CN111302628A - Cold-color jade-like crystal paste for ceramic jade bead colored drawing and preparation method and application thereof - Google Patents

Cold-color jade-like crystal paste for ceramic jade bead colored drawing and preparation method and application thereof Download PDF

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CN111302628A
CN111302628A CN202010258968.XA CN202010258968A CN111302628A CN 111302628 A CN111302628 A CN 111302628A CN 202010258968 A CN202010258968 A CN 202010258968A CN 111302628 A CN111302628 A CN 111302628A
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jade
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范平
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes

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Abstract

The invention provides a cold-color jade-like crystal material paste for ceramic jade bead colored drawing, which is prepared by modulating a crystal material and a color former by a diluent; the crystal material is prepared from the following components in percentage by mass (6-7): 2: (1-2) preparing a first base material, a second base material and a medium fusing agent; the first base material comprises the following components: 90-95 wt% of white crystal material; the balance of natural color materials; the natural color material comprises one or more of natural cold color crystal color material, natural cold color gem color material and natural turquoise scrap material; the second base material comprises the following components: 18-22 wt% of white ceramic mud; 68 wt% -72 wt% of glass powder; the balance of pearl powder. The cold-color jade-like crystal paste for ceramic jade bead colored drawing provided by the invention is used for ceramic jade bead colored drawing, can ensure that the pigment color is bright, the finished product has concave-convex-like, clear level, bright and fine color, and internal color and luster which are warm and moist, has the textures of classic sapphire blue and turquoise, and greatly improves the artistic appreciation and commercial value of ceramic vessels.

Description

Cold-color jade-like crystal paste for ceramic jade bead colored drawing and preparation method and application thereof
Technical Field
The invention relates to the technical field of ceramic artware, in particular to cold-color jade-like crystal paste for ceramic jade bead colored drawing and a preparation method and application thereof.
Background
The ceramic color painting decoration process can be divided into overglaze color, in-glaze color and underglaze color; the overglaze decoration is one of the main decoration techniques of ceramic handicraft, and is made up by using various special-purpose colour drawing pigments for ceramics to draw various patterns on the surface of fired ceramic ware, then placing the ceramic ware into kiln and baking.
In the process of colored drawing decoration by glazing and coloring, a solvent and a diluent are added into pigments of various colors; the solvent facilitates the color development of the pigment, the pigment is easy to attach to the surface of the ceramic body, and the diluent is used for releasing the pigment, so that the pigment is convenient to draw picture details. The traditional solvent and diluent mainly comprise frankincense oil, camphor oil, water and oil solutions such as alcohol, kerosene and the like, and the existing ceramic floating color painting process in the prior art adopts cheese and whey as the solvent and diluent.
The traditional solvent and diluent are simple to prepare and convenient to use, but have some defects. If the pigment is dispersed due to oil infiltration, the problem of blurred picture layers and the like is caused, and even the phenomenon of oil frying after large-area oil diffusion occurs; moreover, the new colored painting on the glaze by using the frankincense oil and the camphor oil, and the cold color pigments such as brilliant black, special black, dark blue, lake blue, dark green and the like are dark and not bright enough after being baked; the powder color painting prepared by water, kerosene and the like has insufficient color development of partial pigments, flat and light color expression and unclear color level; the ceramic floating color process also has certain defects: the ceramic works drawn by using the ceramic painting can form a certain concave-convex color image on the surface of the ceramic after being fired, but the ceramic works can only have a punctiform three-dimensional effect, the painting area is enlarged, and picture cracks can be caused during color baking.
Disclosure of Invention
The cold-color jade-like crystal paste provided by the invention is used for ceramic jade-bead colored drawing, so that the pigment color can be bright, the finished product is three-dimensional in imaging, and the color shows the effects of moisture-wet and internally-accumulated jade substances such as sapphire blue and turquoise.
The invention provides a cold-color jade-like crystal material paste for ceramic jade bead colored drawing, which is prepared by modulating a crystal material and a color former by a diluent;
the crystal material is prepared from the following components in percentage by mass (6-7): 2: (1-2) preparing a first base material, a second base material and a medium fusing agent;
the first base material comprises the following components:
90-95 wt% of white crystal material;
the balance of natural color materials; the natural color material comprises one or more of natural cold color crystal color material, natural cold color gem color material and natural turquoise scrap material;
the second base material comprises the following components:
18-22 wt% of white ceramic mud;
68 wt% -72 wt% of glass powder;
the balance of pearl powder.
