CN111056582A - Air heat dissipation cascade heat pump sea water desalination device of economic benefits and social benefits - Google Patents
Air heat dissipation cascade heat pump sea water desalination device of economic benefits and social benefits Download PDFInfo
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- CN111056582A CN111056582A CN202010018029.8A CN202010018029A CN111056582A CN 111056582 A CN111056582 A CN 111056582A CN 202010018029 A CN202010018029 A CN 202010018029A CN 111056582 A CN111056582 A CN 111056582A
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- 239000013535 sea water Substances 0.000 title claims abstract description 168
- 238000010612 desalination reaction Methods 0.000 title claims abstract description 61
- 230000017525 heat dissipation Effects 0.000 title claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 68
- 239000003507 refrigerant Substances 0.000 claims abstract description 35
- 239000013505 freshwater Substances 0.000 claims abstract description 25
- 239000002351 wastewater Substances 0.000 claims description 44
- 238000001816 cooling Methods 0.000 claims description 6
- 239000013589 supplement Substances 0.000 claims description 6
- 206010024796 Logorrhoea Diseases 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 abstract description 9
- 238000000034 method Methods 0.000 description 7
- 238000001704 evaporation Methods 0.000 description 4
- 230000008020 evaporation Effects 0.000 description 4
- 239000012528 membrane Substances 0.000 description 3
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 238000011033 desalting Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000007710 freezing Methods 0.000 description 2
- 230000008014 freezing Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/02—Treatment of water, waste water, or sewage by heating
- C02F1/04—Treatment of water, waste water, or sewage by heating by distillation or evaporation
- C02F1/16—Treatment of water, waste water, or sewage by heating by distillation or evaporation using waste heat from other processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
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- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Water, Waste Water Or Sewage (AREA)
Abstract
The invention belongs to the technical field of seawater desalination, and particularly relates to a double-effect air heat dissipation cascade type heat pump seawater desalination device, wherein a first refrigerant cycle comprises a first compressor, an evaporative condenser, a first throttle valve and an evaporator; the second refrigerant cycle comprises a second compressor, a condenser, a second throttle valve and an evaporative condenser; the first seawater desalination system comprises a first seawater tank, a first water pump and an evaporator, wherein seawater in the first seawater tank is pumped to the evaporator by the first water pump to form ice without salt; the second seawater desalination system comprises a second seawater tank, a second water pump, a condenser, a vacuum pump, a third heat exchanger and a fresh water tank, wherein seawater in the second seawater tank is pumped to the condenser by the second water pump to be heated and vaporized to form water vapor without salt; the invention adopts the cascade heat pump to prepare fresh water, and is suitable for seawater desalination in severe cold areas in winter; and the condenser is combined with the evaporator to jointly produce fresh water.
Description
Technical Field
The invention belongs to the technical field of seawater desalination, and particularly relates to a double-effect air heat dissipation cascade heat pump seawater desalination device.
Background
With the rapid increase of global population and the increase of per capita income level, the situation of shortage of global fresh water resources is gradually emerging. The global fresh water resources are not only in shortage but also extremely unbalanced in distribution, and north africa, middle east, arab peninsula and australia are extremely lack of fresh water resources. In the face of this situation, seawater desalination is one of the important approaches to solve the crisis problem of fresh water resources.
Sea water desalination, namely, sea water desalination is utilized to produce fresh water. At present, the mature seawater desalination technology comprises a thermal method and a membrane method, particularly the membrane method is commercialized in a large scale, and the thermal method mainly comprises multi-stage flash evaporation, multi-effect distillation and vapor compression distillation. However, the membrane method has high desalination cost, high technical requirements for the thermal method, no universality and difficult popularization. Therefore, a device with low desalination cost, low technical requirement, energy conservation and high efficiency is needed to solve the existing problems. Meanwhile, the common heat pump type seawater desalination device cannot be used under the condition of low outdoor temperature and is not suitable for seawater desalination in severe cold areas.
Disclosure of Invention
The invention aims to solve the problems and provides a double-effect air heat dissipation cascade heat pump seawater desalination device.
