CN111533516A - Self-leveling mortar and foamed ceramic surface hole sealing decoration method - Google Patents

Self-leveling mortar and foamed ceramic surface hole sealing decoration method Download PDF

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CN111533516A
CN111533516A CN202010254248.6A CN202010254248A CN111533516A CN 111533516 A CN111533516 A CN 111533516A CN 202010254248 A CN202010254248 A CN 202010254248A CN 111533516 A CN111533516 A CN 111533516A
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parts
mortar
foamed ceramic
self
agent
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张国涛
冯红坚
杨景琪
胡杰
江峰
邓仕豪
聂新超
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Foshan Jinyi Green Energy New Material Technology Co ltd
Guangdong Golden Green Energy Technology Co ltd
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Foshan Jinyi Green Energy New Material Technology Co ltd
Guangdong Golden Green Energy Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/06Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • C04B41/5079Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5076Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
    • C04B41/508Aluminous cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • C04B2111/00508Cement paints
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/60Flooring materials
    • C04B2111/62Self-levelling compositions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/20Mortars, concrete or artificial stone characterised by specific physical values for the density
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

The invention discloses a self-leveling mortar and foamed ceramic surface hole sealing decoration method, and relates to the technical field of ceramic decoration. The mortar comprises the following raw materials in parts by weight: portland cement: 30-35 parts of aluminate cement: 0-5 parts of fine powder aggregate by polishing: 45-60 parts of assistant, 15-37 parts of leveling agent: 0.2-3 parts; wherein the polishing and grinding fine powder aggregate comprises at least one of foamed ceramic fine powder or ceramic tile polishing slag. The foamed ceramic fine powder or the tile polishing slag in the raw materials of the self-leveling mortar are polishing fine powder generated in daily process production, so that the production cost can be saved by using the self-leveling mortar prepared from the foamed ceramic fine powder or the tile polishing slag. Meanwhile, the reasonable proportion and use of the portland cement, the aluminate cement, the polishing and grinding fine powder aggregate, the auxiliary agent and the leveling agent enable the foamed ceramic to have the characteristics of good fluidity, strong binding performance and excellent compression and freeze resistance, and the hole sealing decoration can be quickly and effectively carried out on the surface of the foamed ceramic, so that the decoration effect is improved.

Description

Self-leveling mortar and foamed ceramic surface hole sealing decoration method
Technical Field
The invention relates to the technical field of ceramic decoration, in particular to a self-leveling mortar and foamed ceramic surface hole sealing decoration method.
Background
At present, the peeling process of the post-processing surface (bottom surface) of the foamed ceramic mostly adopts a grinding disc mode or a scraper leveling process to grind the surface of the plate, thereby achieving the purpose of leveling the surface of the plate. Moreover, the polishing process of the ceramic tiles is also carried out by adopting a grinding disc mode, and a large amount of fine powder is generated. A large amount of ground powder can be applied to the normal production of foamed ceramics after being subjected to filter pressing, the fine powder has no viscosity due to high-temperature firing, the using amount is controlled to be 50-60 percent (the total amount of the fine powder and the polishing slag of the foamed ceramics), the residual 40 percent of the fine powder can replace river sand to be used as aggregate of the cement-based cementing material, but the additional value is limited.
The surface of the foamed ceramic is mostly in a porous open state (the surface layer is opened due to machining, and the internal structure is closed pores), and the next process operation can be performed by firstly closing open pores into a flat surface for the purpose of surface decoration, so far, the mainstream surface decoration process is roughly as follows: putty scraping, cement mortar plastering, tile pasting, real stone paint spraying, artistic coating and the like. In the implementation process of the processes, surface holes are difficult to seal flat quickly, a large number of pinholes are left on the surface to influence the decoration effect, and a large amount of materials are needed even if the surface is sealed flat, so that the construction cost is high.
In view of this, the invention is particularly proposed.
Disclosure of Invention
The invention aims to provide self-leveling mortar, which utilizes polishing fine powder aggregate as a main raw material for preparation, can save production cost, has the characteristics of good fluidity, strong bonding performance and excellent compression and freeze resistance through reasonable proportioning and use of portland cement, aluminate cement, polishing fine powder aggregate, an auxiliary agent and a leveling agent, and can quickly and effectively carry out hole sealing decoration on the surface of foamed ceramic and improve the decoration effect.
The invention also aims to provide a method for hole sealing decoration of the surface of the foamed ceramic, which utilizes the self-leveling mortar to carry out hole sealing decoration, can quickly and effectively carry out hole sealing decoration on the surface of the foamed ceramic, and improves the decoration effect.
The invention is realized by the following steps:
in a first aspect, the invention provides self-leveling mortar, which comprises the following raw materials in parts by mass:
portland cement: 30-35 parts of aluminate cement: 0-5 parts of fine powder aggregate by polishing: 45-60 parts of assistant, 15-37 parts of leveling agent: 0.2-3 parts;
wherein the fine polishing powder aggregate comprises at least one of foamed ceramic fine powder or ceramic tile polishing slag.
