ITMI20070642A1 - SANITIZING ADHESIVE COMPOSITION FOR THE CLEANING AND / OR DISINFECTION AND SANITARY SCENTING - Google Patents
SANITIZING ADHESIVE COMPOSITION FOR THE CLEANING AND / OR DISINFECTION AND SANITARY SCENTING Download PDFInfo
- Publication number
- ITMI20070642A1 ITMI20070642A1 IT000642A ITMI20070642A ITMI20070642A1 IT MI20070642 A1 ITMI20070642 A1 IT MI20070642A1 IT 000642 A IT000642 A IT 000642A IT MI20070642 A ITMI20070642 A IT MI20070642A IT MI20070642 A1 ITMI20070642 A1 IT MI20070642A1
- Authority
- IT
- Italy
- Prior art keywords
- composition
- weight
- respect
- composition according
- total weight
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 153
- 238000011012 sanitization Methods 0.000 title claims description 46
- 238000004140 cleaning Methods 0.000 title claims description 32
- 239000000853 adhesive Substances 0.000 title claims description 29
- 230000001070 adhesive effect Effects 0.000 title claims description 29
- 238000004659 sterilization and disinfection Methods 0.000 title claims description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 26
- 150000001298 alcohols Chemical class 0.000 claims description 17
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 17
- -1 diurethanes Polymers 0.000 claims description 15
- 244000005700 microbiome Species 0.000 claims description 14
- 239000002304 perfume Substances 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 14
- 235000011187 glycerol Nutrition 0.000 claims description 13
- 150000001875 compounds Chemical class 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 11
- 239000011734 sodium Substances 0.000 claims description 11
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 241000193830 Bacillus <bacterium> Species 0.000 claims description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims description 8
- 239000002318 adhesion promoter Substances 0.000 claims description 8
- 239000003945 anionic surfactant Substances 0.000 claims description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims description 8
- 239000004094 surface-active agent Substances 0.000 claims description 8
- 239000002280 amphoteric surfactant Substances 0.000 claims description 7
- 239000000975 dye Substances 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 241000194108 Bacillus licheniformis Species 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- JZKFHQMONDVVNF-UHFFFAOYSA-N dodecyl sulfate;tris(2-hydroxyethyl)azanium Chemical compound OCCN(CCO)CCO.CCCCCCCCCCCCOS(O)(=O)=O JZKFHQMONDVVNF-UHFFFAOYSA-N 0.000 claims description 6
- 230000000694 effects Effects 0.000 claims description 6
- 108010010803 Gelatin Proteins 0.000 claims description 5
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 5
- 235000010443 alginic acid Nutrition 0.000 claims description 5
- 229920000615 alginic acid Polymers 0.000 claims description 5
- 125000000129 anionic group Chemical group 0.000 claims description 5
- 239000003124 biologic agent Substances 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 5
- 239000001913 cellulose Substances 0.000 claims description 5
- 239000000645 desinfectant Substances 0.000 claims description 5
- 230000000249 desinfective effect Effects 0.000 claims description 5
- 239000004088 foaming agent Substances 0.000 claims description 5
- 229920000159 gelatin Polymers 0.000 claims description 5
- 235000019322 gelatine Nutrition 0.000 claims description 5
- 235000011852 gelatine desserts Nutrition 0.000 claims description 5
- 150000004676 glycans Chemical class 0.000 claims description 5
- 229920003063 hydroxymethyl cellulose Polymers 0.000 claims description 5
- 229940031574 hydroxymethyl cellulose Drugs 0.000 claims description 5
- 239000001814 pectin Substances 0.000 claims description 5
- 235000010987 pectin Nutrition 0.000 claims description 5
- 229920001277 pectin Polymers 0.000 claims description 5
- 229920000058 polyacrylate Polymers 0.000 claims description 5
- 229920001282 polysaccharide Polymers 0.000 claims description 5
- 239000005017 polysaccharide Substances 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 5
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 5
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 5
- 239000002562 thickening agent Substances 0.000 claims description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- OWBTYPJTUOEWEK-UHFFFAOYSA-N butane-2,3-diol Chemical compound CC(O)C(C)O OWBTYPJTUOEWEK-UHFFFAOYSA-N 0.000 claims description 4
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 3
- 230000008018 melting Effects 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims description 3
- 239000002736 nonionic surfactant Substances 0.000 claims description 3
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 claims description 3
- 239000007787 solid Substances 0.000 claims description 3
- 239000004711 α-olefin Substances 0.000 claims description 3
- BTVWZWFKMIUSGS-UHFFFAOYSA-N 2-methylpropane-1,2-diol Chemical compound CC(C)(O)CO BTVWZWFKMIUSGS-UHFFFAOYSA-N 0.000 claims description 2
- 244000063299 Bacillus subtilis Species 0.000 claims description 2
- 235000014469 Bacillus subtilis Nutrition 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 241000193386 Lysinibacillus sphaericus Species 0.000 claims description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 125000002947 alkylene group Chemical group 0.000 claims description 2
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 claims description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 235000011837 pasties Nutrition 0.000 claims description 2
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 2
- 238000007711 solidification Methods 0.000 claims description 2
- 230000008023 solidification Effects 0.000 claims description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 claims description 2
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 claims 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical class [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims 1
- 229910001950 potassium oxide Inorganic materials 0.000 claims 1
- 238000005406 washing Methods 0.000 description 3
- 239000002351 wastewater Substances 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical group OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- ANBFRLKBEIFNQU-UHFFFAOYSA-M potassium;octadecanoate Chemical compound [K+].CCCCCCCCCCCCCCCCCC([O-])=O ANBFRLKBEIFNQU-UHFFFAOYSA-M 0.000 description 2
- 229940083575 sodium dodecyl sulfate Drugs 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- 108010059892 Cellulase Proteins 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 240000004808 Saccharomyces cerevisiae Species 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 108010046334 Urease Proteins 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229940106157 cellulase Drugs 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 150000002433 hydrophilic molecules Chemical class 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229940060367 inert ingredients Drugs 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000010002 mechanical finishing Methods 0.000 description 1
- 235000019645 odor Nutrition 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000000546 pharmaceutical excipient Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229940093429 polyethylene glycol 6000 Drugs 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229940114930 potassium stearate Drugs 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- 229910000280 sodium bentonite Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0056—Lavatory cleansing blocks
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/40—Monoamines or polyamines; Salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/75—Amino oxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
- C11D1/8355—Mixtures of non-ionic with cationic compounds containing a combination of non-ionic compounds differently alcoxylised or with different alkylated chains
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
- C11D3/323—Amides; Substituted amides urea or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3753—Polyvinylalcohol; Ethers or esters thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3776—Heterocyclic compounds, e.g. lactam
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/382—Vegetable products, e.g. soya meal, wood flour, sawdust
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/384—Animal products
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Zoology (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Detergent Compositions (AREA)
Description
DESCRIZIONE DESCRIPTION
La presente invenzione riguarda una composizione adesiva igienizzante per la pulizia e/o la disinfezione e/o la profumazione di sanitari. The present invention relates to a sanitizing adhesive composition for cleaning and / or disinfecting and / or perfuming sanitary ware.
