CN111673315A - Special soldering flux for welding multi-main-grid solar cell - Google Patents

Special soldering flux for welding multi-main-grid solar cell Download PDF

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Publication number
CN111673315A
CN111673315A CN202010485471.1A CN202010485471A CN111673315A CN 111673315 A CN111673315 A CN 111673315A CN 202010485471 A CN202010485471 A CN 202010485471A CN 111673315 A CN111673315 A CN 111673315A
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CN
China
Prior art keywords
welding
flux
soldering
solar cell
grid solar
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN202010485471.1A
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Chinese (zh)
Inventor
张春梅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Huanghe Hydropower Xining Solar Power Co ltd
Huanghe Hydropower Development Co Ltd
State Power Investment Corp Xian Solar Power Co Ltd
Original Assignee
Huanghe Hydropower Xining Solar Power Co ltd
Huanghe Hydropower Development Co Ltd
State Power Investment Corp Xian Solar Power Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Huanghe Hydropower Xining Solar Power Co ltd, Huanghe Hydropower Development Co Ltd, State Power Investment Corp Xian Solar Power Co Ltd filed Critical Huanghe Hydropower Xining Solar Power Co ltd
Priority to CN202010485471.1A priority Critical patent/CN111673315A/en
Publication of CN111673315A publication Critical patent/CN111673315A/en
Pending legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/3612Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest with organic compounds as principal constituents
    • B23K35/3615N-compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K35/00Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
    • B23K35/22Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
    • B23K35/36Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
    • B23K35/362Selection of compositions of fluxes

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Electric Connection Of Electric Components To Printed Circuits (AREA)

Abstract

The invention aims to disclose a special soldering flux for welding a multi-main grid solar cell, which comprises the following components in percentage by mass: 1.5-3.2% of active agent, 0.5-1.5% of surfactant, 1.5-2.0% of auxiliary agent and 93.3-96.5% of bulk solvent; compared with the prior art, the welding repair proportion can be reduced by about 10 percent, and the cost price of the component can be reduced by about 0.008 yuan/watt; the welding quality is improved, the reliability of the assembly is improved, the service life is prolonged, the attenuation speed of the assembly is reduced, and the generating capacity is improved; in the using process, the crystal is less, the residues after welding are less, the quality control in the production process of the assembly is facilitated, and the maintenance of automatic welding equipment is facilitated; the solvent can be directly used without blowing and volatilizing the solvent to change the solid content, the field working environment is protected, and the purpose of the invention is realized.

