CN111548847A - Aluminum foil rolling lubricating oil, preparation method and application - Google Patents
Aluminum foil rolling lubricating oil, preparation method and application Download PDFInfo
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- CN111548847A CN111548847A CN202010459547.3A CN202010459547A CN111548847A CN 111548847 A CN111548847 A CN 111548847A CN 202010459547 A CN202010459547 A CN 202010459547A CN 111548847 A CN111548847 A CN 111548847A
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- aluminum foil
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- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 55
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 55
- 239000011888 foil Substances 0.000 title claims abstract description 51
- 238000005096 rolling process Methods 0.000 title claims abstract description 51
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 239000003921 oil Substances 0.000 claims abstract description 25
- -1 unsaturated fatty acid ester Chemical class 0.000 claims abstract description 18
- 239000000314 lubricant Substances 0.000 claims abstract description 15
- 239000002199 base oil Substances 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 3
- 239000010452 phosphate Substances 0.000 claims abstract description 3
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims abstract description 3
- 239000003245 coal Substances 0.000 claims description 7
- 238000003756 stirring Methods 0.000 claims description 6
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- QYDYPVFESGNLHU-UHFFFAOYSA-N elaidic acid methyl ester Natural products CCCCCCCCC=CCCCCCCCC(=O)OC QYDYPVFESGNLHU-UHFFFAOYSA-N 0.000 claims description 4
- QYDYPVFESGNLHU-KHPPLWFESA-N methyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC QYDYPVFESGNLHU-KHPPLWFESA-N 0.000 claims description 4
- 229940073769 methyl oleate Drugs 0.000 claims description 4
- LVGKNOAMLMIIKO-UHFFFAOYSA-N Elaidinsaeure-aethylester Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC LVGKNOAMLMIIKO-UHFFFAOYSA-N 0.000 claims description 3
- LVGKNOAMLMIIKO-QXMHVHEDSA-N ethyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC LVGKNOAMLMIIKO-QXMHVHEDSA-N 0.000 claims description 3
- 229940093471 ethyl oleate Drugs 0.000 claims description 3
- 125000005456 glyceride group Chemical group 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000010731 rolling oil Substances 0.000 abstract description 13
- 238000000137 annealing Methods 0.000 abstract description 9
- 238000005260 corrosion Methods 0.000 abstract description 4
- 230000007797 corrosion Effects 0.000 abstract description 4
- 238000012545 processing Methods 0.000 abstract description 3
- 235000019198 oils Nutrition 0.000 description 21
- 230000015572 biosynthetic process Effects 0.000 description 9
- 238000003786 synthesis reaction Methods 0.000 description 9
- 239000000654 additive Substances 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 7
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- 230000001050 lubricating effect Effects 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910052717 sulfur Inorganic materials 0.000 description 4
- 239000011593 sulfur Substances 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000007841 coal based oil Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 238000005461 lubrication Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- STMLQIACVZOCHU-UHFFFAOYSA-N octan-2-yl dihydrogen phosphate Chemical compound CCCCCCC(C)OP(O)(O)=O STMLQIACVZOCHU-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000013520 petroleum-based product Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
- C10M169/04—Mixtures of base-materials and additives
- C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/40—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling foils which present special problems, e.g. because of thinness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B45/00—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
- B21B45/02—Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for lubricating, cooling, or cleaning
- B21B45/0239—Lubricating
- B21B45/0242—Lubricants
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B3/00—Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
- B21B2003/001—Aluminium or its alloys
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
- C10M2205/17—Fisher Tropsch reaction products
- C10M2205/173—Fisher Tropsch reaction products used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/281—Esters of (cyclo)aliphatic monocarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/28—Esters
- C10M2207/286—Esters of polymerised unsaturated acids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2225/00—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions
- C10M2225/04—Organic macromolecular compounds containing phosphorus as ingredients in lubricant compositions obtained by phosphorisation of macromolecualr compounds not containing phosphorus in the monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
- Metal Rolling (AREA)
Abstract
The invention relates to aluminum foil rolling lubricating oil which comprises the following raw materials in parts by weight: base oil: 50-94 parts of Fischer-Tropsch light oil; lubricant: 2-8 parts of polyricinoleate; an oiliness agent: 2-12 parts of unsaturated fatty acid ester; extreme pressure antiwear agent: 0.5-3 parts of fatty alcohol ethoxylated phosphate or amine phosphate. The aluminum foil rolling oil has the characteristics of low viscosity, good lubricity, good low-temperature annealing cleanness, no corrosion, good processing surface quality and the like, and meets the requirements of a precision rolling process of an aluminum foil continuous multi-roller unit.
