CN111484690A - Low-odor environment-friendly rapid composite decorative material film and preparation method thereof - Google Patents
Low-odor environment-friendly rapid composite decorative material film and preparation method thereof Download PDFInfo
- Publication number
- CN111484690A CN111484690A CN202010446925.4A CN202010446925A CN111484690A CN 111484690 A CN111484690 A CN 111484690A CN 202010446925 A CN202010446925 A CN 202010446925A CN 111484690 A CN111484690 A CN 111484690A
- Authority
- CN
- China
- Prior art keywords
- parts
- material film
- low
- decorative material
- environment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/12—Esters; Ether-esters of cyclic polycarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a low-odor environment-friendly rapid composite decorative material film and a preparation method thereof, wherein the decorative material film comprises the following raw materials in parts by weight: 90-100 parts of PVC resin powder, 20-30 parts of plasticizer, 2-5 parts of epoxidized soybean oil, 3-5 parts of stabilizer, 10-15 parts of antioxidant, 20-30 parts of filler, 10-18 parts of inorganic pigment, 1-2 parts of processing aid and 3-5 parts of flame retardant. According to the invention, the epoxidized soybean oil is added in the process for preparing the environment-friendly decorative material film, so that the environment-friendly decorative material film has a good stabilizing effect on light and heat, and has the advantages of high temperature resistance, low temperature resistance, no migration, no frost spraying and the like; the plasticizer adopts dioctyl terephthalate to replace common diisooctyl phthalate, has the advantages of heat resistance, cold resistance, difficult volatilization, extraction resistance, good flexibility and electrical insulation performance and the like, shows excellent durability, soap water resistance and low-temperature flexibility in products, has simple and easy preparation method, mild reaction conditions, is suitable for large-scale production, and has high popularization and application values.
Description
Technical Field
The invention relates to the technical field of plastic films, in particular to a low-odor, environment-friendly and quick-compounding decorative material film and a preparation method thereof.
Background
Along with the development of economy in China, the housing conditions of people are greatly improved, and the newly finished house generally has a bad smell mainly from harmful gases such as formaldehyde released by furniture, sofas, paint and the like; formaldehyde is a gas with strong pungent smell, and formaldehyde with a certain concentration can cause damage to organs such as human nervous system, lung, liver and the like. Generally, the release period of formaldehyde in furniture is as long as 5 to 10 years, and if the furniture is used at home for a long time, the formaldehyde cannot be removed in time, so that the health of people is necessarily affected; at present, the common methods for removing formaldehyde in home comprise a ventilation method, a plant absorption method, an activated carbon adsorption method, a chemical reagent purification method and the like; the ventilation method is a good method, can effectively reduce the content of formaldehyde in a room, but the use of the ventilation method is limited because the door and the window are often required to be closed when people sleep at night; the absorption effect of the plant absorption method is not very good; the activated carbon adsorption method can adsorb formaldehyde but cannot remove the formaldehyde, and the adsorption effect of the activated carbon is greatly reduced after the activated carbon is used for a certain time; the chemical reagent purification method is complex in operation, has the risk of secondary pollution, and cannot be used every day, so that the purification effect is limited. The existing decorative film for veneering floors and furniture is easy to mildew and breed bacteria after being used for a period of time, and the mildew and the breeding of the bacteria are usually started from inside to outside, so that the existing decorative film is extremely easy to hurt human bodies, cannot meet the daily requirements of people, and brings secondary pollution to the living environment.
The material is prepared by using high-polymerization-degree PVC resin powder, an environment-friendly plasticizer, a stabilizer, a flame retardant, an internal lubricant and a mildew preventive as main raw materials through the procedures of screening, proportioning, high-speed stirring, banburying, rough refining, extrusion filtering, calendering, embossing, cooling and shaping, trimming, coiling and the like. The environment-friendly decorative material film has good environmental protection property, aging resistance and ductility, but has incomplete flame retardant property and impact resistance, and still has certain defects in the use of the decorative material film.
