CN111138909A - Pure cotton infrared-proof fabric digital printing ink combination and method - Google Patents
Pure cotton infrared-proof fabric digital printing ink combination and method Download PDFInfo
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- CN111138909A CN111138909A CN201811307759.9A CN201811307759A CN111138909A CN 111138909 A CN111138909 A CN 111138909A CN 201811307759 A CN201811307759 A CN 201811307759A CN 111138909 A CN111138909 A CN 111138909A
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- vat
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/40—Ink-sets specially adapted for multi-colour inkjet printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/328—Inkjet printing inks characterised by colouring agents characterised by dyes
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/22—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using vat dyestuffs including indigo
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/58—Material containing hydroxyl groups
- D06P3/60—Natural or regenerated cellulose
- D06P3/6025—Natural or regenerated cellulose using vat or sulfur dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The pure cotton infrared-proof fabric digital printing ink combination is composed of infrared-proof digital printing reduction inks magenta, yellow, black, brown, green and blue, wherein the six-color reduction inks are composed of non-soluble and soluble reduction dyes or a mixture of the non-soluble and soluble reduction dyes. Also provides a digital printing method for the pure cotton infrared-proof fabric. According to the invention, by screening the dye ink conforming to infrared camouflage, the fabric produced by digital printing can present an infrared-proof product with millions of color combinations, and the limitation of color register of the product is solved. The ink combination and the digital printing method have the advantages of good product consistency and stability, no plate making, wide color gamut, high fineness of the printed patterns without color limitation, bright and bright patterns, energy saving, accurate ink consumption, no waste and accordance with the requirement of environmental protection. The fabric produced by the screened ink not only reaches the infrared-proof standard, but also reaches the national high-grade product standards in light fastness, washing fastness, perspiration fastness and rubbing fastness.
Description
Technical Field
The invention belongs to the technical field of textile printing and dyeing, and particularly relates to a method for carrying out digital printing by using vat dye ink.
Background
At present, the infrared camouflage all over the world is mainly produced by printing on rotary screen printing equipment by using paint and vat dye, and the colors of the infrared camouflage fabric which can be produced are limited due to the limitation of a printing machine. In China, 7 camouflage clothes with more than 20 sets of colors, such as forest lands, deserts, oceans, cities, mountain lands, snow lands and the like, which are printed by vat dye (vaseline) are mainly used.
Disclosure of Invention
The invention provides an infrared-proof digital printing ink combination, which is printed on a fabric by a digital printing machine, and then is subjected to reduction, oxidation and washing to produce an infrared-proof product with wide color gamut and high fastness.
The invention provides a pure cotton infrared-proof fabric digital printing ink combination which consists of six colors of magenta, yellow, black, brown, green and blue for infrared-proof digital printing reduction ink, wherein the six colors of reduction ink consist of non-soluble and soluble reduction dyes or a mixture of the non-soluble and soluble reduction dyes.
According to an embodiment of the invention, the non-soluble vat dye is selected from one or more of c.i. vat yellow 46, c.i. vat orange 1, c.i. vat orange 11, c.i. vat red 1, c.i. vat red 10, c.i. vat red 13, c.i. vat red 15, c.i. vat violet 1, c.i. vat violet 13, c.i. vat blue 4, c.i. vat blue 5, c.i. vat blue 6, c.i. vat blue 66, c.i. vat blue 20, c.i. vat green 1, c.i. vat green 3, c.i. vat brown 1, c.i. vat brown 33, c.i. vat brown 57, c.i. vat black 9, c.i. vat black 25, c.i. vat black 27, c.i. vat black 65; the soluble vat dye is selected from one or more of c.i. soluble vat orange 1, c.i. soluble vat orange 11, c.i. soluble vat red 1, c.i. soluble vat red 10, c.i. soluble vat violet 1, c.i. vat violet 13, c.i. soluble vat blue 4, c.i. soluble vat blue 5, c.i. soluble vat blue 6, c.i. soluble vat green 1, c.i. soluble vat green 3, c.i. soluble vat brown 1, c.i. soluble vat black 25.
