CN111304927A - Automobile seat cushion leather with crystal effect and preparation method thereof - Google Patents

Automobile seat cushion leather with crystal effect and preparation method thereof Download PDF

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Publication number
CN111304927A
CN111304927A CN202010134899.1A CN202010134899A CN111304927A CN 111304927 A CN111304927 A CN 111304927A CN 202010134899 A CN202010134899 A CN 202010134899A CN 111304927 A CN111304927 A CN 111304927A
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China
Prior art keywords
parts
leather
seat cushion
coating
automobile seat
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CN202010134899.1A
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Chinese (zh)
Inventor
庄君新
张成王
刘贤军
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Mingxin Xuteng New Material Co ltd
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Mingxin Xuteng New Material Co ltd
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Priority to CN202010134899.1A priority Critical patent/CN111304927A/en
Publication of CN111304927A publication Critical patent/CN111304927A/en
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/145Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/007Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by mechanical or physical treatments
    • D06N3/0077Embossing; Pressing of the surface; Tumbling and crumbling; Cracking; Cooling; Heating, e.g. mirror finish
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/0086Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique
    • D06N3/0088Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin
    • D06N3/009Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the application technique by directly applying the resin by spraying components on the web
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/142Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes mixture of polyurethanes with other resins in the same layer
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06NWALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N2211/00Specially adapted uses
    • D06N2211/12Decorative or sun protection articles
    • D06N2211/26Vehicles, transportation
    • D06N2211/263Cars

Abstract

The invention discloses an automobile seat cushion leather with crystal effect and a preparation method thereof, wherein the preparation method comprises the following steps: A. preparing a base coat slurry, coating the base coat slurry on the surface of a leather blank, drying, cooling to form a base coat, and rolling; B. preparing slurry of a coloring layer, coating the slurry on the surface of a leather blank, drying and cooling the leather blank to form the coloring layer; C. preparing intermediate layer slurry, coating the intermediate layer slurry on the surface of a blank, drying and cooling the blank to form an intermediate layer; D. breaking down; E. preparing a top gloss layer slurry, coating the top gloss layer slurry on the surface of a leather blank, drying and cooling the leather blank to form a top gloss layer; and rolling to obtain the automobile seat cushion leather with crystal effect. The preparation method of the invention increases the middle layer in the leather finishing process, and introduces the leather cracking resin and the high-gloss hard wax into the middle layer, so that the crystal water artistic special effect is generated on the surface of the leather after the leather is flaked, thereby increasing the ornamental value of the leather and forming a special artistic special effect.

Description

Automobile seat cushion leather with crystal effect and preparation method thereof
Technical Field
The invention relates to the field of leather products, in particular to automobile seat cushion leather with a crystal effect and a preparation method thereof.
Background
As is well known, leather industry has been in the endeavor of numerous designers, and leather becomes an element leading fashion trend in their hands, and the style of automobile cushion leather is monotonous compared with clothing leather, shoe upper leather and sofa leather under the development of diversified leather.
With the rapid development of the automobile industry, consumers who take europe as a runner begin to pay more attention to the style and appearance of automobile cushion leather and the like. Therefore, the fashion and artistry of the automobile cushion leather also become a focus of attention. The technology enriches the style and the variety of the automobile seat cushion leather under the background, so that the automobile seat cushion leather has high ornamental value and does not lose the original color of practicability.
Based on the situation, the invention provides the automobile seat cushion leather with the crystal effect and the preparation method thereof.
Disclosure of Invention
The invention aims to provide automobile seat cushion leather with a crystal effect and a preparation method thereof. The preparation method of the automobile seat cushion leather with the crystal effect increases the middle layer in the leather finishing process, introduces the leather cracking resin and the high-gloss hard wax into the middle layer, leads the surface of the leather to generate crystal water artistic special effect after being flafted, thereby increasing the ornamental value of the leather, forming special artistic special effect, and simultaneously increases the polyurethane top light layer with high physical property and transparency on the middle layer to meet the physical property requirement of the automobile leather.
