CN111053729A - Transparent hair conditioner with hair and hair scale repairing effect - Google Patents
Transparent hair conditioner with hair and hair scale repairing effect Download PDFInfo
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- CN111053729A CN111053729A CN202010091682.7A CN202010091682A CN111053729A CN 111053729 A CN111053729 A CN 111053729A CN 202010091682 A CN202010091682 A CN 202010091682A CN 111053729 A CN111053729 A CN 111053729A
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- hair
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- 210000004209 hair Anatomy 0.000 title claims abstract description 105
- 230000000694 effects Effects 0.000 title abstract description 6
- 108010006161 conchiolin Proteins 0.000 claims abstract description 23
- VFKZECOCJCGZQK-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCO VFKZECOCJCGZQK-UHFFFAOYSA-M 0.000 claims abstract description 12
- 102000008186 Collagen Human genes 0.000 claims abstract description 12
- 108010035532 Collagen Proteins 0.000 claims abstract description 12
- 108010073771 Soybean Proteins Proteins 0.000 claims abstract description 12
- 229920001436 collagen Polymers 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 125000001453 quaternary ammonium group Chemical class 0.000 claims abstract description 12
- 235000019710 soybean protein Nutrition 0.000 claims abstract description 9
- -1 isoamyl glycol Chemical compound 0.000 claims description 44
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 18
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 239000004698 Polyethylene Substances 0.000 claims description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical class [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 11
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 11
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 11
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 11
- 229920000573 polyethylene Polymers 0.000 claims description 11
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 11
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- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 claims description 9
- 229940035437 1,3-propanediol Drugs 0.000 claims description 9
- 229940082500 cetostearyl alcohol Drugs 0.000 claims description 9
- 229920000166 polytrimethylene carbonate Polymers 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 9
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 claims description 9
- 235000018102 proteins Nutrition 0.000 claims description 8
- 102000004169 proteins and genes Human genes 0.000 claims description 8
- 108090000623 proteins and genes Proteins 0.000 claims description 8
- 239000006228 supernatant Substances 0.000 claims description 8
- 108091005804 Peptidases Proteins 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000012510 hollow fiber Substances 0.000 claims description 6
- 239000012528 membrane Substances 0.000 claims description 6
- 238000002791 soaking Methods 0.000 claims description 6
- 239000004365 Protease Substances 0.000 claims description 5
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 claims description 5
- 230000002255 enzymatic effect Effects 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 239000000413 hydrolysate Substances 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 230000001105 regulatory effect Effects 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 238000005119 centrifugation Methods 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- 230000007062 hydrolysis Effects 0.000 claims 1
- 238000006460 hydrolysis reaction Methods 0.000 claims 1
- 238000012360 testing method Methods 0.000 description 12
- 235000015097 nutrients Nutrition 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 5
- 230000003648 hair appearance Effects 0.000 description 5
- 230000008569 process Effects 0.000 description 4
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- 230000003779 hair growth Effects 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000008439 repair process Effects 0.000 description 3
- 229940001941 soy protein Drugs 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- 229940081733 cetearyl alcohol Drugs 0.000 description 2
- 238000000635 electron micrograph Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 210000003780 hair follicle Anatomy 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 210000003491 skin Anatomy 0.000 description 2
- 210000001519 tissue Anatomy 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- XPFCZYUVICHKDS-UHFFFAOYSA-N 3-methylbutane-1,3-diol Chemical compound CC(C)(O)CCO XPFCZYUVICHKDS-UHFFFAOYSA-N 0.000 description 1
- 201000004384 Alopecia Diseases 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
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- 239000002253 acid Substances 0.000 description 1
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- 231100000360 alopecia Toxicity 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 210000001736 capillary Anatomy 0.000 description 1
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- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
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- 210000002808 connective tissue Anatomy 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
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- 210000002510 keratinocyte Anatomy 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 210000001640 nerve ending Anatomy 0.000 description 1
- 230000035790 physiological processes and functions Effects 0.000 description 1
- 229920001184 polypeptide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 102000004196 processed proteins & peptides Human genes 0.000 description 1
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- 230000009467 reduction Effects 0.000 description 1
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- 210000001732 sebaceous gland Anatomy 0.000 description 1
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- 239000002453 shampoo Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/98—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin
- A61K8/987—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution of animal origin of species other than mammals or birds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/645—Proteins of vegetable origin; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Zoology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses a transparent hair conditioner with the effect of repairing hair scales, wherein the formula of the hair conditioner contains a hair care composition with the mass percentage of 1.3-8%, and the hair care composition contains the following components in parts by mass: 1-5 parts of hydrolyzed conchiolin, 0.1-1 part of stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen, 0.1-1 part of quaternary ammonium salt-79 hydrolyzed silk and 0.1-1 part of hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein.
