CN111690445A - Plant environment-friendly fuel oil and preparation method thereof - Google Patents
Plant environment-friendly fuel oil and preparation method thereof Download PDFInfo
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- CN111690445A CN111690445A CN202010576594.6A CN202010576594A CN111690445A CN 111690445 A CN111690445 A CN 111690445A CN 202010576594 A CN202010576594 A CN 202010576594A CN 111690445 A CN111690445 A CN 111690445A
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- oil
- fuel oil
- terpinene
- alpha
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Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/182—Organic compounds containing oxygen containing hydroxy groups; Salts thereof
- C10L1/1822—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
- C10L1/1824—Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms mono-hydroxy
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/18—Organic compounds containing oxygen
- C10L1/19—Esters ester radical containing compounds; ester ethers; carbonic acid esters
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/10—Liquid carbonaceous fuels containing additives
- C10L1/14—Organic compounds
- C10L1/22—Organic compounds containing nitrogen
- C10L1/222—Organic compounds containing nitrogen containing at least one carbon-to-nitrogen single bond
- C10L1/2222—(cyclo)aliphatic amines; polyamines (no macromolecular substituent 30C); quaternair ammonium compounds; carbamates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L2230/00—Function and purpose of a components of a fuel or the composition as a whole
- C10L2230/22—Function and purpose of a components of a fuel or the composition as a whole for improving fuel economy or fuel efficiency
Abstract
The invention relates to the technical field of novel fuels, in particular to plant environment-friendly fuel oil and a preparation method thereof, wherein the fuel oil mainly comprises the following components in percentage by mass: 60 to 80 percent of vegetable oil, 20 to 40 percent of alpha-terpinene, 1 to 5 percent of combustion improver and 0.3 to 0.7 percent of auxiliary agent. The plant environment-friendly fuel oil is prepared by mixing and reacting the plant oil, the alpha-terpinene, the combustion improver and the auxiliary agent, and has the advantages of simple process, high heat value, low energy consumption, no smoke, no odor, no residue, cleanness, environment friendliness, difficult explosion, flammability and safe and reliable transportation, and is a non-renewable substitute for common diesel oil of petrochemical fuels.
Description
Technical Field
The invention relates to the technical field of novel fuels, in particular to plant environment-friendly fuel oil and a preparation method thereof.
Background
The plant fuel oil is a clean energy source, is a form of earth plant storage solar energy, is the most main plant energy source, is from plants, can be recycled, does not pollute the atmosphere after being combusted, and is environment-friendly fuel oil.
In addition, the indexes of the plant fuel oil are similar to those of diesel oil, even the fuel value of the plant fuel oil is higher than that of the diesel oil, an engine using the plant fuel oil is easy to start, the power is high, the oil consumption is the same as that of a petroleum product, carbon and colloid are not accumulated after long-term use, the mechanical wear is small, the emission of harmful substances in tail gas is lower than the national standard, and the plant fuel oil is fuel oil for any diesel engine and diesel oil combustion system.
The plant fuel oil is a green and renewable substitute for common diesel oil as a petrochemical fuel, has high heat value and no environmental pollution, and achieves multiple purposes. Other plant fuel oil in the existing market has low heat value, high cost and difficult popularization.
In view of the above, the invention provides a plant environment-friendly fuel oil and a preparation method thereof, so as to solve the problems in the prior art.
Disclosure of Invention
The invention aims to overcome the defects of the prior art, and provides the plant environment-friendly fuel oil which has the advantages of high heat value, low energy consumption, no smoke, no odor, no residue, cleanness, environment friendliness, non-renewable petroleum fuel common diesel substitute, simple preparation process and easy preparation.
In order to achieve the purpose, the invention adopts the following technical scheme:
the plant environment-friendly fuel oil mainly comprises the following components in percentage by mass:
60% -80% of vegetable oil;
20% -40% of alpha-terpinene;
1% -5% of combustion improver;
0.3 to 0.7 percent of auxiliary agent.
As a preferable scheme of the invention, the fuel oil mainly comprises the following components:
65% -75% of vegetable oil;
25% -35% of alpha-terpinene;
2.5 to 4.5 percent of combustion improver;
0.4 to 0.6 percent of auxiliary agent.
As a preferred embodiment of the invention, the vegetable oil comprises castor oil, linseed oil and tung oil in a weight ratio of 1:1: 1.
In a preferred embodiment of the present invention, the combustion improver is isobutanol.
As a preferable scheme of the invention, the auxiliary agent is a mixture of ethyl acetate and ethylamine in a weight ratio of 1: 1.