In order to achieve the technical purpose, the invention adopts the following technical scheme:
a double-effect air heat dissipation cascade heat pump seawater desalination device comprises a first refrigerant cycle and a second refrigerant cycle, wherein the first refrigerant cycle comprises a first compressor, an evaporative condenser, a first throttle valve and an evaporator; the second refrigerant cycle comprises a second compressor, a condenser, a second throttle valve and an evaporative condenser; the system also comprises a first seawater desalination system and a second seawater desalination system, wherein the first seawater desalination system comprises a first seawater tank, a first water pump and an evaporator; the first seawater tank is communicated with a seawater inlet of the evaporator through a first water pump; the first seawater tank is provided with a seawater supplement port, and the evaporator is provided with an ice discharge port and a wastewater outlet; the second seawater desalination system comprises a second seawater tank, a second water pump, a condenser, a vacuum pump, a third heat exchanger and a fresh water tank; the vacuum pump enables the second seawater desalination system to be in a vacuum state; the second seawater tank is communicated with a seawater inlet of the condenser through a second water pump, and a water vapor outlet of the condenser is communicated with the fresh water tank through the vacuum pump and the third heat exchanger in sequence; the second seawater tank is provided with a seawater supplement port, and the condenser is provided with a wastewater outlet.
Furthermore, the first seawater desalination system also comprises a first heat exchanger, and a wastewater outlet of the evaporator is communicated with an inlet of the first heat exchanger; the first heat exchanger is positioned in the first seawater tank, and a wastewater discharge pipe extending out of the first seawater tank is arranged at the outlet of the first heat exchanger.
Furthermore, the second seawater desalination system also comprises a second heat exchanger, and a waste water outlet of the condenser is communicated with an inlet of the second heat exchanger; the second heat exchanger is positioned in the second seawater tank, and a wastewater discharge pipe extending out of the second seawater tank is arranged at the outlet of the second heat exchanger.
Further, the third heat exchanger is a forced convection air-cooled fin heat exchanger.
Furthermore, the ice crushing device further comprises an ice crushing rod, wherein the ice crushing rod extends into the evaporator from the ice discharging port to crack ice, and crushed ice is discharged from the ice discharging port.
Compared with the prior art, the invention has the beneficial technical effects that:
(1) the invention adopts the cascade heat pump to evaporate and freeze the seawater to prepare fresh water, can be used under the condition of very low outdoor temperature, and is suitable for seawater desalination in severe cold areas in winter; two refrigerants in the cascade heat pump dual system circularly and synchronously run, so that the evaporation temperature of seawater can be increased, and the freezing temperature of the seawater can be reduced; by recovering the latent heat of condensation at the condenser side of the heat pump, the seawater is heated at the condenser side to form vapor without salt, so that the seawater desalination is completed; meanwhile, the cold energy at the evaporator side of the heat pump is utilized to freeze the seawater at the evaporator side to form ice without salt, thereby completing seawater desalination; the condenser is combined with the evaporator to jointly produce fresh water, thereby improving the speed of seawater desalination and saving the cost of seawater desalination.
(2) The waste water with low temperature and high concentration enters the first heat exchanger from the evaporator to exchange heat with the initial seawater in the first seawater tank, so that the temperature of the initial seawater is reduced, and the seawater entering the evaporator is easier to freeze.
(3) The high-concentration wastewater with higher temperature enters the second heat exchanger from the condenser to exchange heat with the initial seawater in the second seawater tank, so that the temperature of the initial seawater is increased, and the seawater enters the condenser to be evaporated more easily.
Drawings
Fig. 1 is a connection structure diagram of a double-effect air-cooling cascade heat pump seawater desalination device according to this embodiment.
In the figure: 1-a first compressor, 2-an evaporator, 3-a first heat exchanger, 4-a first seawater tank, 5-a first water pump, 6-a first throttle valve, 7-a second throttle valve, 8-a second water pump, 9-a second heat exchanger, 10-a second seawater tank, 11-a condenser, 12-a second compressor, 13-an evaporative condenser, 14-a third heat exchanger, 15-a vacuum pump and 16-a fresh water tank.
Detailed Description
The invention will be further described with reference to specific examples, but the scope of the invention is not limited thereto.