In order to solve the technical problems, the technical scheme provided by the invention is as follows:
a preparation method of automobile seat cushion leather with crystal effect comprises the following steps:
A. preparing a base coat slurry, adjusting the consistency to be 48 +/-4 seconds of a No. 4 Ford cup, and coating the prepared base coat slurry on the surface of a leather blank in a roller coating mode, wherein the coating amount is 7.0 +/-0.5 g/sqft; then drying and cooling the mixture at the temperature of 95-125 ℃ to form a bottom coating, and rolling the mixture;
B. preparing coloring layer slurry, adjusting the consistency to be 38 +/-3 seconds of a No. 4 Ford cup, and coating the prepared coloring layer slurry on the surface of a leather blank in a spraying mode, wherein the coating amount is 2 +/-0.2 g/sqft; then drying and cooling the substrate at the temperature of 105-125 ℃ to form a coloring layer;
C. preparing middle layer slurry, adjusting the consistency to be 35 +/-2 seconds in a No. 4 Ford cup, and coating the prepared middle layer slurry on the surface of a blank in a spraying mode, wherein the coating amount is 3 +/-0.2 g/sqft; then drying and cooling the substrate at the temperature of 110-130 ℃ to form an intermediate layer;
D. and (3) softening: c, under the condition that the rotating speed is 12-15 r/min, the leather blank treated in the step C is flawed for 60 +/-10 min;
E. preparing the top gloss layer slurry, adjusting the consistency to be 35 +/-2 seconds of a No. 4 Ford cup, and coating the prepared top gloss layer slurry on the surface of a blank in a spraying mode, wherein the coating amount is 2 +/-0.2 g/sqft; then drying and cooling the substrate at the temperature of 105-125 ℃ to form a top light layer; and rolling to obtain the automobile seat cushion leather with crystal effect.
The preparation method of the automobile seat cushion leather with the crystal effect can enable the automobile seat cushion leather to form rich artistic special effect, and enable the automobile seat cushion leather to have unique characteristics under the stream of the streamline.
Preferably, in the step a, the priming paint comprises the following raw materials in parts by weight: 85-90 parts of polyurethane resin, 14-15 parts of color paste and 2-2.5 parts of polycarbodiimide crosslinking agent.
Preferably, in step B, the color layer slurry comprises the following raw materials in parts by weight: 82-86 parts of polyurethane resin, 14-15 parts of color paste, 2-2.5 parts of flatting agent and 2-2.5 parts of polycarbodiimide crosslinking agent.
Preferably, in step C, the intermediate layer slurry comprises the following raw materials in parts by weight: 55-65 parts of polycarbonate-polyether transparent polyurethane elastic resin, 30-37 parts of leather cracking resin, 8-12 parts of highlight hard wax, 20-25 parts of color paste, 2-3 parts of a leveling agent and 2-3 parts of a cross-linking agent.
Preferably, the high gloss hard wax is a high gloss super hard wax from Stahl corporation: the WAX 186.
Preferably, in the step E, the top light layer slurry comprises the following raw materials in parts by weight: 80-85 parts of polycarbonate-polyether transparent polyurethane elastic resin, 18-20 parts of color paste, 1-2 parts of organic silicon assistant, 2-3 parts of flatting agent, 8-10 parts of hand feeling agent and 1.5-2.5 parts of cross-linking agent.
Preferably, in the step a, the priming paint comprises the following raw materials in parts by weight: 87.5 parts of polyurethane resin, 14.5 parts of color paste and 2.25 parts of polycarbodiimide crosslinking agent.
Preferably, in step B, the color layer slurry comprises the following raw materials in parts by weight: 84 parts of polyurethane resin, 14.5 parts of color paste, 2.3 parts of flatting agent and 2.25 parts of polycarbodiimide crosslinking agent.
