CN111032841A - 粉末状洗衣清洁剂调配物 - Google Patents
粉末状洗衣清洁剂调配物 Download PDFInfo
- Publication number
- CN111032841A CN111032841A CN201880055705.XA CN201880055705A CN111032841A CN 111032841 A CN111032841 A CN 111032841A CN 201880055705 A CN201880055705 A CN 201880055705A CN 111032841 A CN111032841 A CN 111032841A
- Authority
- CN
- China
- Prior art keywords
- laundry detergent
- weight
- powdered laundry
- powdered
- average molecular
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 91
- 239000000203 mixture Substances 0.000 title claims abstract description 73
- 238000009472 formulation Methods 0.000 title claims abstract description 61
- 239000004094 surface-active agent Substances 0.000 claims abstract description 20
- 229920002125 Sokalan® Polymers 0.000 claims abstract description 9
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 7
- 239000004744 fabric Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 11
- -1 Polyethylene Polymers 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 10
- 238000004140 cleaning Methods 0.000 claims description 8
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 5
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000008237 rinsing water Substances 0.000 claims description 3
- 229940077388 benzenesulfonate Drugs 0.000 claims description 2
- 239000006260 foam Substances 0.000 description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 8
- 239000003945 anionic surfactant Substances 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000007844 bleaching agent Substances 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000010457 zeolite Substances 0.000 description 4
- 102000004190 Enzymes Human genes 0.000 description 3
- 108090000790 Enzymes Proteins 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 3
- 239000012190 activator Substances 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 3
- 229940088598 enzyme Drugs 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 238000005227 gel permeation chromatography Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000000377 silicon dioxide Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000019832 sodium triphosphate Nutrition 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000012512 characterization method Methods 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000001542 size-exclusion chromatography Methods 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000012085 test solution Substances 0.000 description 2
