CN111662012A - Wear-resistant glaze - Google Patents
Wear-resistant glaze Download PDFInfo
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- CN111662012A CN111662012A CN202010584509.0A CN202010584509A CN111662012A CN 111662012 A CN111662012 A CN 111662012A CN 202010584509 A CN202010584509 A CN 202010584509A CN 111662012 A CN111662012 A CN 111662012A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
- C03C8/20—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions containing titanium compounds; containing zirconium compounds
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/85—Coating or impregnation with inorganic materials
- C04B41/86—Glazes; Cold glazes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Glass Compositions (AREA)
Abstract
The invention discloses a wear-resistant glaze, which belongs to the technical field of glaze production and comprises the following components in percentage by weight: 10-15% of frit, 5-15% of spodumene, 7-10% of wollastonite, 5-10% of kaolin, 4-6% of white corundum, 2-5% of calcite, 6-9% of barium carbonate, 8-12% of glass powder, 10-15% of functional powder and the balance of potash feldspar. The glaze material has the characteristics of good wear resistance and high strength and quality, has high bonding strength with ceramic base layers, is not easy to fall off, and has strong use stability and long service life.
Description
Technical Field
The invention belongs to the technical field of glaze production, and particularly relates to a wear-resistant glaze.
Background
The ceramic product is an indispensable daily necessity in people's daily life. With the improvement of living standards, consumers have increasingly demanded safety, beauty, practicability, and the like of ceramic products. The safety problem of the ceramic products for daily use mainly lies in that heavy metals such as lead, chromium and the like exceed the standard, and further the health of human bodies is harmed. The main source of heavy metals such as lead and chromium in the ceramic product is the components in the glaze, and when the ceramic product is used, elements such as lead in the glaze permeate into food and enter into a human body. In addition, people also put forward higher requirements for the qualities of practicality, stability and the like of glaze, and the application numbers are as follows: 201610281839.6 discloses a wear-resistant transparent glaze and a method for preparing glazed brick, wherein spodumene, clinker, potash feldspar, barium carbonate and other components are used, and wollastonite, kaolin and the like are added to improve the wear resistance of the glaze, but the quality and the like of the glaze are still required to be further improved.
Disclosure of Invention
The invention provides a wear-resistant glaze material aiming at the problems in the background technology, and the glaze material has the characteristics of high strength, good wear resistance and the like.
The invention is realized by the following technical scheme:
a wear-resistant glaze comprises the following components in percentage by weight:
10-15% of frit, 5-15% of spodumene, 7-10% of wollastonite, 5-10% of kaolin, 4-6% of white corundum, 2-5% of calcite, 6-9% of barium carbonate, 8-12% of glass powder, 10-15% of functional powder and the balance of potash feldspar.
Preferably, the composition comprises the following components in percentage by weight:
13% of frit, 10% of spodumene, 9% of wollastonite, 8% of kaolin, 5% of white corundum, 4% of calcite, 8% of barium carbonate, 10% of glass powder, 13% of functional powder and 20% of potassium feldspar.
Further, the frit is a high-alumina wear-resistant frit.
Further, the preparation method of the functional powder comprises the following steps:
(1) uniformly mixing graphene, an anionic surfactant, polyvinyl alcohol, a titanate coupling agent, nano titanium dioxide and deionized water to obtain a primary mixed solution for later use;
(2) carrying out water bath heating on the primary mixed liquid obtained in the step (1), and simultaneously carrying out ultrasonic treatment for 1-1.5 h for later use;
(3) mixing the zirconium oxychloride solution and hydrogen peroxide together, uniformly stirring, and standing for 1-2 h to obtain a secondary mixed solution for later use;
(4) and (3) continuously dropwise adding the primary mixed solution treated in the step (2) into the secondary mixed solution obtained in the step (3), uniformly stirring, standing for 45-50 min, then adjusting the pH value of the whole to 6-7, and finally performing centrifugal separation and drying treatment. The functional powder prepared by the invention is prepared by processing and modifying graphene serving as a main substance, nano titanium dioxide is filled and grafted to form composite particles, then zirconium oxychloride solution and hydrogen peroxide are mixed and reacted together, zirconium sol particle molecules are promoted to be adsorbed on the outer surfaces of the composite particles, a stable coating layer is formed, and the finally prepared functional powder has the characteristics of good surface activity, high structural strength and high hardness, and the use quality of glaze can be obviously improved.
