CN111298639A - Composition for reducing peculiar smell of wood chip storage yard, preparation method and application thereof - Google Patents
Composition for reducing peculiar smell of wood chip storage yard, preparation method and application thereof Download PDFInfo
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Abstract
The invention provides a composition for reducing peculiar smell of a wood chip storage yard, which comprises the following components in percentage by weight: 8-10 parts by mass of plant extract and 1 part by mass of biological enzyme; the plant extract comprises: 40-60 parts of bamboo wood extracting solution and 40-60 parts of ginger essential oil. According to the invention, through the combination of the specific plant extract and the biological enzyme and the specific proportion and the synergistic effect of the two, the unpleasant volatile organic compounds generated by the wood chip storage yard can be effectively reduced from the aspects of sense and content. The method has the advantages of no toxicity, no harm, environmental friendliness, effective inhibition of the regeneration of unpleasant volatile organic gas and the like.
Description
Technical Field
The invention relates to the technical field of purification, in particular to a composition for reducing peculiar smell of a wood chip storage yard, and a preparation method and application thereof.
Background
Sour taste gas generated by wood chip fermentation can affect the surrounding environment and bring certain trouble to nearby residents. More effective control methods are needed to address the problem of odor in chip yards.
Through the detection of the gas emitted by the wood chips, the main components of the odor gas are VOCs such as acetic acid and the like, and the odor gas needs to be controlled according to the national environmental protection regulations.
The peculiar smell of the wood chip storage yard is treated, in the prior art, plant extract is mostly used, and the covering effect is achieved through the Lewis acid-base neutralization reaction (food-grade chemical agent) and the chelation effect, so that various acidic smells generated by wood chip fermentation are eliminated. But has the defects of only having a covering effect, treating the symptoms and not treating the root causes, and not really eliminating the acidic odor generated by the fermentation of the wood chips. The odor of the gases generated by the pile of chips is continuously emitted into the surrounding air. Therefore, the control of the odor is inefficient. Therefore, a product with good odor control effect is developed.
Disclosure of Invention
In view of the above, the technical problem to be solved by the present invention is to provide a composition for reducing odor in a wood chip yard.
The invention provides a composition for reducing peculiar smell of a wood chip storage yard, which comprises the following components in percentage by weight:
8-10 parts by mass of plant extract and 1 part by mass of biological enzyme;
the plant extract comprises: 40-60 parts of bamboo wood extracting solution and 40-60 parts of ginger essential oil.
Preferably, the plant extract comprises: 45-55 parts by mass of bamboo wood extracting solution and 45-55 parts by mass of ginger essential oil.
Preferably, the biological enzymes include:
2-4 parts by mass of fendortin; 1-2 parts by mass of hydrolyzed protein; 0.3 to 1 part by mass of glycine; 0.2 to 1 part by mass of glutamine; 0.1 to 1.5 parts by mass of phenylalanine; 3-5 parts by mass of zinc ricinoleate; 90-91 parts by mass of deionized water
Preferably, the bamboo wood extracting solution is prepared by the following method:
removing impurities from bamboo, heating, keeping the temperature, heating up, and collecting the bamboo extract.
Preferably, the heating, heat preservation and temperature rise specifically comprise:
heating to 88-92 ℃, keeping the temperature for 2-4 h, then continuously heating to 96-100 ℃, collecting the gas-phase bamboo extracting solution, heating to 116-120 ℃ within 7-9 h, and cooling the gas-phase bamboo extracting solution to obtain the bamboo wood composite material.
Preferably, the ginger essential oil is prepared by the following method:
slicing rhizoma Zingiberis recens, mixing with starch solution, soaking, drying, and pulverizing to obtain rhizoma Zingiberis recens powder;
mixing the ginger powder with an ionic liquid system, adding cellulase for enzymolysis, then carrying out water bath enzyme deactivation, ultrasonic extraction, microwave treatment, filtration, centrifugation, taking the lower layer and concentrating to obtain the ginger essential oil.
Preferably, the starch solution is 0.5-0.9 wt% of starch solution; the soaking time is 10-15 min; the crushing specifically comprises the following steps: after crushing, sieving the powder by a sieve of 60-80 meshes; the ionic liquid system comprises: disodium hydrogen phosphate-citric acid buffer and 1-ethyl-3-methylimidazolium acetate; the ratio of the ginger powder to the ionic liquid system is 1: 10-1: 20 g/mL;
the enzyme activity ratio of the cellulase is 2000-4000U/g; the enzymolysis temperature is 40-50 ℃; the enzymolysis time is 3-5 h; the microwave power is 300 Hz; the microwave time is 10 min.