Description
Technical Field
The invention relates to the field of cosmetics, and in particular relates to a transparent hair conditioner with an effect of repairing hair scales.
Background
The hair is the accessory fiber tissue of the human body, is an important component of the human body, has the physiological functions of keeping warm in winter, preventing the head from being exposed to strong sunlight and the like, and can beautify the personal image.
The hair grows in the hair follicle, the hair follicle tissue is divided into hair papilla, hair bulb and sebaceous gland, and capillaries, nerve endings, connective tissue and the like grow in the hair papilla, so that the hair growth nutrient solution provides nutrients for the hair growth and plays an important role in the hair growth.
The part of the hair in the follicle is called the root and the exposed part is called the shaft, which is divided from the inside to the outside into the medulla, cortex and the cortex. The fur cuticle is the outermost layer of hair, and is formed by stacking 6 to 10 layers of non-nuclear squamous keratinocyte in an imbricate shape. The hair scales are the outermost tissues for protecting hair, the smoothness of the hair scales determines the luster and the combing property of the hair, and the hair scales arranged flatly are relatively glossy, because when light irradiates the hair from one direction, if the hair scales are relatively regular, the reflection of the light is relatively large, and the generated diffuse reflection is relatively small, so that the glossiness of the hair is higher. When the fur skin is affected by the outside, the fur scales are warped or damaged to be uneven and even stripped seriously, so that the outer surface of the hair is uneven, the light irradiates the damaged hair, and the surface of the hair is dull after the light is diffused and reflected. The damaged scales can cause the hair to be easily wound and knotted and difficult to comb.
The conventional hair conditioner is used after hair washing, and no matter the conventional hair conditioner is a rinse-off hair conditioner or a leave-on hair conditioner, the conventional hair conditioner does not contain obvious cleaning ingredients, so the conventional hair conditioner can be effectively spread on the surface of hair in the using process and cannot be washed away by water, the raised hair scales on the surface of the hair can be smoothed, and meanwhile, the negative charge strength on the surface of the hair is reduced, so that the surface of the hair is smooth and soft. However, it is a palliative type product, and when the conditioner attached to the skin is gradually consumed over time, the hair returns to a dull, dull state, which is easily tangled and knotted.
Disclosure of Invention
The invention aims to provide a transparent hair conditioner with the effect of repairing hair scales, which can provide nutrients for the growth of hair, moisten and repair the hair scales, enable the hair to become glossy, smooth and elegant and obviously improve the hair quality.
The specific technical scheme of the invention is as follows:
a transparent hair conditioner contains a hair care composition with the mass percentage of 1.3-8%, and the hair care composition contains the following components in parts by mass: 1-5 parts of hydrolyzed conchiolin, 0.1-1 part of stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen, 0.1-1 part of quaternary ammonium salt-79 hydrolyzed silk and 0.1-1 part of hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein.
Preferably, the hair care composition comprises the following components in parts by mass: hydrolyzed conchiolin 3 parts, stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen 0.5 part, quaternary ammonium salt-79 hydrolyzed silk 0.5 part, and hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein 0.5 part.
Further, the formula of the transparent hair conditioner also comprises the following components in percentage by mass:
10-30% of isoamyl glycol
10-30% of 1, 3-propylene glycol
Cetostearyl alcohol 1-3%
1-5% of aminopropyl polydimethylsiloxane
Polyethylene glycol-90M 0.1-0.5%
Stearyl PG-dimethylamine 0.1-1%
Polyquaternary ammonium salt-610.1-1%
The balance of water.