In an alternative embodiment, the fine foamed ceramic powder is obtained by grinding a surface peeling grinding disc of a foamed ceramic plate, and the average particle size of the fine foamed ceramic powder is 85.535 micrometers, D50-76.686 micrometers and D97-205.900 micrometers; and the fine powder of the foamed ceramic comprises SiO in terms of mass fraction2: 70-71 parts of Al2O3: 15-16 parts of Fe2O3: 1-2 parts of TiO2: 0.1-0.4 part of CaO: 1-2 parts of MgO: 3-4 parts of, K2O: 1-2 parts of Na2O: 3-4 parts, L.O.I: 0.05-0.1 part;
the ceramic tile polishing slag is obtained by filter pressing of wastewater of a polishing process for producing ceramic glazed tiles, and the average fineness of powder is 325 meshes; and isThe fine powder of the foamed ceramic comprises SiO in terms of mass fraction2:60-63,AL2O3:18-19,Fe2O3:0.5-1,TiO2:0.1-0.2,CaO:5-6,MgO:1-2,K2O:2-3,Na2O: 2-3, L.O.I: 2-3 parts.
In an alternative embodiment, the aluminate cement includes AL in mass fraction2O3: 50-53 parts of SiO2: 6-7 parts of Fe2O3: 2-3 parts of a solvent; and the specific surface area S of the aluminate cement is as follows: 433m2Kg, initial/final setting time: 126/252min, flexural strength 1d/3 d: 10.7/11.7MPa, compressive strength 1d/3 d: 73.8/83.3 MPa.
In an alternative embodiment, the leveling agent includes one or more of dodecafluoroheptyl methacrylate, perfluoroalkylethyl acrylate, propylene glycol methyl ether acetate, a solvent, and azobisisobutyronitrile.
In an alternative embodiment, the auxiliary agent comprises the following raw materials in parts by mass:
exciting agent: 1-5 parts, mineral powder: 8-12 parts of a thickening agent: 0.1-0.5 part, early strength agent: 0.5-1.0 part of retarder: 0.5-1.0 part of swelling agent: 0.3-0.5 part of water reducing agent: 0.1-0.3 part, defoaming agent: 0.1-0.3 parts and dispersible latex: 5-15 parts.
In an alternative embodiment, the excitant comprises one or more of lime, cement clinker, gypsum, phosphogypsum and fluorgypsum;
the mineral powder comprises one or more of fly ash, water granulated slag and silicon powder;
the thickening agent comprises one or more of hydroxypropyl methyl cellulose ether, starch ether, methyl cellulose, hydroxyethyl methyl cellulose ether and hydroxypropyl methyl cellulose;
the early strength agent comprises one or more of aluminum sulfate, lithium carbonate and calcium formate;
the retarder comprises one or more of sodium gluconate, tartaric acid and citric acid;
the expanding agent comprises aluminum sulfate or a compound thereof;
the water reducing agent comprises a high-performance water reducing agent;
the defoaming agent comprises an organic silicon defoaming agent or a higher fatty acid defoaming agent;
the dispersible latex comprises one or more of vinyl acetate-ethylene copolymer rubber powder, ethylene-polyvinyl chloride-vinyl laurate ternary copolymer rubber powder, ethyl acetate-ethylene-higher fatty acid vinyl ester ternary copolymer rubber powder, vinyl acetate-higher fatty acid copolymer rubber powder, acrylate-styrene copolymer rubber powder, vinyl acetate-acrylate-higher fatty acid ternary copolymer rubber powder, vinyl acetate homopolymerization rubber powder and styrene-butadiene copolymer rubber powder.
In an alternative embodiment, the excitant is phosphogypsum; and the phosphogypsum comprises SiO in percentage by mass2: 6.7-6.88 parts of Al2O3: 1.54-2.24 parts of Fe2O3: 0.14 to 0.18 portion of TiO2: 0.03-0.04 parts of MgO: 0.04-0.07 part of K2O: 0.07 part of Na2O: 0.03 part, l.o.i: 6.53-7.72 parts;
the mineral powder is fly ash, and the fly ash comprises SiO calculated according to mass fraction2: 49-50 parts of Al2O3: 38-39 parts of Fe2O3: 1-2 parts of TiO2: 0.03-0.04 parts of CaO: 2-4 parts of MgO: 0.4-0.5 part, K2O: 0.5-0.6 part of Na2O: 0.05-0.07 parts, L.O.I: 2-3 parts of a solvent;
the thickening agent is hydroxypropyl methyl cellulose with 20 ten thousand of viscosity;
the early strength agent is calcium formate;
the retarder is tartaric acid;
the expanding agent comprises aluminum sulfate, the fineness of the aluminum sulfate is 0.08mm, and the fineness is less than 10 percent after 100 meshes;
the defoaming agent is an organic silicon defoaming agent.