La presente invenzione si inserisce nel settore tecnico dei prodotti per la pulizia e/o per la disinfezione e/o per la profumazione di sanitari, quali WC, bidet, pissoir e lavabi, in particolare, di prodotti o composizioni igieniche direttamente applicate al sanitario, a cui aderiscono cioè senza l'ausilio di sostegni e/o contenitori, e che agiscono mediante dilavamento con acqua per effetto delle operazioni di scarico. The present invention is part of the technical sector of products for cleaning and / or disinfection and / or for the perfume of sanitary ware, such as toilets, bidets, pissoir and washbasins, in particular, of hygienic products or compositions directly applied to sanitary ware, that is, to which they adhere without the aid of supports and / or containers, and which act by washing with water as a result of the unloading operations.
I tradizionali prodotti utilizzati per la pulizia e/o per la disinfezione e/o per la profumazione di sanitari (nel seguito, "prodotti igienizzanti"), sono generalmente costituiti da composizioni chimiche (nel seguito, "composizioni igienizzanti") contenute all'interno di "gabbiette" munite di appositi sostegni che ne rendono possibile l'applicazione al bordo del sanitario. L'azione pulente è esplicata per dilavamento della composizione igienizzante, cioè per effetto del trascinamento della composizione igienizzante da parte dell'acqua che investe la composizione ed il suo contenitore ogni volta che viene attivato il flusso d'acqua durante l'operazione di scarico. The traditional products used for cleaning and / or disinfection and / or fragrance of sanitary ware (hereinafter, "sanitizing products"), generally consist of chemical compositions (hereinafter, "sanitizing compositions") contained within of "cages" equipped with special supports that make it possible to apply them to the edge of the sanitary ware. The cleaning action is carried out by washing away the sanitizing composition, ie by the effect of the dragging of the sanitizing composition by the water which invests the composition and its container every time the water flow is activated during the unloading operation.
Questi prodotti igienizzanti presentano, però, una scarsa praticità e igienicità per l'utilizzatore sia nel momento della loro sostituzione sia in occasione della pulizia manuale del sanitario. However, these sanitizing products are not practical and hygienic for the user both when replacing them and when manually cleaning the sanitary ware.
Per ovviare a questi inconvenienti sono stati sviluppati più recentemente prodotti igienizzanti in forma solida o pastosa applicabili direttamente ai sanitari, a cui aderiscono senza l'ausilio di alcun contenitore e/o sostegno. Anche in questo caso l'azione pulente è esplicata attraverso il dilavamento della composizione da parte del flusso d'acqua di scarico ed il prodotto è dilavato completamente solo dopo un certo numero di operazioni di scarico. To overcome these drawbacks, sanitizing products in solid or pasty form have been developed more recently, which can be applied directly to sanitary ware, to which they adhere without the aid of any container and / or support. Also in this case the cleaning action is carried out through the washing away of the composition by the waste water flow and the product is completely washed only after a certain number of unloading operations.
Le suddette composizioni igienizzanti comprendono generalmente acqua, tensioattivi, promotori di adesione, profumi ed eventualmente altri additivi . The above sanitizing compositions generally comprise water, surfactants, adhesion promoters, perfumes and possibly other additives.
Esempi di prodotti igienizzanti applicabili direttamente al sanitario senza l'ausilio di alcun sostegno e/o contenitore si possono trovare in EP 1086199 e EP1325103. Essi descrivono prodotti igienizzanti caratterizzati da un contenuto d'acqua variabile tra il 20% e il 70% in peso del prodotto. Secondo tali documenti l'acqua è un componente indispensabile per ottenere l'adesione del prodotto igienizzante al sanitario cui è applicata. Examples of sanitizing products that can be applied directly to sanitary ware without the aid of any support and / or container can be found in EP 1086199 and EP1325103. They describe sanitizing products characterized by a water content varying between 20% and 70% by weight of the product. According to these documents, water is an indispensable component for obtaining the adhesion of the sanitizing product to the sanitary ware to which it is applied.
L'impiego dei prodotti igienizzanti applicabili direttamente ai sanitari attualmente reperibili in commercio presenta, però, alcuni inconvenienti. In primo luogo, il prodotto applicato presenta dimensioni rilevanti, se rapportate alla dimensione della superficie del sanitario, con conseguente ingombro della stessa superficie nonché un effetto estetico poco gradevole. Tale ingombro rende anche poco agevole la pulizia del sanitario. Il prodotto si applica poi impiegando dispositivi o metodi abbastanza complessi, di difficile attuazione da parte dell'utilizzatore . However, the use of sanitizing products applicable directly to sanitary ware currently available on the market has some drawbacks. In the first place, the applied product has significant dimensions, if compared to the size of the surface of the sanitary ware, with consequent encumbrance of the same surface as well as an unpleasant aesthetic effect. This bulk also makes cleaning the sanitary ware difficult. The product is then applied using fairly complex devices or methods, which are difficult for the user to implement.
La Richiedente ha ora sorprendentemente trovato una composizione adesiva igienizzante per la pulizia e/o la disinfezione e/o la profumazione di sanitari che supera gli inconvenienti evidenziati dallo stato dell 'arte. The Applicant has now surprisingly found a sanitizing adhesive composition for cleaning and / or disinfecting and / or perfuming sanitary ware which overcomes the drawbacks highlighted by the state of the art.
Scopo principale della presente invenzione è quindi quello di individuare una composizione adesiva igienizzante per la pulizia e/o la disinfezione e/o la profumazione di sanitari, applicabile direttamente al sanitario a cui aderisce senza l'ausilio di sostegni e/o contenitori, che presenti un ingombro ridotto, ma allo stesso tempo una adesione alla parete del sanitario e una durata ottimali. The main purpose of the present invention is therefore to identify a sanitizing adhesive composition for the cleaning and / or disinfection and / or perfuming of sanitary ware, applicable directly to the sanitary ware to which it adheres without the aid of supports and / or containers, which present a small footprint, but at the same time an optimal adhesion to the sanitary wall and a duration.
Ulteriore scopo della presente invenzione è quello di semplificare la preparazione delle composizioni adesive igienizzanti per la pulizia e/o la disinfezione e/o la profumazione di sanitari applicabili direttamente ai sanitari e di ridurne i costi di produzione. A further object of the present invention is to simplify the preparation of the sanitizing adhesive compositions for the cleaning and / or disinfection and / or perfuming of sanitary ware applicable directly to sanitary ware and to reduce their production costs.
