CN111731019A - Embossed stained paper and preparation method and application thereof - Google Patents
Embossed stained paper and preparation method and application thereof Download PDFInfo
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- CN111731019A CN111731019A CN202010392011.4A CN202010392011A CN111731019A CN 111731019 A CN111731019 A CN 111731019A CN 202010392011 A CN202010392011 A CN 202010392011A CN 111731019 A CN111731019 A CN 111731019A
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- Prior art keywords
- pigment
- embossed
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- printing
- drying
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/16—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like
- B44C1/165—Processes, not specifically provided for elsewhere, for producing decorative surface effects for applying transfer pictures or the like for decalcomanias; sheet material therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/001—Applying decorations on shaped articles, e.g. by painting
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/12—Stencil printing; Silk-screen printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/009—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using thermal means, e.g. infrared radiation, heat
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
Abstract
The invention relates to the technical field of ceramic stained paper, in particular to embossed stained paper and a preparation method and application thereof. The preparation method of the embossed stained paper comprises the following steps: coating photosensitive glue on the polyester silk screen to obtain a photosensitive silk screen; mixing and calcining silicon dioxide, lead-free frit, boron oxide, feldspar and pigment, cooling, ball-milling, drying, sieving to obtain a color pigment, and mixing the color pigment with varnish to obtain a color printing pigment; mixing and calcining silicon dioxide, lead-free frit, zinc oxide and feldspar, cooling, ball-milling, drying and sieving to obtain an embossment pigment, and mixing the embossment pigment with varnish to obtain an embossment printing pigment; and printing the color printing pigment and the relief printing pigment on the base paper in sequence, drying, printing the cover oil, and drying to obtain the relief stained paper. The invention can obtain various color three-dimensional effects, and the phenomena of explosion and powder falling can not occur in the firing process, thereby realizing high product yield; the mechanical wear resistance and stain resistance of the enamel on the surface of the product are improved, and the lead and cadmium release amount is low.
Description
Technical Field
The invention relates to the technical field of ceramic stained paper, in particular to embossed stained paper and a preparation method and application thereof.
Background
The ceramic applique is formed by transferring the colorful patterns on the stained paper to a ceramic blank or glaze surface by a pasting method, and the ceramic ornaments serving as embossment products in the existing ceramics are more and more popular with people, so that the ceramic applique has good market prospect.
In the prior art, in order to obtain colored drawing ceramics with strong three-dimensional sense, colored drawing drying is mainly carried out on fired porcelain, firing is carried out, then dry grain glaze is coated on a sieve mesh, and finally firing is carried out, although the ceramic obtained by the method has strong three-dimensional sense, the product has the conditions of serious chromatic aberration, fuzzy pattern, blackened color and discolored color in the long-time high-temperature treatment process of the ceramics, and the phenomena of explosion and powder falling are easy to occur; the existing embossed three-dimensional stained paper is only one type of metal embossed stained paper, has single product and lacks the diversification of ceramic art, and limits the diversity of ceramic embossed effects.
Disclosure of Invention
Aiming at the defects in the prior art, the invention provides a preparation method of embossed stained paper, which comprises the following steps:
coating photosensitive glue on a 120-250-mesh polyester silk screen to obtain a photosensitive silk screen;
mixing and calcining silicon dioxide, lead-free frit, boron oxide, feldspar and a pigment, cooling, ball-milling, drying and sieving to obtain a color pigment, and mixing the color pigment with varnish to obtain a color printing pigment;
mixing and calcining silicon dioxide, lead-free frit, zinc oxide and feldspar, cooling, ball-milling, drying and sieving to obtain an embossment pigment, and mixing the embossment pigment with varnish to obtain an embossment printing pigment;
and (3) according to the pattern of the stained paper, sequentially adopting photosensitive screen printing to the pattern base paper for drying, then carrying out cover oil printing and drying to obtain the embossed stained paper.
The invention also provides embossed stained paper which is prepared by the method.
Has the advantages that:
the stained paper obtained by the embossed stained paper provided by the invention can obtain various colorful three-dimensional effects, and the phenomena of explosion and powder falling can not occur in the firing process, so that the high yield of products and no defects are realized; the lead-cadmium-free enamel has the advantages that the lead-cadmium-free enamel is suitable for different glazes, the mechanical wear resistance and stain resistance of the enamel on the surface of a product are improved, in addition, the lead-cadmium release amount is low and is less than 0.005mg/L, and the international standard is met.
Detailed Description
In order to clearly illustrate the technical content of the present invention, the detailed description is given in conjunction with specific examples, and it is obvious that the examples are only the preferred embodiments of the technical solution, and other technical solutions which can be obviously derived by those skilled in the art from the technical content disclosed still belong to the protection scope of the present invention.