As shown in fig. 1, the double-effect air-cooling cascade heat pump seawater desalination apparatus of this embodiment includes a first refrigerant cycle, a second refrigerant cycle, a first seawater desalination system, and a second seawater desalination system. The first refrigerant cycle comprises a first compressor 1, an evaporative condenser 13, a first throttle valve 6 and an evaporator 2, wherein the first compressor 1, the evaporative condenser 13, the first throttle valve 6 and the evaporator 2 are sequentially connected into a closed loop through pipelines, the outlet of the first compressor 1 is connected with the first inlet of the evaporative condenser 13, the first outlet of the evaporative condenser 13 is connected with the inlet of the first throttle valve 6, the outlet of the first throttle valve 6 is connected with the refrigerant inlet of the evaporator 2, and the refrigerant outlet of the evaporator 2 is connected with the inlet of the first compressor 1, so that the low-temperature-level refrigerant cycle loop of the cascade heat pump is formed. The second refrigerant cycle comprises a second compressor 12, a condenser 11, a second throttle valve 7 and an evaporative condenser 13, the second compressor 12, the condenser 11, the second throttle valve 7 and the evaporative condenser 13 are sequentially connected into a closed loop through pipelines, wherein the outlet of the second compressor 12 is connected with the refrigerant inlet of the condenser 11, the refrigerant outlet of the condenser 11 is connected with the inlet of the second throttle valve 7, the outlet of the second throttle valve 7 is connected with the second inlet of the evaporative condenser 13, and the second outlet of the evaporative condenser 13 is connected with the inlet of the second compressor 12, so that the high-temperature-stage refrigerant cycle loop of the cascade heat pump is formed. The refrigerant in the first refrigerant cycle exchanges heat with the refrigerant in the second refrigerant cycle in the evaporative condenser 13.
The first seawater desalination system comprises a first seawater tank 4, a first water pump 5 and an evaporator 2. The first seawater tank 4 is communicated with the seawater inlet of the evaporator 2 through a first water pump 5. The first seawater tank 4 is provided with a seawater supplement port, and the evaporator 2 is provided with an ice discharge port and a wastewater outlet. Seawater in the first seawater tank 4 is sent to the evaporator 2 by the first water pump 5 to form ice without salt, the ice is discharged from an ice discharge port of the evaporator 2 after being crushed, and high-concentration wastewater is discharged from a wastewater outlet of the evaporator 2. The second seawater desalination system comprises a second seawater tank 10, a second water pump 8, a condenser 11, a vacuum pump 15, a third heat exchanger 14 and a fresh water tank 16. The vacuum pump 15 makes the second seawater desalination system in a vacuum state, the second seawater tank 10 is communicated with the seawater inlet of the condenser 11 through the second water pump 8, and the water vapor outlet of the condenser 11 is communicated with the fresh water tank 16 through the vacuum pump 15 and the third heat exchanger 14 in sequence. The second seawater tank 10 is provided with a seawater supplement port, and the condenser 11 is provided with a wastewater outlet. The seawater in the second seawater tank 10 is sent to the condenser 11 by the second water pump 8 to be heated and vaporized to form water vapor without salt, the water vapor enters the third heat exchanger 14 by the vacuum pump 15 to be condensed to form fresh water, then enters the fresh water tank 16, and the high-concentration wastewater is discharged from the wastewater outlet of the condenser 11.
In the evaporator 2, the refrigerant flows in the corresponding refrigerant pipeline, the seawater flows in the seawater channel outside the refrigerant pipeline, the refrigerant transfers cold energy to the seawater, so that the seawater is frozen on the inner wall of the seawater channel, the seawater channel is provided with an ice discharge port and a wastewater outlet, the ice is crushed and then is discharged through the ice discharge port, thereby obtaining fresh water, and the wastewater with high concentration is discharged from the wastewater outlet. In the condenser 11, the refrigerant flows in the corresponding refrigerant pipeline, the seawater flows in the corresponding seawater pipeline, and the heat released by the refrigerant is transferred to the seawater, so that the seawater is changed into vapor. The embodiment adopts the cascade heat pump to evaporate and freeze the seawater to prepare the fresh water, can be used under the condition of low outdoor temperature, and is suitable for seawater desalination in severe cold areas in winter. Two refrigerants in the cascade heat pump double-system are in synchronous operation in a circulating mode, the evaporation temperature of the seawater can be increased, and the freezing temperature of the seawater can be reduced. In the embodiment, the seawater is heated to form the vapor without salt at the condenser 11 side by recovering the latent heat of condensation at the condenser 11 side of the heat pump, so that the seawater desalination is completed; meanwhile, the cold energy at the side of the heat pump evaporator 2 is utilized to freeze the seawater at the side of the evaporator 2 to form ice without salt, thereby completing seawater desalination; the condenser 11 is combined with the evaporator 2 to produce fresh water together, thereby improving the speed of seawater desalination and saving the cost of seawater desalination.