The invention also provides a digital printing method for pure cotton infrared-proof fabric, which comprises the following steps: sizing and presetting a semi-finished product, digitally printing, steaming, washing and finishing; the ink combination adopted in the digital printing step is six colors of reduction ink magenta, yellow, black, brown, green and blue for infrared prevention, and the reduction ink of the six colors consists of non-soluble and soluble reduction dyes or a mixture thereof.
According to an embodiment of the invention, the non-soluble vat dye is selected from one or more of c.i. vat yellow 46, c.i. vat orange 1, c.i. vat orange 11, c.i. vat red 1, c.i. vat red 10, c.i. vat red 13, c.i. vat red 15, c.i. vat violet 1, c.i. vat violet 13, c.i. vat blue 4, c.i. vat blue 5, c.i. vat blue 6, c.i. vat blue 66, c.i. vat blue 20, c.i. vat green 1, c.i. vat green 3, c.i. vat brown 1, c.i. vat brown 33, c.i. vat brown 57, c.i. vat black 9, c.i. vat black 25, c.i. vat black 27, c.i. vat black 65; the soluble vat dye is selected from one or more of c.i. soluble vat orange 1, c.i. soluble vat orange 11, c.i. soluble vat red 1, c.i. soluble vat red 10, c.i. soluble vat violet 1, c.i. vat violet 13, c.i. soluble vat blue 4, c.i. soluble vat blue 5, c.i. soluble vat blue 6, c.i. soluble vat green 1, c.i. soluble vat green 3, c.i. soluble vat brown 1, c.i. soluble vat black 25.
According to another embodiment of the invention, the digital printing step adopts any one of nozzles SG1024-XS, SA and MA of FUJIFILM company to print in one of the printing modes of 2pass, 3pass, 4pass, 5pass and 6 pass.
According to another embodiment of the present invention, the digital printing step uses RIP software neoStampa or ergsoft textile professional for image color management.
According to another embodiment of the invention, the semi-finished product sizing and pre-setting step adopts a soaking and rolling step, the soaking solution comprises 20-25g/L of thickening agent, 1-2g/L of defoaming agent and 5-8g/L of sodium hexametaphosphate, the rolling residual rate is 65-70%, the setting temperature is 110-120 ℃, and the vehicle speed is 20-25 m/min.
According to another embodiment of the present invention, the temperature of the steaming step is 130-135 ℃, and the steaming time is 20-24 seconds.
According to another embodiment of the invention, the soaping liquid in the water washing step contains 1.5-2g/L of anti-staining soaping agent, and the oxidizing liquid contains 1.8-2g/L of hydrogen peroxide.
According to another embodiment of the invention, the post-finishing step adopts one dipping and one rolling, the dipping solution comprises 30-40g/L of the softening agent, the rolling residual rate is 65-75%, the setting temperature is 110-.
According to the invention, by screening the dye ink conforming to infrared camouflage, the fabric produced by digital printing can present an infrared-proof product with millions of color combinations, and the limitation of color register of the product is solved. The ink combination and the digital printing method have the advantages of good product consistency and stability, no plate making, wide color gamut, high fineness of the printed patterns without color limitation, bright and bright patterns, energy saving, accurate ink consumption, no waste and accordance with the requirement of environmental protection. The fabric produced by the screened ink not only reaches the infrared-proof standard, but also reaches the national high-grade product standards in light fastness, washing fastness, perspiration fastness and rubbing fastness.
Detailed Description
The present invention will be described in detail with reference to the following embodiments.
The invention provides a pure cotton infrared-proof fabric digital printing ink combination which comprises six colors of magenta, yellow, black, brown, green and blue used for infrared-proof digital printing reduction ink, wherein the six colors of reduction ink comprise non-soluble and soluble reduction dyes or a mixture thereof.
