CN111560290A - Blocky pipeline dredging agent and preparation method thereof - Google Patents

Blocky pipeline dredging agent and preparation method thereof Download PDF

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Publication number
CN111560290A
CN111560290A CN202010431848.5A CN202010431848A CN111560290A CN 111560290 A CN111560290 A CN 111560290A CN 202010431848 A CN202010431848 A CN 202010431848A CN 111560290 A CN111560290 A CN 111560290A
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Prior art keywords
dredging agent
pipeline
percent
briquetting
pipeline dredging
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Chinese (zh)
Inventor
孟长安
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Jinhua Guangzili Daily Necessities Co ltd
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Jinhua Guangzili Daily Necessities Co ltd
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Priority to CN202010431848.5A priority Critical patent/CN111560290A/en
Publication of CN111560290A publication Critical patent/CN111560290A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/044Hydroxides or bases
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/08Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/10Carbonates ; Bicarbonates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2006Monohydric alcohols
    • C11D3/201Monohydric alcohols linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2003Alcohols; Phenols
    • C11D3/2065Polyhydric alcohols
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2075Carboxylic acids-salts thereof
    • C11D3/2086Hydroxy carboxylic acids-salts thereof
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/34Organic compounds containing sulfur
    • C11D3/349Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/38Products with no well-defined composition, e.g. natural products
    • C11D3/382Vegetable products, e.g. soya meal, wood flour, sawdust
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/40Dyes ; Pigments
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G5/00Cleaning or de-greasing metallic material by other methods; Apparatus for cleaning or de-greasing metallic material with organic solvents
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D2111/00Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
    • C11D2111/10Objects to be cleaned
    • C11D2111/14Hard surfaces

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Emergency Medicine (AREA)
  • Health & Medical Sciences (AREA)
  • Inorganic Chemistry (AREA)
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  • Mechanical Engineering (AREA)
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  • Detergent Compositions (AREA)

Abstract

A blocky pipeline dredging agent and a preparation method thereof aim to solve the problem that the pipeline dredging agent is lost from a gap of a plug. The key points of the technical scheme are as follows: the dredging agent comprises a dredging agent body, and the raw materials and the components of the dredging agent body are as follows by weight percent: 50% -65% of granular sodium hydroxide; baking soda 10% -12%; 10-15% of anhydrous citric acid; 0.2 to 0.5 percent of polyethylene glycol 6000; 2% -5% of sodium carbonate; 2% -4% of a surfactant; 0.5% -1% of glycerin; the components are sucked into a briquetting machine for briquetting through a vacuum suction machine after being mixed, so that the dredging agent body is blocky. The invention can block the gap of the pipeline in a semi-blocking state, prevent the pipeline dredging agent body from losing from the gap, avoid the waste of the pipeline dredging agent body, simultaneously prolong the reaction time of the pipeline dredging agent body, fully dissolve the pipeline dredging agent body, disperse the blocking object through the actions of decomposition, foaming, swelling and the like, and dredge the pipeline.