Further, in the step (1), when the graphene, the anionic surfactant, the polyvinyl alcohol, the titanate coupling agent, the nano titanium dioxide and the deionized water are mixed, the weight ratio of the graphene to the anionic surfactant to the polyvinyl alcohol to the titanate coupling agent to the nano titanium dioxide to the deionized water is 4-5: 3-4: 2-4: 1-2: 0.5-1: 120-150.
Further, controlling the temperature to be 80-85 ℃ during water bath heating in the step (2); and controlling the ultrasonic frequency to be 340-380 kHz during ultrasonic treatment.
Further, the volume ratio of the zirconium oxychloride solution and hydrogen peroxide in the step (3) is 3-4: 1.
Further, the concentration of the zirconium oxychloride solution is 0.15-0.2 mol/L; the mass fraction of the hydrogen peroxide is 30%.
Further, the dropping amount of the primary mixed liquid in the step (4) is 1-1.2 times of the total mass of the secondary mixed liquid.
Further, the rotating speed of the centrifugation is controlled to be 3000-3500 rpm during the centrifugation in the step (4); and the temperature for controlling drying during drying treatment is 100-110 ℃.
Compared with the prior art, the invention has the beneficial effects that:
the glaze material has the characteristics of good wear resistance and high strength and quality, has high bonding strength with ceramic base layers, is not easy to fall off, has strong use stability and service life, and has great popularization and application values.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. The specific embodiments described herein are merely illustrative of the invention and do not delimit the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
A wear-resistant glaze comprises the following components in percentage by weight:
10-15% of frit, 5-15% of spodumene, 7-10% of wollastonite, 5-10% of kaolin, 4-6% of white corundum, 2-5% of calcite, 6-9% of barium carbonate, 8-12% of glass powder, 10-15% of functional powder and the balance of potash feldspar; the frit is high-aluminum wear-resistant frit; the preparation method of the functional powder comprises the following steps:
(1) uniformly mixing graphene, an anionic surfactant, polyvinyl alcohol, a titanate coupling agent, nano titanium dioxide and deionized water to obtain a primary mixed solution for later use;
(2) carrying out water bath heating on the primary mixed liquid obtained in the step (1), and simultaneously carrying out ultrasonic treatment for 1-1.5 h for later use;
(3) mixing the zirconium oxychloride solution and hydrogen peroxide together, uniformly stirring, and standing for 1-2 h to obtain a secondary mixed solution for later use;
(4) and (3) continuously dropwise adding the primary mixed solution treated in the step (2) into the secondary mixed solution obtained in the step (3), uniformly stirring, standing for 45-50 min, then adjusting the pH value of the whole to 6-7, and finally performing centrifugal separation and drying treatment.
In the step (1), when the graphene, the anionic surfactant, the polyvinyl alcohol, the titanate coupling agent, the nano titanium dioxide and the deionized water are mixed, the corresponding weight ratio is 4-5: 3-4: 2-4: 1-2: 0.5-1: 120-150.
Controlling the temperature to be 80-85 ℃ during water bath heating in the step (2); and controlling the ultrasonic frequency to be 340-380 kHz during ultrasonic treatment.
When the zirconium oxychloride solution and hydrogen peroxide are mixed together in the step (3), the corresponding volume ratio is 3-4: 1; the concentration of the zirconium oxychloride solution is 0.15-0.2 mol/L; the mass fraction of the hydrogen peroxide is 30%.
In the step (4), the dropping amount of the primary mixed liquid is 1-1.2 times of the total mass of the secondary mixed liquid.
Controlling the rotation speed of centrifugation to be 3000-3500 rpm during centrifugal separation in the step (4); and the temperature for controlling drying during drying treatment is 100-110 ℃.
