JP5041521B2 - High strength restoration material - Google Patents

Description

  The present invention relates to a mortar or concrete-based restoration material that can exhibit high strength.

In order to increase the strength of mortar and concrete, it is common to reduce the amount of water added to the amount of hydraulic materials used, such as cement. There is a limit to increasing the strength in For this reason, using pozzolanic reactive substances such as silica fume and fly ash together with portland cement, the calcium hydroxide produced by hydration of portland cement reacts with pozzolanic reactive substances to improve the structure and improve long-term strength. The method is known. On the other hand, since the pozzolanic reactive material is replaced with cement, the initial strength is likely to be lowered, and this tendency becomes remarkable particularly at low temperatures. Therefore, steam curing is required to suppress the strength reduction. (For example, refer to Patent Document 1.) However, the steam curing treatment is suitable for relatively small-scale products and the like, but is not suitable for other products and lacks versatility. In addition, type II anhydrous gypsum is mixed and reacted with calcium aluminate in the cement to generate ettringite to enhance strength development. (For example, refer to Patent Document 2.) The greater the amount of ettringite produced, the higher the initial strength. However, since ettringite production is accompanied by expansion, the cured body is relaxed and water tightness is liable to decrease. Since calcium hydroxide, which is a hydrate, is also consumed in the production of ettringite, the strength will decrease over the long term. When alumina cement is used instead of Portland cement, calcium hydroxide is not generated during hydration, so that the initial strength can be increased. For this reason, although it is possible that the construction period of the alumina cement-based restoration material can be significantly shortened, conversion from the initial hydrate accompanied by large-scale shrinkage occurs after curing, resulting in a significant decrease in long-term strength. It is known to produce alumina cement-based polymer mortar using alumina cement in combination with pozzolanic reactive substances such as silica fume and fly ash and polymers to improve workability such as adhesion strength, and use it for floor repair materials. Yes. (For example, see Patent Document 3.) However, alumina cement has low alkalinity, so adding pozzolanic reactive material does not improve the strength like portland cement, and adding pozzolanic reactive material together with the polymer. However, it is not enough to compensate for the drastic drop in long-term intensity caused by conversion.
JP 2001-181004 A JP 2006-248828 A JP-A-4-132648

  The present invention is a cement-based restoration material that exhibits workability suitable as a restoration material, in particular, good coating workability, and can stably exhibit high strength without performing special treatment such as steam curing. It is an issue to provide.

  As a result of intensive studies to solve the problem, the present inventor has prevented the deterioration of long-term strength in addition to high initial strength by adding alumina silicate as a binder component and adding aluminum silicate exhibiting specific reaction characteristics to this. In addition, the present invention was completed because a restoration material having good workability suitable for repairing mortar and concrete structures including adhesion strength was obtained by adding a polymer.

That is, the present invention is a high-strength restoration material represented by the following (1) to (5). (1) Polymer dispersion containing 35 to 50% by mass of alumina cement, 40 to 60% by mass of fine aggregate, 1 to 6% by mass of metakaolin, and polyacrylic acid ester, styrene butadiene or ethylene vinyl acetate, or A polymer consisting of either a polyacrylic acid ester, styrene butadiene, ethylene vinyl acetate, vinyl acetate / versaic acid vinyl ester or re-emulsified powder resin containing vinyl acetate / vinyl versatate / acrylic acid ester as an active ingredient A high-strength restoration material comprising 0.1 to 10% by mass . (2) The high strength of (1) above, wherein the metakaolin is a chemical component having an Al ₂ O ₃ content of 20% by mass or more and an SiO ₂ content of 50% by mass or more and having a Blaine specific surface area of 8000 to 110000 cm ² / g. Restoration material. (3) The high-strength restoration material according to (1) or (2), further comprising 1 to 10% by mass of silica fume and / or fly ash. (4) The high-strength restoration material according to any one of claims 1 to 3, further comprising 0.5 to 5% by mass of Portland cement. (5) In addition, fibers, Ri Na contain one kind or two or more kinds of thickeners water reducing agent and water-soluble cellulose derivative, the content of the time containing the fiber 0.03 to 0.20 The content when containing a mass%, a water reducing agent is 0.1 to 10 mass% in terms of solid content, and the content when containing a water-soluble cellulose derivative thickener is 0.01 to 0 in terms of solid content The high-strength restoration material according to any one of (1) to (4), which is 1 % by mass .

  According to the present invention, for example, it is excellent in coating workability for repairing a cross section of a concrete structure, and it is possible to obtain a repair material having high strength development from the initial stage to a long period of time. In addition, a restoration that exhibits stable durability over a long period of time can be obtained.