The invention provides a preparation method of the composition for reducing the peculiar smell of the wood chip storage yard, which comprises the following steps:
mixing the plant extract with biological enzyme.
The invention provides application of the composition for reducing the peculiar smell of the wood chip storage yard in the technical scheme in reducing the peculiar smell of the wood chip storage yard.
The invention provides a method for reducing peculiar smell of a wood chip storage yard, which comprises the following steps:
spraying the composition for reducing the peculiar smell of the wood chip storage yard in the wood chip.
Compared with the prior art, the invention provides a composition for reducing peculiar smell of a wood chip storage yard, which comprises the following components: 8-10 parts by mass of plant extract and 1 part by mass of biological enzyme; the plant extract comprises: 40-60 parts of bamboo wood extracting solution and 40-60 parts of ginger essential oil. According to the invention, through the combination of the specific plant extract and the biological enzyme and the specific proportion and the synergistic effect of the two, the unpleasant volatile organic compounds generated by the wood chip storage yard can be effectively reduced from the aspects of sense and content. The method has the advantages of no toxicity, no harm, environmental friendliness, effective inhibition of the regeneration of unpleasant volatile organic gas and the like.
Drawings
FIG. 1 is a diagram of an experimental apparatus in example 3 of the present invention.
Detailed Description
The invention provides a composition for reducing peculiar smell of a wood chip storage yard, a preparation method and application thereof, and a person skilled in the art can use the content to appropriately improve the process parameters for realizing. It is expressly intended that all such similar substitutes and modifications apparent to those skilled in the art are deemed to be within the scope of the invention. While the methods and applications of this invention have been described in terms of preferred embodiments, it will be apparent to those of ordinary skill in the art that variations and modifications in the methods and applications described herein, as well as other suitable variations and combinations, may be made to implement and use the techniques of this invention without departing from the spirit and scope of the invention.
The invention provides a composition for reducing peculiar smell of a wood chip storage yard, which comprises the following components in percentage by weight:
8-10 parts by mass of plant extract and 1 part by mass of biological enzyme;
the plant extract comprises: 40-60 parts of bamboo wood extracting solution and 40-60 parts of ginger essential oil.
According to the invention, through detecting the gas emitted by the wood chips, the main components of the peculiar smell gas are VOCs such as acetic acid, and a handheld VOCs tester is adopted as an instrument for detecting the content (or concentration) value of the target gas. Note: VOCs (volatile organic compounds) are organic compounds having a saturated vapor pressure at room temperature of more than 133.32Pa (saturated vapor pressure at acetic acid at room temperature of 1.5KPa) and a boiling point at normal pressure of 260 ℃ or less (boiling point at acetic acid at normal pressure of 117.9 ℃), and any organic solid or liquid that can volatilize at room temperature and normal pressure.
The composition for reducing the peculiar smell of the wood chip storage yard comprises 8-10 parts by mass of plant extract; preferably, the amount of the plant extract may be 8 parts by mass, 9 parts by mass or 10 parts by mass; or a point value between any of the above.
According to the invention, the plant extract comprises: 40-60 parts by mass of bamboo wood extracting solution and 40-60 parts by mass of ginger essential oil; preferably 45-55 parts by mass of bamboo wood extracting solution and 45-55 parts by mass of ginger essential oil; more preferably, the bamboo wood essence oil comprises 50 parts by mass of bamboo wood extract and 50 parts by mass of ginger essential oil.
In the invention, the bamboo wood extracting solution is prepared by the following method:
removing impurities from bamboo, heating, keeping the temperature, heating up, and collecting the bamboo extract.
Firstly, selecting fresh and clean bamboo wood, and manually removing impurities, stones, crushed mud and the like.
The heating, heat preservation and temperature rise specifically comprises the following steps:
heating to 88-92 ℃, keeping the temperature for 2-4 h, then continuously heating to 96-100 ℃, collecting the gas-phase bamboo extracting solution, heating to 116-120 ℃ within 7-9 h, and cooling the gas-phase bamboo extracting solution to obtain the bamboo wood composite material.
