CN111423753A - Wear-resistant wet-feel road marking paint - Google Patents

Wear-resistant wet-feel road marking paint Download PDF

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Publication number
CN111423753A
CN111423753A CN201911033937.8A CN201911033937A CN111423753A CN 111423753 A CN111423753 A CN 111423753A CN 201911033937 A CN201911033937 A CN 201911033937A CN 111423753 A CN111423753 A CN 111423753A
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CN
China
Prior art keywords
wet
parts
marking
sensitive
marked line
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Pending
Application number
CN201911033937.8A
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Chinese (zh)
Inventor
乔建刚
彭斌
张恒
史果香
谢一丹
王敏
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Hebei University of Technology
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Hebei University of Technology
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Priority to CN201911033937.8A priority Critical patent/CN111423753A/en
Publication of CN111423753A publication Critical patent/CN111423753A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/002Priming paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01CCONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
    • E01C23/00Auxiliary devices or arrangements for constructing, repairing, reconditioning, or taking-up road or like surfaces
    • E01C23/16Devices for marking-out, applying, or forming traffic or like markings on finished paving; Protecting fresh markings
    • E01C23/20Devices for marking-out, applying, or forming traffic or like markings on finished paving; Protecting fresh markings for forming markings in situ
    • EFIXED CONSTRUCTIONS
    • E01CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
    • E01FADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
    • E01F9/00Arrangement of road signs or traffic signals; Arrangements for enforcing caution
    • E01F9/50Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
    • E01F9/576Traffic lines

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Architecture (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Road Repair (AREA)
  • Road Signs Or Road Markings (AREA)

Abstract

The invention discloses wear-resistant and wet-feeling road marking paint which is designed according to the following principle: carrying out double-layer paving treatment on the ground marked line, wherein the marked line of the base layer is made of yellow acrylic resin material; and the surface course marking is the wet coating of feeling of white that covers the effect well under the dry condition, and when rainy day or road surface humidity are great, the road marking can show the colour of basic unit, shows the white of surface course again after the road surface is dry. The surface layer material of the wet-sensitive marking line is prepared from a wet-sensitive color-changing body, a sensitizing agent, a toner, a film-forming agent and the likeThe wet paint consists of cobalt chloride and hexamethylene tetramine as color changing material capable of changing color with the change of humidity in atmosphere and urea as sensitizer6ON2) The toner is chlorinated phthalocyanine and the film-forming agent is butyl acrylate. The proportion of each component is 15-20 parts of cobalt chloride, 15-20 parts of hexamethylenetetramine, 1-3 parts of urea, 5-10 parts of chlorinated phthalocyanine and 55-60 parts of butyl acrylate.