The high-strength restoration material of the present invention contains alumina cement as a binder phase forming component. The alumina cement is not particularly limited as long as it contains CaO.Al ₂ O ₃ as a main component. For example, any commercially available alumina cement can be used. The alumina cement content in the high strength restoration material of the present invention is preferably 35 to 50% by mass. More preferably, the content is 35 to 46% by mass. If it is less than 35% by mass, it may be difficult to obtain high strength for a short time. If it exceeds 50% by mass, cracking may occur after curing, and plastering workability may be deteriorated.

The high-strength restoration material of the present invention contains metakaolin. The metakaolin referred to in the present invention is a general term for intermediates that pass or appear from kaolinite until mullite, which is a dehydrated mineral phase, is formed by, for example, heat treatment. By containing metakaolin, a CaO—SiO ₂ —Al ₂ O ₃ —H ₂ O-based gel is generated by reacting with the alumina cement, thereby sufficiently suppressing the decrease in long-term strength accompanying the transition. For the case of a general pozzolanic reactants such as fly ash and silica fume, alumina cement which is less reactive and less fly ash low for fineness alkaline, also silica fume does not include Al ₂ O _3, CaO-SiO _{Since the 2-} Al ₂ O ₃ —H ₂ O-based gel is difficult to form, the long-term strength lowering compensation action is weak. The metakaolin to be used is preferably a chemical component having an Al ₂ O ₃ content of 20% by mass or more and an SiO ₂ content of 50% by mass or more and a Blaine specific surface area of 8000 to 110000 cm ² / g. In the case of metakaolin having an Al ₂ O ₃ content of less than 20% by mass or an SiO ₂ content of less than 50% by mass, the amount of CaO—SiO ₂ —Al ₂ O ₃ —H ₂ O-based gel produced is insufficient to obtain high strength. So it is not appropriate. Metakaolin having a Blaine specific surface area of less than 8000 cm ² / g is not suitable because the reactivity with alumina cement is low and a CaO—SiO ₂ —Al ₂ O ₃ —H ₂ O-based gel is not sufficiently formed. On the other hand, if the Blaine specific surface area exceeds 110,000 cm ² / g, it is necessary to increase the amount of blended water in order to improve the reactivity. As a result, it is difficult to obtain high strength, which is not suitable. The content of metakaolin in the high-strength restoration material is preferably 1 to 6% by mass. More preferably, the content is 1 to 4% by mass. If the content of metakaolin is less than 1% by mass, a CaO—SiO ₂ —Al ₂ O ₃ —H ₂ O-based gel is hardly formed, and is not suitable. If it exceeds 6% by mass, CaO—SiO ₂ —Al ₂ O ₃ —H is not suitable. _This is not appropriate because the amount of ₂ O-based gel produced is excessive and strength development may be reduced.

  Moreover, the high-strength restoration material of the present invention contains a polymer. The polymer is not particularly limited as long as it is a polymer dispersion or re-emulsified powder resin that can be used for mortar and concrete. Specifically, for example, polymer dispersion, polyacrylic acid ester, styrene butadiene, ethylene vinyl acetate, vinyl acetate containing polyacrylic acid ester, styrene butadiene or ethylene vinyl acetate as active ingredients as defined in JIS A 6203. And re-emulsified powder resin containing vinyl acetate / vinyl versatate and vinyl acetate / vinyl versatate / acrylic acid ester as active ingredients. By including the polymer, properties such as adhesion, bending strength, water absorption, and crack resistance can be improved and improved. The polymer content in the high-strength restoration material for obtaining such properties is preferably 0.1 to 10% by mass in terms of solid content. If it is less than 0.1% by mass, such properties are hardly imparted, and if it exceeds 10% by mass, high strength development cannot be obtained, and the viscosity becomes so high that the workability may be deteriorated. Absent.

  In addition, the high-strength restoration material of the present invention can contain silica fume and / or fly ash in order to further improve the workability. Silica fume and fly ash that can be used are not particularly limited. The total content of silica fume and fly ash in the high-strength restoration material (the content when only one is contained alone) is preferably 1 to 10% by mass. If the amount is less than 1% by mass, the inclusion effect is not substantially obtained, and if it exceeds 10% by mass, unless the amount of water is increased, fluidity is deteriorated so as to hinder the workability. . In addition, the mixing ratio between the two when silica fume and fly ash are used in combination is not limited at all, and may be appropriately selected.

  The high-strength restoration material of the present invention preferably contains Portland cement. The kind of Portland cement to be used is not particularly limited, and examples thereof include normal, early strength, super early strength, moderate heat, low heat, and the like. By containing Portland cement, the reaction between alumina cement and metakaolin is promoted, and water tightness is improved. As for content in the high intensity | strength restoration material in the case of containing Portland cement, 0.5-5 mass% is preferable. If it is less than 0.5% by mass, the content effect cannot be obtained. On the other hand, if it exceeds 5% by mass, the consistency is lowered, and it may be difficult to obtain appropriate workability.