Namely, after impurity removal, the preferable method is as follows:
putting the bamboo wood into a dry distillation furnace, heating and raising the temperature under the normal pressure state, and preserving the heat for 2-4 hours when the temperature reaches 88-92 ℃ to fully dehydrate the bamboo wood; and (3) keeping the temperature, then continuously and slowly heating, collecting the bamboo extracting solution in the gas phase when the temperature reaches 96-100 ℃ until the temperature reaches 116-120 ℃, and cooling the bamboo extracting solution in the gas phase through a condenser to obtain liquid bamboo extracting solution.
In the process, the time from 96 ℃ to 100 ℃ to 103 ℃ to 107 ℃ is controlled to be 4-5 hours, and the time from 103 ℃ to 107 ℃ to 116 ℃ to 120 ℃ is controlled to be 3-4 hours;
preferably, the temperature is controlled from 96 ℃ to 100 ℃ to 103 ℃ to 107 ℃ for 5 hours, and the temperature is controlled from 103 ℃ to 107 ℃ to 116 ℃ to 120 ℃ for 3 hours.
In the invention, the ginger essential oil is prepared by the following method:
slicing rhizoma Zingiberis recens, mixing with starch solution, soaking, drying, and pulverizing to obtain rhizoma Zingiberis recens powder;
mixing the ginger powder with an ionic liquid system, adding cellulase for enzymolysis, then carrying out water bath enzyme deactivation, ultrasonic extraction, microwave treatment, filtration, centrifugation, taking the lower layer and concentrating to obtain the ginger essential oil.
The fresh ginger is firstly taken and sliced, and the slices are not limited and can be cut into threads.
And then soaking the mixture in a starch solution with the mass concentration of 0.5-0.9% for 10-15 min, and more preferably in a starch solution with the mass concentration of 0.6-0.8% for 11-14 min.
Drying, crushing, and sieving with a 60-80 mesh sieve to obtain ginger powder. The present invention is not limited to the specific operation of the pulverizing and sieving, and those skilled in the art will be familiar with the operation.
Mixing the ginger powder with an ionic liquid system.
The ionic liquid system comprises: disodium hydrogen phosphate-citric acid buffer and 1-ethyl-3-methylimidazolium acetate; the mass ratio of the disodium hydrogen phosphate-citric acid buffer solution to the 1-ethyl-3-methylimidazole acetate is 1: 1; the ratio of the ginger powder to the ionic liquid system is preferably 1: 10-1: 20 g/mL; more preferably 1:12 to 1:18 g/mL.
Adding cellulase for enzymolysis, wherein the enzyme activity ratio of the cellulase is preferably 2000-4000U/g; more preferably 2200 to 3800U/g; the preferable enzymolysis temperature is 40-50 ℃; more preferably 42-48 ℃; the enzymolysis time is 3-5 h.
Then water bath enzyme deactivation, ultrasonic extraction, microwave treatment, filtration, centrifugation, lower layer concentration are carried out to obtain the ginger essential oil.
Inactivating enzyme in a water bath system after reaction, wherein the temperature of the water bath is 85-95 ℃; preferably 90 ℃; the water bath time is 25-35 min; preferably 30 min.
The ultrasonic power of the ultrasonic extraction is 320 w; the extraction time is 10 min.
The microwave power is 300 Hz; the microwave time is 10 min.
Filtering with gauze, centrifuging, standing, collecting lower layer ionic liquid, rotary steaming, collecting oily substance with strong fragrance, and drying with anhydrous sodium sulfate to obtain rhizoma Zingiberis recens essential oil.
The invention adopts microwave and ultrasonic synergistic extraction, so that the extraction rate is higher, and the enzyme inactivation effect is better. Meanwhile, the specific ultrasonic power and microwave power of the invention are adopted to ensure that the extraction effect of the plant extract such as ginger essential oil is good.
The composition for reducing the peculiar smell of the wood chip storage yard comprises 1 part by mass of biological enzyme.
According to the invention, the biological enzymes preferably comprise:
2-4 parts by mass of fendortin; 1-2 parts by mass of hydrolyzed protein; 0.3 to 1 part by mass of glycine; 0.2 to 1 part by mass of glutamine; 0.1 to 1.5 parts by mass of phenylalanine; 3-5 parts by mass of zinc ricinoleate; 90-91 parts by mass of deionized water;
more preferably, it comprises:
2-4 parts by mass of fendortin; 1-2 parts by mass of hydrolyzed protein; 0.4 to 0.9 parts by mass of glycine; 0.3 to 0.9 parts by mass of glutamine; 0.2 to 1.3 parts by mass of phenylalanine; 3-5 parts by mass of zinc ricinoleate; 90-90.5 parts by mass of deionized water.
