CN111454796B - Transparent soap-based antibacterial cleaning composition - Google Patents
Transparent soap-based antibacterial cleaning composition Download PDFInfo
- Publication number
- CN111454796B CN111454796B CN202010260232.6A CN202010260232A CN111454796B CN 111454796 B CN111454796 B CN 111454796B CN 202010260232 A CN202010260232 A CN 202010260232A CN 111454796 B CN111454796 B CN 111454796B
- Authority
- CN
- China
- Prior art keywords
- soap
- cleaning composition
- fatty acid
- surfactant
- transparent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/042—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on anionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/04—Carboxylic acids or salts thereof
- C11D1/10—Amino carboxylic acids; Imino carboxylic acids; Fatty acid condensates thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
- C11D1/146—Sulfuric acid esters
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/90—Betaines
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Dermatology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
The invention discloses a transparent soap-based antibacterial cleaning composition, which relates to the technical field of daily chemical washing products and comprises the following components in percentage by mass: 4-15% of fatty acid; 1 to 4.5 percent of potassium hydroxide; 1-10% of polyol; 1-5% of an anionic surfactant; 3-10% of a zwitterionic surfactant; 0-5% of a nonionic surfactant; 0.1-0.3% of a bactericide; 1-5% of auxiliary components; the balance being water. The transparent soap base antibacterial cleaning composition provided by the invention has a transparent appearance under the combined action of the components, is stable at a low temperature and does not precipitate; the composition has the characteristics of strong cleaning power, easy flushing and fresh use of the soap-based cleaning agent, can effectively play a role in inhibiting bacteria, is particularly suitable for people who often engage in outdoor work and participate in outdoor activities and work in hospital places, and is also suitable for wide consumer groups in epidemic seasons.
Description
Technical Field
The invention relates to the technical field of daily chemical washing products, in particular to a transparent soap-based antibacterial cleaning composition.
Background
With the improvement of the living standard of consumers, the demand of personal daily cleaning products is also increased, especially for people who often work outdoors, participate in outdoor activities, and work in hospital places, because skin pores are open and exposed outdoors or in environments containing germs for a long time, the people are easy to be infected with other diseases and inflammation caused by blocking the pores by dust and sweat, and therefore, the consumers need a personal cleaning product which has deep cleaning effect and can provide bacteriostatic activity to resist various bacteria outside. At present, the antibacterial cleaning agent on the market is mainly in the form of a composite bactericide of a lauryl alcohol polyether sulfate (AES) system or a soap-based system, but is limited by the difficult-to-wash property of AES, and the antibacterial cleaning agent of the AES system often has residual feeling in actual use, so that consumers cannot remove deep dirt of the skin, the residence time of the bactericide on the surface of the skin is prolonged, irritation is easily generated, and the allergy probability is increased. The soap-based system has higher cleaning power, is easy to wash, gives consumers a fresh and deep cleaning feeling, and better meets the requirements of deep cleanness and bacteriostasis.
For soap-based formulations, the difficulty of development is mainly poor low-temperature stability of the system, because the solubility of soap at low temperature is reduced, and the solubility of soap to free fatty acid is also reduced, so that the system is precipitated at low temperature, which greatly affects the appearance of the product and also affects the fluidity of the product. Therefore, the solution to this problem for commercially available soap-based products is usually to add an opacifier, create an opaque system, and add an opaque wrapper. In fact, for bacteriostatic cleansers, consumers prefer to see a clear, transparent product to better link the product with safe bacteriostasis.
Patent document CN 106619182a discloses a transparent soap-based body wash comprising fatty acids, anionic surfactants, thickeners, polyols, alkali, cocamide MEA, cocamidopropyl betaine, preservatives and water. The soap base shower gel has a transparent appearance, but the pH value of the system is too high (more than 10), so that the stability of the soap base at low temperature is ensured, but the too high pH value easily causes irritation to the skin, and the use comfort of the soap base shower gel needs to be enhanced.