Description

Blocky pipeline dredging agent and preparation method thereof
Technical Field
The invention relates to the technical field of preparation of pipeline dredging products, in particular to a blocky pipeline dredging agent and a preparation method thereof.
Background
The pipeline dredging agent is a novel kitchen and toilet pipeline dredging product, and is mainly used for dredging blockage caused by various organic substances such as grease, hair, vegetable residue, paper cotton fiber and the like in a kitchen and toilet pipeline. Meanwhile, the adhesive can effectively eradicate attachments accumulated in the pipeline all the year round, in particular to some germs, cockroaches, winged insects and the like in the pipeline. The main components of the pipeline dredging agent are sodium hydroxide, sodium carbonate, calcium hypochlorite and foaming agent, and the main shapes of the pipeline dredging agent are granules, powder, liquid and the like. And in daily life, people often find that the pipeline has appeared and has blockked up the situation when the pipeline forms the state of partly blockking up (being jagged on the plug, water still can slowly run off from the breach), under the state of partly blockking up of pipeline, add the pipeline dredging agent of granule, powder, and liquid, this body of pipeline dredging agent can run off from the breach, the waste of pipeline dredging agent body has been caused, simultaneously, along with the loss of pipeline dredging agent, the reaction time who leaves for pipeline dredging agent also becomes very short, make partly pipeline dredging agent body can not abundant dissolve. Therefore, there is a need for improvements in the dosage forms and shapes of prior art channel openers.
Disclosure of Invention
In view of the defects of the prior art, the invention aims to provide a block-shaped pipeline dredging agent.
The invention also aims to provide a preparation method of the blocky pipeline dredging agent.
The technical scheme adopted by the invention for solving the technical problems is as follows:
the bulk pipeline dredging agent comprises a dredging agent body, wherein the dredging agent body comprises the following raw materials in percentage by weight:
50 to 65 percent of granular sodium hydroxide
10 to 12 percent of baking soda
10 to 15 percent of anhydrous citric acid
Polyethylene glycol 60000.2% -0.5%
2 to 5 percent of sodium carbonate
2 to 4 percent of surfactant
0.5 to 1 percent of glycerin
The sum of the weight percentages of the components is 100 percent.
Preferably, the surfactant is a powdered sodium alpha-alkenyl sulfonate.
Preferably, the dredging agent body also comprises anhydrous sodium silicate, and the weight percentage of the anhydrous sodium silicate is 2-4%.
Preferably, the dredging agent body also comprises an inorganic pigment and absolute ethyl alcohol, wherein the weight percentage of the inorganic pigment is 0.1-0.2%, and the weight percentage of the absolute ethyl alcohol is 0.05-0.1%.
Preferably, the inorganic pigment is weakly acidic brilliant blue BA.
Preferably, the dredging agent body also comprises plant essence which accounts for 0.02-0.0.08% by weight.
Preferably, the plant essence is one of honeysuckle, sophora flower and lavender extracts, or any of the extracts are compounded.
A preparation method of a blocky pipeline dredging agent comprises the following steps:
a. dissolving inorganic pigment in absolute ethyl alcohol to obtain solution A for later use;
b. b, putting the baking soda and the sodium carbonate into a vacuum stirrer, spraying the solution A obtained in the step a, stirring and mixing, and uniformly stirring to obtain a material B for later use;
c. grinding polyethylene glycol 6000 in a grinder to about 200 meshes to obtain polyethylene glycol 6000 powder;
d. adding plant essence, polyethylene glycol 6000 powder, granular sodium hydroxide, anhydrous citric acid, anhydrous sodium silicate, powdery alpha-alkenyl sodium sulfonate and inorganic pigment into the material B obtained in the step B, spraying glycerol in a spray form, stirring by using a vacuum stirrer, and uniformly stirring to obtain a material C;
e. and d, sucking the material C obtained in the step d into a briquetting machine through a vacuum suction machine for briquetting, and putting the material C into a vacuum packaging machine for packaging after the briquetting is finished.
Preferably, in the briquetting process of the step e, a powder spraying machine is used for spraying magnesium stearate to the upper punch and the lower punch of the briquetting machine.
The dredging agent body has the following functions of the components: the granular sodium hydroxide is used for playing a role in corrosion and ensuring the dredging effect of the dredging agent body; the baking soda, the anhydrous citric acid and the soda ash are used for achieving an effervescent disintegration effect and ensuring that the dredging agent body can be quickly dissolved; the polyethylene glycol 6000 is used for bonding the components together; the inorganic pigment and the absolute ethyl alcohol are used for playing a role in beauty, and on the other hand, when the dredging agent body is dissolved, the dissolution degree of the dredging agent body can be judged according to the dispersion degree of the inorganic pigment; the anhydrous sodium silicate is used for protecting the metal pipeline and preventing the metal pipeline from being damaged; the surfactant is used for playing a role of oil dissolving and oil dirt dissolving; the glycerin and magnesium stearate are used to release the mold and prevent the powder from sticking to the punch of the briquetting machine.