The invention provides a preparation method of embossed stained paper, which is characterized by comprising the following steps: coating photosensitive glue on a 120-250-mesh polyester silk screen to obtain a photosensitive silk screen; mixing and calcining silicon dioxide, lead-free frit, boron oxide, feldspar and a pigment, cooling, ball-milling, drying and sieving to obtain a color pigment, and mixing the color pigment with varnish to obtain a color printing pigment; mixing and calcining silicon dioxide, lead-free frit, zinc oxide and feldspar, cooling, ball-milling, drying and sieving to obtain an embossment pigment, and mixing the embossment pigment with varnish to obtain an embossment printing pigment; and (3) according to the pattern of the stained paper, sequentially adopting photosensitive screen printing to the pattern base paper for drying, then carrying out cover oil printing and drying to obtain the embossed stained paper.
Further, the color pigment comprises the following raw materials in parts by weight: 20-30 parts of silicon dioxide, 10-15 parts of lead-free frit, 22-30 parts of boron oxide, 30-40 parts of feldspar and 5-30 parts of pigment.
Further, the relief pigment comprises the following raw materials in parts by weight: 10-20 parts of silicon dioxide, 8-13 parts of lead-free frit, 12-20 parts of zinc oxide and 38-48 parts of feldspar.
Further, the calcining temperature in the calcining step of the obtained color pigment and the relief pigment is 1200-1400 ℃; the mass ratio of the color pigment, the relief pigment and the varnish is 10: 5-7; the process parameters of the drying process are as follows: temperature: 30-38 ℃, relative humidity: 40-60%, duration: 6-12 h; the particle size of the color printing pigment and the particle size of the relief printing pigment are 15-25 mu m.
The invention also provides embossed stained paper which is prepared by the preparation method.
The invention also provides the application of the ceramic three-dimensional stained paper on ceramic applique, and the baking temperature after applique is 780-800 ℃.
The present invention is specifically illustrated by the following specific examples:
example 1
Photosensitive glue with the thickness of 0.3mm and 0.1mm is respectively coated on the polyester silk screens with the meshes of 140 and 300 to obtain the photosensitive silk screens.
Taking 20 parts of silicon dioxide, 10 parts of lead-free frit, 30 parts of boron oxide, 30 parts of feldspar and 8 parts of pigment (the pigment is zirconium praseodymium yellow zircon, blue spinel, cobalt chromium iron black spinel and chromium titanium yellow stone to prepare four color pigments with different colors), mixing at 1250 ℃, calcining for 8 hours, cooling, performing ball milling for 6 days, drying at 60 ℃, sieving by a 300-mesh sieve to obtain the color pigment, and mixing the color pigment and the varnish according to the mass ratio of 10:5 to obtain the color printing pigment.
Mixing 12 parts of silicon dioxide, 12 parts of lead-free frit, 12 parts of zinc oxide and 38 parts of feldspar, calcining for 12 hours at 1300 ℃, cooling, performing ball milling for 4 days, drying at 52 ℃, sieving by a 300-mesh sieve to obtain the relief pigment, and mixing the relief pigment and the ink mixing oil according to the mass ratio of 10:6 to obtain the relief printing pigment.
According to a stained paper pattern, printing a color printing pigment on a base paper by adopting a 300-mesh photosensitive screen, drying for 6 hours at the temperature of 30 ℃ and the relative humidity of 40% to obtain colored pigment stained paper, printing a relief pigment on the colored pigment stained paper by adopting a 140-mesh photosensitive screen, drying for 10 hours at the temperature of 36 ℃ and the relative humidity of 48%, repeatedly carrying out the printing operation for many times until all colors of the stained paper pattern are printed, printing a cover oil by adopting a 300-mesh photosensitive screen, and drying for 60 minutes at the temperature of 35 ℃ and the relative humidity of 44% to obtain the relief stained paper.
Example 2
Photosensitive glue with the thickness of 0.3mm and 0.1mm is respectively coated on the polyester silk screens with the meshes of 140 and 300 to obtain the photosensitive silk screens.
Taking 30 parts of silicon dioxide, 15 parts of lead-free frit, 22 parts of boron oxide, 38 parts of feldspar and 25 parts of pigment (the pigment is zirconium praseodymium yellow zircon, blue spinel, cobalt chromium iron black spinel and chromium titanium yellow stone to prepare four color pigments with different colors), mixing at 1250 ℃, calcining for 11h, cooling, performing ball milling for 4 days, drying at 56 ℃ and sieving by a 300-mesh sieve to obtain the color pigment, and mixing the color pigment and the varnish according to the mass ratio of 10:6 to obtain the color printing pigment.