In addition, the invention also provides a preparation method of the plant environment-friendly fuel oil, which comprises the following steps:
(1) weighing vegetable oil according to the mass percent, and sending the vegetable oil into a stirring tank;
(2) weighing alpha-terpinene according to the mass percent, putting the alpha-terpinene into a stirring tank, heating the alpha-terpinene to 55-60 ℃, and stirring the alpha-terpinene for 1.8-2.2 hours at the temperature;
(3) weighing the combustion improver and the auxiliary agent according to the mass percentage, and adding the combustion improver and the auxiliary agent into a stirring tank for pressurized stirring;
(4) and (3) sending the stirred oil into a storage tank, and continuing to react for 45-50h to obtain the plant environment-friendly fuel oil finished product.
As a preferable embodiment of the present invention, the stirring speed in the step (2) is 300-400 rpm.
In a preferred embodiment of the present invention, the pressure stirring conditions in step (3) are: stirring for 2-3h under the conditions of pressure of 2-3MPa and stirring speed of 600-700 rpm.
Compared with the prior art, the invention has the following beneficial effects:
the plant environment-friendly fuel oil is prepared by mixing and reacting the plant oil, the alpha-terpinene, the combustion improver and the auxiliary agent, has simple working procedures, high heat value, low energy consumption, no smoke, no odor, no residue, cleanness, environment friendliness, difficult explosion and flammability, safe and reliable transportation and non-renewable substitute of common diesel oil as a petrochemical fuel;
according to the invention, castor oil, linseed oil and tung oil are selected and changed into high-calorific-value, environment-friendly and renewable plant fuel, so that the castor oil, linseed oil and tung oil become a substitute of non-renewable petroleum fuel common diesel;
the fuel oil can be completely combusted by adding the alpha-terpinene, and the fuel oil is free of impurities, smoke and odor and environmental pollution after being combusted; the addition of the auxiliary agent consisting of ethyl acetate and ethylamine can promote the reaction and improve the generation speed of the plant environment-friendly fuel oil.
Detailed Description
The foregoing aspects of the present invention are described in further detail below by way of examples, but it should not be construed that the scope of the subject matter of the present invention is limited to the following examples, and that all the technologies that can be realized based on the above aspects of the present invention are within the scope of the present invention.
Example 1
The plant environment-friendly fuel oil comprises the following components in percentage by weight:
vegetable oil: 75kg (75%)
Castor oil 25kg (25%)
Linseed oil 25kg (25%)
Tung oil 25kg (23%)
23.7kg (23.7%)
Combustion improver:
isobutanol 1kg (1%)
Auxiliary agent:
ethyl acetate 0.15kg (0.15%)
Ethylamine 0.15kg (0.15%)
The preparation method of the plant environment-friendly fuel oil comprises the following steps:
(1) weighing vegetable oil according to the mass percent, and sending the vegetable oil into a stirring tank;
(2) weighing alpha-terpinene according to the mass percent, putting the alpha-terpinene into a stirring tank, heating the alpha-terpinene to 58 ℃, and stirring the alpha-terpinene for 2 hours at the temperature;
(3) weighing the combustion improver and the auxiliary agent according to the mass percentage, and adding the combustion improver and the auxiliary agent into a stirring tank for pressurized stirring;
(4) and (3) sending the stirred oil into a storage tank, and continuing to react for 47 hours to obtain the finished product of the plant environment-friendly fuel oil.
Wherein the stirring speed in the step (2) is 350 rpm.
Wherein the pressure stirring conditions in the step (3) are as follows: stirring was carried out under a pressure of 2.5MPa and a stirring speed of 650rpm for 2.5 hours.
Example 2
The plant environment-friendly fuel oil comprises the following components in percentage by weight:
vegetable oil: 60kg (60%)
Castor oil 20kg (20%)
Linseed oil 20kg (20%)
Tung oil 20kg (20%)
34.4kg (34.4%)
Combustion improver:
isobutanol 5kg (5%)
Auxiliary agent:
ethyl acetate 0.3kg (0.3%)
Ethylamine 0.3kg (0.3%)
The preparation method of the plant environment-friendly fuel oil comprises the following steps:
(1) weighing vegetable oil according to the mass percent, and sending the vegetable oil into a stirring tank;
(2) weighing alpha-terpinene according to the mass percent, putting the alpha-terpinene into a stirring tank, heating the alpha-terpinene to 56 ℃, and stirring the alpha-terpinene for 1.9 hours at the temperature;
(3) weighing the combustion improver and the auxiliary agent according to the mass percentage, and adding the combustion improver and the auxiliary agent into a stirring tank for pressurized stirring;
(4) and (3) sending the stirred oil into a storage tank, and continuing to react for 46 hours to obtain the finished product of the plant environment-friendly fuel oil.