The invention has the beneficial effects that: the process flow is simple, the raw material proportion is reasonable, and compared with the traditional pipeline dredging agent, the pipeline dredging agent can block the gap in a semi-blocking state of the pipeline, prevent the pipeline dredging agent body from losing from the gap, avoid the waste of the pipeline dredging agent body, simultaneously prolong the reaction time of the pipeline dredging agent body, fully dissolve the pipeline dredging agent body, disperse the blockage through the effects of decomposition, foaming, swelling and the like, and dredge the pipeline.
Detailed Description
The technical solution of the present invention will be further specifically described below by way of specific examples. It is to be understood that the practice of the invention is not limited to the following examples, and that any variations and/or modifications may be made thereto without departing from the scope of the invention.
In the present invention, all parts and percentages are by weight, unless otherwise specified, and the equipment and materials used are commercially available or commonly used in the art. The methods in the following examples are conventional in the art unless otherwise specified.
Examples 1 to 3:
dissolving inorganic pigment in absolute ethyl alcohol to obtain solution A for later use; placing the baking soda and the sodium carbonate into a vacuum stirrer, spraying the solution A, stirring and mixing, and uniformly stirring to obtain a material B for later use; grinding polyethylene glycol 6000 in a grinder to about 200 meshes to obtain polyethylene glycol 6000 powder; adding plant essence, polyethylene glycol 6000 powder, granular sodium hydroxide, anhydrous citric acid, anhydrous sodium silicate, powdery alpha-alkenyl sodium sulfonate and inorganic pigment into the material B, spraying glycerol in a spraying mode, stirring uniformly by a vacuum stirrer to obtain a material C, sucking the material C into a briquetting machine by a vacuum suction machine for briquetting, spraying magnesium stearate to upper and lower punches of the briquetting machine by a powder spraying machine in the briquetting process, and putting the briquetted material into a vacuum packaging machine for packaging after the briquetting is finished. The properties of the obtained opener body are shown in table 2.
TABLE 1 Components and proportions of the Dredging agent body (unit: kg)
Examples 1 2 3
Granular sodium hydroxide 65 65 59
Baking soda 10 12 12
Anhydrous citric acid 11 15 15
Soda ash 5 2 5
Polyethylene glycol 6000 0.5 0.5 0.5
α sodium alkenyl sulfonate 4 2 4
Glycerol 1 1 1
Anhydrous sodium silicate 3.2 2.2 3.2
Inorganic pigments 0.15 0.15 0.15
Anhydrous ethanol 0.1 0.1 0.1
Plant essence 0.05 0.05 0.05
Total up to 100 100 100
TABLE 2 comparison of Performance
Examples 1 2 3
Required time (min) for pipeline smoothness 25 25 27
Dissolving time (min) of dredging agent 15 17 10
Experimental methods
The test base material selected by the experimental method is a No. 45 steel pipe. The plug is a mixture of hair and grease in the sewer line of the kitchen.
Putting a mixture of equivalent hair and grease of a kitchen sewer pipeline into three identical No. 45 steel pipes, blocking the No. 45 steel pipes, reserving gaps, respectively pouring equivalent dredging agent bodies prepared in the embodiment 1, the embodiment 2 and the embodiment 3, pouring equivalent water, visually observing the color change of the water, judging the reaction time of the dredging agent bodies, and simultaneously recording the time required by pipeline smoothness by a timer.
And (4) conclusion: the pipeline dredging agent has better comprehensive performance, can block a gap in a semi-blocked state of a pipeline, prevents the pipeline dredging agent body from losing from the gap, avoids the waste of the pipeline dredging agent body, prolongs the reaction time of the pipeline dredging agent body, enables the pipeline dredging agent body to be fully dissolved, and disperses a blocking object through the effects of decomposition, foaming, swelling and the like, thereby dredging the pipeline. Meanwhile, from the difference in the results of the examples in table 2, the ratio of the granular sodium hydroxide affects the time required for the pipeline to be unblocked, but the difference between the values in the range of the present invention is small, and the appropriate value can be selected in the range of the present invention in consideration of the corrosivity of the granular sodium hydroxide. The baking soda, the anhydrous citric acid and the soda ash have little influence on the dissolution time of the dredging agent.
It should be noted that the above embodiments are only for further illustration and understanding of the technical solutions of the present invention, and should not be understood as further limitations of the technical solutions of the present invention, and the invention with non-prominent essential features and significant advances made by those skilled in the art still belongs to the protection scope of the present invention.