Preferably, in step C, the intermediate layer slurry comprises the following raw materials in parts by weight: 60 parts of polycarbonate-polyether transparent polyurethane elastic resin, 34 parts of leather cracking resin, 10 parts of highlight hard wax, 23 parts of color paste, 2.5 parts of flatting agent and 2.5 parts of cross-linking agent.
Preferably, the high gloss hard wax is a high gloss super hard wax from Stahl corporation: the WAX 186.
Preferably, in the step E, the top light layer slurry comprises the following raw materials in parts by weight: 82.5 parts of polycarbonate-polyether transparent polyurethane elastic resin, 19 parts of color paste, 1.5 parts of organic silicon assistant, 2.5 parts of flatting agent, 9 parts of hand feeling agent and 2 parts of cross-linking agent.
The invention also provides the automobile seat cushion leather with the crystal effect, which is prepared by adopting the preparation method of the automobile seat cushion leather with the crystal effect.
Compared with the prior art, the invention has the following advantages and beneficial effects:
the preparation method of the automobile seat cushion leather with the crystal effect increases the middle layer in the leather finishing process, introduces the leather cracking resin and the high-gloss hard wax into the middle layer, leads the surface of the leather to generate crystal water artistic special effect after being flafted, thereby increasing the ornamental value of the leather, forming special artistic special effect, and simultaneously increases the polyurethane top light layer with high physical property and transparency on the middle layer to meet the physical property requirement of the automobile leather.
The invention relates to a preparation method of automobile seat cushion leather with crystal effect, which is characterized in that a certain proportion of cracking resin and high gloss hard wax are introduced into a leather coating intermediate layer, then through a coating and softening process, the cracking resin in the leather intermediate layer cracks under the action of mechanical force in the softening process to form the crystal glittering natural artistic effect, a top light layer is top-coated by polyurethane (top light layer slurry such as polycarbonate-polyether transparent polyurethane elastic resin and the like) with high physical property and transparency, and the crystal glittering natural artistic effect is expressed by transparent top light resin.
The invention introduces leather cracking resin and high gloss hard wax in the intermediate layer (slurry) to be matched with other components, so as to play a good synergistic effect, so that the leather produces a crystal effect after being finished, and the top finish layer adopts polyurethane (top finish slurry of polycarbonate-polyether transparent polyurethane elastic resin and the like) with high physical property and transparency to top coat so as to meet the physical property requirement of the automobile leather.
The preparation method of the automobile seat cushion leather with the crystal effect can enable the automobile seat cushion leather to form rich artistic special effect, and enable the automobile seat cushion leather to have unique characteristics under the stream of the streamline.
Detailed Description
In order that those skilled in the art will better understand the technical solutions of the present invention, the following description of the preferred embodiments of the present invention is provided in connection with specific examples, which should not be construed as limiting the present patent.
The test methods or test methods described in the following examples are conventional methods unless otherwise specified; the reagents and materials, unless otherwise indicated, are conventionally obtained commercially or prepared by conventional methods.
Example 1:
a preparation method of automobile seat cushion leather with crystal effect comprises the following steps:
A. preparing a base coat slurry, adjusting the consistency to be 48 +/-4 seconds of a No. 4 Ford cup, and coating the prepared base coat slurry on the surface of a leather blank in a roller coating mode, wherein the coating amount is 7.0 +/-0.5 g/sqft; then drying and cooling the mixture at the temperature of 95-125 ℃ to form a bottom coating, and rolling the mixture;
B. preparing coloring layer slurry, adjusting the consistency to be 38 +/-3 seconds of a No. 4 Ford cup, and coating the prepared coloring layer slurry on the surface of a leather blank in a spraying mode, wherein the coating amount is 2 +/-0.2 g/sqft; then drying and cooling the substrate at the temperature of 105-125 ℃ to form a coloring layer;
C. preparing middle layer slurry, adjusting the consistency to be 35 +/-2 seconds in a No. 4 Ford cup, and coating the prepared middle layer slurry on the surface of a blank in a spraying mode, wherein the coating amount is 3 +/-0.2 g/sqft; then drying and cooling the substrate at the temperature of 110-130 ℃ to form an intermediate layer;
D. and (3) softening: c, under the condition that the rotating speed is 12-15 r/min, the leather blank treated in the step C is flawed for 60 +/-10 min;
E. preparing the top gloss layer slurry, adjusting the consistency to be 35 +/-2 seconds of a No. 4 Ford cup, and coating the prepared top gloss layer slurry on the surface of a blank in a spraying mode, wherein the coating amount is 2 +/-0.2 g/sqft; then drying and cooling the substrate at the temperature of 105-125 ℃ to form a top light layer; and rolling to obtain the automobile seat cushion leather with crystal effect.