In a second aspect, the invention provides a method for hole sealing decoration of a foamed ceramic surface, comprising the following steps:
dry-mixing the portland cement, the aluminate cement, the polishing and grinding fine powder aggregate and the auxiliary agent of the self-leveling mortar to obtain dry-mixed mortar; mixing the dry-mixed mortar and the flatting agent to obtain self-leveling mortar; spraying self-leveling mortar on the surface of the foamed ceramic, and naturally curing after uniformly blowing the mortar;
or,
dry-mixing the portland cement, the aluminate cement, the polishing and grinding fine powder aggregate and the auxiliary agent of the self-leveling mortar to obtain dry-mixed mortar; adjusting the dry-mixed mortar into paste, printing the paste on the surface of the foamed ceramic by adopting a screen printing mode, adding the dry-mixed mortar into a flatting agent to obtain self-leveling mortar, spraying the self-leveling mortar on the surface of the foamed ceramic, and naturally curing the self-leveling mortar after uniformly blowing the mortar.
In an alternative embodiment, the method further comprises: and polishing the surface of the naturally cured foamed ceramic, and polishing the surface by using 500-sand-paper 1000 meshes to remove surface nails or impurities.
In an optional embodiment, a large-caliber elastic coating spray gun with the caliber of 4-6mm is adopted in the spraying step, the spraying air pressure is 0.5-0.8MPa, and the thickness is controlled to be less than 3 mm; the step of uniformly blowing and smearing the mortar adopts a sawtooth type scraper or airflow, the tooth pitch of the sawtooth type scraper is 2-3mm, and the airflow is controlled to be less than or equal to 0.5 Mpa.
Embodiments of the invention have at least the following advantages or benefits:
the embodiment of the invention provides self-leveling mortar which comprises the following raw materials in parts by mass: portland cement: 30-35 parts of aluminate cement: 0-5 parts of fine powder aggregate by polishing: 45-60 parts of assistant, 15-37 parts of leveling agent: 0.2-3 parts; wherein the polishing and grinding fine powder aggregate comprises any one of foamed ceramic fine powder or ceramic tile polishing slag. The foamed ceramic fine powder or the tile polishing slag in the raw materials of the self-leveling mortar are polishing fine powder generated in daily process production, so that the production cost can be saved by using the self-leveling mortar prepared from the foamed ceramic fine powder or the tile polishing slag. Meanwhile, the reasonable proportion and use of the portland cement, the aluminate cement, the polishing and grinding fine powder aggregate, the auxiliary agent and the leveling agent enable the foamed ceramic to have the characteristics of good fluidity, strong binding performance and excellent compression and freeze resistance, and the hole sealing decoration can be quickly and effectively carried out on the surface of the foamed ceramic, so that the decoration effect is improved.
The embodiment of the invention also provides a hole sealing decoration method for the surface of the foamed ceramic, which utilizes the self-leveling mortar to carry out hole sealing decoration, can quickly and effectively carry out hole sealing decoration on the surface of the foamed ceramic, and improves the decoration effect.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings needed to be used in the embodiments will be briefly described below, it should be understood that the following drawings only illustrate some embodiments of the present invention and therefore should not be considered as limiting the scope, and for those skilled in the art, other related drawings can be obtained according to the drawings without inventive efforts.
FIG. 1 is a powder particle size analysis diagram of fine foamed ceramic powder produced by grinding a surface peeling disc of a foamed ceramic plate provided in an embodiment of the present invention;
fig. 2 is a flow chart of a preparation process of the self-leveling mortar provided by the embodiment of the invention;
fig. 3 is a process flow chart of the hole sealing decoration on the surface of the foamed ceramic according to the embodiment of the present invention.
Detailed Description
In order to make the objects, technical solutions and advantages of the embodiments of the present invention clearer, the technical solutions in the embodiments of the present invention will be clearly and completely described below. The examples, in which specific conditions are not specified, were conducted under conventional conditions or conditions recommended by the manufacturer. The reagents or instruments used are not indicated by the manufacturer, and are all conventional products available commercially.
The features and properties of the present invention are described in further detail below with reference to examples.
The embodiment of the invention provides self-leveling mortar which comprises the following raw materials in parts by mass: portland cement: 30-35 parts of aluminate cement: 0-5 parts of fine powder aggregate by polishing: 45-60 parts of assistant, 15-37 parts of leveling agent: 0.2-3 parts; wherein the fine polishing powder aggregate comprises any one of foamed ceramic fine powder or ceramic tile polishing slag.