Description

Special soldering flux for welding multi-main-grid solar cell
Technical Field
The invention relates to a soldering flux, in particular to a special soldering flux for soldering a multi-main-grid solar cell.
Background
Welding is the most important process for producing the photovoltaic module, and the welding quality determines the power generation capacity and the service life of the module. The soldering flux is an auxiliary material used in welding, and the main function of the soldering flux is to remove oxides on the surfaces of solder and a welded base metal so as to ensure that the metal surface reaches necessary cleanliness; the surface is prevented from being oxidized again during welding, the surface tension of the welding flux is reduced, and the welding performance is improved; the welding area is protected, the overflow of the liquid solder is improved, the infiltration capacity is enhanced, the heat transfer of the welding area is improved, the performance of the flux is balanced, and the quality of the assembly is directly influenced.
At present, the active ingredients of the traditional soldering flux on the market contain halogen, and the soldering flux containing the halogen can quickly remove the oxide film of a welding pad and enhance the wettability of solder, but the addition of the halogen can weaken the reliability of the welding point, reduce the surface insulation resistance and is unfavorable for the ecological environment.
At present, infrared welding is a general process technology in automatic welding, and on the premise of ensuring product quality, a multi-section heating method is improved to increase welding starting temperature, shorten welding period and improve welding efficiency, so that the phenomenon of hidden cracking of a battery piece caused by rapid temperature rise is greatly improved, and equipment stability and production efficiency are improved. In automatic production equipment, the production speed and the production efficiency are gradually improved, and the requirement on the soldering flux is higher and higher.
The number of welding points of the multi-main-grid solar cell is multiplied due to the increase of the number of grid lines, and the width of the grid lines is narrowed; the circular thin welding strip is adopted to replace a traditional flat welding strip during welding of the multi-main-grid solar cell, more accurate positioning precision is needed, the positioning difficulty of the welding strip is increased, the welding contact area is small, the false welding is easy, and the requirements on welding quality, welding uniformity and welding consistency are higher.
The existing soldering flux pollutes the working environment during welding; the solid content value and acid value index of the soldering flux can not be accurately controlled; lamination bubbles are easily caused due to much residual soldering flux after welding; the production efficiency of automatic welding equipment is reduced due to more residual and more crystals of the soldering flux; the active components of the soldering flux contain halogen, and the reliability of the soldering flux on a welding point cannot be guaranteed.
Therefore, a flux dedicated for soldering a multi-main grid solar cell is particularly needed to solve the existing problems.
Disclosure of Invention
The invention aims to provide a special soldering flux for welding a multi-main-grid solar cell, which solves the problems of unstable welding quality caused by inaccurate welding positioning of a circular welding strip and poor soldering effect and environmental pollution of the traditional conventional soldering flux due to more residues after welding.
The technical problem solved by the invention can be realized by adopting the following technical scheme:
the special soldering flux for welding the multi-main grid solar cell is characterized by comprising the following components in percentage by mass:
1.5-3.2% of active agent, 0.5-1.5% of surfactant, 1.5-2.0% of auxiliary agent and 93.3-96.5% of bulk solvent.
In one embodiment of the invention, the activator is adipic acid, dimethylamine, octadecanoic acid and the temperature at which the activator is mixed is 25-55 ℃.
In one embodiment of the invention, the surfactant is nonylphenol polyoxyethylene ether.
In one embodiment of the invention, the auxiliary agent is glyceryl stearate, benzotriazole, toluene diisocyanate, diphenylmethane diisocyanate, 1, 6-hexamethylene diisocyanate, and titanium dioxide.
In one embodiment of the present invention, the bulk solvent is alcohol ethers such as isopropyl alcohol, butyl cellosolve and the like.
In one embodiment of the invention, the physical properties of the flux special for soldering the multi-master-grid solar cell are as follows:
the specific gravity is 0.795 +/-0.005, the solid content is 3.8 +/-0.3 percent, and the acid value is 31.0 +/-3 mg KOH/g of flux.
In one embodiment of the invention, the reliability test result of the flux special for soldering the multi-master-grid solar cell is as follows:
and (3) a copper mirror corrosion test is performed, wherein the copper mirror corrosion test is performed, the chromium acid salt test paper is qualified, the chloride and the bromide are not detected, the fluoride is detected to be qualified, and the surface insulation resistance (85 ℃, 85% RH) is passed.
In one embodiment of the invention, the storage condition of the flux special for soldering the multi-master-grid solar cell is as follows:
the soldering flux is flammable, needs to be far away from a fire source, is stored under the environment of 10-25 ℃ (50-77 DEG F), and has a shelf life of 1 year.
Compared with the prior art, the special soldering flux for welding the multi-main grid solar cell can reduce the welding repair proportion by about 10 percent, and reduce the cost price of the component by about 0.008 yuan/watt; the welding quality is improved, the reliability of the assembly is improved, the service life is prolonged, the attenuation speed of the assembly is reduced, and the generating capacity is improved; in the using process, the crystal is less, the residues after welding are less, the quality control in the production process of the assembly is facilitated, and the maintenance of automatic welding equipment is facilitated; the solvent can be directly used without blowing and volatilizing the solvent to change the solid content, the field working environment is protected, and the purpose of the invention is realized.
The features of the present invention will be clearly understood by reference to the following detailed description of the preferred embodiments of the present invention.
Detailed Description
In order to make the technical means, the creation characteristics, the achievement purposes and the effects of the invention easy to understand, the invention is further explained by combining the concrete.