Patent document CN 108066164a discloses a transparent soap-based body wash comprising fatty acid, inorganic base, polyhydric alcohol, zwitterionic surfactant, C8-14Alkyl glycoside, cellulose, disodium EDTA, dibutyl hydroxy toluene, methyl isothiazolinone and water. The soap-based shower gel has a transparent appearance, but the stability of the formula is insufficient, the problem of soap base precipitation still occurs in the preferable formula at a low temperature (4 ℃), and the formula stability effect needs to be enhanced.
The prior art can realize the construction of a transparent soap-based detergent system to a certain extent, but has certain problems, such as over-high pH value of the system, insufficient formula stability, inhibited activity of a bactericide, poor sterilizing effect and the like. .
Disclosure of Invention
The invention aims to solve the technical problems that the bactericide of the existing bactericidal product is inhibited and the bactericidal activity is low, and provides a transparent soap-based bacteriostatic cleaning composition which is stable at a low temperature, so that the bactericidal activity of the bactericide in a soap-based detergent system is improved, and the purchase desire of consumers on the bacteriostatic detergent product is increased.
In order to solve the above problems, the present invention proposes the following technical solutions:
a transparent soap-based antibacterial cleaning composition comprises the following components in percentage by mass:
4-15% of fatty acid; 1 to 4.5 percent of potassium hydroxide; 1-10% of polyol; 1-5% of an anionic surfactant; 3-10% of a zwitterionic surfactant; 0-5% of a nonionic surfactant; 0.1-0.3% of a bactericide; 1-5% of auxiliary components; the balance being water.
As a preferred embodiment of the invention, the transparent soap-based bacteriostatic cleaning composition consists of the following raw materials in percentage by weight: 6-11% of fatty acid, 1.8-3.4% of potassium hydroxide, 2-10% of polyhydric alcohol, 1-5% of anionic surfactant, 3-5% of zwitterionic surfactant, 0-5% of nonionic surfactant, 0.1-0.3% of bactericide, 1-5% of auxiliary component and the balance of water.
The further technical scheme is that the fatty acid is one or a combination of lauric acid, myristic acid and palmitic acid.
The further technical scheme is that the polyalcohol group is glycerol and/or methyl propylene glycol.
The further technical scheme is that the weight ratio of the fatty acid to the polyalcohol is 1: 0.25-1: 0.67.
The further technical scheme is that the anionic surfactant is one or a combination of sodium lauryl sulfate and sodium cocoyl glycinate.
The further technical scheme is that the weight ratio of the fatty acid to the anionic surfactant is 1: 0.09-1: 0.83.
The further technical scheme is that the zwitterionic surfactant is one or a combination of more of cocamidopropyl betaine and lauramidopropyl betaine.
The further technical scheme is that the weight ratio of the fatty acid to the zwitterionic surfactant is 1: 0.33-1: 0.50.
The technical scheme is that the nonionic surfactant composition is one or a combination of coco glucoside, lauryl glucoside and decyl glucoside.
The technical scheme is that the bactericide is parachlorometaxylenol.
The further technical proposal is that the auxiliary ingredient bag comprises at least one of chelating agent, anhydrous sodium sulphate, antioxidant BHT, preservative, essence and pigment.
The technical scheme is that the chelating agent in the auxiliary component is one of disodium EDTA, trisodium EDTA and tetrasodium EDTA, and the weight ratio of the chelating agent in the transparent soap-based antibacterial cleaning composition is 0.05-0.2%.
The further technical scheme is that the weight ratio of anhydrous sodium sulphate in the auxiliary components in the transparent soap-based antibacterial cleaning composition is 0-0.5%.
The technical scheme is that the weight ratio of the antioxidant in the auxiliary components in the transparent soap-based antibacterial cleaning composition is 0-0.1%.
The further technical scheme is that the preservative in the auxiliary components is a composition of phenoxyethanol and methylisothiazolinone, and the weight ratio of the phenoxyethanol to the methylisothiazolinone is 25: 1.
The further technical scheme is that the weight ratio of essence in the auxiliary components in the transparent soap-based antibacterial cleaning composition is 0.2%.