E' perciò oggetto della presente invenzione una composizione adesiva igienizzante per la pulizia e/o la disinfezione e/o la profumazione di sanitari, priva di acqua, comprendente: The object of the present invention is therefore a sanitizing adhesive composition for cleaning and / or disinfection and / or perfuming of sanitary ware, without water, comprising:
i) almeno un promotore di adesione scelto tra polialcossialcani , cellulosa, sodiocarbossimet ilcellulosa, i) at least one adhesion promoter selected from polyalkoxyalkanes, cellulose, sodium carboxymethylcellulose,
idrossimet ilcellulosa, poliacrilati, polisaccaridi, polivinilalcooli , polivinilpirrolidone, alginati, diuretani, gelatine, pectine, oleilamine, ossidi di alchildimet ilamina, stearato di sodio o potassio, sodiododecilsolf ato e/o loro miscele, preferibilmente polialcossialcani ; ii) almeno un tensioattivo scelto tra tensioattivi non ionici e/o anionici e/o anfoterici , hydroxymethylcellulose, polyacrylates, polysaccharides, polyvinyl alcohols, polyvinylpyrrolidone, alginates, diurethanes, gelatins, pectins, oleylamines, oxides of alkyldimethylamine, sodium or potassium stearate, sodiumdodecylsulfate and / or their mixtures, preferably polyalkyalkanes; ii) at least one surfactant selected from non-ionic and / or anionic and / or amphoteric surfactants,
iii) agenti disinfettanti e/o profumanti, iii) disinfectant and / or perfuming agents,
iv) opzionalmente un composto di tipo poliossidrilico, iv) optionally a polyhydric type compound,
v) opzionalmente coloranti e/o coadiuvanti di pulizia e/o schiumogeni e/o agenti ispessenti . v) optionally dyes and / or cleaning aids and / or foaming agents and / or thickening agents.
I principali vantaggi della composizione adesiva igienizzante secondo la presente invenzione consistono nella sua diretta applicabilità al sanitario, nell'elevata efficacia, nella lunga durata nel tempo e nell'aspetto estetico migliorato. The main advantages of the sanitizing adhesive composition according to the present invention consist in its direct applicability to sanitary ware, in its high efficacy, in its long duration over time and in its improved aesthetic appearance.
Inoltre, la formulazione della composizione adesiva igienizzante secondo la presente invenzione è tale da non richiedere l'impiego di ingredienti inerti aventi la sola funzione di eccipiente riempitivo . Furthermore, the formulation of the sanitizing adhesive composition according to the present invention is such as not to require the use of inert ingredients having the sole function of filler excipient.
La composizione igienizzante adesiva secondo la presente invenzione, inoltre, pur avendo un volume ridotto, esercita la propria azione pulente per dilavamento ed è dilavata completamente solo dopo un elevato numero di flussi d'acqua di scarico. The adhesive sanitizing composition according to the present invention, moreover, despite having a reduced volume, exerts its cleaning action by leaching and is completely washed out only after a high number of waste water flows.
È ulteriore oggetto della presente invenzione il procedimento di preparazione di dette composizioni igieniche ed il loro uso per la pulizia e/o disinfezione e/o profumazione dei sanitari. È altresì oggetto della presente invenzione il procedimento di applicazione di tale prodotto direttamente al sanitario, a cui aderisce senza l'ausilio di sostegni e/o contenitori. A further object of the present invention is the preparation process of said hygienic compositions and their use for cleaning and / or disinfection and / or perfuming of sanitary ware. The present invention also relates to the process of applying this product directly to the sanitary ware, to which it adheres without the aid of supports and / or containers.
Promotori di adesione utili ai fini della presente invenzione sono composti organici a catena lunga idrofili o aventi almeno una parte della molecola con proprietà idrofile. Tra le molecole idrofile sono preferibili i polialcossialcani , la cellulosa, la sodio-carbossimetilcellulosa o l'idrossimetilcellulosa. Adhesion promoters useful for the purposes of the present invention are long-chain organic compounds that are hydrophilic or have at least a part of the molecule with hydrophilic properties. Among the hydrophilic molecules, polyalkoxyalkanes, cellulose, sodium-carboxymethylcellulose or hydroxymethylcellulose are preferable.
Altri promotori di adesione adatti ai fini della presente invenzione sono i polimeri sintetici come i poliacrilat i, i polisaccaridi, i polivinilalcooli o il polivinilpirrolidone . Alternativamente, si possono utilizzare composti del tipo alginati, diuretani, gelatine, pectine, oleilamine, ossidi di alchildimetilamina, stearati di sodio o potassio o sodiododecilsolfato. Other adhesion promoters suitable for the purposes of the present invention are synthetic polymers such as polyacrylates, polysaccharides, polyvinyl alcohols or polyvinylpyrrolidone. Alternatively, compounds such as alginates, diurethanes, gelatins, pectins, oleylamines, alkyl dimethylamine oxides, sodium or potassium stearates or sodiumdodecyl sulfate can be used.
Composti particolarmente preferiti ai fini della presente invenzione sono i polialcossialcani, in cui la parte idrofila può essere costituita da gruppi polietossi-, polipropossi- o polibutossi- o miscele di gruppi polialcossi come ad esempio i gruppi poli (etossipropossi ). I composti del tipo polietossialcano hanno preferibilmente un numero di gruppi etossi che varia tra 15 e 55, preferibilmente da 25 a 45, ancora più preferibilmente da 20 a 30. Il radicale alchilico dei polialcossialcani ha almeno 12 atomi di carbonio, preferibilmente da 16 a 30 atomi di carbonio. Particularly preferred compounds for the purposes of the present invention are the polyalkoxyalkanes, in which the hydrophilic part can be constituted by polyethoxy-, polypropoxy- or polybutoxy- groups or mixtures of polyalkoxy groups such as for example the poly (ethoxypropoxy) groups. The compounds of the polyethoxyalkane type preferably have a number of ethoxy groups ranging from 15 to 55, preferably from 25 to 45, even more preferably from 20 to 30. The alkyl radical of the polyalkoxyalkanes has at least 12 carbon atoms, preferably from 16 to 30 carbon atoms.
In una forma di applicazione preferita, il promotore di adesione è scelto fra alcol etossilato con catena di 22 atomi di carbonio (C22) e con 30 gruppi etossi, alcol etossilato (C16/18) con 25 gruppi etossi e/o loro miscele, preferibilmente alcol etossilato con catena di 22 atomi di carbonio (C22) e con 30 gruppi etossi. In a preferred form of application, the adhesion promoter is selected from ethoxylated alcohol with a chain of 22 carbon atoms (C22) and with 30 ethoxy groups, ethoxylated alcohol (C16 / 18) with 25 ethoxy groups and / or mixtures thereof, preferably ethoxylated alcohol with a chain of 22 carbon atoms (C22) and with 30 ethoxy groups.
Per ottenere una buona adesione della composizione igienizzante secondo la presente invenzione, il componente i) è presente in una quantità che varia dal 20% al 80% in peso rispetto al peso totale della composizione, preferibilmente dal 30% al 70% e, ancor più preferibilmente dal 45% al L'azione detergente della composizione secondo la presente invenzione è esplicata da un composto tensioattivo scelto tra tensioattivi non ionici e/o anionici e/o anfoterici. To obtain a good adhesion of the sanitizing composition according to the present invention, component i) is present in an amount ranging from 20% to 80% by weight with respect to the total weight of the composition, preferably from 30% to 70% and, even more preferably from 45% to the detergent action of the composition according to the present invention is carried out by a surfactant compound selected from non-ionic and / or anionic and / or amphoteric surfactants.