In detail, the Portland cement is specifically selected to be ordinary Portland cement which is used as an inorganic cementing material and can be naturally cured to improve the strength of the product. Meanwhile, based on the principle of cement selection, the embodiment of the invention specifically adopts P.042.5 common Portland cement as local cement in the three-water area of the Foshan, and the 28-day strength is 56.6 Mpa.
In detail, the aluminate cement specifically comprises Al in terms of mass fraction2O3: 50-53 parts of SiO2: 6-7 parts of Fe2O3: 2-3 parts. Optionally, AL2O3: 52.99 parts of SiO2: 6.03 parts of Fe2O3: 2.08 parts. And the specific surface area S of the aluminate cement is as follows: 433m2Kg, initial/final setting time: 126/252min, flexural strength 1d/3 d: 10.7/11.7MPa, compressive strength 1d/3 d: 73.8/83.3 MPa. The aluminate cement has high early strength, stable long-term strength and good low-temperature hardening performance, and can effectively ensure the compressive and flexural strength of the self-leveling mortar.
In detail, the foamed ceramic fine powder is obtained by grinding a surface peeling and grinding disc of a foamed ceramic plate, and the average particle size of the powder is 85.535 micrometers, D50 is 76.686 micrometers, and D97 is 205.900 micrometers; and the fine powder of the foamed ceramic comprises SiO in terms of mass fraction2: 70-71 parts of Al2O3: 15-16 parts of Fe2O3: 1-2 parts of TiO2: 0.1-0.4 part of CaO: 1-2 parts of MgO: 3-4 parts of, K2O: 1-2 parts of Na2O: 3-4 parts, L.O.I: 0.05 to 0.1 portion, and the embodiment of the invention specifically adopts the aggregate components shown in the following table 1, and the powder particle size is shown in figure 1.
TABLE 1 analysis of the ingredients
Figure BDA0002436670400000061
In detail, the tile polishing slag is obtained by filter pressing the wastewater of the polishing process for producing the porcelain glazed tile, and the average fineness of the powder is 325 meshes; and the fine powder of the foamed ceramic comprises SiO in terms of mass fraction2:60-63,AL2O3:18-19,Fe2O3:0.5-1,TiO2:0.1-0.2,CaO:5-6,MgO:1-2,K2O:2-3,Na2O: 2-3, L.O.I: 2-3 parts, and the aggregate components of table 2 below are specifically adopted in the examples of the present invention.
TABLE 2 analysis of the ingredients
Figure BDA0002436670400000071
The foamed ceramic fine powder or the tile polishing slag in the raw materials of the self-leveling mortar are polishing fine powder generated in daily process production, so that the production cost can be saved by using the self-leveling mortar prepared from the foamed ceramic fine powder or the tile polishing slag. Meanwhile, the Mohs hardness of the used foamed ceramic fine powder is 6-7 grades (the Mohs hardness of the polishing slag powder is different between 5-7 grades), and after the cement dry-mixed leveling mortar prepared by adopting the scheme is naturally cured, the hardness of the plate can be greatly improved. In addition, unreacted SiC is contained in the fine powder, and the SiC is a high-hardness material, so that the wear resistance of the surface of the decorative plate can be improved. In addition, it should be noted that the embodiment of the present invention mainly uses the foamed ceramic fine powder, and certainly, in other embodiments, the polishing slag may be completely or partially substituted for the foamed ceramic fine powder, and the embodiment of the present invention is not limited.
In detail, the auxiliary agent comprises the following raw materials in percentage by mass: exciting agent: 1-5 parts, mineral powder: 8-12 parts of a thickening agent: 0.1-0.5 part, early strength agent: 0.5-1.0 part of retarder: 0.5-1.0 part of swelling agent: 0.3-0.5 part of water reducing agent: 0.1-0.3 part, defoaming agent: 0.1-0.3 parts and dispersible latex: 5-15 parts. Correspondingly, the raw material formula of the whole self-leveling mortar can be determined as follows: 42.5 ordinary portland cement: 30-35, aluminate cement: 0-5 parts of foamed ceramic fine powder (polishing slag): 45-60 parts of an exciting agent: 1-5 parts, mineral powder: 8-12 parts of a thickening agent: 0.1-0.5 part, early strength agent: 0.5-1.0 part of retarder: 0.5-1.0 part of swelling agent: 0.3-0.5 part of water reducing agent: 0.1-0.3 part, defoaming agent: 0.1-0.3 parts, dispersible latex: 5-15 parts of leveling agent and 0.2-3 parts of leveling agent.
The exciting agent is one or more of lime, cement clinker, gypsum, phosphogypsum and fluorgypsum, the phosphogypsum tailings in southeast Guizhou area are used in the experimental scheme, and the sample numbers and corresponding components are shown in the following table 3.