Example 1
A wear-resistant glaze comprises the following components in percentage by weight:
10% of frit, 5% of spodumene, 7% of wollastonite, 5% of kaolin, 4% of white corundum, 2% of calcite, 6% of barium carbonate, 8% of glass powder, 10% of functional powder and the balance of potassium feldspar; the frit is high-aluminum wear-resistant frit; the preparation method of the functional powder comprises the following steps:
(1) uniformly mixing graphene, an anionic surfactant, polyvinyl alcohol, a titanate coupling agent, nano titanium dioxide and deionized water to obtain a primary mixed solution for later use;
(2) carrying out water bath heating on the primary mixed liquid obtained in the step (1), and carrying out ultrasonic treatment simultaneously for 1h for standby;
(3) mixing the zirconium oxychloride solution and hydrogen peroxide together, stirring uniformly, and standing for 1h to obtain a secondary mixed solution for later use;
(4) and (3) continuously dropwise adding the primary mixed solution treated in the step (2) into the secondary mixed solution obtained in the step (3), uniformly stirring, standing for 45min, then adjusting the overall pH value to 6, and finally performing centrifugal separation and drying treatment.
In the step (1), the graphene, the anionic surfactant, the polyvinyl alcohol, the titanate coupling agent, the nano titanium dioxide and the deionized water are mixed according to a weight ratio of 4:3:2: 1: 0.5:120.
Controlling the temperature to be 80 ℃ during the water bath heating in the step (2); the ultrasonic frequency is controlled to be 340kHz during ultrasonic treatment.
The corresponding volume ratio of the zirconium oxychloride solution and hydrogen peroxide in the step (3) is 3: 1; the concentration of the zirconium oxychloride solution is 0.15 mol/L; the mass fraction of the hydrogen peroxide is 30%.
And (4) the dropping amount of the primary mixed solution is 1 time of the total mass of the secondary mixed solution.
Controlling the rotation speed of centrifugation to be 3000 r/min during the centrifugal separation in the step (4); the temperature for drying is controlled to be 100 ℃ during the drying treatment.
Example 2
A wear-resistant glaze comprises the following components in percentage by weight:
10% of frit, 10% of spodumene, 9% of wollastonite, 13% of kaolin, 5% of white corundum, 2% of calcite, 6% of barium carbonate, 8% of glass powder, 10% of functional powder and the balance of potassium feldspar; the frit is high-aluminum wear-resistant frit; the preparation method of the functional powder comprises the following steps:
(1) uniformly mixing graphene, an anionic surfactant, polyvinyl alcohol, a titanate coupling agent, nano titanium dioxide and deionized water to obtain a primary mixed solution for later use;
(2) carrying out water bath heating on the primary mixed liquid obtained in the step (1), and carrying out ultrasonic treatment simultaneously for 1h for standby;
(3) mixing the zirconium oxychloride solution and hydrogen peroxide together, stirring uniformly, standing for 1.5h to obtain a secondary mixed solution for later use;
(4) and (3) continuously dropwise adding the primary mixed solution treated in the step (2) into the secondary mixed solution obtained in the step (3), uniformly stirring, standing for 48min, then adjusting the overall pH value to 6, and finally performing centrifugal separation and drying treatment.
In the step (1), the weight ratio of the graphene to the anionic surfactant to the polyvinyl alcohol to the titanate coupling agent to the nano titanium dioxide to the deionized water is 4.5:3.6:2: 1: 0.5:120.
Controlling the temperature to be 83 ℃ during the water bath heating in the step (2); and controlling the ultrasonic frequency to be 360kHz during ultrasonic treatment.
The corresponding volume ratio of the zirconium oxychloride solution and hydrogen peroxide in the step (3) is 3: 1; the concentration of the zirconium oxychloride solution is 0.15 mol/L; the mass fraction of the hydrogen peroxide is 30%.
And (4) the dropping amount of the primary mixed solution is 1 time of the total mass of the secondary mixed solution.