The invention also provides a preparation method of the transparent soap-based antibacterial cleaning composition, which comprises the following steps:
s1 adding EDTA tetrasodium and potassium hydroxide into water, stirring and heating to 70-85 deg.C to obtain component A.
S2 heating fatty acid, antioxidant BHT to 70-85 deg.C as component B.
S3, adding the component B into the component A, performing saponification reaction, and continuously stirring for 20-60 minutes until the system is clear and transparent and has no agglomeration.
And (3) after the saponification reaction of S4, adding the bactericide into the system, and stirring while keeping the temperature until the bactericide is dissolved.
S5 naturally cooling the system at room temperature, and adding anhydrous sodium sulphate, polyol composition, cocoyl glycinate composition, sodium xylene sulfonate, zwitterionic surfactant composition, sodium lauryl sulfate and alkyl glucoside when the temperature is reduced to 50-60 ℃.
And S6, when the temperature of the system is further reduced to 35-45 ℃, adding essence and preservative, and stirring uniformly.
Compared with the prior art, the invention can achieve the following technical effects:
(1) the transparent soap base antibacterial cleaning composition provided by the invention has a transparent appearance under the combined action of the components, is stable at a low temperature and does not precipitate; the composition has the characteristics of strong cleaning power, easy flushing and fresh use of the soap-based cleaning agent, can effectively play a role in inhibiting bacteria, is particularly suitable for people who often engage in outdoor work and participate in outdoor activities and work in hospital places, and is also suitable for wide consumer groups in epidemic seasons.
(2) The transparent soap-based antibacterial cleaning composition provided by the invention is a transparent soap-based cleaning agent, can still keep stable at low temperature, and can provide transparent appearance and increase the purchasing desire of consumers while keeping the characteristics of strong cleaning power, easiness in washing and refreshing use of the soap-based cleaning agent.
(3) The transparent soap base bacteriostatic cleaning composition provided by the invention has the characteristic of strong bacteriostatic effect, the killing rate on escherichia coli reaches 99.9%, the killing rate on staphylococcus aureus reaches 99%, the requirement that the antibacterial rate is more than or equal to 90% in the standards of GB19877.2-2005 special bath foam and GB19877.1-2005 special hand sanitizer is met, and the transparent soap base bacteriostatic cleaning composition can effectively remove harmful bacteria on the surface of skin by matching with deep cleaning of soap base, and can be popularized and used.
Detailed Description
The present invention will be further described below by way of specific embodiments, but the present invention is not limited to only the following examples. It will be apparent to those skilled in the art that suitable modifications and substitutions of equivalent components of the soap-based cleansing composition and method of preparation thereof, as described herein, can be made without departing from the spirit and scope of the invention and are intended to be included within the scope of the invention.
The content of each component of the transparent soap-based antibacterial cleaning composition provided by the embodiments 1 to 7 is shown in table 1, and the transparent soap-based antibacterial cleaning composition is prepared by the following preparation method:
(1) the component A is stirred and heated to 80 ℃.
(2) The B component was heated to 80 ℃.
(3) And adding the component B into the component A, performing saponification reaction, and continuously stirring for 50 minutes until the system is clear and transparent and has no agglomeration to obtain the system.
(4) And after the saponification reaction is finished, adding lauryl glucoside and sodium lauryl sulfate in the component C and the component D into the system, and stirring while keeping the temperature until the components are dissolved.
(5) Naturally cooling the system at room temperature, and adding the rest triclosan in the component C and the rest anhydrous sodium sulphate, glycerol, propylene glycol, methyl propylene glycol, sodium cocoyl glycinate, sodium xylene sulfonate, lauramidopropyl betaine and cocamidopropyl betaine in the component D when the temperature is reduced to 55 ℃.
(6) And when the temperature of the system is further reduced to 40 ℃, adding essence and preservative, and uniformly stirring.