Further, preferably, the formula of the transparent hair conditioner also comprises the following components in percentage by mass:
20 percent of isoamyl glycol
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternary ammonium salt-610.5%
The balance of water.
The embodiment of the invention also provides a preparation method of the hydrolyzed conchiolin, which comprises the following steps:
(1) crushing shells, adding 2mol/L potassium hydroxide aqueous solution, and soaking under stirring to obtain a soaked substance;
(2) regulating the pH value of the soaked substance to 7.0, adding protease accounting for 1-2% of the mass of the raw materials for enzymolysis to obtain an enzymolysis liquid;
(3) centrifuging the enzymatic hydrolysate to obtain supernatant, and filtering the supernatant with hollow fiber membrane to obtain hydrolyzed conchiolin.
In some of the examples, the amount of the aqueous solution of potassium hydroxide added in step (1) is 1 to 5 times the weight of the shell; the soaking time is 1-5 hours.
In some of these embodiments, the proteolytic enzyme conditions in step (2) are at 40 ℃ for 1-2 hours.
In some of these embodiments, the centrifugation conditions in step (3) are centrifugation at 2000rpm for 20 minutes; the specification of the hollow fiber membrane is protein with the molecular weight cutoff of more than 50 KD.
The technical scheme provided by the embodiment of the invention has the following beneficial effects:
the formula of the transparent hair conditioner contains a certain amount of hydrolyzed conchiolin, stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen, quaternary ammonium salt-79 hydrolyzed silk, hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein and other components, and can provide nutrients for the growth of hair, moisten and repair hair scales, enable the hair to become glossy, smooth and elegant, and obviously improve the hair quality.
Drawings
FIG. 1 Hair combing force test;
FIG. 2 shows electron micrographs before testing;
fig. 3 electron micrograph of hair after testing.
Detailed Description
The embodiments in the description are only for illustrating the present invention and do not limit the scope of the present invention. The scope of the present invention is defined only by the appended claims, and any omissions, substitutions, or modifications made based on the embodiments disclosed herein will fall within the scope of the present invention.
The disclosure may be understood more readily by reference to the following detailed description of preferred embodiments of the invention and the examples included therein. Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. In case of conflict, the present specification, including definitions, will control.
The term "prepared from …" as used herein is synonymous with "comprising". The terms "comprises," "comprising," "includes," "including," "has," "having," "contains," "containing," or any other variation thereof, as used herein, are intended to cover a non-exclusive inclusion. For example, a composition, process, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but may include other elements not expressly listed or inherent to such composition, process, method, article, or apparatus.
When an amount, concentration, or other value or parameter is expressed as a range, preferred range, or as a range of upper preferable values and lower preferable values, this is to be understood as specifically disclosing all ranges formed from any pair of any upper range limit or preferred value and any lower range limit or preferred value, regardless of whether ranges are separately disclosed. For example, when a range of "1 to 5" is disclosed, the described range should be interpreted to include the ranges "1 to 4", "1 to 3", "1 to 2 and 4 to 5", "1 to 3 and 5", and the like. When a range of values is described herein, unless otherwise stated, the range is intended to include the endpoints thereof and all integers and fractions within the range.
In addition, the indefinite articles "a" and "an" preceding an element or component of the invention are not intended to limit the number requirement (i.e., the number of occurrences) of the element or component. Thus, "a" or "an" should be read to include one or at least one, and the singular form of an element or component also includes the plural unless the stated number clearly indicates that the singular form is intended.
For the purpose of enhancing understanding of the present invention, the present invention will be further described in detail with reference to the following examples, which are provided for illustration only and are not to be construed as limiting the scope of the present invention.
The transparent hair conditioner disclosed by the invention contains a hair care composition with the mass percentage of 1.3-8% in the formula of the hair conditioner, and the hair care composition contains the following components in parts by mass: 1-5 parts of hydrolyzed conchiolin, 0.1-1 part of stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen, 0.1-1 part of quaternary ammonium salt-79 hydrolyzed silk and 0.1-1 part of hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein.