Wherein the stirring speed in the step (2) is 330 rpm.
Wherein the pressure stirring conditions in the step (3) are as follows: stirring was carried out for 2.3h under a pressure of 2.3MPa and a stirring speed of 630 rpm.
Example 3
The plant environment-friendly fuel oil comprises the following components in percentage by weight:
vegetable oil: 75kg (75%)
Castor oil 25kg (25%)
Linseed oil 25kg (25%)
Tung oil 25kg (23%)
23.7kg (23.7%)
Combustion improver:
isobutanol 1kg (1%)
Auxiliary agent:
ethyl acetate 0.15kg (0.15%)
Ethylamine 0.15kg (0.15%)
The preparation method of the plant environment-friendly fuel oil comprises the following steps:
(1) weighing vegetable oil according to the mass percent, and sending the vegetable oil into a stirring tank;
(2) weighing alpha-terpinene according to the mass percent, putting the alpha-terpinene into a stirring tank, heating the alpha-terpinene to 58 ℃, and stirring the alpha-terpinene for 2.1 hours at the temperature;
(3) weighing the combustion improver and the auxiliary agent according to the mass percentage, and adding the combustion improver and the auxiliary agent into a stirring tank for pressurized stirring;
(4) and (3) sending the stirred oil into a storage tank, and continuing to react for 48 hours to obtain the finished product of the plant environment-friendly fuel oil.
Wherein the stirring speed in the step (2) is 380 rpm.
Wherein the pressure stirring conditions in the step (3) are as follows: stirring was carried out under a pressure of 2.8MPa and a stirring speed of 680rpm for 2.7 hours.
Example 4
The plant environment-friendly fuel oil comprises the following components in percentage by weight:
vegetable oil: 72kg (72%)
Castor oil 24kg (24%)
Linseed oil 24kg (24%)
Tung oil 24kg (24%)
23.6kg (23.6%)
Combustion improver:
isobutanol 4kg (4%)
Auxiliary agent:
ethyl acetate 0.2kg (0.2%)
Ethylamine 0.2kg (0.2%)
The preparation method of the plant environment-friendly fuel oil comprises the following steps:
(1) weighing vegetable oil according to the mass percent, and sending the vegetable oil into a stirring tank;
(2) weighing alpha-terpinene according to the mass percent, putting the alpha-terpinene into a stirring tank, heating the alpha-terpinene to 58 ℃, and stirring the alpha-terpinene for 1.8 hours at the temperature;
(3) weighing the combustion improver and the auxiliary agent according to the mass percentage, and adding the combustion improver and the auxiliary agent into a stirring tank for pressurized stirring;
(4) and (3) sending the stirred oil into a storage tank, and continuing to react for 47 hours to obtain the finished product of the plant environment-friendly fuel oil.
Wherein the stirring speed in the step (2) is 370 rpm.
Wherein the pressure stirring conditions in the step (3) are as follows: stirring was carried out under a pressure of 2.8MPa and a stirring speed of 640rpm for 2.5 hours.
In conclusion, the plant environment-friendly fuel oil is prepared by mixing and reacting the plant oil, the alpha-terpinene, the combustion improver and the auxiliary agent, has the advantages of simple process, high heat value, low energy consumption, no smoke, no smell, no residue, cleanness, environmental protection, difficult explosion and flammability, safe and reliable transportation and non-renewable petroleum fuel common diesel substitute.
The above-mentioned embodiments are merely preferred embodiments for fully illustrating the present invention, and the scope of the present invention is not limited thereto. The equivalent substitution or change made by the technical personnel in the technical field on the basis of the invention is all within the protection scope of the invention. The protection scope of the invention is subject to the claims.
Claims (8)
1. The plant environment-friendly fuel oil is characterized by mainly comprising the following components in percentage by mass:
60% -80% of vegetable oil;
20% -40% of alpha-terpinene;
1% -5% of combustion improver;
0.3 to 0.7 percent of auxiliary agent.
2. The plant environment-friendly fuel oil as claimed in claim 1, characterized in that the fuel oil mainly comprises the following components:
65% -75% of vegetable oil;
25% -35% of alpha-terpinene;
2.5 to 4.5 percent of combustion improver;
0.4 to 0.6 percent of auxiliary agent.