Most preferably comprising:
2-4 parts by mass of fendortin; 1-2 parts by mass of hydrolyzed protein; 0.5-0.8 parts by mass of glycine; 0.4 to 0.8 parts by mass of glutamine; 0.3 to 1.2 parts by mass of phenylalanine; 3-5 parts by mass of zinc ricinoleate; 90.5 parts by mass of deionized water.
The invention provides a preparation method of the composition for reducing the peculiar smell of the wood chip storage yard, which comprises the following steps:
mixing the plant extract with biological enzyme.
The plant extract and the biological enzyme are clearly defined in the invention, and are not described in detail herein.
The preparation method of the composition for reducing the peculiar smell of the wood chip storage yard is obtained by mixing the plant extract and the biological enzyme.
The mixing method of the present invention is not limited, and the mixing may be performed uniformly as known to those skilled in the art.
The invention provides application of the composition for reducing the peculiar smell of the wood chip storage yard in the technical scheme in reducing the peculiar smell of the wood chip storage yard.
The composition for reducing the peculiar smell of the wood chip storage yard, provided by the invention, can reduce the peculiar smell of the wood chip storage yard and prevent the peculiar smell from being regenerated.
The plant extract and biological enzyme synergistic treatment technology adopted by the method can be used for effectively controlling the peculiar smell of the wood chip storage yard and eliminating the unpleasant volatile organic compounds generated by the wood chip storage yard. The technology is nontoxic and harmless, is environment-friendly, and effectively inhibits the regeneration of unpleasant volatile organic gas.
The invention provides a method for reducing peculiar smell of a wood chip storage yard, which comprises the following steps:
spraying the composition for reducing the peculiar smell of the wood chip storage yard in the wood chip.
The method for reducing the peculiar smell of the wood chip storage yard provided by the invention is to spray the composition for reducing the peculiar smell of the wood chip storage yard in any one of the technical schemes into the wood chips.
The injection amount of the invention is specifically as follows: 50-60 mL of liquid medicine is adopted per ton of wet wood chips, and the liquid medicine is diluted by 100 times and sprayed when in use.
The invention provides a composition for reducing peculiar smell of a wood chip storage yard, which comprises the following components in percentage by weight: 8-10 parts by mass of plant extract and 1 part by mass of biological enzyme; the plant extract comprises: 40-60 parts of bamboo wood extracting solution and 40-60 parts of ginger essential oil. According to the invention, through the combination of the specific plant extract and the biological enzyme and the specific proportion and the synergistic effect of the two, the unpleasant volatile organic compounds generated by the wood chip storage yard can be effectively reduced from the aspects of sense and content. The method has the advantages of no toxicity, no harm, environmental friendliness, effective inhibition of the regeneration of unpleasant volatile organic gas and the like.
In order to further illustrate the present invention, the following examples are provided to describe a composition for reducing odor in a wood chip yard, its preparation method and application.
Example 1
Preparing a bamboo extracting solution:
selecting fresh and clean bamboo wood, and manually removing impurities, stones, crushed mud and the like; putting the bamboo into a dry distillation furnace, heating and raising the temperature under normal pressure, and preserving the heat for 3 hours when the temperature reaches 88-92 ℃ to fully dehydrate the bamboo; and (3) after heat preservation, continuously and slowly raising the temperature, collecting the bamboo extracting solution in the gas phase when the temperature reaches 96-100 ℃ until the temperature reaches 116-120 ℃, and cooling the bamboo extracting solution in the gas phase through a condenser to obtain liquid bamboo extracting solution, wherein in the process, the temperature is controlled to be 5 hours from 96-100 ℃ to 103-107 ℃, and the temperature is controlled to be 3 hours from 103-107 ℃ to 116-120 ℃.
