CN102899197A - Toilet cleaning spindle and manufacturing method thereof - Google Patents
Toilet cleaning spindle and manufacturing method thereof Download PDFInfo
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- CN102899197A CN102899197A CN2012103901462A CN201210390146A CN102899197A CN 102899197 A CN102899197 A CN 102899197A CN 2012103901462 A CN2012103901462 A CN 2012103901462A CN 201210390146 A CN201210390146 A CN 201210390146A CN 102899197 A CN102899197 A CN 102899197A
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Abstract
The invention discloses a toilet cleaning spindle and a manufacturing method thereof. The toilet cleaning spindle is suitable for cleaning flush toilets to remove odor. The product is prepared by mixing dichloro-5,5-dimethylhydantoin, bromo-3-chloro-5,5-dimethylhydantoin, 5,5-dimethylhydantoin and absolute citric acid according to a mass percentage. The manufacturing method comprises the following steps of: drying the components respectively, weighting, mixing, granulating, tabletting or blocking and packaging. The toilet cleaning spindle manufactured by the method, with a sustained release effect, can be directly put into a water tank to inhibit bacteria constantly, thereby effectively removing urea stains, water stains and iron rust on the glazed surface of the toilet, eliminating odor, and keeping the toilet clean and smooth. The toilet cleaning spindle has the characteristics of quick sterilization effect, safety, stability, high efficiency, no toxic effect, no pollution, no toxic and side effect in use, and the like. The toilet cleaning spindle and the manufacturing method have the characteristics of low production cost, simplicity in operation of equipment, and no discharge of waste gas, waste water and waste residue. The toilet cleaning spindle and the manufacturing method are suitable for industrial production.
Description
Technical field the present invention relates to a kind of toilet seat cleaning ingot and preparation method thereof, and toilet scale removal cleaning, disinfecting, deodorizing are applicable to draw water.
Background technology
Along with the raising of people's living standard and the improvement of living conditions, the cleaning of toilet and everyone physical and mental health relation are very big, and cleaning agent has become the daily necessities that people are familiar with.Be mainly used in cleaning and the taste removal of metope, floor ceramic tile and glaze porcelain sanitary equipment.The cleaning agent of toilet of being used for drawing water has two kinds of liquid and solids, according to chemical composition can be divided into neutrality, acidity and alkaline three types, acid cleaning agent main component is mineral acid and tensio-active agent, alkalescence cleaning agent hypochlorous sodium and tensio-active agent are formulated, acid and alkaline cleaning agent all has sad and shrill irritating smell, and corrodibility is large, and life-time service can corrode porcelain facing, if in use shed because of carelessness on clothing or skin, can cause damage to clothing and skin.Neutral cleaning agent just grew up in recent years, and two kinds of solid and liquid are arranged, solid toilet cleaning agent wherein, and such as blue bubble cleaning toilet treasured, toilet cleaning block and cleaning toilet powder etc., it is quite convenient to use.The adding mode slowly discharges by developing into the present water tank of directly putting into the brush cleaning in the adding pond.But the sapphire blue bubble of solid toilet cleaning is made raw material: include biphenyl, Biphenyl Ether, nonyl phenol, sodium stearate, Sodium dodecylbenzene sulfonate, polyvinyl alcohol, fatty alcohol-polyoxyethylene ether, paraffin, cetyl trimethylammonium bromide, pigment one-tenth wherein and grade; more than directly emitted after these substance dissolves; can pollute underground water, soil and atmosphere for a long time; destroy ecotope, the crisis human survival.Therefore research and development have safety, environmental protection, easy to use, sheet or block cleaning agent toilet seat cleaning ingot, are necessary.
Summary of the invention the object of the present invention is to provide a kind of safety, environmental protection, sheet or block toilet seat cleaning ingot cleaning agent easy to use, put and have slow releasing function in the water tank, can remove urine dirt, incrustation scale, iron rust and the deodorizing that carries out disinfection on the toilet vitreous enamel surface of drawing water.
Purpose of the present invention is achieved through the following technical solutions.
A kind of toilet seat cleaning ingot is to be formed by by mass percentage mixing granulation, the compacting of following component:
The mass percent sum of each component is 100%,
Toilet seat cleaning ingot making method:
At first with above-mentioned two chlordantoin powder, bromochlorohydantoin powder, 5,5-dimethyl hydantion and Citric Acid, usp, Anhydrous Powder are dried respectively, and moisture requirement is below 0.3%; Then by each constituent mass per-cent weighing, add mixing and stirring in the mixing machine, churning time is controlled at 30-50 minute; With the material after mixing, make 8-35 purpose particle through tablets press; Again particle is packed in flakes or after block with the tabletting machine compacting.