The non-soluble vat dye is selected from one or more of c.i. vat yellow 46, c.i. vat orange 1, c.i. vat orange 11, c.i. vat red 1, c.i. vat red 10, c.i. vat red 13, c.i. vat red 15, c.i. vat violet 1, c.i. vat violet 13, c.i. vat blue 4, c.i. vat blue 5, c.i. vat blue 6, c.i. vat blue 66, c.i. vat blue 20, c.i. vat green 1, c.i. vat green 3, c.i. vat brown 1, c.i. vat brown 33, c.i. vat brown 57, c.i. vat black 9, c.i. vat black 25, c.i. vat black 27, c.i. vat black 65. The soluble vat dye is selected from one or more of c.i. soluble vat orange 1, c.i. soluble vat orange 11, c.i. soluble vat red 1, c.i. soluble vat red 10, c.i. soluble vat violet 1, c.i. vat violet 13, c.i. soluble vat blue 4, c.i. soluble vat blue 5, c.i. soluble vat blue 6, c.i. soluble vat green 1, c.i. soluble vat green 3, c.i. soluble vat brown 1, c.i. soluble vat black 25.
Another embodiment of the present invention further provides a digital printing method for pure cotton infrared-proof fabric, comprising: sizing and presetting a semi-finished product, digitally printing, steaming, washing and finishing; the ink combination adopted in the digital printing step is six colors of infrared-proof digital printing reduction ink magenta, yellow, black, brown, green and blue, and the six color reduction ink is composed of non-soluble and soluble reduction dyes or a mixture thereof.
The sizing and pre-setting step of the semi-finished product adopts one step of dipping and one step of rolling, wherein the dipping solution comprises 20-25g/L of thickening agent, 1-2g/L of defoaming agent and 5-8g/L of sodium hexametaphosphate, the rolling residual rate is 65-70%, the setting temperature is 110-120 ℃, and the vehicle speed is 20-25 m/min. The above numerical ranges are preferred and those skilled in the art can adjust the color and pattern style as required.
The non-soluble vat dye in the ink composition used for digital printing is selected from one or more of c.i. vat yellow 46, c.i. vat orange 1, c.i. vat orange 11, c.i. vat red 1, c.i. vat red 10, c.i. vat red 13, c.i. vat red 15, c.i. vat violet 1, c.i. vat violet 13, c.i. vat blue 4, c.i. vat blue 5, c.i. vat blue 6, c.i. vat blue 66, c.i. vat blue 20, c.i. vat green 1, c.i. vat green 3, c.i. vat brown 1, c.i. vat brown 33, c.i. vat brown 57, c.i. vat black 9, c.i. vat black 25, c.i. vat black 27, c.i. vat black 65, and industrial vat black. The soluble vat dye is selected from one or more of c.i. soluble vat orange 1, c.i. soluble vat orange 11, c.i. soluble vat red 1, c.i. soluble vat red 10, c.i. soluble vat violet 1, c.i. vat violet 13, c.i. soluble vat blue 4, c.i. soluble vat blue 5, c.i. soluble vat blue 6, c.i. soluble vat green 1, c.i. soluble vat green 3, c.i. soluble vat brown 1, c.i. soluble vat black 25.
The digital printing step can be carried out by adopting any one of nozzles SG1024-XS, SA and MA of FUJIFILM company, and the printing mode can be one of 2pass, 3pass, 4pass, 5pass and 6 pass. RIP software neoStampa or ergsoft textile professional versions can be used for image color management.
The temperature of the steaming step is 130-135 ℃, and the steaming time is 20-24 seconds. In the water washing step, the soaping liquid contains 1.5-2g/L of anti-staining soaping agent, and the oxidizing liquid contains 1.8-2g/L of hydrogen peroxide. The post-finishing step adopts one step of dipping and one step of rolling, the dipping solution comprises 30-40g/L of softening agent, the rolling residual rate is 65-75%, the setting temperature is 110-120 ℃, and the vehicle speed is 20-25 m/min. The parameters in the above steps are preferred ranges, and can be adjusted by those skilled in the art according to actual needs.