Disclosure of Invention
The invention aims to provide a low-odor environment-friendly rapid composite decorative material film and a preparation method thereof, so as to solve the problems in the background technology.
In order to achieve the purpose, the invention provides the following technical scheme: a low-odor environment-friendly rapid composite decorative material film comprises the following raw materials in parts by weight: 90-100 parts of PVC resin powder, 20-30 parts of plasticizer, 2-5 parts of epoxidized soybean oil, 3-5 parts of stabilizer, 10-15 parts of antioxidant, 20-30 parts of filler, 10-18 parts of inorganic pigment, 1-2 parts of processing aid and 3-5 parts of flame retardant.
Preferably, the plasticizer is dioctyl terephthalate.
Preferably, the stabilizer is a calcium-zinc composite stabilizer.
Preferably, the antioxidant is an aluminum magnesium zinc antioxidant.
Preferably, the inorganic pigment is titanium dioxide.
Preferably, the processing aid is an acrylate copolymer.
A preparation method of a low-odor environment-friendly rapid composite decorative material film comprises the following steps:
step 1: adding PCV resin powder into a stirrer according to the weight of the ingredients and uniformly stirring;
step 2: adding a plasticizer, epoxidized soybean oil, a stabilizer, a filler, an inorganic pigment and a processing aid into a stirrer, and uniformly mixing with PVC resin powder to obtain a mixture I;
and step 3: introducing the mixture I, the flame retardant and the antioxidant into an internal mixer for internal mixing to obtain a mixture II;
and 4, step 4: and (4) introducing the mixture II into an extruder, extruding, cooling and molding.
Preferably, in step 1, the stirring speed of the stirrer is 230-250r/min, the stirring temperature is 70-120 ℃, and the stirring time is 40-45min, and in step 2, the stirring speed of the stirrer is 150-200r/min, the stirring temperature is 60-80 ℃, and the stirring time is 6-10 min.
Preferably, in the step 3, the mixing temperature of the internal mixer is 90-130 ℃, and the mixing time is 40-45 min.
Preferably, in step 4, the extruder extrusion temperature is 105-.
Compared with the prior art, the invention has the beneficial effects that:
according to the invention, the epoxidized soybean oil is added in the process for preparing the environment-friendly decorative material film, so that the environment-friendly decorative material film has a good stabilizing effect on light and heat, and has the advantages of high temperature resistance, low temperature resistance, no migration, no frost spraying and the like; the plasticizer adopts dioctyl terephthalate to replace common diisooctyl phthalate, has the advantages of heat resistance, cold resistance, difficult volatilization, extraction resistance, good flexibility and electrical insulation performance and the like, and shows excellent durability, soap water resistance and low-temperature flexibility in products; the selected processing aid is acrylate copolymer, the impact modification effect is obvious, a wide processing temperature range can be obtained while higher normal-temperature and low-temperature impact strength can be obtained by adding a small amount of processing aid, and the low film expansion property is suitable for high-speed extrusion of profiled bars; the flame retardant has a flame retardant effect and can improve the mechanical property of the prepared film material; the titanium dioxide can be used as a catalyst of a light coating pigment, not only is an environment-friendly cleaning agent, but also has the functions of saving energy and protecting environment resources, and the preparation method is simple and easy to implement, mild in reaction conditions, suitable for large-scale production and high in popularization and application value.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
Example 1:
the invention provides a technical scheme that: a low-odor environment-friendly rapid composite decorative material film comprises the following raw materials in parts by weight: 90 parts of PVC resin powder, 20 parts of plasticizer, 2 parts of epoxidized soybean oil, 3 parts of stabilizer, 10 parts of antioxidant, 20 parts of filler, 10 parts of inorganic pigment, 1 part of processing aid and 3 parts of flame retardant, wherein the plasticizer is dioctyl terephthalate, the stabilizer is calcium-zinc composite stabilizer, the antioxidant is aluminum-magnesium-zinc antioxidant, the inorganic pigment is titanium dioxide, and the processing aid is acrylate copolymer.