Description
Technical Field
The invention belongs to the technical field of lubricating oil, and particularly relates to aluminum foil rolling lubricating oil, a preparation method and application.
Background
The aluminum foil rolling process is formed by rolling from thick to thin and comprises rough rolling and fine rolling, wherein the rough rolling is generally performed when the outlet thickness is larger than 0.05mm, the fine rolling is performed when the outlet thickness is smaller than 0.05mm, the process of the aluminum foil is performed by a reversible continuous rolling mill with multiple rollers in the fine rolling process, high friction is generated in the process, the rolling pressure is increased, the roller abrasion is aggravated, the surface of the aluminum foil is seriously damaged, and rolling oil is required for lubrication.
Under the finish rolling process of a continuous multi-roller unit, the temperature of a binding piece and a roller is raised by the thermal deformation and the friction heat of aluminum, the rolling speed is high, the rolling pressure is high, and the rolling oil meets the requirements of rolling lubrication of aluminum foil, and simultaneously considers that the annealing cleaning performance of the surface of the aluminum foil is not influenced.
Through searching, the following patent publications related to the patent application of the invention are found:
1. patent publication CN106010748A discloses a high-quality aluminum foil rolling oil, which is provided by compounding Fischer-Tropsch synthetic light oil and epoxy soybean oil to prolong the service life of the rolling oil.
2. Patent publication CN102703171A discloses an additive for aluminum rolling oil and a preparation method thereof, wherein the additive content is more than 50%, and the additive has good lubricity, but the cost is high, and the influence of excessive additive content on annealing detergency is large.
3. The patent publication CN102229843A aluminum material rolling oil additive composition uses a combination of long chain fatty acid, alcohol and ester with high addition amount, and has low oil film strength and poor lubricity.
None of these patent publications mention highly lubricating rolling oil suitable for use in the finish rolling process of aluminum foil continuous multi-roll mill. Therefore, the present patent application is fundamentally different from the above patent publications.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides aluminum foil rolling lubricating oil, a preparation method and application.
The technical scheme adopted by the invention for solving the technical problem is as follows:
the aluminum foil rolling lubricating oil comprises the following raw material components in parts by weight:
base oil: 50-94 parts of Fischer-Tropsch light oil;
lubricant: 2-8 parts of polyricinoleate;
an oiliness agent: 2-12 parts of unsaturated fatty acid ester;
extreme pressure antiwear agent: fatty alcohol ethoxylated phosphate esters (also known as "fatty acid polyglycol ether based phosphate esters", reference commercial products:https://www.pvc123.com/b-yzw54394636/sell3357964/orhttps:// detail.1688.com/offer/619042702088.htmlspm＝a26352.13672862.offerlist.49.35f 97e1fS07Ri7) Or 0.5-3 parts of amine phosphate.
The lubricant is one or more of dinierein, tetrapolyricinoleate and hexapolyricinoleate.
The oiliness agent is one or more of methyl oleate, ethyl oleate and unsaturated fatty glyceride.
And the extreme pressure antiwear agent is one or more of fatty alcohol ethoxylated phosphate, isooctyl acid phosphate octadecylamine salt and butyl isooctyl phosphate dodecylamine salt.
The base oil is coal liquefied Fischer-Tropsch light oil, and the component is C12～C21Alkane, content > 95%, wherein C12～C13Alkane content > 90%, C14～C21The alkane content is 9-10%.