TABLE 3 analysis of the ingredients
Sample numbering SiO2 AL2O3 Fe2O3 TiO2 MgO K2O Na2O L.O.I
Phosphogypsum-1 6.70 1.54 0.14 0.03 0.04 0.07 0.03 6.53
Phosphogypsum-2 6.88 2.24 0.18 0.04 0.07 0.07 0.03 7.72
The mineral powder is one or a mixture of more of fly ash, water granulated slag and silicon powder, and the fly ash is used for testing in the experiment; the fly ash uses Shanxi Jincheng grade I fly ash, the fineness of the fly ash is 43 microns (about 320 meshes, the density is 2.4g/cm3), the fineness of the fly ash is stable, the activity of the fly ash in 28 days is better, and the fluidity of mortar and the compactness after hardening can be increased under the micro-aggregate effect and the shape effect of the fly ash. In addition, the volcanic ash effect of the fly ash can react with the cement hydration product calcium hydroxide to generate hydrated calcium silicate, so that the later strength is increased.
It should be noted that, in the embodiment of the present invention, the fly ash includes SiO in terms of mass fraction2: 49-50 parts of Al2O3: 38-39 parts of Fe2O3: 1-2 parts of TiO2: 0.03-0.04 parts of CaO: 2-4 parts of MgO: 0.4-0.5 part, K2O: 0.5-0.6 part of Na2O: 0.05-0.07 parts, L.O.I: 2-3 parts. And in particular in the examples the amounts and ingredients in table 4 below may be selected.
TABLE 4 analysis of the components
Sample numbering SiO2 AL2O3 Fe2O3 TiO2 CaO MgO K2O Na2O L.O.I
Fly ash 49.49 38.51 3.81 1.1 3.73 0.46 0.57 0.06 2.19
Wherein the thickening agent comprises one or more of hydroxypropyl methyl cellulose ether, starch ether, methyl cellulose, hydroxyethyl methyl cellulose ether and hydroxypropyl methyl cellulose. The thickening agent can be combined with water to generate low-viscosity gel, the viscosity of cement is increased, the mortar has stronger surface tension, the shrinkage cracking of the mortar is prevented, and the thickening agent has the characteristics of thickening, bonding, dispersing, emulsifying, film forming adsorption, gelling, mortar settlement improvement and the like. The examples of the present invention used primarily hydroxypropyl methylcellulose (HMPC20s), 20 thousand viscosity.
The early strength agent includes one or more of aluminum sulfate, lithium carbonate and calcium formate, in the embodiment of the present invention, calcium formate is specifically used as the early strength agent, and other embodiments may be selected according to requirements. The retarder comprises one or more of sodium gluconate, tartaric acid and citric acid. Embodiments of the invention specifically use tartaric acid.
It is to be noted that, the retarder, the early strength agent and the thickener are used in combination to adjust the bonding speed and the surface viscosity of the mortar, and the purpose is as follows:
A. the surface of the foamed ceramic plate is in an open porous state, and after the mortar is coated on the surface, gas in pores can be extruded out, so that pinholes in the mortar are exhausted, and the pinholes need to be repaired by strong surface tension; B. the retarder can effectively relieve the solidification process of the mortar, help harmful gas in the holes on the surface of the plate to be discharged, and improve the self-leveling surface effect of the mortar; C. the capillary action of the board and mortar can strengthen the bond between the board and mortar, but requires a slow time course, and therefore a retarder is required to relieve the setting so that the fluidity of the board and mortar is not lost in 30 minutes.
Wherein the expanding agent comprises aluminum sulfate or a compound thereof. The expanding agent can improve the compactness of the mortar, generate a proper amount of reverse expansion to overcome the drying shrinkage of the mortar and prevent cracking, and has the fineness of 0.08mm and the fineness of less than 10 percent of a 100-mesh sieve.
Wherein the water reducing agent comprises a high-performance water reducing agent; the water reducing agent can keep high fluidity of the mortar under the condition of low water-cement ratio, and can improve certain strength.
Wherein the defoaming agent comprises an organic silicon defoaming agent or a higher fatty acid defoaming agent. The defoaming agent is used for eliminating harmful bubbles generated in slurry stirring and gas generated in the coating process and leveling the hardened surface, and is generally an organic silicon or higher fatty acid defoaming agent.
Wherein the dispersible latex comprises one or more of vinyl acetate-ethylene copolymer rubber powder, ethylene-polyvinyl chloride-vinyl laurate ternary copolymer rubber powder, ethyl acetate-ethylene-higher fatty acid vinyl ester ternary copolymer rubber powder, vinyl acetate-higher fatty acid copolymer rubber powder, acrylate-styrene copolymer rubber powder, vinyl acetate-acrylate-higher fatty acid ternary copolymer rubber powder, vinyl acetate homopolymerization rubber powder and styrene-butadiene copolymer rubber powder. The dispersible latex powder can improve the following characteristics of the mortar: 1. the bending strength and the breaking strength of the mortar are improved; 2. the bonding degree and the cohesion of the mortar are improved; 3. the impact resistance, durability and corrosion resistance of the mortar are improved; 4. the corrosion resistance and the freeze-thaw property of the mortar are improved, and the mortar is prevented from cracking; 5. the hydrophobicity is improved, and the water absorption rate is reduced; 6. the workability of the construction mortar is improved.