A preparation method of a low-odor environment-friendly rapid composite decorative material film comprises the following steps:
step 1: according to the weight of the ingredients, adding PCV resin powder into a stirrer to be uniformly stirred, wherein the stirring speed of the stirrer is 230r/min, the stirring temperature is 70 ℃, and the stirring time is 40 min;
step 2: adding a plasticizer, epoxidized soybean oil, a stabilizer, a filler, an inorganic pigment and a processing aid into a stirrer, and uniformly mixing with PVC resin powder to obtain a mixture I, wherein the stirring speed of the stirrer is 150r/min, the stirring temperature is 60 ℃, and the stirring time is 6 min;
and step 3: introducing the mixture I, the flame retardant and the antioxidant into an internal mixer for internal mixing to obtain a mixture II, wherein the internal mixing temperature of the internal mixer is 90 ℃, and the internal mixing time is 40 min;
and 4, step 4: and (4) introducing the mixture II into an extruder, extruding, cooling and molding, wherein the extrusion temperature of the extruder is 105 ℃.
Example 2:
the invention provides a technical scheme that: a low-odor environment-friendly rapid composite decorative material film comprises the following raw materials in parts by weight: 95 parts of PVC resin powder, 25 parts of plasticizer, 3 parts of epoxidized soybean oil, 4 parts of stabilizer, 12 parts of antioxidant, 25 parts of filler, 15 parts of inorganic pigment, 1 part of processing aid and 4 parts of flame retardant, wherein the plasticizer is dioctyl terephthalate, the stabilizer is calcium-zinc composite stabilizer, the antioxidant is aluminum-magnesium-zinc antioxidant, the inorganic pigment is titanium dioxide, and the processing aid is acrylate copolymer.
A preparation method of a low-odor environment-friendly rapid composite decorative material film comprises the following steps:
step 1: according to the weight of the ingredients, adding PCV resin powder into a stirrer to be uniformly stirred, wherein the stirring speed of the stirrer is 240r/min, the stirring temperature is 100 ℃, and the stirring time is 40 min;
step 2: adding a plasticizer, epoxidized soybean oil, a stabilizer, a filler, an inorganic pigment and a processing aid into a stirrer, and uniformly mixing with PVC resin powder to obtain a mixture I, wherein the stirring speed of the stirrer is 180r/min, the stirring temperature is 70 ℃, and the stirring time is 8 min;
and step 3: introducing the mixture I, the flame retardant and the antioxidant into an internal mixer for internal mixing to obtain a mixture II, wherein the internal mixing temperature of the internal mixer is 115 ℃, and the internal mixing time is 40 min;
and 4, step 4: and (3) introducing the mixture II into an extruder, extruding, cooling and molding, wherein the extrusion temperature of the extruder is 110 ℃.
Example 3:
the invention provides a technical scheme that: a low-odor environment-friendly rapid composite decorative material film comprises the following raw materials in parts by weight: 100 parts of PVC resin powder, 30 parts of plasticizer, 5 parts of epoxidized soybean oil, 5 parts of stabilizer, 15 parts of antioxidant, 30 parts of filler, 18 parts of inorganic pigment, 2 parts of processing aid and 5 parts of flame retardant, wherein the plasticizer is dioctyl terephthalate, the stabilizer is calcium-zinc composite stabilizer, the antioxidant is aluminum-magnesium-zinc antioxidant, the inorganic pigment is titanium dioxide, and the processing aid is acrylate copolymer.