Fischer-Tropsch synthesis is a process for preparing hydrocarbon compounds by using synthesis gas as a raw material. The synthesis gas can be prepared from natural gas, coal, light hydrocarbon, heavy oil, biomass and other raw materials. According to the raw material of the synthesis gas, the Fischer-Tropsch synthesis oil can be divided into: coal-to-liquids (CTL), Biomass-to-liquids (BTL) and Gas-to-liquids (GTL). Indirect liquefaction of coal first gasifies the coal, which is then converted to hydrocarbon fuels by fischer-tropsch synthesis. The produced oil has the characteristics of high octane number, high H/C content, low sulfur and low aromatic hydrocarbon, mutual solubility with common oil, and the like. Meanwhile, the coal-to-liquid has the characteristics of low kinematic viscosity, small density, low volume heat value and the like. The coal-based oil is beneficial to China to get rid of excessive dependence on imported crude oil and petroleum products, so that the energy safety is improved, and the coal-based oil is an important product in the field of coal chemical industry. The industrial products refer to the following links:http:// www.yitaigroup.com/product/4215.htm。
the preparation method of the lubricating oil for rolling the aluminum foil comprises the following steps:
weighing base oil, an oiliness agent, a lubricant and an extreme pressure antiwear agent according to a mass ratio;
heating the stirring kettle to 40-60 ℃, adding the base oil, starting stirring, then sequentially adding the oiliness agent, the lubricant and the extreme pressure antiwear agent, rotating at the speed of 60-120r/min for 120-150min, and obtaining the aluminum foil rolling lubricating oil.
The application of the aluminum foil rolling lubricating oil in aluminum foil rolling.
The invention has the advantages and positive effects that:
1. the lubricating oil of the invention adopts Fischer-Tropsch synthesis light oil as a main component, has high alkane component content, basically does not contain miscellaneous components such as aromatic hydrocarbon, sulfur and the like, and has the advantages of low viscosity, narrow distillation range, high flash point, small additive dosage, good lubricating property, good annealing cleanness and the like.
2. The lubricating oil disclosed by the invention can meet the requirement of a precision rolling process of an aluminum foil continuous multi-roller unit by compounding an oiliness agent, a high-efficiency lubricant and an extreme pressure agent, and meanwhile, the aluminum foil rolling lubricating oil is easy to biodegrade and environment-friendly, and does not influence the annealing cleaning performance of the surface of an aluminum foil.
3. The aluminum foil rolling oil has the characteristics of low viscosity, good lubricity, good low-temperature annealing cleanness, no corrosion, good processing surface quality and the like, and meets the requirements of a precision rolling process of an aluminum foil continuous multi-roller unit.
4. Compared with petroleum-based base oil used in the prior art, the Fischer-Tropsch synthesis light oil used as the lubricating oil has the advantages of high alkane content (more than 99%), basically no sulfur, aromatic hydrocarbon and other components, narrow distillation range, low kinematic viscosity, better lubricating performance and the like, and better meets the use requirements of metal foil and strip rolling. The Fischer-Tropsch synthetic oil of the coal liquefied gas is an important strategic storage technology in China, the development of the high value-added product of the Fischer-Tropsch synthetic oil effectively improves the application value of the Fischer-Tropsch synthetic oil, reduces the dependence on petroleum-based products, and has important social and economic benefits.
5. One of the technical problems to be solved by the invention is to provide a novel aluminum foil rolling lubricating oil which can improve the lubricating property of rolling oil and can meet the requirements of the aluminum foil continuous multi-roller unit finish rolling process because the lubricating property of the conventional aluminum foil rolling lubricating oil is not enough to meet the requirements of the aluminum foil continuous multi-roller unit finish rolling process and because the aluminum material is soft, the aluminum foil can reach the thickness of micron grade and the surface is easy to scratch, wrinkle, fracture and the like. The aluminum foil rolling lubricating oil has the characteristics of no phosphorus, good biodegradability and environmental friendliness, and does not influence the surface annealing cleaning performance of the aluminum foil.
Drawings
FIG. 1 is a diagram showing the results of the measurement of the aluminum foil rolling oil according to the present invention.
Detailed Description
The present invention is further illustrated by the following examples, which are intended to be illustrative, not limiting and are not intended to limit the scope of the invention.
The raw materials used in the invention are all conventional commercial products if no special description is provided, the method used in the invention is all conventional methods in the field if no special description is provided, and the mass of all the materials used in the invention is the conventional use mass.
Example 1
The aluminum foil rolling lubricating oil comprises the following components in percentage by mass:
91% of Fischer-Tropsch synthetic light oil, 5% of hexapolyricinoleate, 3% of methyl oleate and 1% of isooctyl acid phosphate ester octadecylamine salt.