Controlling the rotation speed of centrifugation to be 3000 r/min during the centrifugal separation in the step (4); the temperature for drying is controlled to be 100 ℃ during the drying treatment.
Example 3
A wear-resistant glaze comprises the following components in percentage by weight:
13% of frit, 10% of spodumene, 9% of wollastonite, 8% of kaolin, 5% of white corundum, 4% of calcite, 8% of barium carbonate, 10% of glass powder, 13% of functional powder and 20% of potassium feldspar; the frit is high-aluminum wear-resistant frit; the preparation method of the functional powder comprises the following steps:
(1) uniformly mixing graphene, an anionic surfactant, polyvinyl alcohol, a titanate coupling agent, nano titanium dioxide and deionized water to obtain a primary mixed solution for later use;
(2) carrying out water bath heating on the primary mixed liquid obtained in the step (1), and simultaneously carrying out ultrasonic treatment for 1.3h for standby;
(3) mixing the zirconium oxychloride solution and hydrogen peroxide together, stirring uniformly, standing for 1.5h to obtain a secondary mixed solution for later use;
(4) and (3) continuously dropwise adding the primary mixed solution treated in the step (2) into the secondary mixed solution obtained in the step (3), uniformly stirring, standing for 48min, then adjusting the overall pH value to 6.5, and finally performing centrifugal separation and drying treatment.
In the step (1), the weight ratio of the graphene to the anionic surfactant to the polyvinyl alcohol to the titanate coupling agent to the nano titanium dioxide to the deionized water is 4.5:3.5:3: 1.6: 0.8:140.
Controlling the temperature to be 82 ℃ during the water bath heating in the step (2); and controlling the ultrasonic frequency to be 360kHz during ultrasonic treatment.
The corresponding volume ratio of the zirconium oxychloride solution and hydrogen peroxide in the step (3) is 3.5: 1; the concentration of the zirconium oxychloride solution is 0.18 mol/L; the mass fraction of the hydrogen peroxide is 30%.
In the step (4), the dropping amount of the primary mixed solution is 1.1 times of the total mass of the secondary mixed solution.
Controlling the rotation speed of centrifugation to 3300 rpm during the centrifugation in the step (4); the drying temperature is controlled to be 105 ℃ during the drying treatment.
Example 4
A wear-resistant glaze comprises the following components in percentage by weight:
15% of frit, 15% of spodumene, 10% of wollastonite, 10% of kaolin, 6% of white corundum, 5% of calcite, 9% of barium carbonate, 12% of glass powder, 15% of functional powder and the balance of potassium feldspar; the frit is high-aluminum wear-resistant frit; the preparation method of the functional powder comprises the following steps:
(1) uniformly mixing graphene, an anionic surfactant, polyvinyl alcohol, a titanate coupling agent, nano titanium dioxide and deionized water to obtain a primary mixed solution for later use;
(2) carrying out water bath heating on the primary mixed liquid obtained in the step (1), and simultaneously carrying out ultrasonic treatment for 1.5h for standby;
(3) mixing the zirconium oxychloride solution and hydrogen peroxide together, stirring uniformly, and standing for 2 hours to obtain a secondary mixed solution for later use;
(4) and (3) continuously dropwise adding the primary mixed solution treated in the step (2) into the secondary mixed solution obtained in the step (3), uniformly stirring, standing for 50min, then adjusting the overall pH value to 7, and finally performing centrifugal separation and drying treatment.
In the step (1), the corresponding weight ratio of the graphene to the anionic surfactant to the polyvinyl alcohol to the titanate coupling agent to the nano titanium dioxide to the deionized water is 5:4:4: 2: 1:150.
Controlling the temperature to be 85 ℃ during the water bath heating in the step (2); the ultrasonic frequency is controlled to be 380kHz during ultrasonic treatment.
The corresponding volume ratio of the zirconium oxychloride solution and hydrogen peroxide in the step (3) is 4: 1; the concentration of the zirconium oxychloride solution is 0.2 mol/L; the mass fraction of the hydrogen peroxide is 30%.