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 2
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 235000010254 Jasminum officinale Nutrition 0.000 description 1
- 240000005385 Jasminum sambac Species 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 229940048820 edetates Drugs 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 239000006081 fluorescent whitening agent Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical class OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 1
- 229960001922 sodium perborate Drugs 0.000 description 1
- 229940045872 sodium percarbonate Drugs 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0094—High foaming compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3761—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D2111/00—Cleaning compositions characterised by the objects to be cleaned; Cleaning compositions characterised by non-standard cleaning or washing processes
- C11D2111/10—Objects to be cleaned
- C11D2111/12—Soft surfaces, e.g. textile
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
- Accessory Of Washing/Drying Machine, Commercial Washing/Drying Machine, Other Washing/Drying Machine (AREA)
Abstract
提供一种粉末状洗衣清洁剂调配物,其具有清洁剂表面活性剂;助洗剂;重量平均分子量Mw为750,000道尔顿到10,000,000道尔顿的聚氧化乙烯;和重量平均分子量Mw为1,000到20,000的聚(丙烯酸)。
Description
技术领域
本发明涉及一种粉末状洗衣清洁剂调配物。具体来说,本发明涉及一种粉末状洗衣清洁剂调配物,其具有清洁剂表面活性剂;助洗剂;重量平均分子量MW为750,000道尔顿到10,000,000道尔顿的聚氧化乙烯;和重量平均分子量MW为1,000到20,000的聚(丙烯酸)。
背景技术
尽管越来越多人使用自动洗衣机,但手洗织物在许多地区仍很普遍。因此,一直需要含有表面活性剂的经过改进的粉末状洗衣调配物。
使用粉末状洗衣调配物手洗织物的消费者通常将泡沫形成视为给定调配物清洗效力的主要指标。因此,消费者将高泡沫体积视为理想的。然而,将较多的表面活性剂添加到清洁剂是很昂贵的,只能改进泡沫形成和稳定性。
Mort等人的美国专利申请公开第20140366271号中公开一种提高洗衣清洁剂调配物的泡沫性能的方法。Mort等人公开一种粒状清洁剂组合物,按所述组合物的总重量计,其包含1%到99%的结构化粒子,所述结构化粒子包含:(1)按结构化粒子的总重量计,35%到80%的阴离子表面活性剂;和2)按结构化粒子的总重量计,8%到50%的亲水性二氧化硅,其中所述结构化粒子以粒度分布Dw50在250pm到1000um范围内并且容积密度在500到1000g/L范围内为特征,其中所述阴离子表面活性剂是平均乙氧基化程度在0.1到5.0范围内的C10-20直链或分支链烷基乙氧基硫酸酯或其盐,其中所述亲水性二氧化硅按二氧化硅的总重量计包含不到10%的残余盐,并且在水合作用后能够形成膨胀的二氧化硅粒子,并且其中所述膨胀的二氧化硅粒子的粒度分布Dv50为1pm到100pm。
因此,一直需要在洗涤期间能够产生较多泡沫,但不增加调配物中表面活性剂的量的粉末状洗衣调配物。
发明内容
本发明提供一种粉末状洗衣清洁剂调配物,其包含:5到50重量%的清洁剂表面活性剂;25到80重量%的助洗剂;和0.01到1重量%的重量平均分子量MW为750,000道尔顿到10,000,000道尔顿的聚氧化乙烯;0.01到5重量%的重量平均分子量MW为1,000到20,000的聚(丙烯酸)。
本发明提供一种清洗织物的方法,其包含:提供织物;提供洗涤水;提供漂洗水;提供本发明的粉末状洗衣清洁剂;混合粉末状洗衣清洁剂和洗涤水,形成洗衣液;用洗衣液处理织物;并且用漂洗水漂洗织物。
具体实施方式