Preparing ginger essential oil: taking fresh ginger, slicing, soaking in a starch solution with the mass concentration of 0.5-0.9% for 10-15 min, drying, crushing, and sieving with a 60-80-mesh sieve; preparing an enzymolysis liquid: adding ionic liquid 1-ethyl-3-methylimidazolium acetate into a disodium hydrogen phosphate-citric acid buffer solution to prepare an ionic liquid system. Adding ginger powder into an ionic liquid system, wherein the material-liquid ratio is 1: 10-1: 20g/mL, adding cellulase with the enzyme activity ratio of 2000-4000U/g, and performing enzymolysis for 3-5 hours at 40-50 ℃; extracting essential oil: and (3) inactivating enzyme in a water bath of the system after reaction, performing ultrasonic 320W extraction for 5-10 min, performing 300MHz microwave treatment, filtering by using gauze, centrifuging, standing to take down a lower-layer ionic liquid, performing rotary evaporation, collecting oily substances with strong fragrance, and drying by using anhydrous sodium sulfate to obtain the ginger essential oil, wherein the extraction rate is 31%.
2-4 parts by mass of fendortin; 1-2 parts by mass of hydrolyzed protein; 0.3 to 1 part by mass of glycine; 0.2 to 1 part by mass of glutamine; 0.1 to 1.5 parts by mass of phenylalanine; 3-5 parts by mass of zinc ricinoleate; 90.5 parts by mass of deionized water were mixed to obtain a biological enzyme.
Comparative example 1
Preparing a bamboo extracting solution:
selecting fresh and clean bamboo wood, and manually removing impurities, stones, crushed mud and the like; putting the bamboo into a dry distillation furnace, heating and raising the temperature under normal pressure, and preserving the heat for 3 hours when the temperature reaches 88-92 ℃ to fully dehydrate the bamboo; and (3) after heat preservation, continuously and slowly raising the temperature, collecting the bamboo extracting solution in the gas phase when the temperature reaches 96-100 ℃ until the temperature reaches 116-120 ℃, and cooling the bamboo extracting solution in the gas phase through a condenser to obtain liquid bamboo extracting solution, wherein in the process, the temperature is controlled to be 5 hours from 96-100 ℃ to 103-107 ℃, and the temperature is controlled to be 3 hours from 103-107 ℃ to 116-120 ℃.
Preparing ginger essential oil: taking fresh ginger, slicing, soaking in a starch solution with the mass concentration of 0.5-0.9% for 10-15 min, drying, crushing, and sieving with a 60-80-mesh sieve; preparing an enzymolysis liquid: adding ionic liquid 1-ethyl-3-methylimidazolium acetate into a disodium hydrogen phosphate-citric acid buffer solution to prepare an ionic liquid system. Adding ginger powder into an ionic liquid system, wherein the material-liquid ratio is 1: 10-1: 20g/mL, adding cellulase with the enzyme activity ratio of 2000-4000U/g, and performing enzymolysis for 3-5 hours at 40-50 ℃; extracting essential oil: and (3) inactivating enzyme in a water bath of the system after reaction, performing ultrasonic 300W extraction for 5-10 min, performing 400MHz microwave treatment, filtering by using gauze, centrifuging, standing to take down a lower-layer ionic liquid, performing rotary evaporation, collecting oily substances with strong fragrance, and drying by using anhydrous sodium sulfate to obtain the ginger essential oil, wherein the extraction rate is 25.7%.
2-4 parts by mass of fendortin; 1-2 parts by mass of hydrolyzed protein; 0.3 to 1 part by mass of glycine; 0.2 to 1 part by mass of glutamine; 0.1 to 1.5 parts by mass of phenylalanine; 3-5 parts by mass of zinc ricinoleate; 90.5 parts by mass of deionized water were mixed to obtain a biological enzyme.
Comparative example 2
Preparing a bamboo extracting solution:
selecting fresh and clean bamboo wood, and manually removing impurities, stones, crushed mud and the like; putting the bamboo into a dry distillation furnace, heating and raising the temperature under normal pressure, and preserving the heat for 3 hours when the temperature reaches 88-92 ℃ to fully dehydrate the bamboo; and (3) after heat preservation, continuously and slowly raising the temperature, collecting the bamboo extracting solution in the gas phase when the temperature reaches 96-100 ℃ until the temperature reaches 116-120 ℃, and cooling the bamboo extracting solution in the gas phase through a condenser to obtain liquid bamboo extracting solution, wherein in the process, the temperature is controlled to be 5 hours from 96-100 ℃ to 103-107 ℃, and the temperature is controlled to be 3 hours from 103-107 ℃ to 116-120 ℃.