In order to recover the cold energy of the wastewater in the first seawater desalination system, the first seawater desalination system also comprises a first heat exchanger 3, and a wastewater outlet of the evaporator 2 is communicated with an inlet of the first heat exchanger 3; the first heat exchanger 3 is positioned in the first seawater tank 4, and a wastewater discharge pipe extending out of the first seawater tank 4 is arranged at the outlet of the first heat exchanger 3. The waste water discharged from the waste water outlet of the evaporator 2 enters the first heat exchanger 3, and the waste water is discharged from the outlet pipeline of the first heat exchanger 3. The waste water with low temperature and high concentration enters the first heat exchanger 3 from the evaporator 2 to exchange heat with the initial seawater in the first seawater tank 4, so that the temperature of the initial seawater is reduced, and the seawater entering the evaporator 2 is easier to freeze. In order to recover the heat of the second seawater desalination system, the second seawater desalination system also comprises a second heat exchanger 9, and a waste water outlet of a condenser 11 is communicated with an inlet of the second heat exchanger 9; the second heat exchanger 9 is positioned in the second seawater tank 10, and a wastewater discharge pipe extending out of the second seawater tank 10 is arranged at the outlet of the second heat exchanger 9. The waste water discharged from the waste water outlet of the condenser 11 enters the second heat exchanger 9. The waste water is discharged from the outlet pipe of the second heat exchanger 9. The high-concentration waste water with higher temperature enters the second heat exchanger 9 from the condenser 11 to exchange heat with the initial seawater in the second seawater tank 10, so that the temperature of the initial seawater is raised, and the seawater enters the condenser 11 to be evaporated more easily.
In order to enhance the heat exchange effect of the third heat exchanger 14, the third heat exchanger 14 is a forced convection air-cooled fin heat exchanger, and the fin heat exchanger exchanges heat with air to dissipate the heat into the air. This embodiment is still including frustrating the ice pole, and it makes ice break in ice mouth stretches into evaporimeter 2 from row ice, and the garrulous ice is followed row ice mouth is discharged.
The process of desalinating seawater in this embodiment is as follows: on the first refrigerant circulation side, a first water pump 5 pumps seawater from a first seawater tank 4, the seawater enters an evaporator 2 through a pipeline, ice is formed in the evaporator 2 when the seawater meets cold, the ice is attached to the inner wall of a seawater channel in the evaporator, an ice crushing rod extends into the seawater channel of the evaporator 2 from an ice discharge port to crush the ice, and the crushed ice is discharged; meanwhile, high-concentration wastewater is discharged from a wastewater outlet of the evaporator 2 and enters the first heat exchanger 3 in the first seawater tank 4, and as the wastewater is cooled in the evaporator 2 and has a lower temperature, the wastewater exchanges heat with initial seawater in the first heat exchanger 3, so that the temperature of the seawater is reduced, and the seawater can be more easily frozen when entering the evaporator 2. On the second refrigerant cycle side, a second water pump 8 draws seawater from a second seawater tank 10, through a pipe into a condenser 11, the latent heat is utilized in the condenser 11 to evaporate the seawater, the principle that the condenser 11 obtains the fresh water is based on the principle that salt is almost insoluble in low-pressure water vapor, the vacuum pump 15 is used to keep the second seawater desalination system at a higher vacuum degree during the operation, then the seawater is heated by the condenser 11 to be evaporated and vaporized under high vacuum, the obtained water vapor enters the third heat exchanger 14 through a pipeline, after being condensed in the third heat exchanger 14, the waste water enters a fresh water tank 16, and simultaneously the waste water left after evaporation enters the second heat exchanger 9, since the waste water absorbs latent heat in the condenser 11 and has a high temperature, the waste water exchanges heat with the initial seawater in the second heat exchanger 9 to raise the temperature of the initial seawater, and the seawater is more easily evaporated in the condenser 11. The heat pump seawater desalination device does not operate intermittently to obtain fresh water. The embodiment can be used for desalting seawater and can also be used for desalting and extracting water in other solutions or sewage.