Preferably, in the step a, the priming paint comprises the following raw materials in parts by weight: 85-90 parts of polyurethane resin, 14-15 parts of color paste and 2-2.5 parts of polycarbodiimide crosslinking agent.
Preferably, in step B, the color layer slurry comprises the following raw materials in parts by weight: 82-86 parts of polyurethane resin, 14-15 parts of color paste, 2-2.5 parts of flatting agent and 2-2.5 parts of polycarbodiimide crosslinking agent.
Preferably, in step C, the intermediate layer slurry comprises the following raw materials in parts by weight: 55-65 parts of polycarbonate-polyether transparent polyurethane elastic resin, 30-37 parts of leather cracking resin, 8-12 parts of highlight hard wax, 20-25 parts of color paste, 2-3 parts of a leveling agent and 2-3 parts of a cross-linking agent.
Preferably, the high gloss hard wax is a high gloss super hard wax from Stahl corporation: the WAX 186.
Preferably, in the step E, the top light layer slurry comprises the following raw materials in parts by weight: 80-85 parts of polycarbonate-polyether transparent polyurethane elastic resin, 18-20 parts of color paste, 1-2 parts of organic silicon assistant, 2-3 parts of flatting agent, 8-10 parts of hand feeling agent and 1.5-2.5 parts of cross-linking agent.
Preferably, in the step a, the priming paint comprises the following raw materials in parts by weight: 87.5 parts of polyurethane resin, 14.5 parts of color paste and 2.25 parts of polycarbodiimide crosslinking agent.
Preferably, in step B, the color layer slurry comprises the following raw materials in parts by weight: 84 parts of polyurethane resin, 14.5 parts of color paste, 2.3 parts of flatting agent and 2.25 parts of polycarbodiimide crosslinking agent.
Preferably, in step C, the intermediate layer slurry comprises the following raw materials in parts by weight: 60 parts of polycarbonate-polyether transparent polyurethane elastic resin, 34 parts of leather cracking resin, 10 parts of highlight hard wax, 23 parts of color paste, 2.5 parts of flatting agent and 2.5 parts of cross-linking agent.
Preferably, the high gloss hard wax is a high gloss super hard wax from Stahl corporation: the WAX 186.
Preferably, in the step E, the top light layer slurry comprises the following raw materials in parts by weight: 82.5 parts of polycarbonate-polyether transparent polyurethane elastic resin, 19 parts of color paste, 1.5 parts of organic silicon assistant, 2.5 parts of flatting agent, 9 parts of hand feeling agent and 2 parts of cross-linking agent.
The invention also provides the automobile seat cushion leather with the crystal effect, which is prepared by adopting the preparation method of the automobile seat cushion leather with the crystal effect.