Preferibilmente, i tensioattivi non ionici sono scelti tra alcoli alifatici, lineari o ramificati, aventi una catena contenente da 8 a 15 atomi di carbonio condensati con da 3 a 12 moli di alchilenossido per mole di alcol. Ancor più preferibilmente il tensioattivo non ionico è trietanolamina (TEA) laurilsolfato . Preferably, the non-ionic surfactants are selected from aliphatic, linear or branched alcohols, having a chain containing from 8 to 15 carbon atoms condensed with from 3 to 12 moles of alkylene oxide per mol of alcohol. Even more preferably the nonionic surfactant is triethanolamine (TEA) lauryl sulfate.
I tensioattivi anionici che si possono usare ai fini della presente invenzione sono scelti tra dodecilbenzensolfonato di sodio, alcansolfonati sodici, alchil solfati, alchiletere solfati, alfaolefine solfonate, alcoleteri solfati, alchilsolfosuccinati e/o loro miscele. The anionic surfactants which can be used for the purposes of the present invention are selected from sodium dodecylbenzenesulphonate, sodium alkanesulfonates, alkyl sulfates, alkyl ether sulfates, sulphonated alphaolefins, sulfated alcohol ethers, alkylsulfosuccinates and / or their mixtures.
Ai fini della presente invenzione si possono usare anche tensioattivi anfoterici scelti tra alchil-betaine e/o alchilammido-betaine e/o alchilammino-ossidi . For the purposes of the present invention it is also possible to use amphoteric surfactants selected from alkyl-betaines and / or alkylamido-betaines and / or alkylamino-oxides.
Il tensioattivo utilizzato nella composizione secondo la presente invenzione è presente in una quantità variabile dal 20% al 50% in peso rispetto al peso totale della composizione, preferibilmente dal 30% al 40%. The surfactant used in the composition according to the present invention is present in an amount ranging from 20% to 50% by weight with respect to the total weight of the composition, preferably from 30% to 40%.
La composizione secondo la presente invenzione prevede anche l'impiego di sostanze che favoriscono il mantenimento della consistenza solida della composizione igienizzante adesiva anche durante l'uso . The composition according to the present invention also provides for the use of substances which favor the maintenance of the solid consistency of the adhesive sanitizing composition even during use.
Sostanze utili a tal fine sono i composti poliossidrili appartenenti al gruppo comprendente glicerina, polietilenglicole, 1,3-diidrossipropano, 1,3- o 1,4 diidrossibutano, 1 ,3-diidrossiisobutano, pentaeritritol, 1,2-idrossipropano, 1,2- o 2,3-diidrossibutano, 1,2-diidrossiisobutano, glicole dietilenico, glicole trietilenico, preferibilmente glicerina o polietilenglicole e/o loro miscele. Useful substances for this purpose are polyhydroxy compounds belonging to the group comprising glycerin, polyethylene glycol, 1,3-dihydroxypropane, 1,3- or 1,4 dihydroxybutane, 1, 3-dihydroxyisobutane, pentaerythritol, 1,2-hydroxypropane, 1,2 - or 2,3-dihydroxybutane, 1,2-dihydroxyisobutane, diethylene glycol, triethylene glycol, preferably glycerin or polyethylene glycol and / or their mixtures.
La concentrazione dell'eventuale composto poliossidrilico e/o della miscela di composti ossidrilici all'interno della composizione può variare dall'1% al 10% in peso rispetto al peso totale della composizione, preferibilmente dal 2% al 6% . The concentration of the possible polyhydric compound and / or of the mixture of hydroxyl compounds within the composition can vary from 1% to 10% by weight with respect to the total weight of the composition, preferably from 2% to 6%.
La composizione adesiva igienizzante secondo la presente invenzione contiene anche agenti disinfettanti e/o profumanti ed eventualmente coloranti e/o coadiuvanti di pulizia e/o agenti schiumogeni e/o agenti ispessenti, scelti tra quelli comunemente noti al tecnico esperto del ramo. The sanitizing adhesive composition according to the present invention also contains disinfectant and / or perfuming agents and optionally dyes and / or cleaning aids and / or foaming agents and / or thickening agents, selected from those commonly known to those skilled in the art.
La concentrazione degli agenti profumanti può variare dall'1% al 15% in peso rispetto al peso totale della composizione, preferibilmente dal 4% al 10% . The concentration of the perfuming agents can vary from 1% to 15% by weight with respect to the total weight of the composition, preferably from 4% to 10%.
La concentrazione dei coadiuvanti di pulizia può variare dallo 0,1% al 10% in peso rispetto al peso totale della composizione, preferibilmente dallo 0,5% al 5%. The concentration of the cleaning aids can vary from 0.1% to 10% by weight with respect to the total weight of the composition, preferably from 0.5% to 5%.
I coadiuvanti di pulizia possono essere preferibilmente una miscela di agenti biologici in grado di produrre microrganismi gram-positivi scelti tra batteri, lieviti, spore, ecc. Più preferibilmente, i coadiuvanti di pulizia sono una miscela di microrganismi gram-positivi e/o agenti biologici in grado di produrre tali microrganismi in una concentrazione compresa tra 10<4>e 10<12>cfu/g, detti microrganismi appartenendo alle specie Bacillus subtìlìs , Bacillus licheniformis, Bacillus sphaericus, Bacillus thuringensis e/o Paenicillium camenbertii . The cleaning aids can preferably be a mixture of biological agents capable of producing gram-positive microorganisms selected from bacteria, yeasts, spores, etc. More preferably, the cleaning aids are a mixture of gram-positive microorganisms and / or biological agents capable of producing such microorganisms in a concentration between 10 <4> and 10 <12> cfu / g, said microorganisms belonging to the Bacillus species subtìlìs, Bacillus licheniformis, Bacillus sphaericus, Bacillus thuringensis and / or Paenicillium camenbertii.
I microrganismi gram-positivi appartengono preferibilmente alla specie Bacillus subtìlìs e/o Bacillus licheniformis . The gram-positive microorganisms preferably belong to the Bacillus subtìlìs and / or Bacillus licheniformis species.
I microrganismi gram-positivi e/o agenti biologici in grado di produrre tali microrganismi sono presenti preferibilmente in una concentrazione compresa tra 10<6>e IO<10>cfu/g, più preferibilmente tra IO<7>e IO<9>cfu/g. Gram-positive microorganisms and / or biological agents capable of producing such microorganisms are preferably present in a concentration between 10 <6> and 10 <10> cfu / g, more preferably between 10 <7> and 10 <9> cfu / g.