TABLE 1 formulation List for inventive examples 1-7
Comparative examples 1 to 8 were prepared according to the contents of the components in table 2 by the following preparation methods:
(1) the A component is stirred and heated to 80 ℃, and simultaneously the C component is heated to 80 ℃, and stirred for 30 minutes until being dissolved.
(2) The B component was heated to 80 ℃.
(3) Adding the component B into the component A, performing saponification reaction, continuously stirring for 50 minutes until the system is clear and transparent and has no agglomeration, adding the component C into the system after the saponification reaction, and continuously stirring with heat preservation.
(4) Adding the lauryl glucoside in the component D and the component E into the system, and stirring while keeping the temperature until the lauryl glucoside is dissolved.
(5) And naturally cooling the system at room temperature, and adding the rest anhydrous sodium sulphate, glycerol, propylene glycol, methyl propylene glycol, sodium cocoyl glycinate, sodium xylene sulfonate, lauramidopropyl betaine, cocamidopropyl betaine and lauryl hydroxy sulfobetaine in the component E when the temperature is reduced to 55 ℃.
(6) And when the temperature of the system is further reduced to 40 ℃, adding essence and preservative, and uniformly stirring.
Table 2 comparative example formulation list
Test of antibacterial Property
The above examples 1 to 7 were carried out according to GB15979-2002 "Disposable sanitary products"; the antibacterial performance tests were carried out for comparative examples 1 to 2, 4, and 7 to 8, respectively, and the results are shown in table 3 below.
TABLE 3 bacteriostatic effect of the transparent soap-based bacteriostatic cleaning composition of the invention
As can be seen from the above table 3, the transparent soap-based antibacterial cleaning composition disclosed in the embodiments 1-8 of the invention has a good antibacterial effect, and the killing rate of Escherichia coli reaches 99.9%; the killing rate of staphylococcus aureus reaches 99 percent (example 6 reaches 99.9 percent), and the requirements that the antibacterial rate is more than or equal to 90 percent in the standards of GB19877.2-2005 'Special bath agent' and GB19877.1-2005 'Special hand sanitizer' are met. Therefore, the transparent soap-based antibacterial cleaning composition can reach an antibacterial level, and can be popularized and used as antibacterial bath lotion or antibacterial hand sanitizer. In the case of the bactericide PCMX, the bactericidal performance is easily affected by surfactants and other substances (such as partial polyols), especially the bactericidal performance against staphylococcus aureus. The sterilization rates of the comparative example 1 and the comparative example 2 to golden yellow are only 73.9 percent and 80.1 percent respectively, and compared with the example 3, the laureth sulfate has larger adverse effect on the bacteriostasis performance of the PCMX; the sterilization rate of the comparative example 5 to golden yellow is 96.3 percent, and the comparison with the example 2 shows that the propylene glycol has certain adverse effect on the antibacterial performance of the PCMX; the bactericidal rate of comparative example 7 and comparative example 8 to golden yellow is about 95%, and comparison with example 6 shows that lauryl hydroxy sulfobetaine has a certain inhibitory effect on the antibacterial performance of PCMX.
And (3) stability testing:
the stability at high and low temperatures was examined for examples 1 to 7 and comparative examples 1 to 8, respectively, and the results are shown in Table 4 below.
Table 4 high and low temperature stability performance of the clear soap-based bacteriostatic cleansing compositions of the invention
As can be seen from the test results in table 4, the polyol is one of the important factors for maintaining the low temperature stability of the soap-based system, because the polyol has the function of dispersing and dissolving the free soap, preventing further agglomeration and precipitation; in order to maintain the stability of the system at low temperatures, the weight ratio of polyol to fatty acid needs to be greater than 1: 4. In combination with the results of the antimicrobial tests in table 3, propylene glycol had some negative impact on bacteriostasis and therefore need to be excluded when selecting polyols. Betaine amphoteric surfactant has the same effect on stabilizing a soap base system, and under a low addition ratio, lauramidopropyl betaine has stronger soap stabilizing capability than cocoamidopropyl betaine; lauryl hydroxy sulfobetaine also has good soap stabilizing capability, but also has a certain inhibition effect on bacteriostatic agents, so that the lauryl hydroxy sulfobetaine needs to be removed when selecting soap stabilizing amphoteric surfactant. In addition, sodium lauryl sulfate has a certain improvement effect on the bacteriostatic effect, but the risk of the precipitation of a soap-based system is increased, and lauryl glucoside can be added into the system to improve the low-temperature stability.