Example 2
The aluminum foil rolling lubricating oil comprises the following components in percentage by mass:
88.8 percent of Fischer-Tropsch synthesis light oil, 6 percent of tetrapolyricinoleate, 4 percent of methyl oleate and 1.2 percent of butyl isooctyl phosphate ester dodecylamine salt.
Example 3
The aluminum foil rolling lubricating oil comprises the following components in percentage by mass:
93.2 percent of Fischer-Tropsch synthetic light oil, 4 percent of tetrapolyricinoleate, 2 percent of ethyl oleate and 0.8 percent of fatty alcohol ethoxylated phosphate.
Example 4
The aluminum foil rolling lubricating oil comprises the following components in percentage by mass:
94% of Fischer-Tropsch synthetic light oil, 3% of hexapolyricinoleate, 2% of unsaturated fatty glyceride and 1% of fatty alcohol ethoxylated phosphate.
The above examples 1-4 were prepared by the following method:
(1) weighing base oil, an oiliness agent, a lubricant and an extreme pressure antiwear agent according to the mass ratio;
(2) heating the stirring kettle to 45 ℃, adding Fischer-Tropsch synthetic light oil, starting stirring, then sequentially adding the polyricinoleate agent, the fatty acid ester agent and the extreme pressure antiwear agent, rotating at 80r/min for 120min to obtain the aluminum foil rolling lubricating oil.
The results of the tests related to the aluminum foil rolling oil of the present invention are shown in fig. 1 and table 1.
TABLE 1 Main technical physicochemical indexes of lubricating oil for aluminum foil rolling of the present invention
| Item | Example 1 | Example 2 | Example 3 | Example 4 |
| Kinematic viscosity (40 ℃, mm)2/s) | 1.68 | 1.62 | 1.62 | 1.66 |
| Distillation range (annealing cleanness,. degree.C.) | 235-250 | 235-250 | 235-250 | 235-250 |
| Extreme pressure/N | 425 | 429 | 436 | 438 |
| Lubricity/f | 0.072 | 0.078 | 0.081 | 0.076 |
| Copper corrosion (100 ℃, 3h, grade) | ＜1a | ＜1a | ＜1a | ＜1a |
| Aromatic hydrocarbon content/ppm | 3 | 3 | 3 | 3 |
1. The invention adopts Fischer-Tropsch synthetic oil as base oil, has the advantages of higher alkane content (more than 99.8 percent), less components such as sulfur, aromatic hydrocarbon and the like, narrow distillation range and the like, and endows the processed oil with better annealing detergency than the traditional aluminum foil rolling oil, better surface property after processing and the characteristic of environmental friendliness. (narrower distillation range, less aluminum corrosion, environmental friendly.)
2. The additive is reasonably used, so that the low kinematic viscosity of an oil product is kept, the oil product is endowed with better extreme pressure lubricity, and the speed and the quality of continuous multi-roller rolling of aluminum foil rolling can be effectively ensured. (lower kinematic viscosity, lower coefficient of friction, higher extreme pressure value.)
Although the embodiments of the present invention have been disclosed for illustrative purposes, those skilled in the art will appreciate that: various substitutions, changes and modifications are possible without departing from the spirit and scope of the invention and the appended claims, and therefore the scope of the invention is not limited to the embodiments disclosed.
Claims (7)
1. The aluminum foil rolling lubricating oil is characterized in that: the raw material components and parts by weight are as follows:
base oil: 50-94 parts of Fischer-Tropsch light oil;
lubricant: 2-8 parts of polyricinoleate;
an oiliness agent: 2-12 parts of unsaturated fatty acid ester;
extreme pressure antiwear agent: 0.5-3 parts of fatty alcohol ethoxylated phosphate or amine phosphate.
2. The aluminum foil rolling lubricant according to claim 1, characterized in that: the lubricant is one or more of dinierein, tetrapolyricinoleate and hexapolyricinoleate.
3. The aluminum foil rolling lubricant according to claim 1, characterized in that: the oiliness agent is one or more of methyl oleate, ethyl oleate and unsaturated fatty glyceride.