A preparation method of a low-odor environment-friendly rapid composite decorative material film comprises the following steps:
step 1: according to the weight of the ingredients, adding PCV resin powder into a stirrer to be uniformly stirred, wherein the stirring speed of the stirrer is 250r/min, the stirring temperature is 120 ℃, and the stirring time is 45 min;
step 2: adding a plasticizer, epoxidized soybean oil, a stabilizer, a filler, an inorganic pigment and a processing aid into a stirrer, and uniformly mixing with PVC resin powder to obtain a mixture I, wherein the stirring speed of the stirrer is 200r/min, the stirring temperature is 80 ℃, and the stirring time is 10 min;
and step 3: introducing the mixture I, the flame retardant and the antioxidant into an internal mixer for internal mixing to obtain a mixture II, wherein the internal mixing temperature of the internal mixer is 130 ℃, and the internal mixing time is 45 min;
and 4, step 4: and (4) introducing the mixture II into an extruder, extruding, cooling and molding, wherein the extrusion temperature of the extruder is 120 ℃.
In summary, in the above embodiment, the epoxidized soybean oil is added in the process of preparing the environmentally-friendly decorative material film, so that the environmentally-friendly decorative material film has a good stabilizing effect on light and heat, and has the advantages of high temperature resistance, low temperature resistance, no migration, no blooming and the like; the plasticizer adopts dioctyl terephthalate to replace common diisooctyl phthalate, has the advantages of heat resistance, cold resistance, difficult volatilization, extraction resistance, good flexibility and electrical insulation performance and the like, and shows excellent durability, soap water resistance and low-temperature flexibility in products; the selected processing aid is acrylate copolymer, the impact modification effect is obvious, a wide processing temperature range can be obtained while higher normal-temperature and low-temperature impact strength can be obtained by adding a small amount of processing aid, and the low film expansion property is suitable for high-speed extrusion of profiled bars; the flame retardant has a flame retardant effect and can improve the mechanical property of the prepared film material; the titanium dioxide can be used as a catalyst of a light coating pigment, not only is an environment-friendly cleaning agent, but also has the functions of saving energy and protecting environment resources, and the preparation method is simple and easy to implement, mild in reaction conditions, suitable for large-scale production and high in popularization and application value.
Application method
A preparation method of a low-odor environment-friendly rapid composite decorative material film comprises the following steps:
step 1: adding PCV resin powder into a stirrer according to the weight of the ingredients and uniformly stirring;
step 2: adding a plasticizer, epoxidized soybean oil, a stabilizer, a filler, an inorganic pigment and a processing aid into a stirrer, and uniformly mixing with PVC resin powder to obtain a mixture I;
and step 3: introducing the mixture I, the flame retardant and the antioxidant into an internal mixer for internal mixing to obtain a mixture II;
and 4, step 4: and (4) introducing the mixture II into an extruder, extruding, cooling and molding.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.
Claims (10)
1. The low-odor environment-friendly rapid composite decorative material film is characterized by comprising the following raw materials in parts by weight: 90-100 parts of PVC resin powder, 20-30 parts of plasticizer, 2-5 parts of epoxidized soybean oil, 3-5 parts of stabilizer, 10-15 parts of antioxidant, 20-30 parts of filler, 10-18 parts of inorganic pigment, 1-2 parts of processing aid and 3-5 parts of flame retardant.
2. The low-odor environment-friendly rapid-compounding type decorating material film as claimed in claim 1, wherein: the plasticizer is dioctyl terephthalate.
3. The low-odor environment-friendly rapid-compounding type decorating material film as claimed in claim 1, wherein: the stabilizer is a calcium-zinc composite stabilizer.
4. The low-odor environment-friendly rapid-compounding type decorating material film as claimed in claim 1, wherein: the antioxidant is an aluminum magnesium zinc antioxidant.
5. The low-odor environment-friendly rapid-compounding type decorating material film as claimed in claim 1, wherein: the inorganic pigment is titanium dioxide.
6. The low-odor environment-friendly rapid-compounding type decorating material film as claimed in claim 1, wherein: the processing aid is acrylate copolymer.