Example 2:
a preparation method of automobile seat cushion leather with crystal effect comprises the following steps:
A. preparing a base coat slurry, adjusting the consistency to No. 4 Ford cup for 44 seconds, and coating the prepared base coat slurry on the surface of a leather blank in a roller coating mode, wherein the coating amount is 6.5 g/sqft; then drying and cooling the mixture at the temperature of 95 ℃ to form a bottom coating, and rolling the bottom coating;
B. preparing coloring layer slurry, adjusting the consistency to be No. 4 Ford cup for 35 seconds, and coating the prepared coloring layer slurry on the surface of a leather blank in a spraying mode, wherein the coating amount is 1.8 g/sqft; then drying and cooling the substrate at 105 ℃ to form a coloring layer;
C. preparing middle layer slurry, adjusting the consistency to be No. 4 Ford cup for 33 seconds, and coating the prepared middle layer slurry on the surface of a leather blank in a spraying mode, wherein the coating amount is 2.8 g/sqft; then drying and cooling the mixture at the temperature of 110 ℃ to form an intermediate layer;
D. and (3) softening: c, under the condition that the rotating speed is 12 revolutions per minute, the leather blank treated in the step C is flawed for 50 min;
E. preparing a top gloss layer slurry, adjusting the consistency to be 33 seconds in a No. 4 Ford cup, and coating the prepared top gloss layer slurry on the surface of a blank in a spraying mode, wherein the coating amount is 1.8 g/sqft; then drying and cooling the mixture at 105 ℃ to form a top light layer; and rolling to obtain the automobile seat cushion leather with crystal effect.
In this embodiment, in step a, the base coating paste includes the following raw materials in parts by weight: 85 parts of polyurethane resin, 14 parts of color paste and 2 parts of polycarbodiimide crosslinking agent.
In this embodiment, in step B, the color layer slurry includes the following raw materials in parts by weight: 82 parts of polyurethane resin, 14 parts of color paste, 2 parts of flatting agent and 2 parts of polycarbodiimide crosslinking agent.
In this embodiment, in step C, the interlayer slurry includes the following raw materials in parts by weight: 55 parts of polycarbonate-polyether transparent polyurethane elastic resin, 30 parts of leather cracking resin, 8 parts of high-gloss hard wax, 20 parts of color paste, 2 parts of flatting agent and 2 parts of cross-linking agent.
In this example, the high gloss hard wax is Stahl high gloss super hard wax: the WAX 186.
In this embodiment, in step E, the top light layer slurry includes the following raw materials in parts by weight: 80 parts of polycarbonate-polyether transparent polyurethane elastic resin, 18 parts of color paste, 1 part of organic silicon assistant, 2 parts of flatting agent, 8 parts of hand feeling agent and 1.5 parts of cross-linking agent.
Example 3:
a preparation method of automobile seat cushion leather with crystal effect comprises the following steps:
A. preparing a base coat slurry, adjusting the consistency to 4# Ford cup for 52 seconds, and coating the prepared base coat slurry on the surface of a leather blank in a roller coating mode, wherein the coating amount is 7.5 g/sqft; then drying and cooling the mixture at 125 ℃ to form a base coat, and rolling the base coat;
B. preparing coloring layer slurry, adjusting the consistency to be 4# Ford cup for 41 seconds, and coating the prepared coloring layer slurry on the surface of a leather blank in a spraying mode, wherein the coating amount is 2.2 g/sqft; then drying and cooling the substrate at 125 ℃ to form a coloring layer;
C. preparing middle layer slurry, adjusting the consistency to No. 4 Ford cup for 37 seconds, and coating the prepared middle layer slurry on the surface of a blank in a spraying mode, wherein the coating amount is 3.2 g/sqft; then drying and cooling the mixture at the temperature of 130 ℃ to form an intermediate layer;
D. and (3) softening: c, under the condition that the rotating speed is 15 revolutions per minute, the leather blank treated in the step C is subjected to milling for 70 min;
E. preparing a top gloss layer slurry, adjusting the consistency to No. 4 Ford cup for 37 seconds, and coating the prepared top gloss layer slurry on the surface of a blank in a spraying mode, wherein the coating amount is 2.2 g/sqft; then drying and cooling the mixture at 125 ℃ to form a top light layer; and rolling to obtain the automobile seat cushion leather with crystal effect.