4. The aluminum foil rolling lubricant according to claim 1, characterized in that: the extreme pressure antiwear agent is one or a mixture of more than one of fatty alcohol ethoxylated phosphate, isooctyl acid phosphate ester octadecylamine salt and butyl isooctyl phosphate ester dodecylamine salt.
5. The aluminum foil rolling lubricant oil according to any one of claims 1 to 4, characterized in that: the base oil is coal liquefied Fischer-Tropsch synthetic light oil, and the component of the base oil is C12～C21Alkane, content > 95%, wherein C12～C13Alkane content > 90%, C14～C21The alkane content is 9-10%.
6. The method for producing the lubricating oil for aluminum foil rolling according to any one of claims 1 to 5, characterized by comprising: the method comprises the following steps:
weighing base oil, an oiliness agent, a lubricant and an extreme pressure antiwear agent according to a mass ratio;
heating the stirring kettle to 40-60 ℃, adding the base oil, starting stirring, then sequentially adding the oiliness agent, the lubricant and the extreme pressure antiwear agent, rotating at the speed of 60-120r/min for 120-150min, and obtaining the aluminum foil rolling lubricating oil.
7. Use of the lubricating oil for aluminum foil rolling according to any one of claims 1 to 5 for aluminum foil rolling.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010459547.3A CN111548847B (en) | 2020-05-27 | 2020-05-27 | Aluminum foil rolling lubricating oil, preparation method and application |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010459547.3A CN111548847B (en) | 2020-05-27 | 2020-05-27 | Aluminum foil rolling lubricating oil, preparation method and application |
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| Publication Number | Publication Date |
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| CN111548847A true CN111548847A (en) | 2020-08-18 |
| CN111548847B CN111548847B (en) | 2022-03-18 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113186020A (en) * | 2021-04-16 | 2021-07-30 | 北京科技大学 | Aluminum product rolling oil taking coal-made oil as base oil and preparation method thereof |
| CN113634607A (en) * | 2021-07-01 | 2021-11-12 | 乳源东阳光优艾希杰精箔有限公司 | Aluminum foil rolling mill rolling oil and application thereof in preparation of aluminum foil |
| CN115651741A (en) * | 2022-10-21 | 2023-01-31 | 中海泰州特种油科技有限公司 | Lubricating oil for rolling aluminum plate and aluminum foil and preparation method thereof |
| CN116554948A (en) * | 2023-05-16 | 2023-08-08 | 清华大学天津高端装备研究院 | Deep hole drilling oil with low viscosity and preparation method thereof |
| CN116568783A (en) * | 2020-12-15 | 2023-08-08 | 道达尔能量联动技术公司 | Use of alcohol ethoxylated phosphate compounds in lubricating compositions for preventing corrosion and/or fretting corrosion of internal combustion engine metal parts |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000119679A (en) * | 1998-10-20 | 2000-04-25 | Nippon Mitsubishi Oil Corp | Cold rolling oil composition for aluminum foil |
| JP2008201951A (en) * | 2007-02-21 | 2008-09-04 | Showa Denko Packaging Co Ltd | Lubricant for aluminum foil press molding and method for producing container by using the lubricant |
| CN102229843A (en) * | 2011-05-30 | 2011-11-02 | 石家庄新泰特种油有限公司 | Aluminum rolling oil additive composition |
| CN102977974A (en) * | 2011-09-02 | 2013-03-20 | 中国石油化工股份有限公司 | Hot rolling lubricating oil composition and use thereof |
| CN102994194A (en) * | 2012-12-24 | 2013-03-27 | 彭美东 | Synthetic multiple-effect lubricant additive and preparation method thereof |
| CN103589491A (en) * | 2013-11-29 | 2014-02-19 | 广州机械科学研究院有限公司 | Lubricating material for cold rolling and its preparation method and use |