L'azione lipasica, proteasica, cellulasica, amilasica e ureasica di tali microorganismi grampositivi e/o degli agenti biologici in grado di produrre tali microorganismi, in combinazione con l'azione detergente del composto tensioattivo, permette di ottenere un'elevata efficienza nel rimuovere lo sporco in ogni regione del sanitario a cui è applicata la composizione adesiva igienizzante. Ad esempio, nelle tazze WC, l'azione igienizzante e disinfettante si estende su tutta la superficie della tazza a partire dalla linea dell'acqua sino al bordo superiore della tazza stessa, sia in zone vicine al punto di applicazione, sia in zone più lontane, rimuovendo allo stesso tempo anche gli odori sgradevoli, con un'efficienza sia immediata sia soprattutto ritardata nel tempo che si esplica così non soltanto in corrispondenza di ogni scarico d'acqua, ma anche negli intervalli di tempo tra uno scarico o flusso d'acqua ed il successivo. The lipase, protease, cellulase, amylase and urease action of these gram-positive microorganisms and / or of the biological agents capable of producing such microorganisms, in combination with the detergent action of the surfactant compound, allows to obtain a high efficiency in removing the dirt in each region of the sanitary ware to which the sanitizing adhesive composition is applied. For example, in toilet bowls, the sanitizing and disinfecting action extends over the entire surface of the bowl starting from the water line up to the upper edge of the bowl itself, both in areas close to the point of application and in more distant areas. , removing at the same time also unpleasant odors, with an efficiency both immediate and above all delayed in time which is thus expressed not only in correspondence with each water discharge, but also in the time intervals between a discharge or flow of water and the next.
Gli effetti di tali microorganismi nell'inibizione della formazione e crescita di microorganismi gram-negativi indesiderati è descritta in dettaglio nella domanda di brevetto MI2007A00356 a nome dello stesso Richiedente. The effects of these microorganisms in the inhibition of the formation and growth of undesired gram-negative microorganisms is described in detail in the patent application MI2007A00356 in the name of the same Applicant.
I coloranti che si possono utilizzare per conferire alla composizione adesiva igienizzante particolari effetti estetici comprendono, oltre alle sostanze chimiche appartenenti alle varie classi di coloranti note all'esperto del settore, anche le cosiddette "specole" colorate costituite da miscele comprendenti generalmente sodio carbonato e/o sodio solfato e/o bentonite o suoi derivati e/o materiale plastico (es. politene, polipropilene e loro miscele) e/o composti zeolitici. The dyes that can be used to give the adhesive sanitizing composition particular aesthetic effects include, in addition to the chemicals belonging to the various classes of dyes known to the skilled in the art, also the so-called colored "speculum" consisting of mixtures generally comprising sodium carbonate and / o sodium sulphate and / or bentonite or its derivatives and / or plastic material (eg polythene, polypropylene and their mixtures) and / or zeolitic compounds.
Preferibilmente, una composizione adesiva igienizzante secondo la presente invenzione può essere costituita dai seguenti componenti: Preferably, a sanitizing adhesive composition according to the present invention can consist of the following components:
i) alcool etossilato (C22) con 30 gruppi etossi in quantità uguale al 38% in peso rispetto al peso totale della composizione; alcool etossilato (C16/18) con 25 gruppi etossi in una quantità uguale al 16% in peso rispetto al peso totale della composizione; i) ethoxylated alcohol (C22) with 30 ethoxy groups in an amount equal to 38% by weight with respect to the total weight of the composition; ethoxylated alcohol (C16 / 18) with 25 ethoxy groups in an amount equal to 16% by weight with respect to the total weight of the composition;
ii) TEA laurilsolfato in una quantità uguale al 36% in peso rispetto al peso totale della composizione; ii) TEA lauryl sulfate in an amount equal to 36% by weight with respect to the total weight of the composition;
iii) agenti profumanti in una quantità uguale al 6% in peso rispetto al peso totale della composizione; iii) perfuming agents in an amount equal to 6% by weight with respect to the total weight of the composition;
iv) glicerina in una quantità uguale al 4% in peso rispetto al peso totale della composizione. iv) glycerin in an amount equal to 4% by weight with respect to the total weight of the composition.
In un'altra realizzazione preferita il suddetto componente iv) è una miscela di glicerina e di poliet ilenglicole dove la glicerina è presente in una quantità uguale al 3% in peso rispetto al peso totale della composizione e il polietilenglicole è presente in una quantità uguale all'1% in peso rispetto al peso totale della composizione. In another preferred embodiment the aforesaid component iv) is a mixture of glycerin and polyethylene glycol where the glycerin is present in an amount equal to 3% by weight with respect to the total weight of the composition and the polyethylene glycol is present in an amount equal to 1% by weight with respect to the total weight of the composition.
In una ulteriore realizzazione preferita, una composizione adesiva igienizzante secondo la presente invenzione può essere costituita dai seguenti componenti : In a further preferred embodiment, a sanitizing adhesive composition according to the present invention can consist of the following components:
i) alcool etossilato (C22) con 30 gruppi etossi in quantità uguale al 38% in peso rispetto al peso totale della composizione; alcool etossilato (C16/18) con 25 gruppi etossi in una quantità uguale al 14% in peso rispetto al peso totale della composizione; i) ethoxylated alcohol (C22) with 30 ethoxy groups in an amount equal to 38% by weight with respect to the total weight of the composition; ethoxylated alcohol (C16 / 18) with 25 ethoxy groups in an amount equal to 14% by weight with respect to the total weight of the composition;
ii) TEA laurilsolfato in una quantità uguale al 36% in peso rispetto al peso totale della composizione; ii) TEA lauryl sulfate in an amount equal to 36% by weight with respect to the total weight of the composition;
iii) agenti profumanti in una quantità uguale al 6% in peso rispetto al peso totale della composizione; iii) perfuming agents in an amount equal to 6% by weight with respect to the total weight of the composition;
iv) glicerina in una quantità uguale al 4% in peso rispetto al peso totale della composizione; v) coadiuvanti di pulizia in una quantità uguale al 2% in peso rispetto al peso totale della composizione costituiti da una miscela Bacillus spp comprendente ceppi di Bacillus subtilis e Bacillus licheniformis aventi una attività uguale a circa IO<8>cfu/g. iv) glycerin in an amount equal to 4% by weight with respect to the total weight of the composition; v) cleaning aids in an amount equal to 2% by weight with respect to the total weight of the composition consisting of a Bacillus spp mixture comprising strains of Bacillus subtilis and Bacillus licheniformis having an activity equal to about 10 <8> cfu / g.
Ulteriore oggetto della presente invenzione è il procedimento per la preparazione delle suddette composizioni adesive igienizzanti direttamente applicabili al sanitario, a cui aderiscono cioè senza l'ausilio di sostegni e/o contenitori. A further object of the present invention is the process for the preparation of the aforesaid adhesive sanitizing compositions directly applicable to sanitary ware, to which they adhere, that is, without the aid of supports and / or containers.