In this embodiment, in step a, the base coating paste includes the following raw materials in parts by weight: 90 parts of polyurethane resin, 15 parts of color paste and 2.5 parts of polycarbodiimide crosslinking agent.
In this embodiment, in step B, the color layer slurry includes the following raw materials in parts by weight: 86 parts of polyurethane resin, 15 parts of color paste, 2.5 parts of flatting agent and 2.5 parts of polycarbodiimide crosslinking agent.
In this embodiment, in step C, the interlayer slurry includes the following raw materials in parts by weight: 65 parts of polycarbonate-polyether transparent polyurethane elastic resin, 37 parts of leather cracking resin, 12 parts of highlight hard wax, 25 parts of color paste, 3 parts of flatting agent and 3 parts of cross-linking agent.
In this example, the high gloss hard wax is Stahl high gloss super hard wax: the WAX 186.
In this embodiment, in step E, the top light layer slurry includes the following raw materials in parts by weight: 85 parts of polycarbonate-polyether transparent polyurethane elastic resin, 20 parts of color paste, 2 parts of organic silicon assistant, 3 parts of flatting agent, 10 parts of hand feeling agent and 2.5 parts of cross-linking agent.
Example 4:
a preparation method of automobile seat cushion leather with crystal effect comprises the following steps:
A. preparing a base coat slurry, adjusting the consistency to No. 4 Ford cup for 48 seconds, and coating the prepared base coat slurry on the surface of a leather blank in a roller coating mode, wherein the coating amount is 7.0 g/sqft; then drying and cooling the mixture at the temperature of 110 ℃ to form a base coat, and rolling the base coat;
B. preparing coloring layer slurry, adjusting the consistency to No. 4 Ford cup for 38 seconds, and coating the prepared coloring layer slurry on the surface of a leather blank in a spraying mode, wherein the coating amount is 2 g/sqft; then drying and cooling the substrate at the temperature of 110 ℃ to form a coloring layer;
C. preparing middle layer slurry, adjusting the consistency to be No. 4 Ford cup for 35 seconds, and coating the prepared middle layer slurry on the surface of a blank in a spraying mode, wherein the coating amount is 3 g/sqft; then drying and cooling the mixture at the temperature of 120 ℃ to form an intermediate layer;
D. and (3) softening: c, under the condition that the rotating speed is 14 revolutions per minute, the leather blank treated in the step C is subjected to milling for 60 min;
E. preparing a top gloss layer slurry, adjusting the consistency to be 35 seconds in a No. 4 Ford cup, and coating the prepared top gloss layer slurry on the surface of a blank in a spraying mode, wherein the coating amount is 2 g/sqft; then drying and cooling the mixture at the temperature of 115 ℃ to form a top light layer; and rolling to obtain the automobile seat cushion leather with crystal effect.
In this embodiment, in step a, the base coating paste includes the following raw materials in parts by weight: 87.5 parts of polyurethane resin, 14.5 parts of color paste and 2.25 parts of polycarbodiimide crosslinking agent.
In this embodiment, in step B, the color layer slurry includes the following raw materials in parts by weight: 84 parts of polyurethane resin, 14.5 parts of color paste, 2.3 parts of flatting agent and 2.25 parts of polycarbodiimide crosslinking agent.
In this embodiment, in step C, the interlayer slurry includes the following raw materials in parts by weight: 60 parts of polycarbonate-polyether transparent polyurethane elastic resin, 34 parts of leather cracking resin, 10 parts of highlight hard wax, 23 parts of color paste, 2.5 parts of flatting agent and 2.5 parts of cross-linking agent.
In this example, the high gloss hard wax is Stahl high gloss super hard wax: the WAX 186.
In this embodiment, in step E, the top light layer slurry includes the following raw materials in parts by weight: 82.5 parts of polycarbonate-polyether transparent polyurethane elastic resin, 19 parts of color paste, 1.5 parts of organic silicon assistant, 2.5 parts of flatting agent, 9 parts of hand feeling agent and 2 parts of cross-linking agent.