7. A preparation method of a low-odor environment-friendly rapid composite decorative material film is characterized by comprising the following steps:
step 1: adding PCV resin powder into a stirrer according to the weight of the ingredients and uniformly stirring;
step 2: adding a plasticizer, epoxidized soybean oil, a stabilizer, a filler, an inorganic pigment and a processing aid into a stirrer, and uniformly mixing with PVC resin powder to obtain a mixture I;
and step 3: introducing the mixture I, the flame retardant and the antioxidant into an internal mixer for internal mixing to obtain a mixture II;
and 4, step 4: and (4) introducing the mixture II into an extruder, extruding, cooling and molding.
8. The method for preparing a low-odor environment-friendly rapid composite decorative material film according to claim 7, wherein the method comprises the following steps: in step 1, the stirring speed of the stirrer is 230-.
9. The method for preparing a low-odor environment-friendly rapid composite decorative material film according to claim 7, wherein the method comprises the following steps: in step 3, the banburying temperature of the banbury mixer is 90-130 ℃, and the banburying time is 40-45 min.
10. The method for preparing a low-odor environment-friendly rapid composite decorative material film according to claim 7, wherein the method comprises the following steps: in step 4, the extruder extrusion temperature was 105-120 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010446925.4A CN111484690A (en) | 2020-05-25 | 2020-05-25 | Low-odor environment-friendly rapid composite decorative material film and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010446925.4A CN111484690A (en) | 2020-05-25 | 2020-05-25 | Low-odor environment-friendly rapid composite decorative material film and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN111484690A true CN111484690A (en) | 2020-08-04 |
Family
ID=71790684
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010446925.4A Pending CN111484690A (en) | 2020-05-25 | 2020-05-25 | Low-odor environment-friendly rapid composite decorative material film and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111484690A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113943466A (en) * | 2021-10-25 | 2022-01-18 | 江苏新丰之星膜材料有限公司 | Formula for producing middle-layer film in decorative film |
| CN114085474A (en) * | 2021-12-22 | 2022-02-25 | 江苏吉龙运动休闲用品有限公司 | Low-odor PVC (polyvinyl chloride) film and preparation method thereof |
| CN114854148A (en) * | 2022-05-27 | 2022-08-05 | 中国第一汽车股份有限公司 | Polyvinyl chloride composite material and preparation method and application thereof |
| CN115536950A (en) * | 2022-10-13 | 2022-12-30 | 珠海市利保能新材料有限公司 | Home decoration film based on PP and PVC blending and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059473A (en) * | 2013-01-09 | 2013-04-24 | 浙江明士达新材料有限公司 | Super-wide environmental-friendly decorative film material and preparation technology thereof |
| CN103756197A (en) * | 2014-01-26 | 2014-04-30 | 东莞市悠悠美居家居制造有限公司 | High-definition transparent PVC (polyvinyl chloride) film and preparation method thereof |
| CN107698891A (en) * | 2017-10-23 | 2018-02-16 | 东莞市悠悠美居家居制造有限公司 | A kind of food grade PVC glued membrane and its calendering technology |
| CN108440858A (en) * | 2018-02-05 | 2018-08-24 | 江门市鑫佰威塑胶制品有限公司 | The special harness of environmentally friendly vehicle wraps up PVC film |
| CN110204844A (en) * | 2019-06-10 | 2019-09-06 | 浙江明士达新材料有限公司 | A kind of shock resistance highly effective flame-retardant decorating film and preparation method thereof |
| KR102067870B1 (en) * | 2017-03-20 | 2020-01-17 | (주)엘지하우시스 | Poly vinyl chloride resin composition and poly vinyl chloride film therefrom |
-
2020
- 2020-05-25 CN CN202010446925.4A patent/CN111484690A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103059473A (en) * | 2013-01-09 | 2013-04-24 | 浙江明士达新材料有限公司 | Super-wide environmental-friendly decorative film material and preparation technology thereof |
| CN103756197A (en) * | 2014-01-26 | 2014-04-30 | 东莞市悠悠美居家居制造有限公司 | High-definition transparent PVC (polyvinyl chloride) film and preparation method thereof |