Il procedimento per la preparazione di una composizione adesiva igienizzante per la pulizia e/o la disinfezione e/o la profumazione di sanitari, detta composizione essendo direttamente applicata al sanitario, e comprendendo The process for the preparation of a sanitizing adhesive composition for the cleaning and / or disinfection and / or perfuming of sanitary ware, said composition being directly applied to the sanitary, and comprising
i) almeno un promotore di adesione scelto tra polialcossialcani , cellulosa, sodiocarbossimetilcellulosa, idrossimetilcellulosa, poliacrilati, polisaccaridi, polivinilalcooli , polivinilpirrolidone, alginati, diuretani, gelatine, pectine, oleilamine, ossidi di alchildimetilamina, stearato di sodio o potassio, sodiododecilsolfato e/o loro miscele, preferibilmente polialcossialcani ; ii) almeno un tensioattivo scelto tra tensioattivi non ionici e/o anionici e/o anfoterici , i) at least one adhesion promoter selected from polyalkoxyalkanes, cellulose, sodium carboxymethylcellulose, hydroxymethylcellulose, polyacrylates, polysaccharides, polyvinyl alcohols, polyvinylpyrrolidone, alginates, diurethanes, gelatins, pectins, oleylamines, oxides of alkyldiodimethylamine or sodium / sodium stethylamine or sodium stethylamine or potassium mixtures, preferably polyalkoxyalkanes; ii) at least one surfactant selected from non-ionic and / or anionic and / or amphoteric surfactants,
iii) agenti disinfettanti e/o profumanti, iii) disinfectant and / or perfuming agents,
iv) opzionalmente un composto di tipo poliossidrilico, iv) optionally a polyhydric type compound,
v) opzionalmente coloranti e/o coadiuvanti di pulizia e/o schiumogeni e/o agenti ispessenti , v) optionally dyes and / or cleaning aids and / or foaming agents and / or thickening agents,
comprende le seguenti fasi operative: includes the following operational phases:
- scaldare il componente i) ad una temperatura superiore al suo punto di fusione; - heat component i) to a temperature above its melting point;
- incorporare i componenti ii), iii) e, quando presenti, i componenti iv) e v), - incorporate components ii), iii) and, when present, components iv) and v),
- omogeneizzare la composizione per miscelazione ad una temperatura compresa tra 45°C e 55°C per un tempo che varia tra 5 minuti e 30 minuti, - homogenize the composition by mixing at a temperature between 45 ° C and 55 ° C for a time ranging from 5 minutes to 30 minutes,
- versare la composizione in un contenitore, - lasciare raffreddare la composizione sino a solidificazione . - pour the composition into a container, - allow the composition to cool until solidification.
Nel caso in cui la composizione adesiva igienizzante comprenda anche i coadiuvanti di pulizia, la loro aggiunta alla miscela avviene dopo la fase di omogeneizzazione, ad una temperatura della miscela non superiore a 45°C. La miscela così ottenuta viene ulteriormente miscelata prima di essere versata nel contenitore. If the sanitizing adhesive composition also includes cleaning aids, their addition to the mixture takes place after the homogenization step, at a mixture temperature not exceeding 45 ° C. The mixture thus obtained is further mixed before being poured into the container.
Rispetto al procedimento di preparazione di analoghi prodotti igienizzanti i vantaggi del procedimento oggetto della presente invenzione sono i seguenti : Compared to the preparation process of similar sanitizing products, the advantages of the process object of the present invention are as follows:
- il prodotto finito solidificato non necessita di trattamenti di rifinitura meccanica (es. trafilatura) ; - the solidified finished product does not require mechanical finishing treatments (eg drawing);
- il riscaldamento della composizione è limitato al raggiungimento della temperatura di fusione del componente i) (in genere inferiore a 60°C); ciò evita l'evaporazione di sostanze volatili quali gli agenti profumanti ; - the heating of the composition is limited to reaching the melting temperature of component i) (generally below 60 ° C); this avoids the evaporation of volatile substances such as perfuming agents;
- la composizione è colata e solidificata in un contenitore che conferisce la forma finale del prodotto pronto all'uso e non necessita di ulteriori lavorazioni (es. taglio a fine linea); - the composition is poured and solidified in a container which gives the final shape of the product ready for use and does not require further processing (eg cutting at the end of the line);
- si possono realizzare prodotti finiti di svariate forme, a differenza dei tradizionali procedimenti di trafilatura-estrusione che limitano fortemente la varietà di configurazioni possibili. - it is possible to produce finished products of various shapes, unlike traditional drawing-extrusion processes which severely limit the variety of possible configurations.
In un'applicazione preferita, la composizione adesiva igienizzante secondo la presente invenzione è realizzata in forma di tavoletta delle dimensioni di circa 11 x 4 x 1 cm, risultando così poco visibile all'interno del sanitario a cui è applicata, a differenza di prodotti decisamente più ingombranti ottenibili secondo gli insegnamenti dello stato della tecnica . In a preferred application, the sanitizing adhesive composition according to the present invention is made in the form of a tablet with dimensions of approximately 11 x 4 x 1 cm, thus resulting not very visible inside the sanitary ware to which it is applied, unlike decidedly products. more bulky obtainable according to the teachings of the state of the art.
L'ingombro della composizione adesiva igienizzante per sanitari secondo la presente invenzione dipende principalmente dalla durata dell'efficacia igienizzante che si vuole ottenere. The bulk of the sanitizing adhesive composition for sanitary ware according to the present invention depends mainly on the duration of the sanitizing efficacy to be obtained.
Se per l'igienizzazione di un WC domestico si considera che una composizione igienizzante può essere soggetta a flussi d'acqua di scarico di volume variabile da 6 a 9 litri ciascuno, la composizione adesiva igienizzante secondo la presente invenzione formulata come tavoletta avente un peso di circa 20 grammi è dilavata completamente solo dopo 350-500 flussi circa, tenendo conto che il numero di flussi necessari al completo dilavamento dipende anche dalla geometria della tavoletta e dalle modalità di flusso dell'acqua nel WC. If for the sanitation of a domestic toilet it is considered that a sanitizing composition can be subjected to waste water flows of variable volume from 6 to 9 liters each, the sanitizing adhesive composition according to the present invention formulated as a tablet having a weight of about 20 grams is completely washed out only after about 350-500 flows, taking into account that the number of flows necessary for complete washout also depends on the geometry of the tablet and the way the water flows in the toilet.
L'uso della composizione adesiva igienizzante secondo la presente invenzione per pulire e/o disinfettare e/o profumare i sanitari avviene tramite applicazione diretta al sanitario, a cui aderisce senza l'ausilio di sostegni e/o contenitori. A tal fine, il sanitario a cui si applica la composizione adesiva igienizzante deve essere umido, ad esempio, a seguito di uno scarico d'acqua effettuato prima dell'applicazione della composizione. The use of the sanitizing adhesive composition according to the present invention to clean and / or disinfect and / or perfume sanitary ware takes place through direct application to sanitary ware, to which it adheres without the aid of supports and / or containers. To this end, the sanitary ware to which the sanitizing adhesive composition is applied must be wet, for example, following a drain of water carried out before the application of the composition.
In particolare, per facilitare l'applicazione della composizione al sanitario, la composizione può essere dotata di un supporto, quale ad esempio un supporto termoformato in plastica siliconata e/o teflon e/o materiali colaminati, carta siliconata imbutita, dal quale la composizione sia distaccabile con facilità, eventualmente tramite appositi elementi che ne facilitano l'applicazione sulla parete del sanitario . In particular, to facilitate the application of the composition to the sanitary ware, the composition can be equipped with a support, such as for example a thermoformed support in silicone-coated plastic and / or Teflon and / or colaminated materials, deep-drawn silicone paper, from which the composition is detachable easily, possibly using special elements that facilitate its application on the wall of the sanitary ware.
Si riportano i seguenti esempi a titolo puramente illustrativo. The following examples are given for illustrative purposes only.