Preferably, the color former is oxalic acid.
Preferably, the preparation method of the diluent specifically comprises the following steps:
the mass ratio is (7-9): (0.5-1.5): 1, mixing the water, the walnut oil and the mayonnaise, and emulsifying to obtain the diluent.
Preferably, the mass ratio of the crystal material to the color former is 100: (1-5).
Preferably, the solvent comprises the following components:
68 to 72 weight percent of red lead;
20 wt% -25 wt% of boric acid;
the balance of quartz powder.
The invention also provides a preparation method of the cold-color jade-like crystal paste for the ceramic jade bead colored drawing, which comprises the following steps:
a) respectively grinding the white crystal material and the natural color material into powder and mixing to obtain a first base material; the natural color material comprises one or more of natural cold color crystal color material, natural cold color gem color material and natural turquoise scrap material;
respectively grinding the white ceramic pug, the glass powder and the pearl powder into powder, and mixing to obtain a second base material;
fully and uniformly mixing the first base material, the second base material and the medium flux, firing, grinding and sieving to obtain a crystal material;
b) adding a color former into the crystal material obtained in the step a), fully and uniformly stirring, and then blending by using a diluent to obtain the cold-color jade-like crystal material paste for ceramic jade bead colored drawing.
Preferably, the firing temperature in step a) is 1250 ℃ to 1270 ℃; the size of the screen hole of the porphyrized screen is 180-220 meshes.
Preferably, the blending process in step b) specifically comprises:
and slowly adding a diluent into the mixture of the crystal material and the color former, and stirring until the mixture is blended into thick paste, thereby obtaining the cold jade-like crystal material paste for ceramic jade bead colored drawing.
The invention also provides a ceramic jade bead color drawing method, which comprises the following steps:
according to the creation requirement, a color drawing pen is dipped with a diluent, and then is respectively dipped with color paste and cold-color ceramic glaze colored drawing pigment, and colored drawing is carried out on a ceramic vessel blank; then the ceramic ware blank after colored drawing is put into a kiln and baked for 6 to 8 hours at the temperature of 750 to 850 ℃ to obtain a ceramic jade bead colored drawing finished product;
the material paste is the cold-color jade-like crystal material paste for ceramic jade bead colored drawing in the technical scheme or the cold-color jade-like crystal material paste for ceramic jade bead colored drawing prepared by the preparation method in the technical scheme.
Preferably, after the ceramic ware blank after colored drawing is put into a kiln and is baked for 6 to 8 hours at the temperature of 750 to 850 ℃, the method further comprises the following steps:
the detail of the warm color part is point-dyed by warm color jade-like bead color pigment, and then the ceramic jade-like bead color painting finished product with the warm color effect is obtained by baking the ceramic jade-like bead color painting finished product in a kiln for 5 to 6 hours at 700 to 750 ℃.
The invention provides a cold-color jade-like crystal material paste for ceramic jade bead colored drawing, which is prepared by modulating a crystal material and a color former by a diluent; the crystal material is prepared from the following components in percentage by mass (6-7): 2: (1-2) preparing a first base material, a second base material and a medium fusing agent; the first base material comprises the following components: 90-95 wt% of white crystal material; the balance of natural color materials; the natural color material comprises one or more of natural cold color crystal color material, natural cold color gem color material and natural turquoise scrap material; the second base material comprises the following components: 18-22 wt% of white ceramic mud; 68 wt% -72 wt% of glass powder; the balance of pearl powder. Compared with the prior art, the cold-color jade crystal paste for ceramic jade bead colored drawing provided by the invention is used for ceramic jade bead colored drawing, can enable the pigment to have bright color development, and the finished product has concave-convex-shaped, clear layers, bright and fine colors, and internal and mild colors, has the textures of classic sapphire blue and turquoise, and greatly improves the artistic appreciation and commercial value of ceramic vessels.
In addition, the cold-color jade-like crystal paste for ceramic jade bead color painting provided by the invention can be applied to common light-color ceramic utensils to paint works, can also be applied to black and other dark-color ceramic surface layers and purple sand, black sand, clear inkstone, glass, crystal, metal and other materials to draw and burn into a three-dimensional and bright color picture, and has stable and saturated color, mild and moist color, internal accumulation, clear picture layers and unique visual effect.