3. The plant environment-friendly fuel oil according to claim 1 or 2, wherein the plant oil comprises castor oil, linseed oil and tung oil in a weight ratio of 1:1: 1.
4. The plant environment-friendly fuel oil as claimed in claim 1 or 2, wherein the combustion improver is isobutanol.
5. The plant environment-friendly fuel oil as claimed in claim 1 or 2, wherein the additive is a mixture of ethyl acetate and ethylamine in a weight ratio of 1: 1.
6. The method for preparing the plant environment-friendly fuel oil according to any one of claims 1 to 5, characterized by comprising the following steps:
(1) weighing vegetable oil according to the mass percent, and sending the vegetable oil into a stirring tank;
(2) weighing alpha-terpinene according to the mass percent, putting the alpha-terpinene into a stirring tank, heating the alpha-terpinene to 55-60 ℃, and stirring the alpha-terpinene for 1.8-2.2 hours at the temperature;
(3) weighing the combustion improver and the auxiliary agent according to the mass percentage, and adding the combustion improver and the auxiliary agent into a stirring tank for pressurized stirring;
(4) and (3) sending the stirred oil into a storage tank, and continuing to react for 45-50h to obtain the plant environment-friendly fuel oil finished product.
7. The method for preparing plant environment-friendly fuel oil as claimed in claim 6, wherein the stirring speed in the step (2) is 300-400 rpm.
8. The method for preparing the plant environment-friendly fuel oil according to claim 6, wherein the pressure stirring conditions in the step (3) are as follows: stirring for 2-3h under the conditions of pressure of 2-3MPa and stirring speed of 600-700 rpm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010576594.6A CN111690445A (en) | 2020-06-23 | 2020-06-23 | Plant environment-friendly fuel oil and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010576594.6A CN111690445A (en) | 2020-06-23 | 2020-06-23 | Plant environment-friendly fuel oil and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111690445A true CN111690445A (en) | 2020-09-22 |
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| CN202010576594.6A Pending CN111690445A (en) | 2020-06-23 | 2020-06-23 | Plant environment-friendly fuel oil and preparation method thereof |
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Citations (7)
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| CN101107343A (en) * | 2005-01-25 | 2008-01-16 | Bp北美公司 | Reduced RVP oxygenated gasoline composition and method |
| CN101319146A (en) * | 2007-06-05 | 2008-12-10 | 李泰春 | Novel biological fuel oil and formulating method thereof |
| CN101831326A (en) * | 2010-05-18 | 2010-09-15 | 杭州绿洲能源科技有限公司 | Biomass fuel oil and preparation method thereof |
| CN102604690A (en) * | 2011-01-21 | 2012-07-25 | 张长生 | Environment-friendly fuel for novel automobile and preparation method of the environment-friendly fuel |
| CN103265981A (en) * | 2013-05-20 | 2013-08-28 | 清远市精旺环保设备有限公司 | Alcohol-based fuel combustion improver and alcohol-based fuel |
| CN103911182A (en) * | 2013-01-09 | 2014-07-09 | 刘粤荣 | Multicomponent formula combined biological fuel oil and preparation method thereof |
| CN106381178A (en) * | 2016-11-30 | 2017-02-08 | 广西东奇能源技术有限公司 | Biological fuel with high calorific value |
-
2020
- 2020-06-23 CN CN202010576594.6A patent/CN111690445A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101107343A (en) * | 2005-01-25 | 2008-01-16 | Bp北美公司 | Reduced RVP oxygenated gasoline composition and method |
| CN101319146A (en) * | 2007-06-05 | 2008-12-10 | 李泰春 | Novel biological fuel oil and formulating method thereof |
| CN101831326A (en) * | 2010-05-18 | 2010-09-15 | 杭州绿洲能源科技有限公司 | Biomass fuel oil and preparation method thereof |
| CN102604690A (en) * | 2011-01-21 | 2012-07-25 | 张长生 | Environment-friendly fuel for novel automobile and preparation method of the environment-friendly fuel |
| CN103911182A (en) * | 2013-01-09 | 2014-07-09 | 刘粤荣 | Multicomponent formula combined biological fuel oil and preparation method thereof |
| CN103265981A (en) * | 2013-05-20 | 2013-08-28 | 清远市精旺环保设备有限公司 | Alcohol-based fuel combustion improver and alcohol-based fuel |
| CN106381178A (en) * | 2016-11-30 | 2017-02-08 | 广西东奇能源技术有限公司 | Biological fuel with high calorific value |
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Application publication date: 20200922 |
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