Preparing ginger essential oil: taking fresh ginger, slicing, soaking in a starch solution with the mass concentration of 0.5-0.9% for 10-15 min, drying, crushing, and sieving with a 60-80-mesh sieve; preparing an enzymolysis liquid: adding ionic liquid 1-ethyl-3-methylimidazolium acetate into a disodium hydrogen phosphate-citric acid buffer solution to prepare an ionic liquid system. Adding ginger powder into an ionic liquid system, wherein the material-liquid ratio is 1: 10-1: 20g/mL, adding cellulase with the enzyme activity ratio of 2000-4000U/g, and performing enzymolysis for 3-5 hours at 40-50 ℃; extracting essential oil: and (3) inactivating enzyme in a water bath of the system after reaction, performing ultrasonic 340W extraction for 5-10 min, performing 400MHz microwave treatment, filtering by using gauze, centrifuging, standing to take down a lower-layer ionic liquid, performing rotary evaporation, collecting oily substances with strong fragrance, and drying by using anhydrous sodium sulfate to obtain the ginger essential oil, wherein the extraction rate is 28%.
2-4 parts by mass of fendortin; 1-2 parts by mass of hydrolyzed protein; 0.3 to 1 part by mass of glycine; 0.2 to 1 part by mass of glutamine; 0.1 to 1.5 parts by mass of phenylalanine; 3-5 parts by mass of zinc ricinoleate; 90.5 parts by mass of deionized water were mixed to obtain a biological enzyme.
Comparative example 3
Preparing a bamboo extracting solution:
selecting fresh and clean bamboo wood, and manually removing impurities, stones, crushed mud and the like; putting the bamboo into a dry distillation furnace, heating and raising the temperature under normal pressure, and preserving the heat for 3 hours when the temperature reaches 88-92 ℃ to fully dehydrate the bamboo; and (3) after heat preservation, continuously and slowly raising the temperature, collecting the bamboo extracting solution in the gas phase when the temperature reaches 96-100 ℃ until the temperature reaches 116-120 ℃, and cooling the bamboo extracting solution in the gas phase through a condenser to obtain liquid bamboo extracting solution, wherein in the process, the temperature is controlled to be 5 hours from 96-100 ℃ to 103-107 ℃, and the temperature is controlled to be 3 hours from 103-107 ℃ to 116-120 ℃.
Preparing ginger essential oil: taking fresh ginger, slicing, soaking in a starch solution with the mass concentration of 0.5-0.9% for 10-15 min, drying, crushing, and sieving with a 60-80-mesh sieve; preparing an enzymolysis liquid: adding ionic liquid 1-ethyl-3-methylimidazolium acetate into a disodium hydrogen phosphate-citric acid buffer solution to prepare an ionic liquid system. Adding ginger powder into an ionic liquid system, wherein the material-liquid ratio is 1: 10-1: 20g/mL, adding cellulase with the enzyme activity ratio of 2000-4000U/g, and performing enzymolysis for 3-5 hours at 40-50 ℃; extracting essential oil: and (3) inactivating enzyme in a water bath of the system after reaction, performing ultrasonic 360W extraction for 5-10 min, performing 300MHz microwave treatment, filtering by using gauze, centrifuging, standing to take down a lower-layer ionic liquid, performing rotary evaporation, collecting oily substances with strong fragrance, and drying by using anhydrous sodium sulfate to obtain the ginger essential oil, wherein the extraction rate is 29.5%.
2-4 parts by mass of fendortin; 1-2 parts by mass of hydrolyzed protein; 0.3 to 1 part by mass of glycine; 0.2 to 1 part by mass of glutamine; 0.1 to 1.5 parts by mass of phenylalanine; 3-5 parts by mass of zinc ricinoleate; 90.5 parts by mass of deionized water were mixed to obtain a biological enzyme.
Example 2
Mixing bamboo wood extract and ginger essential oil according to a ratio of 1:1 to obtain plant extract, and mixing the plant extract and biological enzyme according to a ratio of 9:1 to obtain the composition for reducing the peculiar smell of the wood chip storage yard.
Comparative example 4
Mixing bamboo wood extract and ginger essential oil according to a ratio of 1:1 to obtain plant extract.
Comparative example 5
Mixing bamboo wood extract and ginger essential oil according to a ratio of 1:1 to obtain plant extract, and mixing the plant extract and biological enzyme according to a ratio of 8:2 to obtain the composition for reducing the peculiar smell of the wood chip storage yard.
Comparative example 6
Mixing bamboo wood extract and ginger essential oil according to a ratio of 1:1 to obtain plant extract, and mixing the plant extract and biological enzyme according to a ratio of 7:3 to obtain the composition for reducing the peculiar smell of the wood chip storage yard.