Drawings
Fig. 1 is a real object diagram of a finished product of a ceramic jade bead colored drawing "Hongchun rain meaning" formed on a black ceramic tea tray by using the cold-color jade-like crystal paste provided by the embodiment of the invention.
Detailed Description
The technical solutions of the present invention will be described clearly and completely with reference to the following embodiments of the present invention, and it should be understood that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The invention provides a cold-color jade-like crystal material paste for ceramic jade bead colored drawing, which is prepared by modulating a crystal material and a color former by a diluent;
the crystal material is prepared from the following components in percentage by mass (6-7): 2: (1-2) preparing a first base material, a second base material and a medium fusing agent;
the first base material comprises the following components:
90-95 wt% of white crystal material;
the balance of natural color materials; the natural color material comprises one or more of natural cold color crystal color material, natural cold color gem color material and natural turquoise scrap material;
the second base material comprises the following components:
18-22 wt% of white ceramic mud;
68 wt% -72 wt% of glass powder;
the balance of pearl powder.
In the invention, the cold-color jade-like crystal paste for the color painting of the ceramic jade beads is prepared by mixing a crystal material and a color former through a diluent. In the invention, the crystal material is prepared from the following components in percentage by mass (6-7): 2: (1-2) the first base material, the second base material and the medium fusing agent are prepared, and the mass ratio of the first base material to the second base material is preferably 6.5: 2: 1.5 of a first base material, a second base material and a medium fusing agent.
In the present invention, the first base material comprises the following components:
90-95 wt% of white crystal material;
the balance of natural color materials;
preferably:
92 wt% of white crystal material;
8 wt% of natural color materials.
In the invention, the natural color material comprises one or more of natural cold color crystal color material, natural cold color gem color material and natural agapultite scrap material, and is more preferably natural agapultite scrap material. The sources of the white crystal material (colorless) and the natural color material are not particularly limited in the present invention, and commercially available products well known to those skilled in the art can be used.
In the present invention, the second base material comprises the following components:
18-22 wt% of white ceramic mud;
68 wt% -72 wt% of glass powder;
the balance of pearl powder;
preferably:
20 wt% of white ceramic mud;
70 wt% of glass powder;
10 wt% of pearl powder.
The sources of the white ceramic paste, the glass powder and the pearl powder are not particularly limited in the present invention, and commercially available products well known to those skilled in the art may be used.
In the present invention, the flux acts as a combustion-supporting flux; the solvent preferably comprises the following components:
68 to 72 weight percent of red lead;
20 wt% -25 wt% of boric acid;
the balance of quartz powder;
more preferably:
70 wt% of red lead;
23 wt% of boric acid;
7 wt% of quartz powder.
In the present invention, the color former functions to promote color development of the color pigment; the color former is preferably oxalic acid; commercially available products known to those skilled in the art may be used.
In the present invention, the preparation method of the diluent is preferably specifically:
the mass ratio is (7-9): (0.5-1.5): 1, mixing the water, the walnut oil and the mayonnaise, and emulsifying to obtain a diluent;
more preferably:
and (2) mixing the components in a mass ratio of 8: 1: 1, mixing the water, the walnut oil and the mayonnaise, and emulsifying to obtain the diluent. In the present invention, the mixing is preferably performed by using a stirrer well known to those skilled in the art; the emulsification mode is preferably standing, so that the mixture of the water, the walnut oil and the mayonnaise is fully emulsified and mixed to form the water-oil mixture; the standing time is preferably 22 to 26 hours, and more preferably 24 hours.
In the present invention, the mass ratio of the crystal material to the color former is preferably 100: (1-5), more preferably 100: 3.
the cold-color jade-like crystal paste for ceramic jade bead colored drawing provided by the invention is used for ceramic jade bead colored drawing, can ensure that the pigment color is bright, the finished product has concave-convex-like, clear level, bright and fine color, and internal color and luster which are warm and moist, has the textures of classic sapphire blue and turquoise, and greatly improves the artistic appreciation and commercial value of ceramic vessels.