Described toilet seat cleaning ingot is to be formed by by mass percentage mixing granulation, the compacting of following component:
The mass percent sum of each component is 100%.
Toilet seat cleaning ingot preparation mechanism of the present invention: two chlordantoins and bromochlorohydantoin slowly are decomposed into hypochlorous acid and hypobromous acid in water, with the urine dirt, incrustation scale and the iron rust effect that stick to the toilet porcelain surface of drawing water, reach the purpose of scale removal, sterilization and deodorizing.Add 5, the 5-dimethyl hydantion is as the stablizer of chlorine and bromine, prolonged the time of chlorine residue and remaining bromine effect in the water, can increase scale removal, sterilization and deodorizing effect.Can further impel two chlordantoins and bromochlorohydantoin to decomposite the speed of hypochlorous acid and hypobromous acid after the Citric Acid, usp, Anhydrous Powder suction of adding, make the pH value of water in the toilet remain on 3.5-5, be in the Descaled bactericidal state always, keep clean, smooth, non-scaling.
Advantage of the present invention and existing toilet seat cleaning agent comprise acid and the alkaline liquid product, and the product of powdery and the present blue bubble that is using etc. is compared, and are a kind of safety and environmental protection, sheet or block cleaning agent easy to use.It can directly be put into water tank and slow releasing function is arranged, and is in the Descaled bactericidal state always, effectively removes toilet glaze urine dirt, incrustation scale, iron rust and disinfecting, deodorizing.Have sterilization effect fast, stable, efficient, environmental protection, the characteristics such as toxicity is low, environmental pollution is little, have no side effect in the use procedure.The production process cost is low, and apparatus and process is simple to operate, discharges without " three wastes ", can realize industrial scale production, and significant economic benefit is arranged.
After mixing, the by mass percentage weighing of each component of embodiment carries out granulation and compressing tablet or piece:
Embodiment 1
Moisture content index reaches below 0.3% after taking by weighing respectively drying: 5 of the two chlordantoin powder of 58kg, the bromochlorohydantoin powder of 35kg, 3.5kg, the Citric Acid, usp, Anhydrous Powder of 5-dimethyl hydantion, 3.5kg adds in the mixing machine, mix and blend 30-35 minute, make powder mix.
Weighing 400kg powder mix makes 373kg composite grain (remaining powder-material 27kg can be recycled), granularity 8-35 order with the dry roller pressing type prilling machine granulation.
Weighing 400kg composite grain is poured the tabletting machine feed bin into and is carried out compressing tablet, makes the toilet seat cleaning ingot of sheet 394.8kg (waste product sheet 5.2kg, after crushed granulation also can be used for compressing tablet), then is distributed into bag.Yield rate 98.7%, cl content is 25.53% in the product, bromine content is 11.41%.
Embodiment 2
Moisture content index reaches below 0.3% after taking by weighing respectively drying: 5 of the two chlordantoin powder of 62kg, the bromochlorohydantoin powder of 31kg, 3.5kg, the Citric Acid, usp, Anhydrous Powder of 5-dimethyl hydantion, 3.5kg adds in the mixing machine, mix and blend 40-45 minute, make powder mix.
Weighing 400kg powder mix makes 370.5kg composite grain (remaining powder-material 29.5kg can be recycled), granularity 8-35 order with the dry roller pressing type prilling machine granulation.
Weighing 400kg composite grain is poured the tabletting machine feed bin into and is carried out compressing tablet, makes the toilet seat cleaning ingot of sheet 394.2kg (waste product sheet 5.8kg, after crushed granulation also can be used for compressing tablet), then is distributed into bag.Yield rate 98.55%, cl content is 26.27% in the product, bromine content is 10.09%.
Embodiment 3
Moisture content index reaches below 0.3% after taking by weighing respectively drying: 5 of the two chlordantoin powder of 60kg, the bromochlorohydantoin powder of 33kg, 3kg, the Citric Acid, usp, Anhydrous Powder of 5-dimethyl hydantion, 4kg adds in the mixing machine, mix and blend 35-40 minute, makes powder mix.
Weighing 400kg powder mix makes 374.5kg composite grain (remaining powder-material 25.5kg can be recycled), granularity 8-35 order with the dry roller pressing type prilling machine granulation.
Weighing 400kg composite grain is poured the tabletting machine feed bin into and is carried out compressing tablet, makes the toilet seat cleaning ingot of sheet 395.2kg (waste product sheet 4.8kg, after crushed granulation also can be used for compressing tablet), then is distributed into bag., yield rate 98.8%, cl content is 31.84% in the product, bromine content is 10.75%.