Mixing 16 parts of silicon dioxide, 8 parts of lead-free frit, 16 parts of zinc oxide and 46 parts of feldspar, calcining for 12 hours at 1300 ℃, cooling, ball-milling for 6 days, drying at 50 ℃, sieving with a 300-mesh sieve to obtain the relief pigment, and mixing the relief pigment and the ink mixing oil according to the mass ratio of 10:7 to obtain the relief printing pigment.
According to a stained paper pattern, printing a color printing pigment on a base paper by adopting a 300-mesh photosensitive screen, drying for 6 hours at the temperature of 38 ℃ and the relative humidity of 50% to obtain color pigment stained paper, printing a relief pigment on the color pigment stained paper by adopting a 140-mesh photosensitive screen, drying for 8 hours at the temperature of 35 ℃ and the relative humidity of 45%, repeatedly carrying out the printing operation for many times until all colors of the stained paper pattern are printed, printing a cover oil by adopting a 300-mesh photosensitive screen, and drying for 60 minutes at the temperature of 37 ℃ and the relative humidity of 42% to obtain the relief stained paper.
Example 3
Photosensitive glue with the thickness of 0.3mm and 0.1mm is respectively coated on the polyester silk screens with the meshes of 140 and 300 to obtain the photosensitive silk screens.
Taking 25 parts of silicon dioxide, 12 parts of lead-free frit, 25 parts of boron oxide, 35 parts of feldspar and 15 parts of pigment (the pigment is zirconium praseodymium yellow zircon, blue spinel, cobalt chromium iron black spinel and chromium titanium yellow stone to prepare four color pigments with different colors), mixing at 1250 ℃, calcining for 10 hours, cooling, performing ball milling for 5 days, drying at 60 ℃, sieving by a 300-mesh sieve to obtain the color pigment, and mixing the color pigment and the varnish according to the mass ratio of 10:6 to obtain the color printing pigment.
Mixing 20 parts of silicon dioxide, 10 parts of lead-free frit, 20 parts of zinc oxide and 40 parts of feldspar, calcining for 11 hours at 1300 ℃, cooling, performing ball milling for 6 days, drying at 55 ℃, sieving by a 300-mesh sieve to obtain the relief pigment, and mixing the relief pigment and the ink mixing oil according to the mass ratio of 10:7 to obtain the relief printing pigment.
According to a stained paper pattern, printing a color printing pigment on a base paper by adopting a 300-mesh photosensitive screen, drying for 6 hours at the temperature of 35 ℃ and the relative humidity of 42% to obtain colored pigment stained paper, printing a relief pigment on the colored pigment stained paper by adopting a 140-mesh photosensitive screen, drying for 12 hours at the temperature of 35 ℃ and the relative humidity of 42%, repeatedly carrying out the printing operation for many times until all colors of the stained paper pattern are printed, printing a cover oil by adopting a 300-mesh photosensitive screen, and drying for 60 minutes at the temperature of 37 ℃ and the relative humidity of 45% to obtain the relief stained paper.
Comparative example 1
The color pigment comprises the following raw materials in parts by weight: 25 parts of silicon dioxide, 12 parts of lead-free frit, 10 parts of boron oxide, 50 parts of feldspar and 15 parts of pigment. The other pigment compositions and preparation methods were exactly the same as in example 3.
Comparative example 2
The relief pigment comprises the following raw materials in parts by weight: 10 parts of silicon dioxide, 10 parts of lead-free frit, 30 parts of zinc oxide and 30 parts of feldspar. The other pigment compositions and preparation methods were exactly the same as in example 3.
Comparative example 3
The mass ratio of the transparent pigment to the varnish and the mass ratio of the color pigment to the varnish in example 3 were set to 10:8, and the other pigment compositions and the preparation methods were completely the same as those in example 3.
The ceramic three-dimensional stained paper obtained in the examples 1 to 3 and the comparative examples 1 to 3 is pasted on ceramic cups, each group is provided with 100 stained paper, the ceramic cups are baked for 6 hours at 780 ℃, the ceramic cups are obtained, the appearance of the ceramic cups is observed, the number of the stained ceramic cups with flaws is counted to be the number of defective products, the stain resistance, the scrub resistance, the abrasion resistance, the adhesive force and the content of soluble lead and cadmium of the stained ceramic cups are tested according to an industry standard detection method, and the results are shown in the table 1.
TABLE 1 Applique ceramic cup Performance test data
As can be seen from Table 1, when the embossed stained paper obtained by the preparation method is applied to ceramic products, the finished product rate of ceramic cups obtained by decoration firing is high, the ceramic appearance is good, no adverse phenomenon occurs, the ceramic cups have good stain resistance, scrub resistance, abrasion resistance and adhesive force, the soluble lead and cadmium are all less than 0.005mg/L, according to comparative examples 1 and 2, the influence of the components of the color pigment and the embossed pigment on the performance of the stained paper is large, when the weight parts of the components are changed, the expansion coefficients of the embossed pigment and the color pigment are changed, so that the abrasion resistance and the adhesive force of the ceramic products are greatly reduced, the number of defective products is greatly increased, and the matching relationship between the transparent pigment and the color pigment in the application is shown, so that the conditions of explosion and powder falling during decoration firing can be guaranteed after a plurality of printing and drying links, the rate of finished products is greatly improved.