| KR102067870B1 (en) * | 2017-03-20 | 2020-01-17 | (주)엘지하우시스 | Poly vinyl chloride resin composition and poly vinyl chloride film therefrom |
| CN107698891A (en) * | 2017-10-23 | 2018-02-16 | 东莞市悠悠美居家居制造有限公司 | A kind of food grade PVC glued membrane and its calendering technology |
| CN108440858A (en) * | 2018-02-05 | 2018-08-24 | 江门市鑫佰威塑胶制品有限公司 | The special harness of environmentally friendly vehicle wraps up PVC film |
| CN110204844A (en) * | 2019-06-10 | 2019-09-06 | 浙江明士达新材料有限公司 | A kind of shock resistance highly effective flame-retardant decorating film and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113943466A (en) * | 2021-10-25 | 2022-01-18 | 江苏新丰之星膜材料有限公司 | Formula for producing middle-layer film in decorative film |
| CN114085474A (en) * | 2021-12-22 | 2022-02-25 | 江苏吉龙运动休闲用品有限公司 | Low-odor PVC (polyvinyl chloride) film and preparation method thereof |
| CN114854148A (en) * | 2022-05-27 | 2022-08-05 | 中国第一汽车股份有限公司 | Polyvinyl chloride composite material and preparation method and application thereof |
| CN114854148B (en) * | 2022-05-27 | 2023-11-10 | 中国第一汽车股份有限公司 | Polyvinyl chloride composite material and preparation method and application thereof |
| CN115536950A (en) * | 2022-10-13 | 2022-12-30 | 珠海市利保能新材料有限公司 | Home decoration film based on PP and PVC blending and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111484690A (en) | Low-odor environment-friendly rapid composite decorative material film and preparation method thereof | |
| CN110437590B (en) | Composite nano material modified starch-based biodegradable food packaging film and preparation method thereof | |
| CN111572146B (en) | Plastic-wood composite material plate with adsorption and purification functions and preparation method thereof | |
| CN101857703A (en) | Formula of straw composite imitation solid wood board | |
| CN111038051A (en) | PVC (polyvinyl chloride) and ASA (acrylonitrile styrene acrylate) co-extruded section bar and preparation method thereof | |
| CN106519726A (en) | Preparation method for flame-retardant wood-plastic product | |
| CN111070824A (en) | Halogen-free flame-retardant wood-plastic co-extrusion composite material and preparation method thereof | |
| CN102212238A (en) | Environmentally-friendly cable filling material and preparation method thereof | |
| CN1908338A (en) | Green environment-protecting co-squeezing core layer foaming special-shaped material and its production process | |
| CN110039804A (en) | A kind of functional high-polymer thin film preparation process | |
| CN111662558B (en) | High-strength flame-retardant heat-insulation composite door and window | |
| CN102964743A (en) | Energy-saving plastic composite door and window for buildings | |
| CN105131475B (en) | It is a kind of that there is wood plastic composite board of crosslinking microcellular structure and preparation method thereof | |
| CN111574785A (en) | High-gloss transparent film for protecting household products and preparation method thereof | |
| CN114410012A (en) | Piano black polypropylene material with high gloss, high weather resistance and high toughness and preparation method thereof | |
| CN107057392A (en) | A kind of reclaimed rubber ecological wooden and preparation method thereof | |
| CN111169128A (en) | Multi-layer co-extrusion outdoor weather-resistant film | |
| CN106633514A (en) | PVC pinch plate with resistance to ultraviolet aging | |
| CN110283468A (en) | A kind of preparation method of the compound plastic-wood material of high durable | |
| CN111875904A (en) | Rapid decorative plate capable of releasing negative ions and manufacturing method thereof | |
| CN105111616A (en) | Wood-plastic decorative building material | |
| CN112480645A (en) | Preparation method of high-weather-resistance flame-retardant resin tile material | |
| CN108641191A (en) | antibacterial flame retardant plastic | |
| CN109836749A (en) | A kind of preparation method of modified plastics | |
| CN109135126A (en) | A kind of modified spinelle Reinforced PVC decorative panel |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20200804 |