The preparation method of the automobile seat cushion leather with the crystal effect increases the middle layer in the leather finishing process, introduces the leather cracking resin and the high-gloss hard wax into the middle layer, leads the surface of the leather to generate crystal water artistic special effect after being flafted, thereby increasing the ornamental value of the leather, forming special artistic special effect, and simultaneously increases the polyurethane top light layer with high physical property and transparency on the middle layer to meet the physical property requirement of the automobile leather.
The invention relates to a preparation method of automobile seat cushion leather with crystal effect, which is characterized in that a certain proportion of cracking resin and high gloss hard wax are introduced into a leather coating intermediate layer, then through a coating and softening process, the cracking resin in the leather intermediate layer cracks under the action of mechanical force in the softening process to form the crystal glittering natural artistic effect, a top light layer is top-coated by polyurethane (top light layer slurry such as polycarbonate-polyether transparent polyurethane elastic resin and the like) with high physical property and transparency, and the crystal glittering natural artistic effect is expressed by transparent top light resin.
The invention introduces leather cracking resin and high gloss hard wax in the intermediate layer (slurry) to be matched with other components, so as to play a good synergistic effect, so that the leather produces a crystal effect after being finished, and the top finish layer adopts polyurethane (top finish slurry of polycarbonate-polyether transparent polyurethane elastic resin and the like) with high physical property and transparency to top coat so as to meet the physical property requirement of the automobile leather.
The preparation method of the automobile seat cushion leather with the crystal effect can enable the automobile seat cushion leather to form rich artistic special effect, and enable the automobile seat cushion leather to have unique characteristics under the stream of the streamline.
The above is only a preferred embodiment of the present invention, and it should be noted that the above preferred embodiment should not be considered as limiting the present invention, and the protection scope of the present invention should be subject to the scope defined by the claims. It will be apparent to those skilled in the art that various modifications and adaptations can be made without departing from the spirit and scope of the invention, and these modifications and adaptations should be considered within the scope of the invention.

Claims (10)

1. A preparation method of automobile seat cushion leather with crystal effect is characterized by comprising the following steps:
A. preparing a base coat slurry, adjusting the consistency to be 48 +/-4 seconds of a No. 4 Ford cup, and coating the prepared base coat slurry on the surface of a leather blank in a roller coating mode, wherein the coating amount is 7.0 +/-0.5 g/sqft; then drying and cooling the mixture at the temperature of 95-125 ℃ to form a bottom coating, and rolling the mixture;
B. preparing coloring layer slurry, adjusting the consistency to be 38 +/-3 seconds of a No. 4 Ford cup, and coating the prepared coloring layer slurry on the surface of a leather blank in a spraying mode, wherein the coating amount is 2 +/-0.2 g/sqft; then drying and cooling the substrate at the temperature of 105-125 ℃ to form a coloring layer;
C. preparing middle layer slurry, adjusting the consistency to be 35 +/-2 seconds in a No. 4 Ford cup, and coating the prepared middle layer slurry on the surface of a blank in a spraying mode, wherein the coating amount is 3 +/-0.2 g/sqft; then drying and cooling the substrate at the temperature of 110-130 ℃ to form an intermediate layer;
D. and (3) softening: c, under the condition that the rotating speed is 12-15 r/min, the leather blank treated in the step C is flawed for 60 +/-10 min;
E. preparing the top gloss layer slurry, adjusting the consistency to be 35 +/-2 seconds of a No. 4 Ford cup, and coating the prepared top gloss layer slurry on the surface of a blank in a spraying mode, wherein the coating amount is 2 +/-0.2 g/sqft; then drying and cooling the substrate at the temperature of 105-125 ℃ to form a top light layer; and rolling to obtain the automobile seat cushion leather with crystal effect.