ESEMPIO 1 EXAMPLE 1
Utilizzando il procedimento di preparazione sopra descritto è stata preparata una composizione adesiva igienizzante avente la seguente composizione: i) alcool etossilato (C22) con 30 gruppi etossi in quantità uguale al 54% in peso rispetto al peso totale della composizione; Using the preparation process described above, a sanitizing adhesive composition was prepared having the following composition: i) ethoxylated alcohol (C22) with 30 ethoxy groups in an amount equal to 54% by weight with respect to the total weight of the composition;
ii) TEA laurilsolfato in una quantità uguale al 36% in peso rispetto al peso totale della composizione; ii) TEA lauryl sulfate in an amount equal to 36% by weight with respect to the total weight of the composition;
iii) sostanze profumanti in una quantità uguale al 6% in peso rispetto al peso totale della composizione; iii) perfuming substances in an amount equal to 6% by weight with respect to the total weight of the composition;
iv) glicerina in una quantità uguale al 3% e poliet ilenglicole 6000 in una quantità uguale al 1% in peso rispetto al peso totale della composizione. iv) glycerin in an amount equal to 3% and polyethylene glycol 6000 in an amount equal to 1% by weight with respect to the total weight of the composition.
La composizione adesiva igienizzante è stata realizzata in forma di tavoletta di dimensioni 11 x 4 x 1 cm dal peso di 20 grammi circa. The sanitizing adhesive composition was made in the form of a tablet measuring 11 x 4 x 1 cm weighing approximately 20 grams.
La composizione è stata applicata alla tazza di un WC, previa umidificazione della superficie. Il dilavamento completo del prodotto igienizzante è avvenuto solo dopo 400 flussi di scarico. The composition was applied to a toilet bowl, after moistening the surface. The complete washout of the sanitizing product took place only after 400 unloading streams.
Claims (26)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT000642A ITMI20070642A1 (en) | 2007-03-29 | 2007-03-29 | SANITIZING ADHESIVE COMPOSITION FOR THE CLEANING AND / OR DISINFECTION AND SANITARY SCENTING |
| ES08153205.3T ES2606528T3 (en) | 2007-03-29 | 2008-03-25 | Adhesive sanitizing composition for cleaning and / or disinfection and / or perfuming of sanitary devices |
| EP08153205.3A EP1978080B1 (en) | 2007-03-29 | 2008-03-25 | Adhesive hygienizing composition for the cleaning and/or disinfecting and/or perfuming of sanitary fixtures |
| PL08153205T PL1978080T3 (en) | 2007-03-29 | 2008-03-25 | Adhesive hygienizing composition for the cleaning and/or disinfecting and/or perfuming of sanitary fixtures |
| HRP20161610TT HRP20161610T1 (en) | 2007-03-29 | 2016-12-01 | Adhesive hygienizing composition for the cleaning and/or disinfecting and/or perfuming of sanitary fixtures |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT000642A ITMI20070642A1 (en) | 2007-03-29 | 2007-03-29 | SANITIZING ADHESIVE COMPOSITION FOR THE CLEANING AND / OR DISINFECTION AND SANITARY SCENTING |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ITMI20070642A1 true ITMI20070642A1 (en) | 2008-09-30 |
Family
ID=39580622
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| IT000642A ITMI20070642A1 (en) | 2007-03-29 | 2007-03-29 | SANITIZING ADHESIVE COMPOSITION FOR THE CLEANING AND / OR DISINFECTION AND SANITARY SCENTING |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP1978080B1 (en) |
| ES (1) | ES2606528T3 (en) |
| HR (1) | HRP20161610T1 (en) |
| IT (1) | ITMI20070642A1 (en) |
| PL (1) | PL1978080T3 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2141221A1 (en) | 2008-06-30 | 2010-01-06 | Bolton Manitoba SpA | Adhesive toilet product, containment and applicator device thereto |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8143205B2 (en) | 2008-02-21 | 2012-03-27 | S.C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion and providing residual benefits |
| US9481854B2 (en) | 2008-02-21 | 2016-11-01 | S. C. Johnson & Son, Inc. | Cleaning composition that provides residual benefits |
| US9410111B2 (en) | 2008-02-21 | 2016-08-09 | S.C. Johnson & Son, Inc. | Cleaning composition that provides residual benefits |
| US8980813B2 (en) | 2008-02-21 | 2015-03-17 | S. C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion on a vertical hard surface and providing residual benefits |
| US8993502B2 (en) | 2008-02-21 | 2015-03-31 | S. C. Johnson & Son, Inc. | Cleaning composition having high self-adhesion to a vertical hard surface and providing residual benefits |
| IT1396369B1 (en) * | 2009-10-28 | 2012-11-19 | Bolton Manitoba S P A | ADHESIVE COMPOSITION DETERGENT AND / OR PERFUME AND / OR HYGIENIZER. |
| GB201007064D0 (en) | 2010-04-28 | 2010-06-09 | Reckitt Benckiser Inc | Applicator for an adhesive lavatory treatment composition |
| GB201007066D0 (en) | 2010-04-28 | 2010-06-09 | Reckitt Benckiser Inc | Improved applicator for an adhesive lavatory treatment composition |
| GB201010109D0 (en) * | 2010-06-17 | 2010-07-21 | Reckitt Benckiser Inc | Adhesive lavatory treatment compositions |
| GB201016491D0 (en) | 2010-10-01 | 2010-11-17 | Reckitt Benckiser Inc | Adhesive lavatory treatment compositions |
| CA2865885C (en) | 2011-02-28 | 2017-03-28 | Richard Eric Nemeth | Wet sanding composition |
| GB2502763B (en) | 2011-10-14 | 2016-09-28 | Jeyes Group Ltd | An Applicator for a sanitary ware surface |
| IN2014CN02803A (en) | 2012-07-16 | 2015-07-03 | Reckitt Benckiser Llc | |
| WO2014072677A1 (en) | 2012-11-09 | 2014-05-15 | Reckitt Benckiser Llc | Single use, foldable dispenser for an adhesive lavatory treatment composition |
| MX2015015035A (en) | 2013-05-10 | 2016-05-05 | Eurvest Sa | New sanitary composition. |
| ITMI20131535A1 (en) * | 2013-09-18 | 2015-03-19 | Bolton Manitoba S P A | SOLID TABLET FOR WC |
| EP2987850A1 (en) * | 2014-08-20 | 2016-02-24 | Huntsman International Llc | Composition for sanitary cleaning product |
| US10196591B2 (en) | 2015-07-10 | 2019-02-05 | S. C. Johnson & Sons, Inc. | Gel cleaning composition |
| US10358625B2 (en) | 2015-07-17 | 2019-07-23 | S. C. Johnson & Son, Inc. | Non-corrosive cleaning composition |