| CN104293443A (en) * | 2014-09-24 | 2015-01-21 | 中国石油化工股份有限公司 | Rolling emulsified oil composition and application thereof |
| CN105296117A (en) * | 2015-11-26 | 2016-02-03 | 上海帕卡兴产化工有限公司 | Environment-friendly low-odor rolling oil and preparation method thereof |
| CN105925342A (en) * | 2016-04-27 | 2016-09-07 | 中铝润滑科技有限公司 | Aluminum cold rolling composite extreme pressure additive and application thereof |
| CN106010748A (en) * | 2016-05-18 | 2016-10-12 | 安徽省安庆市金誉金属材料有限公司 | High-quality aluminum foil rolling oil |
| CN108774568A (en) * | 2018-05-25 | 2018-11-09 | 清华大学天津高端装备研究院 | A kind of semi-synthetic aluminium alloy working fluid and preparation method thereof |
| CN110846104A (en) * | 2019-11-25 | 2020-02-28 | 上海森帝润滑技术有限公司 | Aluminum plate and foil rolling additive composition |
-
2020
- 2020-05-27 CN CN202010459547.3A patent/CN111548847B/en active Active
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2000119679A (en) * | 1998-10-20 | 2000-04-25 | Nippon Mitsubishi Oil Corp | Cold rolling oil composition for aluminum foil |
| JP2008201951A (en) * | 2007-02-21 | 2008-09-04 | Showa Denko Packaging Co Ltd | Lubricant for aluminum foil press molding and method for producing container by using the lubricant |
| CN102229843A (en) * | 2011-05-30 | 2011-11-02 | 石家庄新泰特种油有限公司 | Aluminum rolling oil additive composition |
| CN102977974A (en) * | 2011-09-02 | 2013-03-20 | 中国石油化工股份有限公司 | Hot rolling lubricating oil composition and use thereof |
| CN102994194A (en) * | 2012-12-24 | 2013-03-27 | 彭美东 | Synthetic multiple-effect lubricant additive and preparation method thereof |
| CN103589491A (en) * | 2013-11-29 | 2014-02-19 | 广州机械科学研究院有限公司 | Lubricating material for cold rolling and its preparation method and use |
| CN104293443A (en) * | 2014-09-24 | 2015-01-21 | 中国石油化工股份有限公司 | Rolling emulsified oil composition and application thereof |
| CN105296117A (en) * | 2015-11-26 | 2016-02-03 | 上海帕卡兴产化工有限公司 | Environment-friendly low-odor rolling oil and preparation method thereof |
| CN105925342A (en) * | 2016-04-27 | 2016-09-07 | 中铝润滑科技有限公司 | Aluminum cold rolling composite extreme pressure additive and application thereof |
| CN106010748A (en) * | 2016-05-18 | 2016-10-12 | 安徽省安庆市金誉金属材料有限公司 | High-quality aluminum foil rolling oil |
| CN108774568A (en) * | 2018-05-25 | 2018-11-09 | 清华大学天津高端装备研究院 | A kind of semi-synthetic aluminium alloy working fluid and preparation method thereof |
| CN110846104A (en) * | 2019-11-25 | 2020-02-28 | 上海森帝润滑技术有限公司 | Aluminum plate and foil rolling additive composition |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116568783A (en) * | 2020-12-15 | 2023-08-08 | 道达尔能量联动技术公司 | Use of alcohol ethoxylated phosphate compounds in lubricating compositions for preventing corrosion and/or fretting corrosion of internal combustion engine metal parts |
| CN113186020A (en) * | 2021-04-16 | 2021-07-30 | 北京科技大学 | Aluminum product rolling oil taking coal-made oil as base oil and preparation method thereof |
| CN113634607A (en) * | 2021-07-01 | 2021-11-12 | 乳源东阳光优艾希杰精箔有限公司 | Aluminum foil rolling mill rolling oil and application thereof in preparation of aluminum foil |
| CN113634607B (en) * | 2021-07-01 | 2023-09-22 | 乳源东阳光优艾希杰精箔有限公司 | Rolling oil of aluminum foil rolling mill and application of rolling oil in aluminum foil preparation |
| CN115651741A (en) * | 2022-10-21 | 2023-01-31 | 中海泰州特种油科技有限公司 | Lubricating oil for rolling aluminum plate and aluminum foil and preparation method thereof |
| CN115651741B (en) * | 2022-10-21 | 2024-03-26 | 中海泰州特种油科技有限公司 | Lubricating oil for aluminum plate aluminum foil rolling and preparation method thereof |
| CN116554948A (en) * | 2023-05-16 | 2023-08-08 | 清华大学天津高端装备研究院 | Deep hole drilling oil with low viscosity and preparation method thereof |
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