Example 1
Selecting a pure cotton fabric, the warp and weft all adopt 10sCotton yarn, fabric warp density 70 pieces/inch, fabric weft density 42 pieces/inch, and width 57 inches.
The fabric is subjected to the working procedures of sizing and presetting of a semi-finished product, digital printing, steaming, washing and after-finishing.
The sizing and pre-shaping of the semi-finished product adopts one-dipping-one-rolling, the rolling residual rate is 70%, the process temperature is 120 ℃, and the vehicle speed is 20-25 m/min. The dipping solution in the rolling groove comprises 20g/L of thickening agent, 2g/L of defoaming agent and 5g/L of sodium hexametaphosphate.
Digital printing: the printing was carried out using the six-color red, yellow, blue, black, brown, green vat ink of yinjitai, celadon, and FUJIFILM corporation, jet SG 1024.
Conditions of the steaming step: the temperature is 130 ℃ and the time for steaming is 20 seconds.
The water washing adopts two cold-flow grids, two oxidation grids, two warm-water washing grids, four soaping grids, two warm-water washing grids, one cold-flow grid and finally drying. Wherein the soaping formula comprises 2g/L of anti-staining soaping agent. The oxidation formula comprises 2g/L of hydrogen peroxide.
And finally, performing after-finishing, namely performing one-time soaking and one-time rolling, wherein the rolling residual rate is 75%, the process temperature is 120 ℃, and the vehicle speed is 20-25 m/min. The impregnation liquid in the mangle comprises 30g/L of softening agent.
The ink combination and the digital printing method can jet ink according to needs by the software control spray head, the printed product has good consistency and stability, the plate making is not needed, the color gamut is wide, the non-color-limited printed pattern has high fineness, the pattern is bright and energy-saving, the ink consumption is accurate, no waste is caused, and the environment-friendly requirement is met. Because of the accurate amount of digital production and the ink jet control according to the requirement, the fabric produced by the screened ink not only reaches the infrared-proof standard, but also reaches the national superior product standards of light fastness, washing fastness, perspiration fastness and rubbing fastness.
Meanwhile, the fabric produced by the digital printing can present millions of color combinations, the natural colors can be simulated more vividly under visible light and infrared light, and compared with the traditional printing mode, the infrared-proof product produced by the digital printing thoroughly solves the limitation of color topping of the product.
The present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof, and it should be understood that various changes and modifications can be effected therein by one skilled in the art without departing from the spirit and scope of the invention as defined in the appended claims.
Claims (10)
1. The pure cotton infrared-proof fabric digital printing ink combination consists of six colors of infrared-proof digital printing reduction ink magenta, yellow, black, brown, green and blue, wherein the six colors of reduction ink consist of non-soluble and soluble reduction dyes or a mixture of the non-soluble and soluble reduction dyes.
2. The pure cotton infrared-resistant fabric digital printing ink set according to claim 1, wherein the non-soluble vat dye is selected from one or more of c.i. vat yellow 46, c.i. vat orange 1, c.i. vat orange 11, c.i. vat red 1, c.i. vat red 10, c.i. vat red 13, c.i. vat red 15, c.i. vat violet 1, c.i. vat violet 13, c.i. vat blue 4, c.i. vat blue 5, c.i. vat blue 6, c.i. vat blue 66, c.i. vat blue 20, c.i. vat green 1, c.i. vat green 3, c.i. vat brown 1, c.i. vat brown 33, c.i. vat brown 57, c.i. vat black 9, c.i. vat black 25, c.i. vat black 27, c.i. vat black 65; the soluble vat dye is selected from one or more of c.i. soluble vat orange 1, c.i. soluble vat orange 11, c.i. soluble vat red 1, c.i. soluble vat red 10, c.i. soluble vat violet 1, c.i. vat violet 13, c.i. soluble vat blue 4, c.i. soluble vat blue 5, c.i. soluble vat blue 6, c.i. soluble vat green 1, c.i. soluble vat green 3, c.i. soluble vat brown 1, c.i. soluble vat black 25.