The invention discloses a special soldering flux for welding a multi-main grid solar cell, which comprises the following components in percentage by mass:
1.5-3.2% of active agent, 0.5-1.5% of surfactant, 1.5-2.0% of auxiliary agent and 93.3-96.5% of bulk solvent.
The activating agent is adipic acid, dimethylamine and octadecanoic acid, and the temperature of the activating agent during mixing is 25-55 ℃.
The surfactant is nonylphenol polyoxyethylene ether.
The auxiliary agent is glyceryl stearate, benzotriazole, toluene diisocyanate, diphenylmethane diisocyanate, 1, 6-hexamethylene diisocyanate and titanium dioxide.
The bulk solvent is alcohol ethers such as isopropanol, butyl cellosolve and the like.
The physical properties of the special soldering flux for welding the multi-main grid solar cell are as follows:
the specific gravity is 0.795 +/-0.005, the solid content is 3.8 +/-0.3 percent, and the acid value is 31.0 +/-3 mg KOH/g of flux.
The reliability test result of the special soldering flux for welding the multi-main grid solar cell is as follows:
and (3) a copper mirror corrosion test is performed, wherein the copper mirror corrosion test is performed, the chromium acid salt test paper is qualified, the chloride and the bromide are not detected, the fluoride is detected to be qualified, and the surface insulation resistance (85 ℃, 85% RH) is passed.
The storage conditions of the special soldering flux for welding the multi-main grid solar cell are as follows:
the soldering flux is flammable, needs to be far away from a fire source, is stored under the environment of 10-25 ℃ (50-77 DEG F), and has a shelf life of 1 year.
In the production process, equipment, raw materials, auxiliary materials and a container for storing the soldering flux can generate tiny granular substances, the performance of the soldering flux can be reduced, and the reliability test of welding and later period is influenced. Therefore, the container needs to be cleaned regularly, and meanwhile, fresh soldering flux needs to be replaced timely, the stability of the soldering flux is kept, and the soldering flux has a positive help on the welding effect, and particularly for automatic welding of the multi-main grid solar cell, the soldering flux in the container needs to be replaced regularly.
Example 1
The special soldering flux for welding the multi-main grid solar cell in the embodiment comprises the following components in percentage by mass: 1.5% of activating agent, 0.5% of surfactant, 1.5% of additive and 96.5% of bulk solvent.
Example 2
The special soldering flux for welding the multi-main grid solar cell in the embodiment comprises the following components in percentage by mass: 2% of activating agent, 0.8% of surfactant, 1.8% of additive and 95.4% of bulk solvent.
Example 3
The special soldering flux for welding the multi-main grid solar cell in the embodiment comprises the following components in percentage by mass: 3.2% of activating agent, 1.5% of surfactant, 2.0% of additive and 93.3% of bulk solvent.
Example 4
The experimental scheme of the soldering effect of the special soldering flux for soldering the multi-master-grid solar cell in the embodiment comprises the following steps:
the first step is as follows: using 720 battery pieces with the same batch, the same power and the same specification;
the second step is that: selecting a series welding machine, and setting the same welding parameters including welding temperature, lamp tube power, welding time, welding strip tension coefficient and the like;
the third step: cleaning the stringer, thoroughly removing the flux residue, and adding conventional flux;
the fourth step: starting a series welding machine, welding 5 assemblies after full preheating, and recording the proportion of the rosin joint after EL test;
the fifth step: cleaning a series welding machine, thoroughly removing the residues of the soldering flux, and adding the special soldering flux;
and a sixth step: starting a series welding machine, welding 5 assemblies after full preheating, and recording the proportion of the rosin joint after EL test;
the seventh step: and through data comparison, the soldering rosin occupation ratio of the conventional soldering flux and the special soldering flux is obtained.
Example 5
The experimental scheme of the soldering effect of the special soldering flux for soldering the multi-master-grid solar cell in the embodiment comprises the following steps:
the first step is as follows: preparing 12 coils of a welding strip A and a welding strip B of the same specification and different manufacturers respectively;
the second step is that: setting the same welding parameters including welding temperature, lamp tube power, welding time, welding strip tension coefficient and the like on the same series welding machine, adding special scaling powder, respectively welding 5 assemblies by using a welding strip A, and welding 5 assemblies by using a welding strip B;
the third step: recording the rosin joint proportion through an EL test;
the fourth step: through data comparison, the matching performance of the welding strip and the special soldering flux of different manufacturers is different.
The soldering flux special for soldering the multi-master-grid solar cell has the following soldering effects compared with the conventional soldering flux:
1. and (3) cold solder joint comparison:
conventional flux welding insufficient solder repair rate: 13 percent; the flux welding rosin joint repair rate special for welding the multi-main grid solar cell of the embodiment is as follows: 6 percent;
2. offset welding comparison:
the conventional soldering flux has the following offset welding repair rate: 3 percent; the special soldering flux for welding the multi-main-grid solar cell of the embodiment has the following welding offset welding repair rate: 1.5 percent;
3. and (3) comparison of welding tension:
welding tension value of conventional soldering flux: 0.6N; the welding tension value of the special soldering flux for welding the multi-main grid solar cell of the embodiment is as follows: 2.73N;
4. hidden crack comparison:
the conventional soldering flux welding hidden crack repair rate is as follows: 9.8 percent; the welding hidden crack repair rate of the special soldering flux for welding the multi-main grid solar cell of the embodiment is as follows: 8.7 percent;
5. comparison of residues after welding:
conventional flux postweld residue: a plurality of; the special soldering flux for welding the multi-main grid solar cell of the embodiment has the following residues after welding: less.
The foregoing shows and describes the general principles and broad features of the present invention and advantages thereof. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are merely illustrative of the principles of the present invention, but that various changes and modifications may be made without departing from the spirit and scope of the invention, which is defined by the appended claims and their equivalents.