According to experimental results, it is found that several raw materials which can play a stabilizing role in a soap-based system, such as propylene glycol and lauryl hydroxy sulfobetaine, all have a certain inhibition role in the bactericide PCMX, which indicates that in the transparent soap-based antibacterial cleaning composition, high sterilization activity is realized, and at the same time, the stability of the soap-based system at low temperature is ensured, so that the mutual synergy of the raw materials in the formula needs to be exerted, and the activity inhibition role in the bactericide is reduced while the solubilization bactericide is ensured.
The transparent soap-based antibacterial cleaning composition can regulate and control the formula within the range of the invention according to the product types and the oriented crowds, and can be finally used as the product forms of antibacterial shower gel, antibacterial hand sanitizer and the like for industrial production.
In the above embodiments, the descriptions of the respective embodiments have respective emphasis, and for parts that are not described in detail in a certain embodiment, reference may be made to related descriptions of other embodiments.
While the invention has been described with reference to specific embodiments thereof, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims. Therefore, the protection scope of the present invention shall be subject to the protection scope of the claims.
Claims (6)
1. The transparent soap-based antibacterial cleaning composition is characterized by comprising the following components in percentage by mass:
4-15% of fatty acid;
1 to 4.5 percent of potassium hydroxide;
1-10% of polyol;
1-5% of an anionic surfactant;
3-10% of a zwitterionic surfactant;
0-5% of a nonionic surfactant;
0.1-0.3% of a bactericide;
1-5% of auxiliary components;
the balance of water;
wherein the bactericide is parachlorometaxylenol; the auxiliary components comprise at least one of a chelating agent, anhydrous sodium sulphate, an antioxidant BHT, a preservative, essence and a pigment; the polyalcohol is one or more of glycerol and methyl propylene glycol; the zwitterionic surfactant is one or more of cocamidopropyl betaine and lauramidopropyl betaine; the nonionic surfactant composition is one of coco glucoside, lauryl glucoside and decyl glucoside or a composition thereof.
2. The soap-based bacteriostatic cleansing composition according to claim 1, wherein the fatty acid is one or more of lauric acid, myristic acid and palmitic acid.
3. The soap-based bacteriostatic cleaning composition according to claim 1, wherein the weight ratio of the fatty acid to the polyol is 1: 0.25-1: 0.67.
4. The soap-based bacteriostatic cleaning composition according to claim 1, wherein the anionic surfactant is one or more of sodium lauryl sulfate and sodium cocoyl glycinate.
5. The transparent soap-based bacteriostatic cleaning composition according to claim 1, wherein the weight ratio of the fatty acid to the anionic surfactant is 1: 0.09-1: 0.83.