3. A digital printing method for pure cotton infrared-proof fabric comprises the following steps: sizing and presetting a semi-finished product, digitally printing, steaming, washing and finishing;
the ink combination adopted in the digital printing step is six colors of reduction ink magenta, yellow, black, brown, green and blue for infrared prevention, and the reduction ink of the six colors consists of non-soluble and soluble reduction dyes or a mixture thereof.
4. The digital printing method for pure cotton infrared-resistant fabric according to claim 3, wherein the non-soluble vat dye is selected from one or more of c.i. vat yellow 46, c.i. vat orange 1, c.i. vat orange 11, c.i. vat red 1, c.i. vat red 10, c.i. vat red 13, c.i. vat red 15, c.i. vat violet 1, c.i. vat violet 13, c.i. vat blue 4, c.i. vat blue 5, c.i. vat blue 6, c.i. vat blue 66, c.i. vat blue 20, c.i. vat green 1, c.i. vat green 3, c.i. vat brown 1, c.i. vat brown 33, c.i. vat brown 57, c.i. vat black 9, c.i. vat black 25, c.i. vat black 27, c.i. vat black 65; the soluble vat dye is selected from one or more of c.i. soluble vat orange 1, c.i. soluble vat orange 11, c.i. soluble vat red 1, c.i. soluble vat red 10, c.i. soluble vat violet 1, c.i. vat violet 13, c.i. soluble vat blue 4, c.i. soluble vat blue 5, c.i. soluble vat blue 6, c.i. soluble vat green 1, c.i. soluble vat green 3, c.i. soluble vat brown 1, c.i. soluble vat black 25.
5. The digital printing method for the pure cotton infrared-proof fabric according to claim 4, wherein the digital printing step adopts any one of nozzles SG1024-XS, SA and MA of FUJIFILM company to print in one of a 2pass, a 3pass, a 4pass, a 5pass and a 6pass mode.
6. A digital printing method for purified cotton infrared-resistant fabrics according to claim 5, wherein said digital printing step uses RIP software neoStampa or ergsoft textile professional for image color management.
7. The digital printing method for the infrared-proof pure cotton fabric as claimed in claim 3, wherein the step of sizing and pre-shaping the semi-finished product adopts a dipping and a rolling step, the dipping solution comprises 20-25g/L of thickener, 1-2g/L of defoamer and 5-8g/L of sodium hexametaphosphate, the rolling residual rate is 65-70%, the shaping temperature is 110-120 ℃, and the speed is 20-25 m/min.
8. A digital printing method for pure cotton infrared-proof fabric as claimed in claim 3, wherein the temperature of the steaming step is 130-135 ℃ and the steaming time is 20-24 seconds.
9. The digital printing method for pure cotton infrared-proof fabrics of claim 3, wherein the soaping liquid in the washing step contains 1.5-2g/L of anti-staining soaping agent, and the oxidizing liquid contains 1.8-2g/L of hydrogen peroxide.
10. The digital printing method for pure cotton infrared-proof fabric as claimed in claim 3, wherein the post-finishing step adopts a dipping and a rolling, the dipping solution comprises 30-40g/L of softening agent, the rolling residual rate is 65-75%, the setting temperature is 110-120 ℃, and the speed is 20-25 m/min.
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CN107268305A (en) * | 2017-07-26 | 2017-10-20 | 青岛英杰泰新材料有限公司 | A kind of inkjet printing colouring agent based on reducing dye and preparation method thereof |
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Application publication date: 20200512 |
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