Claims (2)
1. toilet seat cleaning ingot is characterized in that being formed by by mass percentage mixing granulation, the compacting of following component:
The mass percent sum of each component is 100%,
Toilet seat cleaning ingot making method:
At first with above-mentioned two chlordantoin powder, bromochlorohydantoin powder, 5,5-dimethyl hydantion and Citric Acid, usp, Anhydrous Powder are dried respectively, and moisture requirement is below 0.3%; Then by each constituent mass per-cent weighing, add mixing and stirring in the mixing machine, churning time is controlled at 30-50 minute; With the material after mixing, make 8-35 purpose particle through tablets press; Again particle is packed in flakes or behind the piece with the tabletting machine compacting.
2. toilet seat cleaning ingot according to claim 1 is characterized in that being formed by by mass percentage mixing granulation, the compacting of following component:
The mass percent sum of each component is 100%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210390146.2A CN102899197B (en) | 2012-10-12 | 2012-10-12 | Toilet cleaning spindle and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210390146.2A CN102899197B (en) | 2012-10-12 | 2012-10-12 | Toilet cleaning spindle and manufacturing method thereof |
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| Publication Number | Publication Date |
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| CN102899197A true CN102899197A (en) | 2013-01-30 |
| CN102899197B CN102899197B (en) | 2014-06-25 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210390146.2A Active CN102899197B (en) | 2012-10-12 | 2012-10-12 | Toilet cleaning spindle and manufacturing method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150345123A1 (en) | 2014-05-27 | 2015-12-03 | As Ip Holdco, Llc | Sanitaryware cleaning system |
| US10465366B2 (en) | 2014-05-27 | 2019-11-05 | As America, Inc. | Sanitaryware cleaning system |
| USD914838S1 (en) | 2015-05-27 | 2021-03-30 | AS America Inc. | Cartridge |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1200354A (en) * | 1997-05-27 | 1998-12-02 | 克罗洛斯公司 | Solid, water-degradable disinfectant and cleanser composition, and associated methods of manufacture and use |
| CN102657173A (en) * | 2012-05-16 | 2012-09-12 | 河北亚光精细化工有限公司 | 1-bromo-3-chloro-5, 5-dimethyl hydantoin and 1, 3-dichloro-5, 5-dimethyl hydantoin compound disinfection tablet and method for preparing same |
-
2012
- 2012-10-12 CN CN201210390146.2A patent/CN102899197B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1200354A (en) * | 1997-05-27 | 1998-12-02 | 克罗洛斯公司 | Solid, water-degradable disinfectant and cleanser composition, and associated methods of manufacture and use |
| CN102657173A (en) * | 2012-05-16 | 2012-09-12 | 河北亚光精细化工有限公司 | 1-bromo-3-chloro-5, 5-dimethyl hydantoin and 1, 3-dichloro-5, 5-dimethyl hydantoin compound disinfection tablet and method for preparing same |
Non-Patent Citations (1)
| Title |
|---|
| 王永生: "蛤蟆油药效成分及其质量控制方法的研究", 《中国博士学位论文全文数据库（电子期刊）》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20150345123A1 (en) | 2014-05-27 | 2015-12-03 | As Ip Holdco, Llc | Sanitaryware cleaning system |
| US10465366B2 (en) | 2014-05-27 | 2019-11-05 | As America, Inc. | Sanitaryware cleaning system |
| USD914838S1 (en) | 2015-05-27 | 2021-03-30 | AS America Inc. | Cartridge |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102899197B (en) | 2014-06-25 |
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Owner name: HEBEI XINTAOYUAN ENVIRONMENTAL PROTECTION TECHNOLO Free format text: FORMER OWNER: HEBEI YAGUANG FINE CHEMICAL CO., LTD. Effective date: 20131015 |
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Effective date of registration: 20131015 Address after: North of Quzhou County Hebei province 057250 Handan modern new industrial park Applicant after: Hebei Xintaoyuan Environment Protection Technology Co., Ltd. Address before: 057250 Hebei city of Handan province in Quzhou County in Quzhou City north of Wei Luxi Applicant before: Hebei Yaguang Fine Chemical Co., Ltd. |
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Address after: 057250 North District of Quzhou Modern New Industrial Park, Handan City, Hebei Province Patentee after: Hebei xintaoyuan Pharmaceutical Technology Co.,Ltd. Address before: 057250 North District of Quzhou Modern New Industrial Park, Handan City, Hebei Province Patentee before: HEBEI XINTAOYUAN ENVIRONMENT PROTECTION TECHNOLOGY Co.,Ltd. |