In particular, conchiolin is a unique hard protein in a class of aquatic products that often tightly binds with calcium in the shell to form a glossy nacre layer. The hydrolyzed conchiolin is rich in amino acids, polypeptide and other nutrients.
The three cationized natural active substances of the stearyldimethylammonium hydroxypropyl hydrolyzed collagen, the quaternary ammonium salt-79 hydrolyzed silk and the hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein are combined with the hydrolyzed conchiolin, can provide nutrients for the growth of hair, moisten and repair hair scales, enable the hair to become glossy, smooth and elegant, and obviously improve the hair quality.
Example 1
A method for preparing hydrolyzed conchiolin comprises the following steps:
(1) crushing shells, adding 2mol/L potassium hydroxide aqueous solution which is 1 time of the weight of the shells, and soaking for 5 hours under stirring to obtain a soaked substance;
(2) regulating the pH value of the soaked substance to 7.0, adding protease accounting for 1% of the mass of the raw material, and acting at 40 ℃ for 2 hours to obtain enzymatic hydrolysate;
(3) centrifuging the enzymolysis solution at 2000rpm for 20 min to obtain supernatant, and filtering the supernatant with hollow fiber membrane with protein with molecular weight cutoff of 50KD or more to obtain filtrate, i.e. hydrolyzed conchiolin.
Example 2
A method for preparing hydrolyzed conchiolin comprises the following steps:
(1) crushing shells, adding 2mol/L potassium hydroxide aqueous solution which is 5 times of the weight of the shells, and soaking for 1 hour under stirring to obtain a soaked substance;
(2) regulating the pH value of the soaked substance to 7.0, adding protease accounting for 2% of the mass of the raw material, and acting at 40 ℃ for 1 hour to obtain enzymatic hydrolysate;
(3) centrifuging the enzymolysis solution at 2000rpm for 20 min to obtain supernatant, and filtering the supernatant with hollow fiber membrane with protein with molecular weight cutoff of 50KD or more to obtain filtrate, i.e. hydrolyzed conchiolin.
Example 3
The hydrolyzed conchiolin obtained in example 1-2 was subjected to protein content measurement using KjelMaster K-375 (full-automatic Kjeldahl apparatus).
The mechanism is as follows: the protein is organic compound, the organic compound sample containing protein, concentrated sulfuric acid and catalyst are placed into a test tube to be heated and digested together, the protein can be decomposed, decomposed ammonium ions and sulfate ions are combined to generate ammonium sulfate, then ammonia gas is dissociated under the action of alkaline distillation, and the dissociated ammonia gas and water vapor are cooled together through a condenser tube and then enter a titration cup filled with boric acid. After being absorbed by boric acid, the protein content is obtained by titrating hydrochloric acid titration solution with known concentration and then multiplying the conversion coefficient according to the consumption of acid.
The specific test results are shown in table 1.
TABLE 1 protein content Table
Example 4
A transparent hair conditioner comprises the following components in percentage by mass:
10 percent of isoamyl glycol
1, 3-propanediol 30%
Cetearyl alcohol 1%
Aminopropyl polydimethylsiloxane 5%
Polyethylene glycol-90M 0.1%
Stearyl PG-dimethylamine 1%
Polyquaternary ammonium salt-610.1%
Hydrolyzed conchiolin 5% obtained in example 1
Stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen 0.1%
Quaternary ammonium salt-79 hydrolyzed silk 1%
0.1 percent of soybean protein hydrolyzed by hydroxypropyl trimethyl ammonium chloride
The balance of water.
Example 5
A transparent hair conditioner comprises the following components in percentage by mass:
1, 3-propanediol 10%
Cetearyl alcohol 3%
1 percent of aminopropyl polydimethylsiloxane
Polyethylene glycol-90M 0.5%
Stearyl PG-dimethylamine 0.1%
Polyquaternary ammonium salt-611%
Hydrolyzed conchiolin 1% obtained in example 2
Stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen 1%
0.1 percent of quaternary ammonium salt-79 hydrolyzed silk
Hydroxypropyl trimethyl ammonium chloride hydrolyzed soy protein 1%
The balance of water.