And (4) the dropping amount of the primary mixed solution is 1.2 times of the total mass of the secondary mixed solution.
Controlling the rotation speed of the centrifugation to be 3500 rpm during the centrifugation in the step (4); the drying temperature is controlled to be 110 ℃ during the drying treatment.
Comparative example 1
This comparative example 1 is different from example 3 only in that in the preparation of the functional powder, the nano titanium dioxide component in the step (1) is omitted, except that the other process steps are the same.
Comparative example 2
This comparative example 2 is different from example 3 only in that in the preparation of a functional powder, the treatments of the step (3) and the step (4) are omitted, and the solution treated in the step (2) is directly subjected to centrifugal drying, except that the other steps of the method are the same.
Comparative example 3
This comparative example 3 is different from example 3 only in that the functional powder component is replaced with an equal mass part of graphene, except that the other steps are the same.
Control group
The application numbers are: 201610281839.6 discloses a wear-resistant transparent glaze and a method for preparing a glazed brick by using the same, which particularly adopts the technical scheme of the embodiment 1.
In order to compare the effects of the invention, the glaze materials prepared in the above example 3, comparative examples 1 to 3 and a control group were subjected to performance tests, and the specific comparative data are shown in the following table 1:
TABLE 1
| Hardness (GPa) | Strength (MPa) | Hygroexpansion Rate (%) | Abrasion resistance rating (grade) | |
| Example 3 | 22.1 | 202.5 | 0.028 | 5 |
| Comparative example 1 | 18.7 | 181.8 | 0.049 | 4 |
| Comparative example 2 | 18.2 | 174.6 | 0.054 | 4 |
| Comparative example 3 | 17.6 | 160.3 | 0.085 | 3 |
| Control group | 16.8 | 155.4 | 0.096 | 4 |
Note: the tests of hardness, strength, hygroexpansion coefficient and wear resistance level in the above table 1 are that the prepared glaze is coated on the same ceramic blank (the ceramic blank is a cuboid sample with the length, width and height of 6cm multiplied by 2cm multiplied by 1.5 cm), then the firing treatment is carried out, the firing temperature is controlled to be 1050 ℃, except that the types of the glaze are different, the other processing methods are completely the same, and the performance detection is carried out on the prepared ceramic finished product after the completion; the hygroscopical expansion rate is characterized in that a container filled with distilled water is heated and boiled, a corresponding ceramic finished product is put into boiling water (the ceramic finished product is kept not to be in contact with the wall of the container and the bottom of the container), the ceramic finished product is continuously boiled for 24 hours, then the ceramic finished product is taken out and naturally cooled to room temperature, the length of the ceramic finished product is measured, and the hygroscopical expansion rate is represented by the length change rate of the ceramic finished product before and after boiling; the abrasion resistance rating is tested with reference to GB/T4100-2006.
As can be seen from the above Table 1, the glaze of the present invention has good wear resistance, and simultaneously, the qualities of strength, hardness, etc. are significantly enhanced, and the glaze has long service life and high use value.
Claims (10)
1. The wear-resistant glaze is characterized by comprising the following components in percentage by weight:
10-15% of frit, 5-15% of spodumene, 7-10% of wollastonite, 5-10% of kaolin, 4-6% of white corundum, 2-5% of calcite, 6-9% of barium carbonate, 8-12% of glass powder, 10-15% of functional powder and the balance of potash feldspar.
2. The abrasion-resistant glaze according to claim 1, wherein the abrasion-resistant glaze comprises the following components in percentage by weight:
13% of frit, 10% of spodumene, 9% of wollastonite, 8% of kaolin, 5% of white corundum, 4% of calcite, 8% of barium carbonate, 10% of glass powder, 13% of functional powder and 20% of potassium feldspar.