Claims (9)

1. The bulk pipeline dredging agent comprises a dredging agent body, and is characterized in that the dredging agent body comprises the following raw materials in percentage by weight:
50 to 65 percent of granular sodium hydroxide
10 to 12 percent of baking soda
10 to 15 percent of anhydrous citric acid
Polyethylene glycol 60000.2% -0.5%
2 to 5 percent of sodium carbonate
2 to 4 percent of surfactant
0.5 to 1 percent of glycerin
The sum of the weight percentages of the components is 100 percent.
2. The bulk pipe opener of claim 1, wherein the surfactant is sodium alpha-olefin sulfonate in powder form.
3. The bulk pipe opener according to claim 1, wherein the raw material of the opener body further comprises anhydrous sodium silicate, and the weight percentage of the anhydrous sodium silicate is 2-4%.
4. The bulk pipe opener according to claim 1, wherein the raw materials of the opener body further comprise an inorganic pigment and absolute ethyl alcohol, the weight percentage of the inorganic pigment is 0.1-0.2%, and the weight percentage of the absolute ethyl alcohol is 0.05-0.1%.
5. The block pipeline opener according to claim 4, wherein the inorganic pigment is weakly acidic brilliant blue BA.
6. The bulk pipe opener according to claim 1, wherein the raw material of the opener body further comprises plant essence, and the weight percentage of the plant essence is 0.02-0.0.08%.
7. The blocky pipeline dredging agent as claimed in claim 6, wherein the plant essence is one or any combination of extracts of honeysuckle, sophora flower and lavender.
8. A preparation method of a blocky pipeline dredging agent is characterized by comprising the following steps:
a. dissolving inorganic pigment in absolute ethyl alcohol to obtain solution A for later use;
b. b, putting the baking soda and the sodium carbonate into a vacuum stirrer, spraying the solution A obtained in the step a, stirring and mixing, and uniformly stirring to obtain a material B for later use;
c. grinding polyethylene glycol 6000 in a grinder to about 200 meshes to obtain polyethylene glycol 6000 powder;
d. adding plant essence, polyethylene glycol 6000 powder, granular sodium hydroxide, anhydrous citric acid, anhydrous sodium silicate, powdery alpha-alkenyl sodium sulfonate and inorganic pigment into the material B obtained in the step B, spraying glycerol in a spray form, stirring by using a vacuum stirrer, and uniformly stirring to obtain a material C;
e. and d, sucking the material C obtained in the step d into a briquetting machine through a vacuum suction machine for briquetting, and putting the material C into a vacuum packaging machine for packaging after the briquetting is finished.
9. The method according to claim 8, wherein magnesium stearate is sprayed onto the upper and lower punches of the briquetting machine during the briquetting process in step e by using a powder spraying machine.
CN202010431848.5A 2020-05-20 2020-05-20 Blocky pipeline dredging agent and preparation method thereof Pending CN111560290A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113026901A (en) * 2021-03-04 2021-06-25 殷永乾 Environment-friendly sewage pipeline beneficial to sufficient sewage purification treatment
CN113430058A (en) * 2021-07-07 2021-09-24 珠海市合顺兴日化股份有限公司 Effervescent tablet for clearing pipeline blockage, preparation method and application

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1488781A (en) * 2002-10-10 2004-04-14 汪立强 Solid chemical dredging agent for pipeline dredging and preparing method thereof
CN106635438A (en) * 2016-09-22 2017-05-10 长兴净安环保科技有限公司 Powdered pipeline dredge agent and preparation method thereof
CN109609291A (en) * 2018-12-28 2019-04-12 北京绿伞化学股份有限公司 A kind of pipeline bad smell removal detergent effervescent tablet and preparation method thereof

Patent Citations (3)

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Publication number Priority date Publication date Assignee Title
CN1488781A (en) * 2002-10-10 2004-04-14 汪立强 Solid chemical dredging agent for pipeline dredging and preparing method thereof
CN106635438A (en) * 2016-09-22 2017-05-10 长兴净安环保科技有限公司 Powdered pipeline dredge agent and preparation method thereof
CN109609291A (en) * 2018-12-28 2019-04-12 北京绿伞化学股份有限公司 A kind of pipeline bad smell removal detergent effervescent tablet and preparation method thereof

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Title
杜志明 主编: "《日用化学产品达标生产及质量检测分析标准实用手册 第1册》", 31 March 2003, 吉林摄影出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113026901A (en) * 2021-03-04 2021-06-25 殷永乾 Environment-friendly sewage pipeline beneficial to sufficient sewage purification treatment
CN113430058A (en) * 2021-07-07 2021-09-24 珠海市合顺兴日化股份有限公司 Effervescent tablet for clearing pipeline blockage, preparation method and application

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Application publication date: 20200821