The high-strength restoration material of the present invention preferably contains fine aggregate. Any fine aggregate can be used as long as it can be used for mortar and concrete. For example, natural fine aggregates such as river sand, mountain sand, sea sand and crushed sand, as well as lightweight organic materials such as styrene foam aggregate. Various lightweight aggregates such as aggregates, natural lightweight aggregates obtained by crushing and sizing porous volcanic gravel, and natural artificial ores such as shale, rhyolite, and other mineral ores that are fired by adding a foaming aid if necessary Can be mentioned. More preferably, sand corresponding to JIS No. 3 to JIS No. 8 is used alone, or most preferably, it is used by mixing almost uniformly in mass. Fine aggregate content of the high strength repair material in the present invention is more preferably 40 to 60 wt%. If it is less than 40 % by mass, it is difficult to obtain high tightness after construction, drying shrinkage becomes large, and cracks are likely to occur during curing, which is not suitable. On the other hand, if it exceeds 60 % by mass, it is difficult to obtain high strength, so this is not suitable.

Moreover, the high-strength restorative material of this invention can also contain components other than the above. Examples of such components include water reducing agents that can be used for mortar and concrete (in addition to those that are simply referred to as water reducing agents, for example, high-performance water reducing agents, AE water reducing agents, high-performance AE water reducing agents, fluidizing agents) And water dispersing agents, thickeners, shrinkage reducing agents, expansion materials, fibers, antifoaming agents, water repellents, pigments, and the like. In particular, in order to obtain a low strength water content in order to obtain higher strength, it is recommended to use a water-reducing agent in an amount of about 0.1 to 10% by mass in terms of solid content, and also to prevent cracking. In, for example, it is recommended to use 0.03 to 0.20% by mass of a fiber made of a material such as a water-insoluble polymer or stainless steel, and in order to enhance adhesion at the time of application, for example, water-soluble cellulose. it is recommended to thickener 0.01 wt% content use on the basis of the solids content in the induction body. Moreover, the high-strength restorative material of the present invention is not limited to a mortar blending mode, but may be a concrete blending mode by including, for example, coarse aggregate.

  Moreover, the manufacturing method of the high intensity | strength restoration | repair material of this invention is not specifically limited, For example, it can manufacture by the method substantially the same as general cementitious mortar. When a specific example is shown, each use material is put into a commercially available mortar mixer so that it may become the above content rate, and water is added and mixed. The amount of water to be added is not particularly limited, but in order to stably obtain good workability and high strength development, 100 parts by mass of cement (content when using alumina cement alone, and Portland second) When cement is also used, it is recommended to add approximately 28 to 48 parts by mass with respect to the total content with alumina cement. If it is less than 28 parts by mass, it is difficult to obtain good workability suitable for plastering, for example. On the other hand, if the amount exceeds 48 parts by mass, not only the strength developability is lowered but also the adhesive force during construction is lowered.

  In addition, the construction method when using the high-strength restoration material of the present invention is not particularly limited, but it is applied by painting using a paddle or putty to a place where restoration of a concrete structure or the like is required A construction method is preferred.

  EXAMPLES Hereinafter, the present invention will be described in detail with reference to examples, but the present invention is not limited to the examples shown here.

[Preparation of Mortar] A material selected from A to H 3 and water shown below are put into a Hobart mixer so as to have a blending amount shown in Table 1, and the temperature is about 20 ° C. and humidity is 80% for 3 minutes. It knead | mixed and produced the mortar (this invention products 1-8, the reference products 11-15).

A: Alumina cement (manufactured by Taiheiyo Material Co., Ltd.)
B1: Ordinary Portland cement (manufactured by Taiheiyo Cement Co., Ltd.)
B2: Type II anhydrous gypsum (Brain specific surface area 7000 cm ² / g)
C1; Metakaolin I (BASF Construction Systems Co., Ltd., BET specific surface area 10 m ² / g)
C2: Metakaolin II (Omura Seratec Co., Ltd., Blaine specific surface area 10,000 cm ² / g)
D1; fly ash (JIS A 6201 prescribed fly ash type II equivalent)
D2: Silica fume (manufactured by Sakai Kogyo Co., Ltd., BET specific surface area 21.2 m ² / g)
E1: Ordinary fine aggregate I (Yamagata quartz sand No. 3)
E2: Normal fine aggregate II (Yamagata quartz sand No. 4)
E3: Normal fine aggregate III (Yamagata silica sand No. 5)
E4: Ordinary fine aggregate IV (Yamagata quartz sand No. 7)
E5: Ordinary fine aggregate V (Yamagata quartz sand No. 8)
F: Vinylon fiber (commercial product, fiber length of about 6 mm)
G1: Cellulosic thickener (trade name “Marporose 90MP-4T”, manufactured by Matsumoto Yushi Seiyaku Co., Ltd.)
G2: Naphthalenesulfonic acid-based water reducing agent (manufactured by Kao Corporation)
H1; re-emulsified powder resin (trade name “TITA8100”, manufactured by NSC Japan)
H2: Polymer dispersion (trade name “MOVINYL 7700”, manufactured by Nichigo Movinyl Co., Ltd.)
H3: Polymer dispersion (trade name “Pacific Effect”, manufactured by Taiheiyo Materials Co., Ltd.)