2. The preparation method of the automobile seat cushion leather with crystal effect according to claim 1, wherein in the step A, the base coating slurry comprises the following raw materials in parts by weight: 85-90 parts of polyurethane resin, 14-15 parts of color paste and 2-2.5 parts of polycarbodiimide crosslinking agent.
3. The method for preparing the crystal-effect automobile seat cushion leather according to claim 1, wherein in the step B, the colored layer slurry comprises the following raw materials in parts by weight: 82-86 parts of polyurethane resin, 14-15 parts of color paste, 2-2.5 parts of flatting agent and 2-2.5 parts of polycarbodiimide crosslinking agent.
4. The method for preparing the automobile seat cushion leather with crystal effect according to claim 1, wherein in the step C, the middle layer slurry comprises the following raw materials in parts by weight: 55-65 parts of polycarbonate-polyether transparent polyurethane elastic resin, 30-37 parts of leather cracking resin, 8-12 parts of highlight hard wax, 20-25 parts of color paste, 2-3 parts of a leveling agent and 2-3 parts of a cross-linking agent.
5. The method for preparing automobile seat cushion leather with crystal effect according to claim 4, wherein the high-gloss hard wax is Stahl high-gloss super hard wax: the WAX 186.
6. The method for preparing the automobile seat cushion leather with the crystal effect according to claim 1, wherein in the step E, the top gloss layer slurry comprises the following raw materials in parts by weight: 80-85 parts of polycarbonate-polyether transparent polyurethane elastic resin, 18-20 parts of color paste, 1-2 parts of organic silicon assistant, 2-3 parts of flatting agent, 8-10 parts of hand feeling agent and 1.5-2.5 parts of cross-linking agent.
7. The preparation method of the automobile seat cushion leather with crystal effect according to claim 1, wherein in the step A, the base coating slurry comprises the following raw materials in parts by weight: 87.5 parts of polyurethane resin, 14.5 parts of color paste and 2.25 parts of polycarbodiimide crosslinking agent.
8. The method for preparing the crystal-effect automobile seat cushion leather according to claim 1, wherein in the step B, the colored layer slurry comprises the following raw materials in parts by weight: 84 parts of polyurethane resin, 14.5 parts of color paste, 2.3 parts of flatting agent and 2.25 parts of polycarbodiimide crosslinking agent.
9. The method for preparing the automobile seat cushion leather with crystal effect according to claim 1, wherein in the step C, the middle layer slurry comprises the following raw materials in parts by weight: 60 parts of polycarbonate-polyether transparent polyurethane elastic resin, 34 parts of leather cracking resin, 10 parts of highlight hard wax, 23 parts of color paste, 2.5 parts of flatting agent and 2.5 parts of cross-linking agent.
10. The method for preparing the automobile seat cushion leather with the crystal effect according to claim 1, wherein in the step E, the top gloss layer slurry comprises the following raw materials in parts by weight: 82.5 parts of polycarbonate-polyether transparent polyurethane elastic resin, 19 parts of color paste, 1.5 parts of organic silicon assistant, 2.5 parts of flatting agent, 9 parts of hand feeling agent and 2 parts of cross-linking agent.
CN202010134899.1A 2020-03-02 2020-03-02 Automobile seat cushion leather with crystal effect and preparation method thereof Pending CN111304927A (en)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103484577A (en) * 2013-10-21 2014-01-01 晋江市香江皮革有限公司 Production method of flexing-resistant leather
CN107236833A (en) * 2017-07-27 2017-10-10 漳州香洲皮革有限公司 The preparation method of two layers of double-colored wax sense crackle skin

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103484577A (en) * 2013-10-21 2014-01-01 晋江市香江皮革有限公司 Production method of flexing-resistant leather
CN107236833A (en) * 2017-07-27 2017-10-10 漳州香洲皮革有限公司 The preparation method of two layers of double-colored wax sense crackle skin

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Application publication date: 20200619