Example 6
A transparent hair conditioner comprises the following components in percentage by mass:
20 percent of isoamyl glycol
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternary ammonium salt-610.5%
Hydrolyzed conchiolin 3% obtained in example 2
Stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen 0.5%
0.5 percent of quaternary ammonium salt-79 hydrolyzed silk
Hydroxypropyl trimethyl ammonium chloride hydrolyzed soy protein 0.5%
The balance of water.
Comparative example 1
A transparent hair conditioner comprises the following components in percentage by mass:
20 percent of isoamyl glycol
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternary ammonium salt-610.5%
Hydrolyzed conchiolin 3% obtained in example 2
The balance of water.
Comparative example 2
A transparent hair conditioner comprises the following components in percentage by mass:
20 percent of isoamyl glycol
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternary ammonium salt-610.5%
Stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen 0.5%
The balance of water.
Comparative example 3
A transparent hair conditioner comprises the following components in percentage by mass:
20 percent of isoamyl glycol
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternary ammonium salt-610.5%
0.5 percent of quaternary ammonium salt-79 hydrolyzed silk
The balance of water.
Comparative example 4
A transparent hair conditioner comprises the following components in percentage by mass:
20 percent of isoamyl glycol
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternary ammonium salt-610.5%
Hydroxypropyl trimethyl ammonium chloride hydrolyzed soy protein 0.5%
The balance of water.
Example 7
The transparent conditioners obtained in examples 4 to 6 and comparative examples 1 to 4 were subjected to a combing property test.
The method is carried out by reference documents (Liu Pao, Wan Yue Peng, Selenxia Selenarctica. establishment and evaluation of a novel moisturizing and repairing shampoo system [ J ]. Guangzhou chemical industry, 2010,38(05): 176-:
(1) measuring the dry comb combing force of the blank hair bundle (F1);
(2) the instrument (S-2 combing force tester, TECHNO HASHIMOTO, Co) automatically flushes the hair bundle and measures the wet combing force of the blank hair bundle (F2);
(3) treating the hair bundle twice by taking 0.1g of hair conditioner to be tested, and testing the wet combing force of the hair bundle (F3);
(4) drying, measuring the combing force of the dry comb of the hair bundle (F4);
(5) each of the continuously stabilized 9 combing forces was averaged and the ratio of the friction before and after the comparison was made.
Wet combing force lifting degree% = (F2-F3)/F2X 100%
Dry combing force lifting degree% = (F1-F4)/F1 × 100%
The combing performance of the hair is judged by measuring the resistance and the change condition of the resistance in the process of combing the hair by the mechanical comb under the dry state and the wet state of the hair. More reduction in friction indicates a higher degree of lift, indicating better conditioning. The specific test results are shown in fig. 1.
The test results in FIG. 1 show that examples 4-6 have no significant difference in wet and dry combing performance, and are significantly better than control groups 1-4.
Example 8
Consumer sensory evaluation was performed on the clear conditioner prepared in example 6.
The specific test method is as follows: 10 volunteers with long hair and damaged hair quality used the conditioner once every two days for 2 months. After the test is finished, the volunteers are asked to use the test, the problems of dull feedback and easy winding and knotting are obviously improved, the phenomena of alopecia and hair breakage are reduced, and the hair quality is soft, bright and glossy.
Sampling is carried out on volunteers before and after the test, the condition of hair scales on the surface of hair is visually observed by using a scanning electron microscope, and the condition that the hair scales before and after the product is used are obviously changed, and the hair scales are turned up or damaged to be uneven and become orderly arranged, and the specific effects are shown in figures 2 and 3.
The technical features of the above embodiments can be arbitrarily combined, and for the sake of brevity, all possible combinations of the technical features in the above embodiments are not described, but should be considered as the scope of the present specification as long as there is no contradiction between the combinations of the technical features.