In detail, the leveling agent comprises one or more of dodecafluoroheptyl methacrylate, perfluoroalkyl ethyl acrylate, propylene glycol methyl ether acetate, a solvent and azobisisobutyronitrile. The embodiment of the invention specifically uses polyether modified polydimethylsiloxane, has high activity, can quickly and effectively reduce the surface tension of a water-based system, improves the spreading capacity, improves the leveling, fluidity and substrate wetting performance, and prevents the generation of shrinkage cavity, and the basic performance of the polyether modified polydimethylsiloxane is shown in the following table 5:
TABLE 5 analysis of the ingredients
Figure BDA0002436670400000101
The self-leveling mortar provided by the embodiment of the invention has the characteristics of good fluidity, strong bonding performance and excellent compression and freeze resistance through reasonable proportioning and use of the portland cement, the aluminate cement, the polishing fine powder aggregate, the assistant and the leveling agent, and can be used for quickly and effectively sealing and decorating the surface of the foamed ceramic to improve the decoration effect.
Referring to fig. 2, the preparation process of the self-leveling mortar will be described in detail.
In the process of preparing the self-leveling mortar, raw material treatment, material proportioning, material mixing homogenization and sealing packaging are sequentially carried out. The raw material treatment can be carried out by selecting a treatment method according to raw material requirements, and the steps of mixing and blending are carried out according to formula requirements, then the mixture is fed into blending equipment to be fully homogenized to obtain dry-mixed mortar, namely, portland cement, aluminate cement, polishing and grinding fine powder aggregate and an auxiliary agent of the self-leveling mortar are dry-mixed to obtain the dry-mixed mortar, and the dry-mixed mortar is packaged in a sealing mode, namely, the dry-mixed mortar is dried, sealed and stored. The self-leveling mortar can be prepared by adding the leveling agent in the hole sealing and decoration stages of the dry mortar, and is simple, convenient and high in preparation efficiency.
It should be noted that, when the dry-mixed mortar is subjected to size mixing, the addition amount is controlled to be 35-40%, and the leveling agent is added according to the proportion, so that reasonable correction can be performed according to the production requirements of plate hole sealing, and the embodiment of the invention is not limited.
Referring to fig. 3, an embodiment of the present invention further provides a method for hole sealing decoration of a foamed ceramic surface, which mainly includes the steps of dry mortar preparation, mortar distribution, board spraying, leveling by a scraper, leveling and curing, surface polishing, surface decoration, static drying, finished product trimming, and the like.
Wherein the preparation of the dry-mixed mortar comprises the step of dry-mixing the portland cement, the aluminate cement, the polishing and grinding fine powder aggregate and the auxiliary agent of the self-leveling mortar to obtain the dry-mixed mortar. The water-distributed mortar comprises the step of mixing the dry-mixed mortar with the flatting agent to obtain the self-leveling mortar. The spraying of the panel includes spraying a self-leveling mortar to the surface of the foamed ceramic. The scraper leveling comprises the step of uniformly blowing and smearing the mortar by adopting a sawtooth type scraper, wherein the tooth pitch of the sawtooth type scraper is 2-3mm, and certainly, in other embodiments, the mortar can be leveled by adopting air flow, and the air flow is controlled to be less than or equal to 0.5 Mpa. The leveling solidification is the natural solidification after the mortar is evenly blown and smeared.
In other embodiments, the self-leveling mortar may be obtained by dry-mixing portland cement, aluminate cement, fine-ground polishing aggregate, and an auxiliary agent; and then adjusting the dry-mixed mortar into a paste shape, printing the paste on the surface of the foamed ceramic by adopting a screen printing mode, adding the dry-mixed mortar into a flatting agent to obtain self-leveling mortar, spraying the self-leveling mortar on the surface of the foamed ceramic, and naturally curing the mortar after uniformly blowing and smearing the mortar to obtain the foamed ceramic surface with better surface effect. Wherein, the silk-screen printing is to print on the surface of the foamed ceramic plate by adopting a 60-80 mesh screen in a silk-screen printing mode. Meanwhile, through the arrangement of printing and spraying, the use amount of mortar can be reduced, and the amount of the mortar entering surface holes is reduced; the printing silk screen can be designed into patterns with certain patterns to form relief-shaped patterns, so that the bare concrete surface relief effect is achieved.
It should be further noted that the surface polishing and the surface decoration are implemented by naturally curing the dry-mixed mortar for 10H, then performing surface polishing, and polishing the surface with 500-mesh and 1000-mesh sand paper to remove surface nails or impurities for facilitating later-stage decoration by other processes.