The invention also provides a preparation method of the cold-color jade-like crystal paste for the ceramic jade bead colored drawing, which comprises the following steps:
a) respectively grinding the white crystal material and the natural color material into powder and mixing to obtain a first base material; the natural color material comprises one or more of natural cold color crystal color material, natural cold color gem color material and natural turquoise scrap material;
respectively grinding the white ceramic pug, the glass powder and the pearl powder into powder, and mixing to obtain a second base material;
fully and uniformly mixing the first base material, the second base material and the medium flux, firing, grinding and sieving to obtain a crystal material;
b) adding a color former into the crystal material obtained in the step a), fully and uniformly stirring, and then blending by using a diluent to obtain the cold-color jade-like crystal material paste for ceramic jade bead colored drawing.
Firstly, respectively grinding a white crystal material and a natural color material into powder and then mixing to obtain a first base material; simultaneously, respectively grinding the white ceramic pug, the glass powder and the pearl powder into powder and mixing to obtain a second base material; and then the first base material, the second base material and the medium flux are fully and uniformly mixed, fired, ground and sieved to obtain the crystal material. In the present invention, the white crystal material, the natural color material, the white ceramic pug, the glass powder, the pearl powder and the flux are the same as those described in the above technical solution, and are not described herein again.
In the present invention, the firing temperature is preferably 1250 to 1270 ℃, more preferably 1260 ℃; the purpose is to make the raw material mixture fully melted into a crystal shape; the size of the screen hole of the grinding and sieving is preferably 180-220 meshes, and more preferably 200 meshes; the cold color crystal powder with various colors can be obtained through the process of grinding and sieving after the firing.
After the crystal material is obtained, the color former is added into the obtained crystal material and fully and uniformly mixed, and then the mixture is blended by the diluent, so that the cold-color jade-like crystal material paste for ceramic jade bead colored drawing is obtained. In the present invention, the color former and the diluent are the same as those described in the above technical solution, and are not described herein again.
In the present invention, the blending process preferably includes:
and slowly adding a diluent into the mixture of the crystal material and the color former, and stirring until the mixture is blended into thick paste, thereby obtaining the cold jade-like crystal material paste for ceramic jade bead colored drawing.
The preparation method of the cold-color jade-like crystal paste for the ceramic jade bead colored drawing has the advantages that raw materials are easy to obtain and low in cost, and the surplus materials after products are manufactured in related artware processing industries such as white crystal, natural cold-color crystal color materials, natural cold-color gem color materials, natural turquoise chip materials, white porcelain clay, glass powder, pearl powder materials and the like can be used as the raw materials; compared with the traditional ceramic art colored drawing pigment, the raw materials used in the invention and the cold-color jade crystal-like material paste prepared from the raw materials are new applications in the field of ceramic art colored drawing pigment for the first time; meanwhile, the preparation process is simple and convenient to use.
The invention also provides a ceramic jade bead color drawing method, which comprises the following steps:
according to the creation requirement, a color drawing pen is dipped with a diluent, and then is respectively dipped with color paste and cold-color ceramic glaze colored drawing pigment, and colored drawing is carried out on a ceramic vessel blank; then the ceramic ware blank after colored drawing is put into a kiln and baked for 6 to 8 hours at the temperature of 750 to 850 ℃ to obtain a ceramic jade bead colored drawing finished product;
the material paste is the cold-color jade-like crystal material paste for ceramic jade bead colored drawing in the technical scheme or the cold-color jade-like crystal material paste for ceramic jade bead colored drawing prepared by the preparation method in the technical scheme.
According to the invention, firstly, a color drawing pen is dipped with a diluent according to the creation requirement, and then each color paste and the cold-color ceramic glaze colored drawing pigment are respectively dipped and adjusted, and colored drawing is carried out on a ceramic vessel blank. In the present invention, the diluent is the same as that described in the above technical solution, and is not described herein again.
In the invention, the material paste is the cold-color jade-like crystal material paste for ceramic jade bead color painting in the technical scheme or the cold-color jade-like crystal material paste for ceramic jade bead color painting prepared by the preparation method in the technical scheme.
In the invention, the cold-color ceramic overglaze colored drawing pigment is preferably a traditional ceramic overglaze colored drawing cold-color pigment such as brilliant black, special black, dark blue, lake blue, dark green, grass green and the like; the present invention is not particularly limited in this regard.