Comparative example 7
Mixing bamboo wood extract and ginger essential oil according to a ratio of 1:1 to obtain plant extract, and mixing the plant extract and biological enzyme according to a ratio of 6:4 to obtain the composition for reducing the peculiar smell of the wood chip storage yard.
Comparative example 8
Mixing bamboo wood extract and ginger essential oil according to a ratio of 1:1 to obtain plant extract, and mixing the plant extract and biological enzyme according to a ratio of 5:5 to obtain the composition for reducing the peculiar smell of the wood chip storage yard.
Comparative example 9
Mixing bamboo wood extract and ginger essential oil according to a ratio of 1:1 to obtain plant extract, and mixing the plant extract and biological enzyme according to a ratio of 4:6 to obtain the composition for reducing the peculiar smell of the wood chip storage yard.
Comparative example 10
Mixing bamboo wood extract and ginger essential oil according to a ratio of 1:1 to obtain plant extract, and mixing the plant extract and biological enzyme according to a ratio of 3:7 to obtain the composition for reducing the peculiar smell of the wood chip storage yard.
Comparative example 11
Mixing bamboo wood extract and ginger essential oil according to a ratio of 1:1 to obtain plant extract, and mixing the plant extract and biological enzyme according to a ratio of 2:8 to obtain the composition for reducing the peculiar smell of the wood chip storage yard.
Comparative example 12
Mixing bamboo wood extract and ginger essential oil according to a ratio of 1:1 to obtain plant extract, and mixing the plant extract and biological enzyme according to a ratio of 1:9 to obtain the composition for reducing the peculiar smell of the wood chip storage yard.
Comparative example 13
The biological enzyme alone is used as a substance for reducing the peculiar smell of the wood chip storage yard.
Example 3
The wood chips of the raw material storage yard are taken and distributed in 4 storage boxes with 8L (each box is 800g of wood chips) and sealed. After 10 days, after the wood chips are naturally fermented, measuring the content of the peculiar smell gas at the top in the storage box. As shown in FIG. 1, FIG. 1 is a diagram of an experimental apparatus in example 3 of the present invention; as can be seen from table 1, during the natural fermentation of wood chips, the gas mainly produced is acid gas such as acetic acid. After the compositions for reducing the peculiar smell of the wood chip storage yard, which are prepared in the embodiment 2 and the comparative examples 4 to 13 of the invention, are added according to different volumes, the amount of generated acid gas is reduced.
TABLE 1
Example 4
The wood chip yard odor reducing composition prepared in example 2 of the present invention was tested with the YJF-TR-102 conventional product according to the method described in example 3 of the present invention, and the results are shown in table 2.
TABLE 2
Example 5
The compositions for reducing the odor of the wood chip storage yard prepared in the embodiment 2 of the present invention and the comparative examples 4 to 13 were tested according to the method described in the embodiment 3 of the present invention, and the results of the removal rate (%) of VOCs are shown in table 3.
TABLE 3
The foregoing is only a preferred embodiment of the present invention, and it should be noted that, for those skilled in the art, various modifications and decorations can be made without departing from the principle of the present invention, and these modifications and decorations should also be regarded as the protection scope of the present invention.
Claims (10)
1. A composition for reducing odor in a chip yard comprising:
8-10 parts by mass of plant extract and 1 part by mass of biological enzyme;
the plant extract comprises: 40-60 parts of bamboo wood extracting solution and 40-60 parts of ginger essential oil.
2. The composition of claim 1, wherein the plant extract comprises: 45-55 parts by mass of bamboo wood extracting solution and 45-55 parts by mass of ginger essential oil.
3. The composition of claim 1, wherein the biological enzyme comprises: 2-4 parts by mass of fendortin; 1-2 parts by mass of hydrolyzed protein; 0.3 to 1 part by mass of glycine; 0.2 to 1 part by mass of glutamine; 0.1 to 1.5 parts by mass of phenylalanine; 3-5 parts by mass of zinc ricinoleate; 90-91 parts by mass of deionized water.
4. The composition as claimed in claim 1, wherein the bamboo wood extract is prepared by the following method:
removing impurities from bamboo, heating, keeping the temperature, heating up, and collecting the bamboo extract.
5. The composition according to claim 5, wherein the heating, heat preservation and temperature rise are specifically as follows:
heating to 88-92 ℃, keeping the temperature for 2-4 h, then continuously heating to 96-100 ℃, collecting the gas-phase bamboo extracting solution, heating to 116-120 ℃ within 7-9 h, and cooling the gas-phase bamboo extracting solution to obtain the bamboo wood composite material.
6. The composition of claim 1, wherein the ginger essential oil is prepared by the following method:
slicing rhizoma Zingiberis recens, mixing with starch solution, soaking, drying, and pulverizing to obtain rhizoma Zingiberis recens powder;
mixing the ginger powder with an ionic liquid system, adding cellulase for enzymolysis, then carrying out water bath enzyme deactivation, ultrasonic extraction, microwave treatment, filtration, centrifugation, taking the lower layer and concentrating to obtain the ginger essential oil.
7. The composition of claim 7, wherein the starch solution is 0.5 to 0.9 wt% starch solution; the soaking time is 10-15 min; the crushing specifically comprises the following steps: after crushing, sieving the powder by a sieve of 60-80 meshes; the ionic liquid system comprises: disodium hydrogen phosphate-citric acid buffer and 1-ethyl-3-methylimidazolium acetate; the ratio of the ginger powder to the ionic liquid system is 1: 10-1: 20 g/mL;
the enzyme activity ratio of the cellulase is 2000-4000U/g; the enzymolysis temperature is 40-50 ℃; the enzymolysis time is 3-5 h; the microwave power is 300 Hz; the microwave time is 10 min.
8. A method of making the composition for reducing odor in a chip yard as claimed in any one of claims 1 to 8, comprising:
mixing the plant extract with biological enzyme.
9. Use of the composition for reducing the odor of a wood chip yard according to any one of claims 1 to 8 for reducing the odor of a wood chip yard.
10. A method for reducing odor in a chip yard, comprising:
spraying the composition for reducing odor in a chip yard according to any one of claims 1 to 8 into the chips.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4317389A1 (en) * | 2022-08-04 | 2024-02-07 | Neutec Chemie GmbH | Air pollutant neutralizers with odor absorbing feature to improve room air |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0604323A (en) * | 2005-10-21 | 2007-08-21 | Givaudan Sa | compounds and use to reduce smelly formation |
| CN104232311A (en) * | 2014-09-02 | 2014-12-24 | 华南理工大学 | Extraction method of ginger essential oil |
| CN107362655A (en) * | 2017-08-17 | 2017-11-21 | 广州崃克保化工有限公司 | A kind of environment-friendly water-based eliminating smell agent and its application |
| CN109316957A (en) * | 2018-11-14 | 2019-02-12 | 合肥华盖生物科技有限公司 | A kind of plant air purification and preparation method thereof |
| CN109744268A (en) * | 2018-12-27 | 2019-05-14 | 广东振达康环保科技有限公司 | A kind of natural herb material for air purification and preparation method thereof and application method |
| CN109865423A (en) * | 2019-04-23 | 2019-06-11 | 惠州市铭铠防霉抗菌科技有限公司 | One Plant Extracts and the compound deodorizer of biological enzyme and preparation method thereof |
-
2020
- 2020-03-30 CN CN202010236898.8A patent/CN111298639A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0604323A (en) * | 2005-10-21 | 2007-08-21 | Givaudan Sa | compounds and use to reduce smelly formation |
| CN104232311A (en) * | 2014-09-02 | 2014-12-24 | 华南理工大学 | Extraction method of ginger essential oil |
| CN107362655A (en) * | 2017-08-17 | 2017-11-21 | 广州崃克保化工有限公司 | A kind of environment-friendly water-based eliminating smell agent and its application |
| CN109316957A (en) * | 2018-11-14 | 2019-02-12 | 合肥华盖生物科技有限公司 | A kind of plant air purification and preparation method thereof |
| CN109744268A (en) * | 2018-12-27 | 2019-05-14 | 广东振达康环保科技有限公司 | A kind of natural herb material for air purification and preparation method thereof and application method |
| CN109865423A (en) * | 2019-04-23 | 2019-06-11 | 惠州市铭铠防霉抗菌科技有限公司 | One Plant Extracts and the compound deodorizer of biological enzyme and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 庄淑旗: "《庄淑旗上班族充电健康法》", 30 June 2010 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP4317389A1 (en) * | 2022-08-04 | 2024-02-07 | Neutec Chemie GmbH | Air pollutant neutralizers with odor absorbing feature to improve room air |
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