The following description will be given with reference to specific examples.
Examples 1 to 5
The following experiments are carried out for comparison by taking the provided dry powder mortar formula (unit is g), and the foamed ceramic wallboard is taken as a base material to trial prepare the hole sealing plate, wherein the density of a bare board is 350kg/m3, the compressive strength is 5.25MPa, the breaking strength is 2.03MPa, the apparent aperture is 0.5-1.5mm, and the drying shrinkage is 0.02%. The specific experiments are as follows in table 6:
TABLE 6 Experimental parameters
Figure BDA0002436670400000121
Figure BDA0002436670400000131
The table data shows that the dry-mixed mortar prepared by the process has good fluidity, strong associativity with a foamed ceramic plate, no cracking and no falling, the compressive strength of the plate is more than 6.35MPa, the compressive strength of the plate is improved by 2-4 times of that of a bare plate, the surface is smooth, the decoration of later-stage decoration such as emulsion paint, a film (wallpaper or an organic film) and artistic paint is convenient, the frost resistance is good, and the dry-mixed mortar does not crack and does not delaminate after being frozen and thawed for 25 times.
In conclusion, the self-leveling mortar provided by the embodiment of the invention utilizes the polishing fine powder aggregate as the main raw material for preparation, can save the production cost, and simultaneously has the characteristics of good fluidity, strong bonding performance and excellent compression and freeze resistance through reasonable proportioning and use of the portland cement, the aluminate cement, the polishing fine powder aggregate, the auxiliary agent and the leveling agent, and can quickly and effectively carry out hole sealing decoration on the surface of the foamed ceramic, thereby improving the decoration effect. According to the hole sealing decoration method for the surface of the foamed ceramic, provided by the embodiment of the invention, hole sealing decoration is performed by using the self-leveling mortar, so that hole sealing decoration can be rapidly and effectively performed on the surface of the foamed ceramic, and the decoration effect is improved.
The above description is only a preferred embodiment of the present invention and is not intended to limit the present invention, and various modifications and changes may be made by those skilled in the art. Any modification, equivalent replacement, or improvement made within the spirit and principle of the present invention should be included in the protection scope of the present invention.

Claims (10)

1. The self-leveling mortar is characterized by comprising the following raw materials in parts by weight:
portland cement: 30-35 parts of aluminate cement: 0-5 parts of fine powder aggregate by polishing: 45-60 parts of assistant, 15-37 parts of leveling agent: 0.2-3 parts;
wherein the polishing and grinding fine powder aggregate comprises at least one of foamed ceramic fine powder or ceramic tile polishing slag.
2. The self-leveling mortar of claim 1, wherein:
the fine foamed ceramic powder is obtained by grinding a peeling grinding disc on the surface of a foamed ceramic plate, and the average particle size of the fine foamed ceramic powder is 85.535 micrometers, D50-76.686 micrometers and D97-205.900 micrometers; and the fine powder of the foamed ceramic comprises SiO in terms of mass fraction2: 70-71 parts of Al2O3: 15-16 parts of Fe2O3: 1-2 parts of TiO2: 0.1-0.4 part of CaO: 1-2 parts of MgO: 3-4 parts of, K2O: 1-2 parts of Na2O: 3-4 parts, L.O.I: 0.05-0.1 part;
the ceramic tile polishing slag is wastewater from the polishing process for producing ceramic glazed tilesFilter pressing to obtain powder with the average fineness of 325 meshes; and the fine powder of the foamed ceramic comprises SiO in terms of mass fraction2:60-63,AL2O3:18-19,Fe2O3:0.5-1,TiO2:0.1-0.2,CaO:5-6,MgO:1-2,K2O:2-3,Na2O: 2-3, L.O.I: 2-3 parts.
3. The self-leveling mortar of claim 1, wherein:
the aluminate cement comprises Al in mass fraction2O3: 50-53 parts of SiO2: 6-7 parts of Fe2O3: 2-3 parts of a solvent; and the specific surface area S of the aluminate cement is as follows: 433m2Kg, initial/final setting time: 126/252min, flexural strength 1d/3 d: 10.7/11.7MPa, compressive strength 1d/3 d: 73.8/83.3 MPa.
4. The self-leveling mortar of claim 1, wherein:
the leveling agent comprises one or more of dodecafluoroheptyl methacrylate, perfluoroalkyl ethyl acrylate, propylene glycol monomethyl ether acetate, a solvent and azodiisobutyronitrile.
5. The self-leveling mortar of claim 1, wherein the auxiliary agent comprises the following raw materials in parts by mass:
exciting agent: 1-5 parts, mineral powder: 8-12 parts of a thickening agent: 0.1-0.5 part, early strength agent: 0.5-1.0 part of retarder: 0.5-1.0 part of swelling agent: 0.3-0.5 part of water reducing agent: 0.1-0.3 part, defoaming agent: 0.1-0.3 parts and dispersible latex: 5-15 parts.