Description

Wear-resistant wet-feel road marking paint
Technical Field
The invention relates to the field of traffic markings, in particular to wear-resistant and wet-feel road marking paint.
Background
Road marking is one of the important safety facilities of road, has played instruction and warning effect to the road user, and the most road marking type of using in each country at present mainly has: normal temperature solvent type, heating solvent type, hot melt vibration type, water-based road marking, anti-skid road marking and the like. From the characteristics and the application condition of all kinds of marked lines, most marked lines do not have good wear resistance, and most importantly, the marked lines cannot play a good warning effect on drivers under the weather conditions of rain, snow and haze, and the driving safety cannot be guaranteed. Therefore, the method aims at areas with more days of rain, snow and haze: the road surface marking has poor durability, low visibility when a driver drives a vehicle, wet and smooth road surface and difficulty in being perceived under the condition, so that the problem of frequent traffic accidents is caused, and the novel wear-resistant wet-feeling marking paint is provided.
Disclosure of Invention
The invention aims to: aiming at the defects in the prior art, the road marking which has good wear resistance and can show good warning effect under the weather conditions of rain, snow, haze and the like is designed.
The invention designs a road marking capable of displaying a good warning effect under weather conditions such as rain, snow, haze and the like, which is designed according to the following design principle: the ground marked line is subjected to double-layer paving treatment, the marked line of the base layer is a yellow acrylic resin material, has a carbon double structure, has strong durability and wear resistance, does not fade, is convenient to clean, can reduce the radiant heat of the asphalt pavement, and is an environment-friendly material; and the surface course marking is the wet coating of feeling of white that covers the effect well under the dry condition, and when rainy day or road surface humidity are great, the road marking can show the colour of basic unit, shows the white of surface course again after the road surface is dry. The surface layer of the wet-sensitive marking line is composed of raw materials such as a wet-sensitive color-changing body, a sensitizing agent, a toner, a film-forming agent and the like, wherein the raw materials of the color-changing body are cobalt chloride and hexamethylenetetramine (C)6H12N4) The color of the material can change with the change of humidity in the atmosphere, and the sensitizing agent is urea (CN)6ON2) The toner is chlorinated phthalocyanine and the film-forming agent is butyl acrylate. The proportion of each component is 15-20 parts of cobalt chloride, 15-20 parts of hexamethylenetetramine, 1-3 parts of urea, 5-10 parts of chlorinated phthalocyanine and 55-60 parts of butyl acrylate. When the wet color-changing coating is used as a surface layer material of a wet marking, the covering effect and the color-changing effect when the coating and printing times are 3 times are both optimal; the recommended total thickness of the marked line is about 0.7mm to 2mm, and the marked line with the thickness of 1mm has the highest dynamic stability of 4117.647 times/mm. Through a dynamic stability simulation real vehicle test, the appearance of the marking line is kept unchanged, the conditions of falling and abrasion are avoided, and good abrasion resistance is shown.
① compared with the basic dynamic stability of the rut plate, the dynamic stability is improved by 91.7%, the marking has good anti-rut performance and wear resistance, 14.1% of cost can be saved by adopting the wear-resistant wet-feeling marking, the required construction environment is loose, the working site area is small, the construction can be carried out at-20 to 40 degrees, the traffic can be opened after about half hour after the construction, the laying efficiency is high, the traffic delay caused by the construction is reduced, and the influence on the road traffic flow is small, therefore, compared with the common marking, the novel wear-resistant wet-feeling marking embodies a great economic advantage, ② viewed from the social benefit aspect, the use of the wear-resistant wet-feeling marking as an environment-friendly material has very important significance on prolonging the service life of the marking, reducing the road noise and reducing the environmental pollution, and can show good driving warning effect under the weather conditions of rain, snow, fog and the like, and the safety of drivers and the violation of driving are reduced.
Detailed Description
In order to make the objects, technical solutions and advantages of the present invention more apparent, the present invention is further described in detail with reference to the following embodiments.
Embodiment 1, this embodiment discloses a wet-feel wear-resistant road marking paint, which comprises the following components by weight: 18 parts of cobalt chloride, 17 parts of hexamethylenetetramine, 2 parts of urea, 8 parts of chlorinated phthalocyanine and 55 parts of butyl acrylate in the surface layer; the acrylic resin of the base layer is proper.
1. Construction process of wet-sensing marking line
Mainly comprises four steps: preparation work such as pavement cleaning (pavement protection and priming), preparation and paving of acrylic resin materials (adding coarse sand, adding an auxiliary agent, a reinforcing agent and blade coating operation in raw materials), coating and printing of wet-feel paint and open traffic (tearing of adhesive tapes). The protection of the pavement is to cover the area except the marked line with an adhesive tape so as to prevent the marked line material from sputtering to the normal pavement, and the priming paint is used for enhancing the bonding force between the marked line and the pavement. The formulation of the materials used in the stage of preparing the acrylic resin is shown in the following table.
Figure BSA0000193345300000021
2. Points of construction attention
(1) The surface of the rut plate is not cleaned completely in the test process, so that the marked line falls off, and therefore, in the road surface cleaning stage, the road surface is ensured to be dry, clean, free of oil stains, foreign matters and dust, and otherwise, the construction quality is poor.
(2) In order to ensure that other road surfaces except the marked line region are not polluted by the coating, the road surface of the construction road section needs to be locally protected, and the adhesive tape is pasted on the region except the marked line region.
(3) When the primer is coated on the cement pavement, the primer is uniformly coated, so that the acrylic resin material is tightly adhered to the pavement. The concrete pavement and the asphalt pavement do not need to be brushed with primer, and can be well bonded with the acrylic resin material under the condition of clean pavement.
(4) After the primer is dried, adding the aggregate, the auxiliary agent and the curing agent according to the proportion, uniformly stirring, then carrying out blade coating operation, selecting the particle size of the coarse sand according to different thicknesses, and uniformly stirring before adding the coarse sand. Although the amount of the auxiliary agent and the catalyst is increased to accelerate the curing of the resin material, the mixture ratio is not more than the recommended value for ensuring the safety of constructors because the mixture releases a large amount of heat during the reaction.
(5) After finishing the scratch coating operation of the marked line, the adhesive tape needs to be removed after the marked line is completely dried, and the traffic is opened, so that the quality problem can be caused when the traffic is opened under the condition that the marked line is not dried.
Finally, the above embodiments are only for illustrating the technical solutions of the present invention and not for limiting, although the present invention has been described in detail with reference to the preferred embodiments, it should be understood by those skilled in the art that modifications or equivalent substitutions may be made to the technical solutions of the present invention without departing from the spirit and scope of the technical solutions of the present invention, and all of them should be covered in the claims of the present invention.