6. The soap-based bacteriostatic cleaning composition according to claim 1, wherein the weight ratio of the fatty acid to the zwitterionic surfactant is 1: 0.33-1: 0.50.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010260232.6A CN111454796B (en) | 2020-04-03 | 2020-04-03 | Transparent soap-based antibacterial cleaning composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202010260232.6A CN111454796B (en) | 2020-04-03 | 2020-04-03 | Transparent soap-based antibacterial cleaning composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN111454796A CN111454796A (en) | 2020-07-28 |
| CN111454796B true CN111454796B (en) | 2021-07-02 |
Family
ID=71674897
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202010260232.6A Active CN111454796B (en) | 2020-04-03 | 2020-04-03 | Transparent soap-based antibacterial cleaning composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN111454796B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113136273B (en) * | 2021-04-15 | 2022-04-15 | 广州洁生日化有限公司 | Antibacterial hand-washing soap flakes and preparation method thereof |
| CN113416617A (en) * | 2021-06-23 | 2021-09-21 | 杭州微冠科技有限公司 | Transparent soap key isolation rubber pad |
| CN113403155B (en) * | 2021-06-23 | 2023-04-18 | 浙江大学 | Preparation method of crystal soap |
| CN114921296A (en) * | 2022-06-17 | 2022-08-19 | 上海家化联合股份有限公司 | Soap-based self-thickening cleansing compositions |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830555A (en) * | 2015-05-16 | 2015-08-12 | 青岛德翕拓创高新技术有限公司 | Bactericidal towel detergent |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1162633A (en) * | 1996-04-18 | 1997-10-22 | 赵正治 | Soft soap for skin nursing and production thereof |
| CN106619182B (en) * | 2016-12-29 | 2019-11-15 | 广州市科能化妆品科研有限公司 | A kind of Transparent soap base bath composition of low-temperature stabilization |
| CN108066164B (en) * | 2017-12-28 | 2020-06-19 | 上海家化联合股份有限公司 | Transparent composite cleaning composition and preparation method thereof |
| CN108125812B (en) * | 2018-01-10 | 2019-01-08 | 壹田（广州）生活健康用品有限公司 | A kind of antibacterial foam liquid soap of amino acid pattern and preparation method thereof |
| CN108852860A (en) * | 2018-09-13 | 2018-11-23 | 花安堂生物科技集团有限公司 | A kind of composition and its preparation method and application with layered liquid crystal phase |
| CN110074992A (en) * | 2019-04-24 | 2019-08-02 | 上海中翊日化有限公司 | Transparent soap base shower cream and preparation method |
-
2020
- 2020-04-03 CN CN202010260232.6A patent/CN111454796B/en active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830555A (en) * | 2015-05-16 | 2015-08-12 | 青岛德翕拓创高新技术有限公司 | Bactericidal towel detergent |
Also Published As
| Publication number | Publication date |
|---|---|
| CN111454796A (en) | 2020-07-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN111454796B (en) | Transparent soap-based antibacterial cleaning composition | |
| CN102559408B (en) | Pure plant type antibacterial cleanser and preparation method thereof | |
| JP5140267B2 (en) | Liquid disinfectant cleaning composition | |
| EP2925282B1 (en) | Mild antibacterial cleansing compositions | |
| EP2768473A2 (en) | Triclosan-free antibacterial soap | |
| JP2020514248A (en) | Antimicrobial composition containing trace acting metal | |
| JP5204389B2 (en) | Liquid disinfectant cleaning composition | |
| JP2556973B2 (en) | Antiseptic composition | |
| SA515370197B1 (en) | Low alcohol content disinfection foams | |
| US9855205B2 (en) | Use of zinc coceth sulfate as an antibacterial agent against propionibacterium acnes | |
| JP2003226636A (en) | Weak-acidic cleansing preparation | |
| WO2019081152A1 (en) | Non-soap liquid cleanser composition comprising caprylic acid | |
| KR20090131587A (en) | Disinfectant composition for hand including mastic | |
| US11278480B2 (en) | Antimicrobial composition comprising a fatty acid/soap/polyvinyl alcohol mixture | |
| CN111228177A (en) | Bacteriostatic easy-to-wash foam hand sanitizer and preparation method thereof | |
| CN108653048A (en) | A kind of disposable hand sanitizing fluid of environment-friendly type safety nonhazardous | |
| JP2003160450A (en) | Shampoo composition | |
| US20230381068A1 (en) | Personal care compositions | |
| CN112933005A (en) | Efficient antibacterial skin-moistening type hand sanitizer and preparation method thereof | |
| US20050008606A1 (en) | Personal care composition | |
| WO2024041888A1 (en) | A skin cleansing composition | |
| CN112120950A (en) | Sterilizing bath foam | |
| CN113244129A (en) | Antibacterial hand sanitizer and preparation method thereof | |
| CN108653049A (en) | A kind of persistent form hand cleanser of moisturizing containing shea butter | |
| JP2005187348A (en) | Anti-microbial skin cleanser composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |