CN111218353A - Household antibacterial and acarid-removing laundry detergent - Google Patents
Household antibacterial and acarid-removing laundry detergent Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/88—Ampholytes; Electroneutral compounds
- C11D1/94—Mixtures with anionic, cationic or non-ionic compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
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- C11D3/3796—Amphoteric polymers or zwitterionic polymers
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
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Abstract
The invention provides a household antibacterial and acarid-removing laundry detergent which is characterized by being prepared from the following components in parts by weight: 10-15 parts of 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol copolymer, 2-4 parts of soluble antibacterial mite-removing Chinese herbal medicine extract, 8-12 parts of hyperbranched non-ionic surfactant, 0.3-0.7 part of chelating agent, 1-4 parts of thickening agent and 35-45 parts of water. The invention also discloses a preparation method of the household antibacterial mite-killing laundry detergent. The household antibacterial and mite-killing laundry detergent disclosed by the invention is remarkable in antibacterial and mite-killing effect, strong in washing capacity, small in environmental pollution, stable and good in performance, safe to use and environment-friendly.
Description
Technical Field
The invention relates to the technical field of laundry detergents, in particular to a household antibacterial mite-killing laundry detergent and a preparation method thereof.
Background
In recent years, with the development of society, science and technology and economy, the living consumption level of people is continuously improved, washing products become necessary products for daily life of people, the types of detergent products are continuously increased, the demand is increased, the development speed is very high, and the washing products are gradually developed towards the directions of environmental protection, functionalization, specialization and serialization. The washing powder of the prior common washing product has poor detergency, and stains are difficult to remove if the washing powder is not rubbed with hands. The laundry detergent slowly enters the daily life of people after 90 years in the 20 th century, and is more and more popular with consumers because of the advantages of convenient use, easy dissolution, strong dirt-removing capability, capability of deeply penetrating into the interior of clothes fibers to play a washing role, more thorough dirt removal and the like.
At present, a large amount of harmful chemical agents are added into laundry detergents in the market for decontamination, if the laundry detergents are not cleaned, the laundry detergents can remain on clothes and have side effects such as certain stimulation on the skin of a human body, and waste liquids of the laundry detergents contain the chemical agents and also have certain pollution on the environment. Most of laundry detergents are poor in washing effect on clothes, the clothes become hard after washing, and although the laundry detergents have certain dirt-removing capacity, harmful germs and mites on the clothes cannot be effectively killed, growth of bacteria cannot be inhibited, and the functions of the laundry detergents are too single.
The domestic antibacterial and mite-killing laundry detergent in the prior art usually achieves the antibacterial and mite-killing effect by adding an antibacterial and mite-killing agent into the laundry detergent, and the commonly used antibacterial and mite-killing agents in the market mainly comprise sodium hypochlorite, chlorophenols (such as triclosan. PCMX), diphenylureas (TCC) and quaternary ammonium salts. However, these products have different drawbacks: sodium hypochlorite is highly oxidative corrosive and unstable; chlorophenols (such as triclosan. PCMX) and diphenylureas (TCC) are high in cost, poor in water solubility, complex to use and not suitable for large-area use; the quaternary ammonium salt cannot be compounded with an anion system, and is not suitable for being added into washing products.
The Chinese invention patent with the application number of 201810533004.4 discloses a mite-killing laundry detergent which comprises the following components in parts by weight: 20-45 parts of tea tree essential oil, 15-20 parts of dodecyl ethoxy, 3.7-6 parts of sorbitol, 4-8 parts of sulfobetaine, 1-2 parts of an antibacterial agent, 3-5 parts of castor oil, 1-1.5 parts of essence, 10-20 parts of deionized water and the balance of saponification components. The mite-killing laundry detergent disclosed by the invention has a cleaning effect and can play a role in resisting bacteria and killing mites; the product of the invention has no stimulation to human body temperature and is environment-friendly, thus meeting the requirement of environmental protection; the mite-killing laundry detergent disclosed by the invention is low in cost and low in production cost, and all components are cheap and easy to obtain. However, the antibacterial effect and the washing effect of the tea tree essential oil are required to be further improved, and the tea tree essential oil is poor in water solubility and complex to use.
Therefore, the development of the household antibacterial mite-killing laundry detergent with obvious antibacterial mite-killing effect and strong washing capacity has very important significance for small environmental pollution.
Disclosure of Invention
In order to overcome the defects in the prior art, the invention aims to provide the household antibacterial mite-killing laundry detergent which has the advantages of obvious antibacterial mite-killing effect, strong washing capacity, small environmental pollution, stable and good performance, and safe and environment-friendly use; meanwhile, the invention also provides a preparation method of the household antibacterial and acarid-removing laundry detergent, which is simple and feasible, has high preparation efficiency and yield, is suitable for continuous large-scale production, and effectively realizes organic unification of economic benefit, social benefit and ecological benefit.
The invention is realized by the following technical scheme: the household antibacterial and mite-killing laundry detergent is characterized by being prepared from the following components in parts by weight: 10-15 parts of 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol copolymer, 2-4 parts of soluble antibacterial mite-removing Chinese herbal medicine extract, 8-12 parts of hyperbranched non-ionic surfactant, 0.3-0.7 part of chelating agent, 1-4 parts of thickening agent and 35-45 parts of water.
Preferably, the thickener is at least one of sodium carboxymethylcellulose, hydroxyethyl cellulose, ethyl hydroxyethyl cellulose, fatty acid polyethylene glycol ester and polyvinylpyrrolidone.
Preferably, the chelating agent is at least one of sodium polyaspartate, sodium polycarboxylate and sodium polyepoxysuccinate.
Preferably, the hyperbranched nonionic surfactant is prepared by coupling monomers of hyperbranched polyester (poly 2, 2-dimethylolpropionic acid (bis-MPA)), styrene and phenol, and the preparation method is as follows: chinese patent application No. 201610910237.2, example 1.
Further, the preparation method of the 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acexamine eugenol copolymer comprises the following steps: adding 2-allyl-4-chlorophenol, alliin, polyethylene glycol monoallyl ether, 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acetic amine eugenol and an initiator into a high boiling point solvent, stirring and reacting for 4-6 hours at 70-80 ℃ in the atmosphere of nitrogen or inert gas, and then removing the solvent by rotary evaporation to obtain the 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acetic amine eugenol copolymer.
Preferably, the mass ratio of the 2-allyl-4-chlorophenol, the alliin, the polyethylene glycol monoallyl ether, the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol, the initiator and the high-boiling point solvent is 0.3:0.8 (1.5-2) to 1 (0.04-0.05) to 15-20.
Preferably, the high boiling point solvent is at least one of dimethyl sulfoxide, N-dimethylformamide, N-dimethylacetamide and N-methylpyrrolidone.
Preferably, the inert gas is one of helium, neon and argon.
Preferably, the initiator is at least one of azobisisobutyronitrile and azobisisoheptonitrile.
Further, the preparation method of the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acephate eugenol comprises the following steps: adding 4-chloro-1-hydroxy-butane sodium sulfonate and acetic amine eugenol into tetrahydrofuran, stirring and reacting for 6-8 hours at the temperature of 25-35 ℃, then performing rotary evaporation to remove the tetrahydrofuran, dissolving with dichloromethane in sequence, filtering, and performing rotary evaporation to remove the dichloromethane to obtain the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acetic amine eugenol.
Preferably, the molar ratio of the 4-chloro-1-hydroxy-butane sodium sulfonate to the acephatine eugenol to the tetrahydrofuran is 1:1 (6-10).
Furthermore, the soluble antibacterial mite-killing Chinese herbal medicine extract is prepared by the following steps of boiling the following raw material medicines in parts by weight with water, filtering, concentrating, performing rotary evaporation and drying in sequence: 4-6 parts of wormwood, 1-3 parts of eucalyptus leaves, 2-4 parts of bearberry leaves, 2-5 parts of pomelo peel, 4-8 parts of purple perilla, 1-3 parts of mint leaves, 2-4 parts of common andrographis herbs, 2-6 parts of lemon grass, 1-3 parts of rosemary and 2-5 parts of rhizoma anemarrhenae.
The invention also aims to provide a preparation method of the household antibacterial acarus-killing laundry detergent, which is characterized by comprising the following steps: the components are mixed according to the parts by weight, added into a stirring reactor, and stirred for 1-3 hours under the condition of controlling the rotating speed to be 100-300rpm, so that the finished household antibacterial mite-killing laundry detergent can be prepared.
Adopt the produced beneficial effect of above-mentioned technical scheme to lie in:
(1) the preparation method of the household antibacterial and acarid-removing laundry detergent provided by the invention is simple and easy to implement, high in preparation efficiency and yield, suitable for continuous large-scale production, and capable of effectively realizing organic unification of economic benefits, social benefits and ecological benefits.
(2) The household antibacterial and mite-killing laundry detergent overcomes the defects that the household antibacterial and mite-killing laundry detergent in the prior art has poor washing effect on clothes, the clothes become hard after washing, although the laundry detergent has certain dirt-removing capacity, harmful germs and mites on the clothes cannot be effectively killed, the growth of bacteria cannot be inhibited, and the household antibacterial and mite-killing laundry detergent has a single function, and has the advantages of remarkable antibacterial and mite-killing effect, strong washing capacity, small environmental pollution, stable and good performance, and safety and environmental friendliness in use.
(3) According to the household antibacterial mite-killing laundry detergent, the added 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butanesulfonic acid sodium salt ionized modified acetamine eugenol copolymer contains chlorophenol, alliin and acetamine eugenol structures on a molecular chain, and the laundry detergent has excellent antibacterial mite-killing performance under the synergistic effect; the structures are connected with polyethylene glycol monoallyl ether and an amphoteric surfactant structure formed by ionizing and modifying 4-chloro-1-hydroxy-butane sodium sulfonate in a chemical bond form, so that the antagonism caused by direct mixing of the traditional antibacterial mite-killing laundry detergent surfactant and the antibacterial mite-killing agent is effectively avoided.
(4) According to the household antibacterial and mite-killing laundry detergent, the soluble antibacterial and mite-killing Chinese herbal medicine extract is added, the antibacterial and mite-killing effect is further improved through reasonable compatibility and synergistic effect of all the raw material medicines, and the laundry detergent can achieve the advantages of scratching and fragrance release after being immersed in clothes; the addition of the hyperbranched nonionic surfactant can effectively improve the washing effect, and the addition of the hyperbranched structural surfactant and other components have synergistic effect, so that the hyperbranched structural surfactant has better dispersion stability and excellent storage and transportation stability.
Detailed Description
In order to make the technical solutions of the present invention better understood and make the above features, objects, and advantages of the present invention more comprehensible, the present invention is further described with reference to the following examples. The examples are intended to illustrate the invention only and are not intended to limit the scope of the invention.
The raw materials used in the following examples of the present invention were all purchased commercially, and the preparation method of the hyperbranched nonionic surfactant was referred to as follows: chinese patent application No. 201610910237.2, example 1.
Example 1
A household antibacterial mite-killing laundry detergent is prepared from the following components in parts by weight: 10 parts of 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol copolymer, 2 parts of soluble antibacterial mite-killing Chinese herbal medicine extract, 8 parts of hyperbranched nonionic surfactant, 0.3 part of sodium polyaspartate, 1 part of sodium carboxymethylcellulose and 35 parts of water.
The preparation method of the 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acexamine eugenol copolymer comprises the following steps: adding 2-allyl-4-chlorophenol, alliin, polyethylene glycol monoallyl ether, 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acetamine eugenol and azobisisobutyronitrile into dimethyl sulfoxide, stirring and reacting for 4 hours at 70 ℃ in a nitrogen atmosphere, and then performing rotary evaporation to remove the solvent to obtain a 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acetamine eugenol copolymer; the mass ratio of the 2-allyl-4-chlorophenol, the alliin, the polyethylene glycol monoallyl ether, the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acetominoeugenol, the azobisisobutyronitrile and the dimethyl sulfoxide is 0.3:0.8:1.5:1:0.04: 15.
The preparation method of the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acephate eugenol comprises the following steps: adding 4-chloro-1-hydroxy-butanesulfonic acid sodium salt and acetic amine eugenol into tetrahydrofuran, stirring and reacting for 6 hours at 25 ℃, then performing rotary evaporation to remove the tetrahydrofuran, dissolving with dichloromethane in sequence, filtering, and performing rotary evaporation to remove the dichloromethane to obtain 4-chloro-1-hydroxy-butanesulfonic acid sodium salt ionized modified acetic amine eugenol; the molar ratio of the 4-chloro-1-hydroxy-butane sodium sulfonate to the acephate eugenol to the tetrahydrofuran is 1:1: 6.
The soluble antibacterial mite-killing Chinese herbal medicine extract is prepared by the following steps of steaming and boiling raw material medicines in parts by weight in water, and then sequentially filtering, concentrating, carrying out rotary steaming and drying: 4 parts of wormwood, 1 part of eucalyptus leaf, 2 parts of bearberry leaf, 2 parts of pomelo peel, 4 parts of purple perilla, 1 part of mint leaf, 2 parts of common andrographis herb, 2 parts of lemon grass, 1 part of rosemary and 2 parts of rhizoma anemarrhenae.
A preparation method of the household antibacterial mite-killing laundry detergent comprises the following steps: the components are mixed according to the parts by weight, added into a stirring reactor, and stirred for 1 hour under the condition of controlling the rotating speed to be 100rpm, so that the finished household antibacterial mite-killing laundry detergent can be prepared.
Example 2
A household antibacterial mite-killing laundry detergent is prepared from the following components in parts by weight: 11 parts of 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol copolymer, 2.5 parts of soluble antibacterial mite-removing Chinese herbal medicine extract, 9 parts of hyperbranched nonionic surfactant, 0.4 part of sodium polycarboxylate, 2 parts of hydroxyethyl cellulose and 37 parts of water.
The preparation method of the 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acexamine eugenol copolymer comprises the following steps: adding 2-allyl-4-chlorophenol, alliin, polyethylene glycol monoallyl ether, 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol and azobisisoheptonitrile into N, N-dimethylformamide, stirring and reacting for 4.5 hours at 73 ℃ in a helium atmosphere, and then performing rotary evaporation to remove the solvent to obtain a 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol copolymer; the mass ratio of the 2-allyl-4-chlorophenol, the alliin, the polyethylene glycol monoallyl ether, the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol, the azobisisoheptonitrile and the N, N-dimethylformamide is 0.3:0.8:1.6:1:0.042: 16.
The preparation method of the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acephate eugenol comprises the following steps: adding 4-chloro-1-hydroxy-butanesulfonic acid sodium salt and acetic amine eugenol into tetrahydrofuran, stirring and reacting for 6.5 hours at the temperature of 27 ℃, then performing rotary evaporation to remove the tetrahydrofuran, dissolving with dichloromethane in sequence, filtering, and performing rotary evaporation to remove the dichloromethane to obtain 4-chloro-1-hydroxy-butanesulfonic acid sodium salt ionized modified acetic amine eugenol; the molar ratio of the 4-chloro-1-hydroxy-butane sodium sulfonate to the acephate eugenol to the tetrahydrofuran is 1:1: 7.
The soluble antibacterial mite-killing Chinese herbal medicine extract is prepared by the following steps of steaming and boiling raw material medicines in parts by weight in water, and then sequentially filtering, concentrating, carrying out rotary steaming and drying: 4.5 parts of wormwood, 1.5 parts of eucalyptus leaf, 2.5 parts of bearberry leaf, 2.5 parts of pomelo peel, 5 parts of purple perilla, 1.5 parts of mint leaf, 2.5 parts of common andrographis herb, 3 parts of lemon grass, 1.5 parts of rosemary and 3 parts of rhizoma anemarrhenae.
A preparation method of the household antibacterial mite-killing laundry detergent comprises the following steps: the components are mixed according to the parts by weight, added into a stirring reactor, and stirred for 1.5 hours under the condition of controlling the rotating speed to be 150rpm, so that the finished household antibacterial mite-killing laundry detergent can be prepared.
Example 3
A household antibacterial mite-killing laundry detergent is prepared from the following components in parts by weight: 13 parts of 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol copolymer, 3 parts of soluble antibacterial mite-killing Chinese herbal medicine extract, 10 parts of hyperbranched nonionic surfactant, 0.5 part of polyepoxysuccinic acid, 2.5 parts of ethyl hydroxyethyl cellulose and 40 parts of water.
The preparation method of the 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acexamine eugenol copolymer comprises the following steps: adding 2-allyl-4-chlorophenol, alliin, polyethylene glycol monoallyl ether, 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol and azobisisobutyronitrile into N, N-dimethylacetamide, stirring and reacting for 5 hours at 75 ℃ in a neon atmosphere, and then removing the solvent by rotary evaporation to obtain a 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol copolymer; the mass ratio of the 2-allyl-4-chlorophenol, the alliin, the polyethylene glycol monoallyl ether, the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol, the azobisisobutyronitrile and the N, N-dimethylacetamide is 0.3:0.8:1.7:1:0.045: 18.
The preparation method of the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acephate eugenol comprises the following steps: adding 4-chloro-1-hydroxy-butanesulfonic acid sodium salt and acetic amine eugenol into tetrahydrofuran, stirring and reacting for 7 hours at the temperature of 30 ℃, then performing rotary evaporation to remove the tetrahydrofuran, dissolving with dichloromethane in sequence, filtering, and performing rotary evaporation to remove the dichloromethane to obtain 4-chloro-1-hydroxy-butanesulfonic acid sodium salt ionized modified acetic amine eugenol; the molar ratio of the 4-chloro-1-hydroxy-butane sodium sulfonate to the acephate eugenol to the tetrahydrofuran is 1:1: 8.
The soluble antibacterial mite-killing Chinese herbal medicine extract is prepared by the following steps of steaming and boiling raw material medicines in parts by weight in water, and then sequentially filtering, concentrating, carrying out rotary steaming and drying: 5 parts of wormwood, 2 parts of eucalyptus leaf, 3 parts of bearberry leaf, 3.5 parts of pomelo peel, 6 parts of purple perilla, 2 parts of mint leaf, 3 parts of common andrographis herb, 4 parts of lemon grass, 2 parts of rosemary and 3.5 parts of rhizoma anemarrhenae.
A preparation method of the household antibacterial mite-killing laundry detergent comprises the following steps: the components are mixed according to the parts by weight, added into a stirring reactor, and stirred for 2 hours under the condition of controlling the rotating speed to be 200rpm, so that the finished household antibacterial mite-killing laundry detergent can be prepared.
Example 4
A household antibacterial mite-killing laundry detergent is prepared from the following components in parts by weight: 14 parts of 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol copolymer, 3.5 parts of soluble antibacterial mite-removing Chinese herbal medicine extract, 11 parts of hyperbranched nonionic surfactant, 0.6 part of chelating agent, 3 parts of thickening agent and 43 parts of water; the thickening agent is prepared by mixing sodium carboxymethylcellulose, hydroxyethyl cellulose, ethyl hydroxyethyl cellulose, fatty acid polyglycol ester and polyvinylpyrrolidone according to the mass ratio of 1:1:3:2: 2; the chelating agent is prepared by mixing polyaspartic acid sodium, polycarboxylic acid sodium and polyepoxysuccinic acid sodium according to the mass ratio of 2:3: 5.
The preparation method of the 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acexamine eugenol copolymer comprises the following steps: adding 2-allyl-4-chlorophenol, alliin, polyethylene glycol monoallyl ether, 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acetamine eugenol and an initiator into a high boiling point solvent, stirring and reacting for 5.7 hours at 78 ℃ in an argon atmosphere, and then performing rotary evaporation to remove the solvent to obtain a 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acetamine eugenol copolymer; the mass ratio of the 2-allyl-4-chlorophenol, the alliin, the polyethylene glycol monoallyl ether, the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol, the initiator and the high-boiling point solvent is 0.3:0.8:1.9:1:0.048: 19; the high-boiling-point solvent is formed by mixing dimethyl sulfoxide, N-dimethylformamide, N-dimethylacetamide and N-methylpyrrolidone according to a mass ratio of 1:3:2: 2; the initiator is formed by mixing azodiisobutyronitrile and azodiisoheptonitrile according to the mass ratio of 3: 5.
The preparation method of the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acephate eugenol comprises the following steps: adding 4-chloro-1-hydroxy-butanesulfonic acid sodium salt and acetic amine eugenol into tetrahydrofuran, stirring and reacting for 7.5 hours at 33 ℃, then performing rotary evaporation to remove the tetrahydrofuran, dissolving with dichloromethane in sequence, filtering, and performing rotary evaporation to remove the dichloromethane to obtain 4-chloro-1-hydroxy-butanesulfonic acid sodium salt ionized modified acetic amine eugenol; the molar ratio of the 4-chloro-1-hydroxy-butane sodium sulfonate to the acephate eugenol to the tetrahydrofuran is 1:1: 9.
The soluble antibacterial mite-killing Chinese herbal medicine extract is prepared by the following steps of steaming and boiling raw material medicines in parts by weight in water, and then sequentially filtering, concentrating, carrying out rotary steaming and drying: 5.5 parts of wormwood, 2.5 parts of eucalyptus leaf, 3.5 parts of bearberry leaf, 4.5 parts of pomelo peel, 7 parts of purple perilla, 2.5 parts of mint leaf, 3.5 parts of common andrographis herb, 5 parts of lemon grass, 2.5 parts of rosemary and 4.5 parts of rhizoma anemarrhenae.
A preparation method of the household antibacterial mite-killing laundry detergent comprises the following steps: the components are mixed according to the parts by weight, added into a stirring reactor, and stirred for 2.5 hours under the condition of controlling the rotating speed to be 250rpm, so that the finished household antibacterial mite-killing laundry detergent can be prepared.
Example 5
A household antibacterial mite-killing laundry detergent is prepared from the following components in parts by weight: 15 parts of 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified aceglutamineeugenol copolymer, 4 parts of soluble antibacterial mite-removing Chinese herbal medicine extract, 12 parts of hyperbranched nonionic surfactant, 0.7 part of sodium polyaspartate, 4 parts of polyvinylpyrrolidone and 45 parts of water.
The preparation method of the 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acexamine eugenol copolymer comprises the following steps: adding 2-allyl-4-chlorophenol, alliin, polyethylene glycol monoallyl ether, 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol and azobisisoheptonitrile into N-methylpyrrolidone, stirring and reacting for 6 hours at 80 ℃ in a nitrogen atmosphere, and then performing rotary evaporation to remove the solvent to obtain a 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol copolymer; the mass ratio of the 2-allyl-4-chlorophenol, the alliin, the polyethylene glycol monoallyl ether, the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol, the azobisisoheptonitrile and the N-methyl pyrrolidone is 0.3:0.8:2:1:0.05: 20.
The preparation method of the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acephate eugenol comprises the following steps: adding 4-chloro-1-hydroxy-butanesulfonic acid sodium salt and acetic amine eugenol into tetrahydrofuran, stirring and reacting for 8 hours at 35 ℃, then performing rotary evaporation to remove the tetrahydrofuran, dissolving with dichloromethane in sequence, filtering, and performing rotary evaporation to remove the dichloromethane to obtain 4-chloro-1-hydroxy-butanesulfonic acid sodium salt ionized modified acetic amine eugenol; the molar ratio of the 4-chloro-1-hydroxy-butane sodium sulfonate to the acephate eugenol to the tetrahydrofuran is 1:1: 10.
The soluble antibacterial mite-killing Chinese herbal medicine extract is prepared by the following steps of steaming and boiling raw material medicines in parts by weight in water, and then sequentially filtering, concentrating, carrying out rotary steaming and drying: 6 parts of wormwood, 3 parts of eucalyptus leaf, 4 parts of bearberry leaf, 5 parts of pomelo peel, 8 parts of purple perilla, 3 parts of mint leaf, 4 parts of common andrographis herb, 6 parts of lemon grass, 3 parts of rosemary and 5 parts of rhizoma anemarrhenae.
A preparation method of the household antibacterial mite-killing laundry detergent comprises the following steps: the components are mixed according to the parts by weight, added into a stirring reactor, and stirred for 3 hours under the condition of controlling the rotating speed to be 300rpm, so that the finished household antibacterial mite-killing laundry detergent can be prepared.
Comparative example 1
The formula and the preparation method of the household antibacterial acarus-killing laundry detergent are basically the same as those of the example 1, and the differences are only that: no 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acexamine eugenol copolymer was added.
Comparative example 2
The formula and the preparation method of the household antibacterial acarus-killing laundry detergent are basically the same as those of the example 1, and the differences are only that: no hyperbranched nonionic surfactant was added.
Comparative example 3
The formula and the preparation method of the household antibacterial acarus-killing laundry detergent are basically the same as those of the example 1, and the differences are only that: the soluble antibacterial mite-killing Chinese herbal medicine extract is not added.
Comparative example 4
The formula and the preparation method of the mite-killing laundry detergent are the same as those of the Chinese patent application No. 201110024730.1 in the embodiment 1.
In order to further illustrate the beneficial technical effects of the household antibacterial and mite-killing laundry detergent according to the embodiment of the invention, the household antibacterial and mite-killing laundry detergent obtained in the above embodiments 1-5 and the laundry detergent in the comparative examples 1-4 are tested, and the specific tests are as follows: the antibacterial ability test of the household antibacterial and mite-killing laundry detergent sample is carried out according to QB/T2738-2012 'evaluation method for antibacterial and bacteriostatic effects of daily chemical products', and the mite-killing test of the laundry detergent sample is carried out according to GB13917.2-92 'indoor pesticide effect determination method for aerosol of pesticide indoor pesticide effect determination method for pesticide registration hygiene'. The method specifically comprises the following steps: the method comprises the following steps of placing mites into the bottom of a transparent organic glass cylinder, respectively and cylindrically installing the tested household antibacterial mite-killing laundry detergent on a rack column of an electronic spray controller, flatly placing the rack column of the electronic spray controller, adjusting a time control button of the electronic controller to the time of spraying the usage amount, pressing an operation button, immediately plugging a circular hole with a rubber plug after spraying to enable the contact amount of the surface of a culture dish to be 0.1g, immediately timing, starting recording, taking out the culture dish after 30 minutes, placing the culture dish in a culture box at 26 ℃, and observing mite-killing effect after 24 hours.
TABLE 1
As can be seen from table 1, the household antibacterial and mite-killing laundry detergent disclosed in the embodiment of the invention has more excellent antibacterial and mite-killing performance, which is a result of the synergistic effect of the components.
The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, which are merely illustrative of the principles of the invention, but that various changes and modifications may be made without departing from the spirit and scope of the invention, which fall within the scope of the invention as claimed. The scope of the invention is defined by the appended claims and equivalents thereof.
Claims (10)
1. The household antibacterial and mite-killing laundry detergent is characterized by being prepared from the following components in parts by weight: 10-15 parts of 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acerolol copolymer, 2-4 parts of soluble antibacterial mite-removing Chinese herbal medicine extract, 8-12 parts of hyperbranched non-ionic surfactant, 0.3-0.7 part of chelating agent, 1-4 parts of thickening agent and 35-45 parts of water.
2. The household antibacterial and acaricidal laundry detergent as claimed in claim 1, wherein the thickener is at least one of sodium carboxymethylcellulose, hydroxyethyl cellulose, ethyl hydroxyethyl cellulose, fatty acid polyethylene glycol ester, and polyvinylpyrrolidone.
3. The household antibacterial and acaricidal laundry detergent composition according to claim 1, wherein the chelating agent is at least one of sodium polyaspartate, sodium polycarboxylate and sodium polyepoxysuccinate.
4. The household antibacterial and acarid-removing laundry detergent as claimed in claim 1, wherein the preparation method of the 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butanesulfonic acid sodium salt ionized modified aceamin eugenol copolymer comprises the following steps: adding 2-allyl-4-chlorophenol, alliin, polyethylene glycol monoallyl ether, 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acetic amine eugenol and an initiator into a high boiling point solvent, stirring and reacting for 4-6 hours at 70-80 ℃ in the atmosphere of nitrogen or inert gas, and then removing the solvent by rotary evaporation to obtain the 2-allyl-4-chlorophenol/alliin/polyethylene glycol monoallyl ether/4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acetic amine eugenol copolymer.
5. The household antibacterial and acarid-removing laundry detergent as claimed in claim 4, wherein the mass ratio of the 2-allyl-4-chlorophenol, the alliin, the polyethylene glycol monoallyl ether, the ionized modified acephate eugenol of 4-chloro-1-hydroxy-butane sodium sulfonate, the initiator and the high boiling point solvent is 0.3:0.8 (1.5-2):1 (0.04-0.05): (15-20).
6. The household antibacterial and acarid-removing laundry detergent as claimed in claim 4, wherein the high boiling point solvent is at least one of dimethyl sulfoxide, N-dimethylformamide, N-dimethylacetamide and N-methylpyrrolidone; the inert gas is one of helium, neon and argon; the initiator is at least one of azobisisobutyronitrile and azobisisoheptonitrile.
7. The household antibacterial and acarid-removing laundry detergent as claimed in claim 1, wherein the preparation method of the 4-chloro-1-hydroxy-butanesulfonic acid sodium salt ionized modified acexamine eugenol comprises the following steps: adding 4-chloro-1-hydroxy-butane sodium sulfonate and acetic amine eugenol into tetrahydrofuran, stirring and reacting for 6-8 hours at the temperature of 25-35 ℃, then performing rotary evaporation to remove the tetrahydrofuran, dissolving with dichloromethane in sequence, filtering, and performing rotary evaporation to remove the dichloromethane to obtain the 4-chloro-1-hydroxy-butane sodium sulfonate ionized modified acetic amine eugenol.
8. The household antibacterial and acarid-removing laundry detergent as claimed in claim 7, wherein the molar ratio of the 4-chloro-1-hydroxy-butane sodium sulfonate to the acerolol to the tetrahydrofuran is 1:1 (6-10).
9. The household antibacterial and mite-killing laundry detergent as claimed in claim 1, wherein the soluble antibacterial and mite-killing Chinese herbal medicine extract is prepared by the following steps of decocting raw material medicines in parts by weight with water, filtering, concentrating, steaming in a rotating manner and drying: 4-6 parts of wormwood, 1-3 parts of eucalyptus leaves, 2-4 parts of bearberry leaves, 2-5 parts of pomelo peel, 4-8 parts of purple perilla, 1-3 parts of mint leaves, 2-4 parts of common andrographis herbs, 2-6 parts of lemon grass, 1-3 parts of rosemary and 2-5 parts of rhizoma anemarrhenae.
10. The household antibacterial acarus-killing laundry detergent as claimed in any one of claims 1-9, wherein the preparation method of the household antibacterial acarus-killing laundry detergent comprises the following steps: the components are mixed according to the parts by weight, added into a stirring reactor, and stirred for 1-3 hours under the condition of controlling the rotating speed to be 100-300rpm, so that the finished household antibacterial mite-killing laundry detergent can be prepared.
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Cited By (1)
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| CN114907920A (en) * | 2022-06-27 | 2022-08-16 | 两面针（江苏）实业有限公司 | Mite-removing laundry detergent rich in various plant extracts |
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