6. The self-leveling mortar of claim 5, wherein:
the excitant comprises one or more of lime, cement clinker, gypsum, phosphogypsum and fluorgypsum;
the mineral powder comprises one or more of fly ash, water granulated slag and silicon powder;
the thickening agent comprises one or more of hydroxypropyl methyl cellulose ether, starch ether, methyl cellulose, hydroxyethyl methyl cellulose ether and hydroxypropyl methyl cellulose;
the early strength agent comprises one or more of aluminum sulfate, lithium carbonate and calcium formate;
the retarder comprises one or more of sodium gluconate, tartaric acid and citric acid;
the expanding agent comprises aluminum sulfate or a compound thereof;
the water reducing agent comprises a high-performance water reducing agent;
the defoaming agent comprises an organic silicon defoaming agent or a higher fatty acid defoaming agent;
the dispersible latex comprises one or more of vinyl acetate-ethylene copolymer rubber powder, ethylene-polyvinyl chloride-vinyl laurate ternary copolymer rubber powder, ethyl acetate-ethylene-higher fatty acid vinyl ester ternary copolymer rubber powder, vinyl acetate-higher fatty acid copolymer rubber powder, acrylate-styrene copolymer rubber powder, vinyl acetate-acrylate-higher fatty acid ternary copolymer rubber powder, vinyl acetate homopolymerization rubber powder and styrene-butadiene copolymer rubber powder.
7. The self-leveling mortar of claim 6, wherein:
the excitant is the phosphogypsum; and the phosphogypsum comprises SiO in mass fraction2: 6.7-6.88 parts of Al2O3: 1.54-2.24 parts of Fe2O3: 0.14 to 0.18 portion of TiO2: 0.03-0.04 parts of MgO: 0.04-0.07 part of K2O: 0.07 part of Na2O: 0.03 part, l.o.i: 6.53-7.72 parts;
the mineral powder is the fly ash, and the fly ash comprises SiO calculated according to mass fraction2: 49-50 parts of Al2O3: 38-39 parts of Fe2O3: 1-2 parts of TiO2: 0.03-0.04 parts of CaO: 2-4 parts of MgO: 0.4-0.5 part, K2O: 0.5-0.6 part of Na2O: 0.05-0.07 part of L.O.I: 2-3 parts of a solvent;
the thickener is the hydroxypropyl methyl cellulose with 20 ten thousand viscosity;
the early strength agent is the calcium formate;
the retarder is the tartaric acid;
the expanding agent comprises the aluminum sulfate, the fineness of the aluminum sulfate is 0.08mm, and the fineness is less than 10 percent with a 100-mesh sieve;
the defoaming agent is the organic silicon defoaming agent.
8. A method for hole sealing decoration of a foamed ceramic surface is characterized by comprising the following steps:
dry-mixed mortar obtained by dry-mixing the portland cement, the aluminate cement, the polishing fine powder aggregate and the auxiliary of the self-leveling mortar of any one of claims 1 to 7; mixing the dry-mixed mortar and the flatting agent to obtain the self-leveling mortar; spraying the self-leveling mortar on the surface of the foamed ceramic, and naturally curing after uniformly blowing the mortar;
or,
dry-mixed mortar obtained by dry-mixing the portland cement, the aluminate cement, the polishing fine powder aggregate and the auxiliary of the self-leveling mortar of any one of claims 1 to 7; and adjusting the dry-mixed mortar into a paste shape, printing the paste on the surface of the foamed ceramic by adopting a screen printing mode, adding the dry-mixed mortar into the leveling agent to obtain the self-leveling mortar, spraying the self-leveling mortar on the surface of the foamed ceramic, and naturally curing the mortar after uniformly blowing.
9. The method for hole sealing decoration on the surface of foamed ceramic according to claim 8, further comprising:
and polishing and grinding the surface of the naturally cured foamed ceramic, and polishing the surface by using 500-sand-paper 1000 meshes to remove surface nails or impurities.
10. The method for pore-sealing decoration on the surface of the foamed ceramic according to claim 9, wherein:
the spraying step adopts a large-caliber elastic coating spray gun with the caliber of 4-6mm, the spraying air pressure is 0.5-0.8MPa, and the thickness is controlled below 3 mm; the step of uniformly blowing and smearing the mortar is to adopt a sawtooth type scraper or airflow, wherein the tooth pitch of the sawtooth type scraper is 2-3mm, and the airflow is controlled to be less than or equal to 0.5 Mpa.
CN202010254248.6A 2020-04-02 2020-04-02 Self-leveling mortar and foamed ceramic surface hole sealing decoration method Pending CN111533516A (en)

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