In the invention, the proportion of the dipping color paste and the cold color type ceramic overglaze colored drawing pigment is in negative correlation with the color depth required by drawing, namely the thicker the color is, the less the cold color type jade crystal paste is, and the more the cold color type jade crystal paste is, otherwise, the more the cold color type jade crystal paste is. In order to facilitate the dipping process, the invention preferably uses a special separated pigment tray for ceramic colored drawing to contain the material paste and the cold-color ceramic glaze colored drawing pigment, and the method specifically comprises the following steps: filling the material paste and filling the cold-color ceramic glaze colored drawing pigment; meanwhile, a plurality of special separated pigment discs for ceramic colored drawing are prepared according to the types of the colored drawing pigments on the cold-color ceramic glaze.
In the invention, the ceramic ware blank preferably comprises a common light-color ceramic ware blank, a dark ceramic surface layer such as black and the like, and the surface of materials such as purple sand, black sand, Chengni inkstone, glass, crystal, metal and the like. The cold-color jade-like crystal paste for ceramic jade bead color painting provided by the invention can be applied to common light-color ceramic utensils to draw works, can also be applied to various fired and molded dark-color ceramic glazes and materials such as purple sand, black sand, clear inkstone, glass, crystal, metal and the like to draw and fire into a three-dimensional and bright colored picture, and has stable and saturated color, lubricous color and internal retention, clear picture layers and unique visual effect.
Then, the ceramic ware blank after colored drawing is put into a kiln and baked for 6 to 8 hours at the temperature of 750 to 850 ℃ to obtain a ceramic jade bead colored drawing finished product; the temperature of the baking color is preferably 790-810 ℃, and the time is preferably 6.5-7.5 h.
In the invention, after the ceramic ware blank after colored drawing is put into a kiln and baked for 6 to 8 hours at the temperature of 750 to 850 ℃, the method preferably further comprises the following steps:
dyeing the detail of the warm color part by warm color jade-like bead color pigment, and then baking the color part in a kiln at 700-750 ℃ for 5-6 h to obtain a ceramic jade-like bead colored drawing finished product with warm color effect;
more preferably:
the detail of the warm color part is spot-dyed by warm color jade-like bead color pigment, and then the ceramic jade-like bead color painting finished product with the warm color effect is obtained by baking the ceramic jade-like bead color painting finished product for 5 to 6 hours in a kiln at the temperature of 720 to 730 ℃.
The invention has no special limitation on the type and source of the warm-color jade-like bead color pigment, and the commercial products of the warm-color pigment colored and painted on the traditional ceramic glaze such as purple, red, orange, yellow, emerald green and the like which are well known to the technical personnel in the field can be adopted.
By adopting the preferred technical scheme, the invention realizes the colored drawing creation by matching with the warm-color jade-bead-like color pigment through layered drawing and color baking, thereby drawing more complete ceramic jade-bead color works.
The ceramic jade bead color painting method provided by the invention adopts a specific crystal material, a color former and a diluent to prepare jade bead material paste, and mixes the jade bead material paste with cold-color type overglaze color pigment to prepare jade bead color pigment for ceramic color painting, so that the obtained product has three-dimensional imaging, bright color, stable and saturated color, lubricous color and internal retention, clear picture level and unique visual effect; meanwhile, the ceramic jade bead color drawing method can draw and burn large-area warm and moist concave-convex pictures with sapphire and turquoise texture, so that drawn works show high-end and precious quality.
The invention provides a cold-color jade-like crystal material paste for ceramic jade bead colored drawing, which is prepared by modulating a crystal material and a color former by a diluent; the crystal material is prepared from the following components in percentage by mass (6-7): 2: (1-2) preparing a first base material, a second base material and a medium fusing agent; the first base material comprises the following components: 90-95 wt% of white crystal material; the balance of natural color materials; the natural color material comprises one or more of natural cold color crystal color material, natural cold color gem color material and natural turquoise scrap material; the second base material comprises the following components: 18-22 wt% of white ceramic mud; 68 wt% -72 wt% of glass powder; the balance of pearl powder. Compared with the prior art, the cold-color jade crystal paste for ceramic jade bead colored drawing provided by the invention is used for ceramic jade bead colored drawing, can enable the pigment to have bright color development, and the finished product has concave-convex-shaped, clear layers, bright and fine colors, and internal and mild colors, has the textures of classic sapphire blue and turquoise, and greatly improves the artistic appreciation and commercial value of ceramic vessels.