Claims (3)

1. The utility model provides a can demonstrate wear-resisting wet nature road marking of good warning effect under weather conditions such as sleet, haze, its design principle as follows: the ground marked line is subjected to double-layer paving treatment, the marked line of the base layer is made of yellow acrylic resin material with strong wear resistance, and the marked line of the surface layer is white wet-feel paint with good covering effect under the dry condition.
2. The wear-resistant, wetness-sensitive pavement marker of claim 1, wherein: the surface layer material of the wet-sensitive marking line is a wet-sensitive coating material composed of wet-sensitive color change body, sensitizing agent, toner, film-forming agent and other raw materials, wherein the raw materials of the wet-sensitive color change body are cobalt chloride and hexamethylenetetramine (C)6H12N4) The color of the material can change with the change of humidity in the atmosphere, and the sensitizing agent is urea (CN)6ON2) The toner is chlorinated phthalocyanine and the film-forming agent is butyl acrylate.
3. The white wet paint according to claim 1, characterized in that: the proportion of each component is 15-20 parts of cobalt chloride, 15-20 parts of hexamethylenetetramine, 1-3 parts of urea, 5-10 parts of chlorinated phthalocyanine and 55-60 parts of butyl acrylate.
CN201911033937.8A 2019-10-25 2019-10-25 Wear-resistant wet-feel road marking paint Pending CN111423753A (en)

Priority Applications (1)

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CN201911033937.8A CN111423753A (en) 2019-10-25 2019-10-25 Wear-resistant wet-feel road marking paint

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1035314A (en) * 1988-02-13 1989-09-06 北京纺织科学研究所 Moistrure sensitive allochromic coating
CN1047101A (en) * 1989-05-08 1990-11-21 王胜利 Refletorized paint
CN1048555A (en) * 1990-08-28 1991-01-16 北京纺织科学研究所 Moistrure sensitive allochromic coating
CN101063019A (en) * 2006-04-28 2007-10-31 郭接宁 Aqueous long-acting reflecting road traffic marking paint
CN107503300A (en) * 2017-08-31 2017-12-22 河北工业大学 A kind of traffic alarm graticule and its construction method based on the wet color-change technology of sense
CN108641049A (en) * 2018-05-22 2018-10-12 河北工业大学 A kind of preparation method of the aqueous super hydrophobic material of fluorine-free monomer

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1035314A (en) * 1988-02-13 1989-09-06 北京纺织科学研究所 Moistrure sensitive allochromic coating
CN1047101A (en) * 1989-05-08 1990-11-21 王胜利 Refletorized paint
CN1048555A (en) * 1990-08-28 1991-01-16 北京纺织科学研究所 Moistrure sensitive allochromic coating
CN101063019A (en) * 2006-04-28 2007-10-31 郭接宁 Aqueous long-acting reflecting road traffic marking paint
CN107503300A (en) * 2017-08-31 2017-12-22 河北工业大学 A kind of traffic alarm graticule and its construction method based on the wet color-change technology of sense
CN108641049A (en) * 2018-05-22 2018-10-12 河北工业大学 A kind of preparation method of the aqueous super hydrophobic material of fluorine-free monomer

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Application publication date: 20200717