CN111370234A - 一种MXene/金纳米颗粒复合电极材料的制备方法及其应用 - Google Patents
一种MXene/金纳米颗粒复合电极材料的制备方法及其应用 Download PDFInfo
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- CN111370234A CN111370234A CN202010111680.XA CN202010111680A CN111370234A CN 111370234 A CN111370234 A CN 111370234A CN 202010111680 A CN202010111680 A CN 202010111680A CN 111370234 A CN111370234 A CN 111370234A
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- mxene
- gold nanoparticle
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- 239000010931 gold Substances 0.000 title claims abstract description 91
- 229910052737 gold Inorganic materials 0.000 title claims abstract description 79
- 239000002105 nanoparticle Substances 0.000 title claims abstract description 76
- 239000007772 electrode material Substances 0.000 title claims abstract description 66
- 239000002131 composite material Substances 0.000 title claims abstract description 64
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000000243 solution Substances 0.000 claims abstract description 70
- 239000002253 acid Substances 0.000 claims abstract description 47
- 239000007864 aqueous solution Substances 0.000 claims abstract description 28
- 238000003756 stirring Methods 0.000 claims abstract description 19
- 239000002245 particle Substances 0.000 claims abstract description 14
- 238000003828 vacuum filtration Methods 0.000 claims abstract description 14
- 238000002156 mixing Methods 0.000 claims abstract description 7
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 73
- 239000012528 membrane Substances 0.000 claims description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 18
- 239000008367 deionised water Substances 0.000 claims description 15
- 229910021641 deionized water Inorganic materials 0.000 claims description 15
- 239000006228 supernatant Substances 0.000 claims description 12
- 238000007865 diluting Methods 0.000 claims description 11
- 238000001035 drying Methods 0.000 claims description 10
- 239000002244 precipitate Substances 0.000 claims description 9
- 238000009210 therapy by ultrasound Methods 0.000 claims description 9
- 238000005406 washing Methods 0.000 claims description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- 238000005530 etching Methods 0.000 claims description 4
- 238000005119 centrifugation Methods 0.000 claims description 3
- 239000000084 colloidal system Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 description 21
- 239000006185 dispersion Substances 0.000 description 15
- 239000010410 layer Substances 0.000 description 10
- 239000011259 mixed solution Substances 0.000 description 9
- 238000002441 X-ray diffraction Methods 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 6
- 239000000376 reactant Substances 0.000 description 6
- 238000001878 scanning electron micrograph Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 239000003990 capacitor Substances 0.000 description 4
- 239000003792 electrolyte Substances 0.000 description 4
- 239000002135 nanosheet Substances 0.000 description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 3
- 229910021607 Silver chloride Inorganic materials 0.000 description 3
- 229910009818 Ti3AlC2 Inorganic materials 0.000 description 3
- 238000005273 aeration Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000002484 cyclic voltammetry Methods 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 239000011229 interlayer Substances 0.000 description 3
- 238000003760 magnetic stirring Methods 0.000 description 3
- 239000002082 metal nanoparticle Substances 0.000 description 3
- 229910000510 noble metal Inorganic materials 0.000 description 3
- 229910052697 platinum Inorganic materials 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 3
- 125000006850 spacer group Chemical group 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000005056 compaction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 229910021389 graphene Inorganic materials 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000008358 core component Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
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- 238000004519 manufacturing process Methods 0.000 description 1
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- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- QPJSUIGXIBEQAC-UHFFFAOYSA-N n-(2,4-dichloro-5-propan-2-yloxyphenyl)acetamide Chemical compound CC(C)OC1=CC(NC(C)=O)=C(Cl)C=C1Cl QPJSUIGXIBEQAC-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- -1 transition metal sulfide Chemical class 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/22—Electrodes