3. The abrasive glaze of claim 1 wherein the frit is a high alumina abrasive frit.
4. The wear-resistant glaze according to claim 1, wherein the functional powder is prepared by the following steps:
(1) uniformly mixing graphene, an anionic surfactant, polyvinyl alcohol, a titanate coupling agent, nano titanium dioxide and deionized water to obtain a primary mixed solution for later use;
(2) carrying out water bath heating on the primary mixed liquid obtained in the step (1), and simultaneously carrying out ultrasonic treatment for 1-1.5 h for later use;
(3) mixing the zirconium oxychloride solution and hydrogen peroxide together, uniformly stirring, and standing for 1-2 h to obtain a secondary mixed solution for later use;
(4) and (3) continuously dropwise adding the primary mixed solution treated in the step (2) into the secondary mixed solution obtained in the step (3), uniformly stirring, standing for 45-50 min, then adjusting the pH value of the whole to 6-7, and finally performing centrifugal separation and drying treatment.
5. The wear-resistant glaze material according to claim 4, wherein in the step (1), the graphene, the anionic surfactant, the polyvinyl alcohol, the titanate coupling agent, the nano titanium dioxide and the deionized water are mixed in a weight ratio of 4-5: 3-4: 2-4: 1-2: 0.5-1: 120-150.
6. The wear-resistant glaze material according to claim 4, wherein the temperature of the water bath heating in step (2) is controlled to be 80-85 ℃; and controlling the ultrasonic frequency to be 340-380 kHz during ultrasonic treatment.
7. The wear-resistant glaze material according to claim 4, wherein the volume ratio of the zirconium oxychloride solution and the hydrogen peroxide in the step (3) is 3-4: 1.
8. The wear-resistant glaze according to claim 7, wherein the concentration of said zirconium oxychloride solution is 0.15 to 0.2 mol/L; the mass fraction of the hydrogen peroxide is 30%.
9. The wear-resistant glaze material according to claim 4, wherein the amount of the primary mixed solution added in step (4) is 1-1.2 times of the total mass of the secondary mixed solution.
10. The wear-resistant glaze material as claimed in claim 4, wherein the rotation speed of the centrifugal separation in step (4) is controlled to be 3000-3500 rpm; and the temperature for controlling drying during drying treatment is 100-110 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010584509.0A CN111662012A (en) | 2020-06-24 | 2020-06-24 | Wear-resistant glaze |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010584509.0A CN111662012A (en) | 2020-06-24 | 2020-06-24 | Wear-resistant glaze |
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| CN111662012A true CN111662012A (en) | 2020-09-15 |
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| CN202010584509.0A Withdrawn CN111662012A (en) | 2020-06-24 | 2020-06-24 | Wear-resistant glaze |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112759262A (en) * | 2021-03-05 | 2021-05-07 | 德化县嘉翔工艺品有限公司 | Wear-resistant diamond transparent glaze, wear-resistant diamond transparent glaze ceramic product and preparation method thereof |
| CN112960906A (en) * | 2021-04-13 | 2021-06-15 | 刘永广 | Lead-free environment-friendly ceramic glaze and preparation method thereof |
| CN115159850A (en) * | 2022-08-26 | 2022-10-11 | 佛山市东鹏陶瓷有限公司 | Low-cost wear-resistant glazed brick glaze, preparation method thereof and glazed brick |
-
2020
- 2020-06-24 CN CN202010584509.0A patent/CN111662012A/en not_active Withdrawn
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112759262A (en) * | 2021-03-05 | 2021-05-07 | 德化县嘉翔工艺品有限公司 | Wear-resistant diamond transparent glaze, wear-resistant diamond transparent glaze ceramic product and preparation method thereof |
| CN112960906A (en) * | 2021-04-13 | 2021-06-15 | 刘永广 | Lead-free environment-friendly ceramic glaze and preparation method thereof |
| CN115159850A (en) * | 2022-08-26 | 2022-10-11 | 佛山市东鹏陶瓷有限公司 | Low-cost wear-resistant glazed brick glaze, preparation method thereof and glazed brick |
| CN115159850B (en) * | 2022-08-26 | 2023-08-08 | 佛山市东鹏陶瓷有限公司 | Low-cost wear-resistant glazed brick glaze and preparation method thereof, and glazed brick |
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Application publication date: 20200915 |