be implanted into almost all kinds of building materials to make the ecological essence become healthy green building materials; the ecological environment-friendly mud can be independently used, and ecological, environment-friendly and healthy indoor environment is deduced in a colorful and colorful mode through modern decoration technology.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein. Any reference sign in a claim should not be construed as limiting the claim concerned.
Furthermore, it should be understood that although the present description refers to embodiments, not every embodiment may contain only a single embodiment, and such description is for clarity only, and those skilled in the art should integrate the description, and the embodiments may be combined as appropriate to form other embodiments understood by those skilled in the art.

Claims (9)

1. The negative oxygen ion ecological coating is characterized by comprising the following components in parts by weight: the ecological environment-friendly coating comprises 25-40 parts of ecological essence liquid, 40-50 parts of ecological environment-friendly mud, 5-15 parts of algae, 8-20 parts of retarder, 20-25 parts of calcium-containing inorganic matrix, 10-25 parts of fluorosilicone resin and the balance of deionized and energized water;
the ecological essence comprises the following components in parts by weight: 40-60 parts of pure plant stock solution, 20-35 parts of mineral substances, 8-12 parts of nano photocatalyst materials, 12-30 parts of biological enzymes and 5-10 parts of film forming agents;
the ecological environment-friendly mud comprises the following components in parts by weight: 30-50 parts of sticky mud, 8-12 parts of pigment and filler and 20-30 parts of glutinous rice glue.
2. The negative oxygen ion ecological paint as claimed in claim 1, wherein the ecological essence liquid accounts for 35% of the total proportion of the ecological paint, and the ecological environmental protection mud accounts for 45% of the total proportion of the ecological paint.
3. The negative oxygen ion ecological paint as claimed in claim 1, wherein the nano photocatalyst material is selected from a plurality of oxide sulfide semiconductors such as titanium dioxide, zinc oxide, tin oxide, zirconium dioxide, cadmium sulfide, etc., preferably nano titanium dioxide.
4. The negative oxygen ion ecological paint as claimed in claim 1, wherein the pure plant stock solution is extracted from tea tree leaves, camphor tree leaves, coleus blumei, common lophatherum herb, chlorophytum comosum, cold water flowers, crassula argentea and aloe.
5. The negative oxygen ion ecological paint as claimed in claim 1, wherein the mineral substance is a mineral substance such as tourmaline of Altai mountain of Xinjiang, and the film forming agent is one or more compounds selected from styrene resin, isooctyl acrylate, C9 petroleum resin, urea resin, methyl cellulose, triethyl borate, and ethylene glycol dimethacrylate.
6. The negative oxygen ion ecological paint as claimed in claim 1, wherein the calcium-containing inorganic matrix is one or more of natural calcium sulfate hemihydrate, shell calcium carbonate, and shell calcium oxide.
7. The negative oxygen ion ecological paint as claimed in claim 1, wherein the algae is white diatom powder which is carried by titanium dioxide or bleached and then ground.
8. The negative oxygen ion ecological paint as claimed in claim 1, wherein the preparation method of the ecological essence comprises the following steps:
a1, grinding a certain amount of mineral substances into powder by using a grinder, then putting the ground mineral substances into a stirring tank, adding the nano photocatalyst material and pure plant stock solution into the stirring tank, adding a certain amount of deionized energized water, and uniformly stirring for 15min at the rotating speed of 2000-3000 r/min;
and A2, sequentially adding the biological enzyme and the film-forming agent into the stirring tank after the stirring is finished, continuously stirring for 15min, and uniformly stirring to obtain the ecological essence.
9. The negative oxygen ion ecological paint as claimed in claim 1, wherein the preparation method of the negative oxygen ion ecological paint comprises the following steps:
s1, putting a certain amount of sticky mud, pigment and filler and sticky rice glue into a stirrer, adding a certain amount of deionized and energetic water, and uniformly stirring for 5min at the rotating speed of 1000-2000 r/min to obtain sticky ecological environment-friendly mud;
s2, putting a certain amount of powdery algae and a calcium-containing inorganic matrix into the stirrer, continuously stirring, keeping the temperature condition at 50-70 ℃ during stirring for 10min, then adding a certain amount of fluorosilicone resin and a retarder, and uniformly stirring for 15min to obtain a viscous mixture;
and S3, uniformly mixing and stirring the viscous mixture prepared in the step S2 and the ecological essence, adding the rest deionized and energetic water, and continuously stirring for 30min at the rotating speed of 2500-3500 r/min until the mixture is uniformly stirred to obtain the negative oxygen ion ecological paint.
CN201910230862.6A 2019-03-26 2019-03-26 Negative oxygen ion ecological coating Pending CN111748225A (en)

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Application publication date: 20201009