While the embodiments of the present invention have been described in detail, it will be apparent to those skilled in the art that variations may be made in the embodiments without departing from the spirit of the invention, and such variations are to be considered within the scope of the invention.
Claims (5)
1. A double-effect air heat dissipation cascade heat pump seawater desalination device is characterized in that:
the system comprises a first refrigerant cycle and a second refrigerant cycle, wherein the first refrigerant cycle comprises a first compressor, an evaporative condenser, a first throttling valve and an evaporator; the second refrigerant cycle comprises a second compressor, a condenser, a second throttle valve and an evaporative condenser;
the system also comprises a first seawater desalination system and a second seawater desalination system, wherein the first seawater desalination system comprises a first seawater tank, a first water pump and an evaporator; the first seawater tank is communicated with a seawater inlet of the evaporator through a first water pump; the first seawater tank is provided with a seawater supplement port, and the evaporator is provided with an ice discharge port and a wastewater outlet; the second seawater desalination system comprises a second seawater tank, a second water pump, a condenser, a vacuum pump, a third heat exchanger and a fresh water tank; the vacuum pump enables the second seawater desalination system to be in a vacuum state; the second seawater tank is communicated with a seawater inlet of the condenser through a second water pump, and a water vapor outlet of the condenser is communicated with the fresh water tank through the vacuum pump and the third heat exchanger in sequence; the second seawater tank is provided with a seawater supplement port, and the condenser is provided with a wastewater outlet.
2. The double-effect air-cooling cascade heat pump seawater desalination plant of claim 1, wherein: the first seawater desalination system also comprises a first heat exchanger, and a wastewater outlet of the evaporator is communicated with an inlet of the first heat exchanger; the first heat exchanger is positioned in the first seawater tank, and a wastewater discharge pipe extending out of the first seawater tank is arranged at the outlet of the first heat exchanger.
3. The double-effect air-cooling cascade heat pump seawater desalination plant of claim 1, wherein: the second seawater desalination system also comprises a second heat exchanger, and a condenser wastewater outlet is communicated with an inlet of the second heat exchanger; the second heat exchanger is positioned in the second seawater tank, and a wastewater discharge pipe extending out of the second seawater tank is arranged at the outlet of the second heat exchanger.
4. The double-effect air-cooling cascade heat pump seawater desalination plant of claim 1, wherein: the third heat exchanger is a forced convection air-cooled fin heat exchanger.
5. The double-effect air-cooling cascade heat pump seawater desalination plant of claim 1, wherein: still including frustrating the ice pole, frustrating the ice pole and stretch into in the evaporimeter from the ice discharge mouth and make ice break, garrulous ice is followed the ice discharge mouth is discharged.
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010018029.8A CN111056582A (en) | 2020-01-08 | 2020-01-08 | Air heat dissipation cascade heat pump sea water desalination device of economic benefits and social benefits |
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| Application Number | Priority Date | Filing Date | Title |
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| CN202010018029.8A CN111056582A (en) | 2020-01-08 | 2020-01-08 | Air heat dissipation cascade heat pump sea water desalination device of economic benefits and social benefits |
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| CN111056582A true CN111056582A (en) | 2020-04-24 |
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| CN202010018029.8A Pending CN111056582A (en) | 2020-01-08 | 2020-01-08 | Air heat dissipation cascade heat pump sea water desalination device of economic benefits and social benefits |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111777124A (en) * | 2020-06-18 | 2020-10-16 | 东南大学 | Photovoltaic direct-driven seawater evaporation refrigeration desalination system and desalination method |
| CN115028223A (en) * | 2022-08-10 | 2022-09-09 | 山东天瑞重工有限公司 | System for sea heat pump unites sea water desalination system operation |
| CN115594244A (en) * | 2022-10-17 | 2023-01-13 | 集美大学（Cn） | Floating type photovoltaic direct-drive refrigeration fresh water producing system |
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2020
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| CN102320674A (en) * | 2011-06-08 | 2012-01-18 | 集美大学 | Marine cold and heat cogeneration seawater desalting method and equipment |
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| CN111777124A (en) * | 2020-06-18 | 2020-10-16 | 东南大学 | Photovoltaic direct-driven seawater evaporation refrigeration desalination system and desalination method |
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| CN115594244A (en) * | 2022-10-17 | 2023-01-13 | 集美大学（Cn） | Floating type photovoltaic direct-drive refrigeration fresh water producing system |
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