Claims (8)

1. The special soldering flux for welding the multi-main grid solar cell is characterized by comprising the following components in percentage by mass:
1.5-3.2% of active agent, 0.5-1.5% of surfactant, 1.5-2.0% of auxiliary agent and 93.3-96.5% of bulk solvent.
2. The flux for soldering a multi-master-grid solar cell according to claim 1, wherein the activator is adipic acid, dimethylamine or octadecanoic acid, and the temperature of the activator is 25-55 ℃ during mixing.
3. The flux for soldering a multi-primary grid solar cell according to claim 1, wherein the surfactant is nonylphenol polyoxyethylene ether.
4. The special soldering flux for welding the multi-main-grid solar cell according to claim 1, wherein the auxiliary agent is glyceryl stearate, benzotriazole, toluene diisocyanate, diphenylmethane diisocyanate, 1.6-hexamethylene diisocyanate, and titanium dioxide.
5. The flux for soldering a multi-primary grid solar cell according to claim 1, wherein the bulk solvent is alcohol ethers such as isopropyl alcohol and butyl cellosolve.
6. The special flux for soldering of multi-master grid solar cells according to claim 1, wherein the physical properties of the special flux are as follows:
the specific gravity is 0.795 +/-0.005, the solid content is 3.8 +/-0.3 percent, and the acid value is 31.0 +/-3 mg KOH/g of flux.
7. The flux for soldering a multi-primary grid solar cell according to claim 1, wherein the reliability test result of the flux for soldering is as follows:
and (3) a copper mirror corrosion test is performed, wherein the copper mirror corrosion test is performed, the chromium acid salt test paper is qualified, the chloride and the bromide are not detected, the fluoride is detected to be qualified, and the surface insulation resistance (85 ℃, 85% RH) is passed.
8. The special soldering flux for soldering of multi-master grid solar cells according to claim 1, wherein the special soldering flux is stored under the following conditions:
the soldering flux is flammable, needs to be far away from a fire source, is stored under the environment of 10-25 ℃ (50-77 DEG F), and has a shelf life of 1 year.
CN202010485471.1A 2020-06-01 2020-06-01 Special soldering flux for welding multi-main-grid solar cell Pending CN111673315A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202010485471.1A CN111673315A (en) 2020-06-01 2020-06-01 Special soldering flux for welding multi-main-grid solar cell

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Application Number Priority Date Filing Date Title
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Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11267884A (en) * 1998-03-23 1999-10-05 Mitsubishi Electric Corp Flux and cream solder for solar battery module
US20080135133A1 (en) * 2004-08-31 2008-06-12 Senju Metal Industry Co., Ltd. Soldering Flux
CN103286477A (en) * 2013-05-22 2013-09-11 中南大学 Soldering flux for lead-free solder and preparation method of soldering flux
CN103862200A (en) * 2014-03-24 2014-06-18 吉安谊盛电子材料有限公司 Scaling powder special for welding of solar assemblies
CN104690450A (en) * 2015-04-07 2015-06-10 武汉谊盛新材料科技有限公司 Special scaling powder for automatic welding of photovoltaic battery piece
CN105269181A (en) * 2015-06-19 2016-01-27 常州天合光伏焊带材料有限公司 High-activity scaling powder for photovoltaic solder strip
CN111055045A (en) * 2019-12-29 2020-04-24 武汉风帆电化科技股份有限公司 Special soldering flux for photovoltaic solder strip

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11267884A (en) * 1998-03-23 1999-10-05 Mitsubishi Electric Corp Flux and cream solder for solar battery module
US20080135133A1 (en) * 2004-08-31 2008-06-12 Senju Metal Industry Co., Ltd. Soldering Flux
CN103286477A (en) * 2013-05-22 2013-09-11 中南大学 Soldering flux for lead-free solder and preparation method of soldering flux
CN103862200A (en) * 2014-03-24 2014-06-18 吉安谊盛电子材料有限公司 Scaling powder special for welding of solar assemblies
CN104690450A (en) * 2015-04-07 2015-06-10 武汉谊盛新材料科技有限公司 Special scaling powder for automatic welding of photovoltaic battery piece
CN105269181A (en) * 2015-06-19 2016-01-27 常州天合光伏焊带材料有限公司 High-activity scaling powder for photovoltaic solder strip
CN111055045A (en) * 2019-12-29 2020-04-24 武汉风帆电化科技股份有限公司 Special soldering flux for photovoltaic solder strip

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Title
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