In addition, the cold-color jade-like crystal paste for ceramic jade bead color painting provided by the invention can be applied to common light-color ceramic utensils to paint works, can also be applied to black and other dark-color ceramic surface layers and purple sand, black sand, clear inkstone, glass, crystal, metal and other materials to draw and burn into a three-dimensional and bright color picture, and has stable and saturated color, mild and moist color, internal accumulation, clear picture layers and unique visual effect.
To further illustrate the present invention, the following examples are provided for illustration. The medium flux used in the following examples of the present invention comprises the following components: 70 wt% of red lead, 23 wt% of boric acid and 7 wt% of quartz powder; the color former is oxalic acid (C)2H2O4·2H2O); the preparation method of the used diluent comprises the following steps: clear water, walnut oil and mayonnaise are used according to the ratio of 8: 1: 1, pouring the mixture into a stirrer for stirring, and then standing for 24 hours to fully emulsify and mix the mixture into a water-oil mixture to obtain the diluent.
Examples
(1) Respectively grinding a white crystal material (colorless) and a natural color material into powder, and then mixing the powder according to the weight ratio of 9.2: fully mixing the raw materials in a mass ratio of 0.8 to obtain a first base material; the natural color material is selected from a cold color crystal color material, a natural cold color gem color material and a natural turquoise scrap material with equal mass;
respectively grinding white ceramic pug, glass powder and pearl powder into powder, and then mixing the powder according to the weight ratio of 2: 7: 1 to obtain a second base material;
mixing a first base material, a second base material and a medium flux according to the weight ratio of 6.5: 2: 1.5, firing at 1260 ℃ in a kiln to fully melt the mixture into a crystal shape, taking out the crystal shape, grinding the crystal shape, and sieving the crystal shape by a 200-mesh sieve to obtain a crystal material.
(2) And (2) adding 3g of color former into 100g of the crystal material obtained in the step (1), fully stirring uniformly, slowly adding diluent, and stirring until the mixture is blended into thick paste, thereby obtaining the cold-color jade-like crystal material paste for ceramic jade bead colored drawing.
Application examples
Firstly, using a special separated pigment disk for ceramic colored drawing (a plurality of pigment disks are prepared according to the types of the cold-color ceramic overglaze colored drawing pigments), containing the cold-color jade-like crystal material paste obtained in the embodiment and containing the cold-color ceramic overglaze colored drawing pigments; then dipping a diluent in a color drawing pen, respectively dipping the cold-color jade crystal paste and a small amount of cold-color ceramic glaze color drawing pigment, and carrying out color drawing on a ceramic vessel (black pottery tea tray) blank:
drawing three-dimensional shapes of temple, mountain stone, spruce, pallor and the like by a stacking technique, and modulating colorful black, blue and other colored pigments on the glaze by a diluent to draw light and dark textures on the surface layer;
dipping a diluent in a small-size powder color ink pen, and then dipping in a cold-color jade crystal material paste, a sea green, a dark blue, a dark green, a purple and other color pigments for halation cloud layers, spot-dyeing trees, bushes and florists, wherein the theme of the work shows the first spring scene of the anthriscus sylvestris, so that the cold-color pigment and the crystal material paste are mixed in different proportions, so that the color level of the picture is as rich as possible;
finally, dipping a diluent in a large-size powder color material pen, then dipping a small amount of jade crystal paste and sea jade color, and dyeing uniform color tones between the hillstone and the tree cluster in a way of touching with a sketchy pen;
finally, putting the ceramic ware blank subjected to color painting into a kiln for baking color at the temperature of 790-810 ℃ for 6.5-7.5 h to obtain a ceramic jade bead colored painting finished product; and dyeing the detail of the warm color part by using warm color jade-like bead color pigment, and then baking the ceramic jade-like bead color paint in a kiln at 700-750 ℃ for 5-6 h to form a finished ceramic jade-like bead color painting product, namely Hongchun rain meaning.