The above examples only show some embodiments of the present invention, and the description thereof is more specific and detailed, but not construed as limiting the scope of the invention. It should be noted that, for a person skilled in the art, several variations and modifications can be made without departing from the inventive concept, which falls within the scope of the present invention. Therefore, the protection scope of the present patent shall be subject to the appended claims.
Claims (8)
1. The transparent hair conditioner is characterized in that the hair conditioner formula contains a hair care composition with the mass percentage of 1.3-8%, and the hair care composition contains the following components in parts by mass: 1-5 parts of hydrolyzed conchiolin, 0.1-1 part of stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen, 0.1-1 part of quaternary ammonium salt-79 hydrolyzed silk and 0.1-1 part of hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein.
2. The transparent hair conditioner according to claim 1, wherein the hair care composition comprises the following components in parts by mass: hydrolyzed conchiolin 3 parts, stearyl dimethyl ammonium hydroxypropyl hydrolyzed collagen 0.5 part, quaternary ammonium salt-79 hydrolyzed silk 0.5 part, and hydroxypropyl trimethyl ammonium chloride hydrolyzed soybean protein 0.5 part.
3. The transparent hair conditioner according to claim 1 or 2, wherein the transparent hair conditioner formula further comprises the following components in percentage by mass:
10-30% of isoamyl glycol
10-30% of 1, 3-propylene glycol
Cetostearyl alcohol 1-3%
1-5% of aminopropyl polydimethylsiloxane
Polyethylene glycol-90M 0.1-0.5%
Stearyl PG-dimethylamine 0.1-1%
Polyquaternary ammonium salt-610.1-1%
The balance of water.
4. The transparent hair conditioner according to claim 3, wherein the transparent hair conditioner formula further comprises the following components in percentage by mass:
20 percent of isoamyl glycol
1, 3-propanediol 20%
Cetostearyl alcohol 2%
Aminopropyl polydimethylsiloxane 3%
Polyethylene glycol-90M 0.3%
Stearyl PG-dimethylamine 0.5%
Polyquaternary ammonium salt-610.5%
The balance of water.
5. The clear hair conditioner according to claim 1 or 2, wherein the method for preparing hydrolyzed conchiolin comprises the steps of:
(1) crushing shells, adding 2mol/L potassium hydroxide aqueous solution, and soaking under stirring to obtain a soaked substance;
(2) regulating the pH value of the soaked substance to 7.0, adding protease accounting for 1-2% of the mass of the raw materials for enzymolysis to obtain an enzymolysis liquid;
(3) centrifuging the enzymatic hydrolysate to obtain supernatant, and filtering the supernatant with hollow fiber membrane to obtain hydrolyzed conchiolin.
6. The transparent hair conditioner according to claim 5, wherein the amount of the aqueous solution of potassium hydroxide added in step (1) is 1 to 5 times the weight of the shell; the soaking time is 1-5 hours.
7. The clear hair conditioner according to claim 1, wherein the protease hydrolysis condition in step (2) is 1-2 hours at 40 ℃.
8. The clear hair conditioner according to claim 1, wherein the centrifugation in step (3) is carried out at 2000rpm for 20 minutes; the specification of the hollow fiber membrane is protein with the molecular weight cutoff of more than 50 KD.
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103442683A (en) * | 2011-03-25 | 2013-12-11 | 汉高股份有限及两合公司 | Process for producing a conditioning cleaning agent |
| CN108066237A (en) * | 2017-12-29 | 2018-05-25 | 无限极（中国）有限公司 | It is a kind of that there are whitening, the composition of light spot effect and its application, skin care item |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103442683A (en) * | 2011-03-25 | 2013-12-11 | 汉高股份有限及两合公司 | Process for producing a conditioning cleaning agent |
| CN108066237A (en) * | 2017-12-29 | 2018-05-25 | 无限极（中国）有限公司 | It is a kind of that there are whitening, the composition of light spot effect and its application, skin care item |
Non-Patent Citations (1)
| Title |
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| 蔻丝魅株式会社: "安姬蜜奢华修复滋养护发素", 国家药品监督管理局数据查询 * |
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