The above-mentioned embodiments are only preferred embodiments of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered as the technical scope of the present invention, and equivalents and modifications of the technical solutions and concepts of the present invention should be covered by the scope of the present invention.
Claims (9)
1. The preparation method of the embossed stained paper is characterized by comprising the following steps of:
coating photosensitive glue on a 120-250-mesh polyester silk screen to obtain a photosensitive silk screen;
mixing and calcining silicon dioxide, lead-free frit, boron oxide, feldspar and a pigment, cooling, ball-milling, drying and sieving to obtain a color pigment, and mixing the color pigment with varnish to obtain a color printing pigment;
mixing and calcining silicon dioxide, lead-free frit, zinc oxide and feldspar, cooling, ball-milling, drying and sieving to obtain an embossment pigment, and mixing the embossment pigment with varnish to obtain an embossment printing pigment;
and (3) according to the pattern of the stained paper, sequentially adopting photosensitive screen printing to the pattern base paper for drying, then carrying out cover oil printing and drying to obtain the embossed stained paper.
2. A method for preparing embossed stained paper according to claim 1, wherein the color pigment comprises the following raw materials in parts by weight: 20-30 parts of silicon dioxide, 10-15 parts of lead-free frit, 22-30 parts of boron oxide, 30-40 parts of feldspar and 5-30 parts of pigment.
3. The preparation method of the embossed stained paper according to claim 1, wherein the embossed pigment comprises the following raw materials in parts by weight: 10-20 parts of silicon dioxide, 8-13 parts of lead-free frit, 12-20 parts of zinc oxide and 38-48 parts of feldspar.
4. The method for preparing embossed decal paper according to claim 1, wherein the calcining temperature in said step of calcining said obtained color pigment and embossed pigment is 1200-1400 ℃.
5. The method for preparing embossed stained paper according to claim 1, wherein the mass ratio of the color pigment, the embossed pigment and the varnish is 10: 5-7.
6. A method for preparing embossed decal paper according to claim 1, wherein the process parameters of said drying process are:
temperature: 30-38 ℃, relative humidity: 40-60%, duration: 6-12 h.
7. The method for preparing embossed decal paper according to claim 1, wherein the particle size of the colored printing pigment and embossed printing pigment particles is 15 to 25 μm.
8. A decal paper for relief, wherein said decal paper is made by the process of any one of claims 1 to 7.
9. Use of any of the embossed decal papers of claim 8 on a ceramic applique wherein the post-applique firing temperature is 780-800 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010392011.4A CN111731019A (en) | 2020-05-11 | 2020-05-11 | Embossed stained paper and preparation method and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010392011.4A CN111731019A (en) | 2020-05-11 | 2020-05-11 | Embossed stained paper and preparation method and application thereof |
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| CN111731019A true CN111731019A (en) | 2020-10-02 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN202010392011.4A Pending CN111731019A (en) | 2020-05-11 | 2020-05-11 | Embossed stained paper and preparation method and application thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113427938A (en) * | 2021-07-26 | 2021-09-24 | 淄博泰康轻工制品有限公司 | Decalcomania paper and application thereof |
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| JP2003136899A (en) * | 2001-11-05 | 2003-05-14 | Osamu Tsutsui | Method for decoration on surface of product such as pottery and glass, and ink ribbon for transferring pigment |
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| CN106314002A (en) * | 2016-08-30 | 2017-01-11 | 福建省德化铭丰金花纸有限公司 | Ceramic overglazed pearlescent relief pigment, ceramic overglazed pearlescent relief color decal paper and manufacturing method thereof |
| CN109824384A (en) * | 2019-04-15 | 2019-05-31 | 淄博丰之源贸易有限公司 | The ceramics preparation method and decal method of fluorescence embossment marble paper |
| CN111070952A (en) * | 2019-12-28 | 2020-04-28 | 福建省德化县华兴陶瓷有限公司 | Ceramic-glazed pearlescent relief color paper and manufacturing method thereof |
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| JP2003136899A (en) * | 2001-11-05 | 2003-05-14 | Osamu Tsutsui | Method for decoration on surface of product such as pottery and glass, and ink ribbon for transferring pigment |
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| CN109824384A (en) * | 2019-04-15 | 2019-05-31 | 淄博丰之源贸易有限公司 | The ceramics preparation method and decal method of fluorescence embossment marble paper |
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