| US10000728B2 (en) | 2015-07-17 | 2018-06-19 | S. C. Johnson & Son, Inc. | Cleaning composition with propellant |
| US10604724B2 (en) | 2015-08-27 | 2020-03-31 | S. C. Johnson & Son, Inc. | Cleaning gel with glycine betaine amide/nonionic surfactant mixture |
| WO2017034792A1 (en) * | 2015-08-27 | 2017-03-02 | S. C. Johnson & Son, Inc. | Cleaning gel with glycine betaine ester |
| US10836980B2 (en) | 2015-12-07 | 2020-11-17 | S. C. Johnson & Son, Inc. | Acidic hard surface cleaner with glycine betaine amide |
| US11339353B2 (en) | 2015-12-07 | 2022-05-24 | S.C. Johnson & Son, Inc. | Acidic hard surface cleaner with glycine betaine ester |
| ITUA20163446A1 (en) * | 2016-05-16 | 2017-11-16 | Bolton Manitoba S P A | HYGIENIZATION DEVICE, PARTICULARLY FOR SANITARY AND SIMILAR PRODUCTS AND ITS FILLING PROCEDURE. |
| CN106148035A (en) * | 2016-08-16 | 2016-11-23 | 仇颖莹 | A kind of preparation method of adhesive sticker cleaning agent |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1465475A (en) * | 1974-05-23 | 1977-02-23 | Ciba Geigy Ag | Lavatory cleaning composition |
| GB2061996B (en) * | 1979-09-21 | 1983-06-22 | Jeyes Group Ltd | Lavatory cleansing blocks |
| CA1182371A (en) * | 1980-12-18 | 1985-02-12 | Jeyes Group Limited | Lavatory cleansing blocks |
| DE3264050D1 (en) * | 1981-08-24 | 1985-07-11 | Unilever Nv | Lavatory cleansing block |
| DE3424317A1 (en) * | 1984-07-02 | 1986-01-23 | Henkel KGaA, 4000 Düsseldorf | Means for toilet cleaning |
| US4722801A (en) * | 1986-06-20 | 1988-02-02 | Kiwi Brands, Inc. | Toilet bowl cleaner in cake form containing a polyethyleneglycol distearate |
| DE3640090A1 (en) * | 1986-11-24 | 1988-06-01 | Henkel Kgaa | CLEANING BLOCK FOR THE WATER CASE OF SINK TOILETS |
| US4861511A (en) * | 1987-06-26 | 1989-08-29 | Nalco Chemical Company | Toilet bowl cleaner and stain-inhibiting composition |
| US4911859A (en) * | 1988-09-15 | 1990-03-27 | Kiwi Brands, Inc. | Toilet bowl cleaners containing iodophors |
| GB9018779D0 (en) * | 1990-08-28 | 1990-10-10 | Jeyes Ltd | Lavatory cleansing |
| WO1996004362A1 (en) * | 1994-08-01 | 1996-02-15 | Albemarle Corporation | Toilet bowl cleaner |
| US5759974A (en) * | 1994-11-07 | 1998-06-02 | Henkel Kommanditgesellschaft Auf Aktien | Block-form cleaners for flush toilets |
| US5863876A (en) * | 1997-02-11 | 1999-01-26 | S. C. Johnson & Son, Inc. | In-tank toilet cleansing block having polyacrylic acid/acrylate |
| GB2322632B (en) * | 1997-02-20 | 2001-02-21 | Reckitt & Colman Of India Ltd | A toilet block composition |
| CA2320776A1 (en) * | 1998-04-09 | 1999-10-21 | Unilever Plc | Toilet cleaning blocks |
| DE19826293A1 (en) | 1998-06-12 | 2000-03-23 | Buck Chemie Gmbh | Sanitary ware |
| US7795199B2 (en) | 2000-06-29 | 2010-09-14 | Ecolab Inc. | Stable antimicrobial compositions including spore, bacteria, fungi, and/or enzyme |
| DE10048887A1 (en) | 2000-09-29 | 2002-04-18 | Buck Chemie Gmbh | Adhesive sanitary cleaner and fragrance |
| DE102004035655A1 (en) * | 2004-07-22 | 2006-02-16 | Henkel Kgaa | Method for producing multi-phase sticks for toilet cleaning |
| DE102004036635A1 (en) * | 2004-07-28 | 2006-03-23 | Buck-Chemie Gmbh | Cleaning and fragrancing products for the toilet area |
| DE102004056554A1 (en) | 2004-11-23 | 2006-05-24 | Buck-Chemie Gmbh | Adhesive sanitary cleaning and scenting agent |
| DE102005029812A1 (en) | 2005-06-27 | 2006-12-28 | Siemens Ag | Link adaptation optimizing method for e.g. speech transmission, involves initiating new determination of parameters according to criteria based on monitoring of quality, and changing parameter according to service type and /or quality |
| CA2740067C (en) | 2008-02-29 | 2014-04-08 | Buck-Chemie Gmbh | Adhesive agent for application on a sanitary object |
-
2007
- 2007-03-29 IT IT000642A patent/ITMI20070642A1/en unknown
-
2008
- 2008-03-25 PL PL08153205T patent/PL1978080T3/en unknown
- 2008-03-25 ES ES08153205.3T patent/ES2606528T3/en active Active
- 2008-03-25 EP EP08153205.3A patent/EP1978080B1/en not_active Revoked
-
2016
- 2016-12-01 HR HRP20161610TT patent/HRP20161610T1/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2141221A1 (en) | 2008-06-30 | 2010-01-06 | Bolton Manitoba SpA | Adhesive toilet product, containment and applicator device thereto |
Also Published As
| Publication number | Publication date |
|---|---|
| EP1978080A1 (en) | 2008-10-08 |
| ES2606528T3 (en) | 2017-03-24 |
| HRP20161610T1 (en) | 2017-01-13 |
| EP1978080B1 (en) | 2016-09-07 |
| PL1978080T3 (en) | 2017-03-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ITMI20070642A1 (en) | SANITIZING ADHESIVE COMPOSITION FOR THE CLEANING AND / OR DISINFECTION AND SANITARY SCENTING | |
| AU2010276734B2 (en) | Cleaning composition having high self-adhesion and providing residual benefits | |
| AU2010276733B2 (en) | Cleaning composition that provides residual benefits | |
| JP5524108B2 (en) | Adhesive for application on sanitary articles | |
| AU2009215861B2 (en) | Cleaning composition having high self-adhesion and providing residual benefits | |
| AU2011285051B2 (en) | Adhering acidic sanitary cleaner and fragrancer | |
| AU2009215860B2 (en) | Cleaning composition that provides residual benefits | |
| RU2588577C2 (en) | Self-adhesive cleaning composition with high viscosity | |
| JP5006540B2 (en) | Slowly water soluble composition and cleaning method using the same | |
| CN103068959B (en) | A sanitary agent covered by a film | |
| BRPI1012851A2 (en) | spherical toilet cleaner blocks, method for their production, and cleaning carrier comprising spherical toilet cleaner blocks | |
| US9399752B2 (en) | Cleaning composition having high self-adhesion and providing residual benefits | |
| ITMI20091874A1 (en) | ADHESIVE COMPOSITION DETERGENT AND / OR PERFUME AND / OR HYGIENIZER | |
| JP2005330498A (en) | Freshener-/cleaner-system for lavatory | |
| TW201508059A (en) | Adhesive agent for application on a sanitary object | |
| AU2013200944B2 (en) | Cleaning composition having high self-adhesion and providing residual benefits |