- H01G11/30—Electrodes characterised by their material
- H01G11/32—Carbon-based
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01G—CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE
- H01G11/00—Hybrid capacitors, i.e. capacitors having different positive and negative electrodes; Electric double-layer [EDL] capacitors; Processes for the manufacture thereof or of parts thereof
- H01G11/84—Processes for the manufacture of hybrid or EDL capacitors, or components thereof
- H01G11/86—Processes for the manufacture of hybrid or EDL capacitors, or components thereof specially adapted for electrodes
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- Engineering & Computer Science (AREA)
- Power Engineering (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
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CN202010111680.XA CN111370234B (zh) | 2020-02-24 | 2020-02-24 | 一种MXene/金纳米颗粒复合电极材料的制备方法及其应用 |
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CN202010111680.XA CN111370234B (zh) | 2020-02-24 | 2020-02-24 | 一种MXene/金纳米颗粒复合电极材料的制备方法及其应用 |
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CN111370234A true CN111370234A (zh) | 2020-07-03 |
CN111370234B CN111370234B (zh) | 2021-01-26 |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112928279A (zh) * | 2021-01-28 | 2021-06-08 | 山东大学 | 一种三维锂电池集流体及其制备方法与应用 |
CN113218296A (zh) * | 2021-03-23 | 2021-08-06 | 上海交通大学 | 一种弹性应变传感器及其制备方法 |
CN113223776A (zh) * | 2021-05-11 | 2021-08-06 | 北京理工大学前沿技术研究院 | 一种自支撑MXene/MWCNT柔性复合薄膜及其制备方法和应用 |
CN113267276A (zh) * | 2021-05-18 | 2021-08-17 | 电子科技大学 | 一种柔性电子材料及其制备方法和应用 |
CN114264702A (zh) * | 2021-12-24 | 2022-04-01 | 安徽工业大学 | 一种MXene@Au自修复水凝胶气敏材料、气敏元件、气体传感器、制备方法及其应用 |
CN114621633A (zh) * | 2020-12-10 | 2022-06-14 | 中国科学院大连化学物理研究所 | 水系MXene基储能电极材料3D打印油墨、其制备方法以及应用 |
CN114672233A (zh) * | 2022-03-15 | 2022-06-28 | 电子科技大学长三角研究院(湖州) | 一种基于MXene@Au杂化物的光热超疏水涂层及其制备方法 |
CN115060775A (zh) * | 2022-06-29 | 2022-09-16 | 西北师范大学 | MXene负载金纳米团簇复合材料的制备及作为同型半胱氨酸电化学传感器的应用 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107221428A (zh) * | 2017-06-13 | 2017-09-29 | 苏州大学 | 一种金属氧化物/MXene二维纳米复合物、其制备方法与应用 |
CN108793166A (zh) * | 2018-07-10 | 2018-11-13 | 中国科学院宁波材料技术与工程研究所 | 副族金属复合MXenes的复合材料、其制法及应用 |
-
2020
- 2020-02-24 CN CN202010111680.XA patent/CN111370234B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107221428A (zh) * | 2017-06-13 | 2017-09-29 | 苏州大学 | 一种金属氧化物/MXene二维纳米复合物、其制备方法与应用 |
CN108793166A (zh) * | 2018-07-10 | 2018-11-13 | 中国科学院宁波材料技术与工程研究所 | 副族金属复合MXenes的复合材料、其制法及应用 |
Non-Patent Citations (3)
Title |
---|
ELUMALAI SATHEESHKUMAR: ""One-step Solution Processing of Ag, Au and Pd@MXene Hybrids for SERS"", 《SCIENTIFIC REPORTS》 * |
SATHEESHKUMAR ELUMALAI: ""A composite film prepared from titanium carbide Ti3C2Tx (MXene) and gold nanoparticles for voltammetric determination of uric acid and folic acid"", 《MICROCHIMICA ACTA》 * |
孟奇: ""MXene/ 银纳米线超级电容器电极材料的电化学性能"", 《储能科学与技术》 * |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN114621633A (zh) * | 2020-12-10 | 2022-06-14 | 中国科学院大连化学物理研究所 | 水系MXene基储能电极材料3D打印油墨、其制备方法以及应用 |
CN114621633B (zh) * | 2020-12-10 | 2022-10-04 | 中国科学院大连化学物理研究所 | 水系MXene基储能电极材料3D打印油墨、其制备方法以及应用 |
CN112928279A (zh) * | 2021-01-28 | 2021-06-08 | 山东大学 | 一种三维锂电池集流体及其制备方法与应用 |
CN113218296A (zh) * | 2021-03-23 | 2021-08-06 | 上海交通大学 | 一种弹性应变传感器及其制备方法 |
CN113218296B (zh) * | 2021-03-23 | 2022-05-31 | 上海交通大学 | 一种弹性应变传感器及其制备方法 |
CN113223776A (zh) * | 2021-05-11 | 2021-08-06 | 北京理工大学前沿技术研究院 | 一种自支撑MXene/MWCNT柔性复合薄膜及其制备方法和应用 |
CN113267276A (zh) * | 2021-05-18 | 2021-08-17 | 电子科技大学 | 一种柔性电子材料及其制备方法和应用 |
CN113267276B (zh) * | 2021-05-18 | 2022-07-01 | 电子科技大学 | 一种柔性电子材料及其制备方法和应用 |
CN114264702A (zh) * | 2021-12-24 | 2022-04-01 | 安徽工业大学 | 一种MXene@Au自修复水凝胶气敏材料、气敏元件、气体传感器、制备方法及其应用 |
CN114672233A (zh) * | 2022-03-15 | 2022-06-28 | 电子科技大学长三角研究院(湖州) | 一种基于MXene@Au杂化物的光热超疏水涂层及其制备方法 |
CN115060775A (zh) * | 2022-06-29 | 2022-09-16 | 西北师范大学 | MXene负载金纳米团簇复合材料的制备及作为同型半胱氨酸电化学传感器的应用 |
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Inventor after: Hou Xinmei Inventor after: Wu Wei Inventor after: Yang Tao Inventor after: Wang Enhui Inventor after: Chen Junhong Inventor after: Li Bin Inventor before: Hou Xinmei Inventor before: Wu Wei Inventor before: Yang Tao Inventor before: Wang Enhui Inventor before: Chen Junhong Inventor before: Li Bin |
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