  [Evaluation of Consistency] With respect to the prepared mortar, the mortar flow value immediately after being kneaded indoors at 20 ° C. was measured by a method based on JIS R 5201, and used as an evaluation index for consistency. The results are shown in Table 2.

  [Evaluation of glazing workability] The mortar was evaluated for glazing workability by the following method. That is, a concrete plate of 100 × 100 × 15 cm was placed perpendicular to the ground with one surface of 100 × 15 cm as the bottom. The prepared fresh mortar was applied to one side of 100 × 100 cm of the installed concrete flat plate using a commercially available hammer. Even if the applied mortar has good wrinkle elongation, almost no mortar remains attached to the gold bar used after application, and the vertical surface is applied to a thickness of about 3 cm or more Mortars with no sag of mortar applied after 24 hours were judged to be “good”, and all other mortars were judged to be “bad”. . The evaluation results are summarized in Table 2.

  [Evaluation of Crack Resistance] In the above test, the mortar applied to the concrete slab was not dripped or peeled off, and the temperature was about 20 in a state where the mortar was applied with one side of 300 × 60 mm as the bottom. It was allowed to stand for 7 days in an environment of 60 ° C. and humidity of 60%. After standing still, the surface of the construction object on the flat plate was visually observed to check for cracks. Those in which no cracks were observed were judged as “good”, and those in which any cracks were seen were judged as “bad”. This evaluation result is also shown in Table 2.

  [Evaluation of Strength] A specimen for a strength test of 4 × 4 × 16 cm was produced from the produced mortar by a method based on JIS R 5201. The specimens were subjected to wet air curing (temperature 20 ° C., humidity 80%) for 24 hours, followed by water curing at 20 ° C. until the age of 3 or 28 days. After the underwater curing, the compressive strength was measured immediately. The compressive strength measurement results are also shown in Table 2.

  From the results shown in Table 2, all of the products of the present invention can have a very high strength expression, and in addition to this, they have a consistency suitable for coating application, and are generally good in tanning. No cracks are observed after curing, and it can be seen that a repair material having high durability over the medium to long term is obtained. On the other hand, it can be seen that the reference product outside of the present invention has poor coating workability or low long-term strength development, and cannot be a repair material with excellent durability.

  The high-strength restoration material of the present invention can be used as a material for coating construction such as a wall surface or a ceiling surface, or a repair material for a mortar / concrete structure, or a structure made of a material other than mortar, concrete, or mortar / concrete. It can also be used as a filler.

Claims (5)

Polymer dispersion or polyacrylic acid containing 35 to 50% by mass of alumina cement, 40 to 60% by mass of fine aggregate, 1 to 6% by mass of metakaolin, and polyacrylic acid ester, styrene butadiene or ethylene vinyl acetate as active ingredients A polymer composed of any one of ester, styrene butadiene, ethylene vinyl acetate, vinyl acetate / vinyl versatate or re-emulsified powder resin containing vinyl acetate / vinyl versatate / acrylic acid as an active ingredient is 0.1 in terms of solid content. A high-strength restorative material containing 10 mass% . The high-strength restorative material according to claim 1, wherein the metakaolin is a chemical component having an Al ₂ O ₃ content of 20% by mass or more and an SiO ₂ content of 50% by mass or more and a Blaine specific surface area of 8000 to 110000 cm ² / g. The high-strength restoration material according to claim 1 or 2, further comprising 1 to 10% by mass of silica fume and / or fly ash. Furthermore, the high strength restoration | repair material in any one of Claims 1-3 formed by containing Portland cement 0.5-5 mass% . Further, fibers, Ri Na contain more water reducing agents and any one thickener of water-soluble cellulose derivative or two, the content of the time containing the fiber 0.03 to 0.20 wt%, The content when containing a water reducing agent is 0.1 to 10% by mass in terms of solid content, and the content when containing a thickener of a water-soluble cellulose derivative is 0.01 to 0.1% in terms of solid content. The high-strength restoration material according to any one of claims 1 to 4, wherein the high-strength restoration material is % .