Referring to fig. 1, fig. 1 is a diagram of a ceramic jade bead colored drawing finished product "hong chun rain meaning" formed on a black ceramic tea tray by using the cold-color jade-like crystal material paste provided by the embodiment of the present invention; the product after baking color forming has the special visual effect of uneven picture and the texture like sapphire blue and turquoise.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein but is to be accorded the widest scope consistent with the principles and novel features disclosed herein.

Claims (10)

1. A cold color jade-like crystal paste for color painting of ceramic jade beads is prepared by mixing crystal material and color former with diluent;
the crystal material is prepared from the following components in percentage by mass (6-7): 2: (1-2) preparing a first base material, a second base material and a medium fusing agent;
the first base material comprises the following components:
90-95 wt% of white crystal material;
the balance of natural color materials; the natural color material comprises one or more of natural cold color crystal color material, natural cold color gem color material and natural turquoise scrap material;
the second base material comprises the following components:
18-22 wt% of white ceramic mud;
68 wt% -72 wt% of glass powder;
the balance of pearl powder.
2. The cold-color jade-like crystal paste for color painting of ceramic jade beads according to claim 1, wherein the color former is oxalic acid.
3. The cold-color jade-like crystal paste for color painting of ceramic jade beads according to claim 1, wherein the preparation method of the diluent comprises the following specific steps:
the mass ratio is (7-9): (0.5-1.5): 1, mixing the water, the walnut oil and the mayonnaise, and emulsifying to obtain the diluent.
4. The cold-color jade-like crystal paste for color painting of ceramic jade beads according to claim 1, wherein the mass ratio of the crystal material to the color former is 100: (1-5).
5. The cold-color jade-like crystal paste for ceramic jade bead color painting according to claim 1, wherein the solvent comprises the following components:
68 to 72 weight percent of red lead;
20 wt% -25 wt% of boric acid;
the balance of quartz powder.
6. A preparation method of the cold-color jade-like crystal paste for the color painting of the ceramic jade beads as claimed in any one of claims 1 to 5 comprises the following steps:
a) respectively grinding the white crystal material and the natural color material into powder and mixing to obtain a first base material; the natural color material comprises one or more of natural cold color crystal color material, natural cold color gem color material and natural turquoise scrap material;
respectively grinding the white ceramic pug, the glass powder and the pearl powder into powder, and mixing to obtain a second base material;
fully and uniformly mixing the first base material, the second base material and the medium flux, firing, grinding and sieving to obtain a crystal material;
b) adding a color former into the crystal material obtained in the step a), fully and uniformly stirring, and then blending by using a diluent to obtain the cold-color jade-like crystal material paste for ceramic jade bead colored drawing.
7. The method of claim 6, wherein the firing temperature in step a) is 1250 ℃ to 1270 ℃; the size of the screen hole of the porphyrized screen is 180-220 meshes.
8. The preparation method according to claim 6, wherein the blending process in step b) is specifically:
and slowly adding a diluent into the mixture of the crystal material and the color former, and stirring until the mixture is blended into thick paste, thereby obtaining the cold jade-like crystal material paste for ceramic jade bead colored drawing.
9. A ceramic jade bead color drawing method comprises the following steps:
according to the creation requirement, a color drawing pen is dipped with a diluent, and then is respectively dipped with color paste and cold-color ceramic glaze colored drawing pigment, and colored drawing is carried out on a ceramic vessel blank; then the ceramic ware blank after colored drawing is put into a kiln and baked for 6 to 8 hours at the temperature of 750 to 850 ℃ to obtain a ceramic jade bead colored drawing finished product;
the paste is the cold-color jade-like crystal paste for ceramic jade bead color painting according to any one of claims 1 to 5 or the cold-color jade-like crystal paste for ceramic jade bead color painting prepared by the preparation method according to any one of claims 6 to 8.
10. The method for drawing a crystal stack color according to claim 9, wherein the step of baking the ceramic ware blank after color drawing in a kiln at 750-850 ℃ for 6-8 h further comprises:
the detail of the warm color part is point-dyed by warm color jade-like bead color pigment, and then the ceramic jade-like bead color painting finished product with the warm color effect is obtained by baking the ceramic jade-like bead color painting finished product in a kiln for 5 to 6 hours at 700 to 750 ℃.
CN202010258968.XA 2020-04-03 2020-04-03 Cold-color jade-like crystal paste for ceramic jade bead colored drawing and preparation method and application thereof Active CN111302628B (en)

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