我们现已发现,包括重量平均分子量MW为750,000到10,000,000道尔顿的聚氧化乙烯与重量平均分子量MW为1,000到20,000道尔顿的聚(丙烯酸)的掺合物的粉末状洗衣清洁剂调配物已改进发泡体积和稳定性。
除非另外指示,否则比例、百分比、份数和其类似物皆按重量计。
如本文所用,除非另外指示,否则短语「分子量"或Mw是指如以常规方式用凝胶渗透色谱法(GPC)和聚(氧化乙烯)标准品所测量的重量平均分子量。GPC技术详细论述于中《现代尺寸排阻色谱法(Modem Size Exclusion Chromatography)》,W.W.Yau,J.J.Kirkland,D.D.Bly;Wiley-lnterscience,1979中和《材料特征和化学分析的引导(AGuide to Materials Characterization and Chemical Analysis)》,J.P.Sibilia;VCH,1988,第81-84页中。分子量在本文中以道尔顿为单位进行报导。
除非另外规定,否则本文所述的操作在室温(20-25℃)下进行。
优选地,本发明的粉末状洗衣清洁剂调配物包含:5到50重量%(优选地,7.5到30重量%;更优选地,10到25重量%;最优选地,14到20重量%)的清洁剂表面活性剂;25到80重量%(优选地,30到75重量%;更优选地,35到70;最优选地,40到65重量%)的助洗剂;0.01到1重量%(优选地,≥0.05重量%;更优选地,≥0.07重量%;再更优选地,≥0.09重量%;优选地,≤0.8重量%;更优选地,≤0.6重量%;最优选地,≤0.5重量%)的重量平均分子量MW为750,000道尔顿到10,000,000(优选地,≥1,000,000;更优选地,≥2,000,000;再更优选地,≥4,000,000;优选地,≤8,000,000;更优选地,≤7,000,000;最优选地,≤6,000,000)的聚氧化乙烯;和0.01到5重量%(优选地,≥0.1重量%;更优选地,≥0.5重量%;再更优选地;≥0.75重量%;优选地,≤4重量%;更优选地,≤3重量%;再更优选地,≤2重量%;最优选地,≤1.5重量%)的重量平均分子量MW为1,000到20,000(优选地,≥1,500;更优选地,≥2,500;再更优选地,≥3,000;优选地,≤15,000;更优选地,≤10,000;再更优选地,≤7,000;最优选地,≤6,000)的聚(丙烯酸)。
优选地,本发明的粉末状洗衣清洁剂调配物包含5到50重量%的清洁剂表面活性剂。更优选地,本发明的粉末状洗衣清洁剂调配物包含7.5到30重量%的清洁剂表面活性剂。再更优选地,本发明的粉末状洗衣清洁剂调配物包含10到25重量%的清洁剂表面活性剂。最优选地,本发明的粉末状洗衣清洁剂调配物包含14到20重量%的清洁剂表面活性剂。
优选地,本发明的粉末状洗衣清洁剂调配物包含≥5重量%(优选地,≥7.5重量%;更优选地,≥10重量%;最优选地,≥14重量%)的清洁剂表面活性剂。
优选地,本发明的粉末状洗衣清洁剂调配物包含≤50重量%(优选地,≤30重量%;更优选地,≤25重量%;最优选地,≤20重量%)的清洁剂表面活性剂。
优选地,用于本发明的粉末状洗衣清洁剂调配物的清洁剂表面活性剂选自由以下组成的群组:阴离子表面活性剂、非离子表面活性剂、两性离子表面活性剂、两性表面活性剂、阳离子表面活性剂和其混合物。更优选地,用于本发明的粉末状洗衣清洁剂调配物的清洁剂表面活性剂包括选自由烷基苯磺酸盐、醇硫酸盐、醇乙氧基化物组成的群组的表面活性剂。最优选地,用于本发明的粉末状洗衣清洁剂调配物的清洁剂表面活性剂包括阴离子表面活性剂。优选地,阴离子表面活性剂选自由烷基苯磺酸盐、脂肪醇醚硫酸盐和其混合物组成的群组。优选地,阴离子表面活性剂包括烷基苯磺酸盐。更优选地,阴离子表面活性剂包括直链烷基苯磺酸盐。最优选地,阴离子表面活性剂包括直链C10-20烷基苯磺酸盐。
优选地,本发明的粉末状洗衣清洁剂调配物包含25到80重量%的助洗剂。更优选地,本发明的粉末状洗衣清洁剂调配物包含30到75重量%的助洗剂。再更优选地,本发明的粉末状洗衣清洁剂调配物包含35到70重量%的助洗剂。最优选地,本发明的粉末状洗衣清洁剂调配物包含40到65重量%的助洗剂。
优选地,本发明的粉末状洗衣清洁剂调配物包含≥25重量%(优选地,≥30重量%;更优选地,≥35重量%;最优选地,≥40重量%)的助洗剂。
优选地,本发明的粉末状洗衣清洁剂调配物包含≤80重量%(优选地,≤75重量%;更优选地,≤70重量%;最优选地,≤65重量%)的助洗剂。
优选地,用于本发明的粉末状洗衣清洁剂调配物的助洗剂选自常规用作粉末状洗衣清洁剂中的助洗剂的有机材料和无机材料。优选地,用于本发明的粉末状洗衣清洁剂调配物的助洗剂选自由以下组成的群组:可水合的碱金属磷酸盐、碱金属碳酸盐(包括碳酸盐和碳酸氢盐)、沸石、乙二胺四乙酸盐、氮基三乙酸盐和其混合物。更优选地,用于本发明的粉末状洗衣清洁剂调配物的助洗剂包括以下中的至少一种:沸石、三磷酸钠、三聚磷酸钠、柠檬酸钠、硅酸钠、碳酸钠、碳酸钙、碳酸氢钠和碳酸氢钙。最优选地,用于本发明的粉末状洗衣清洁剂调配物的助洗剂包括沸石、三聚磷酸钠、碳酸钠和碳酸钙中的至少一种。
优选地,本发明的粉末状洗衣清洁剂调配物包含0.01到1重量%的重量平均分子量MW为750,000道尔顿到10,000,000(优选地,≥1,000,000;更优选地,≥2,000,000;再更优选地,≥4,000,000;优选地,≤8,000,000;更优选地,≤7,000,000;最优选地,≤6,000,000)的聚氧化乙烯。
优选地,本发明的粉末状洗衣清洁剂调配物包含≥0.01重量%(优选地,≥0.05重量%;更优选地,≥0.07重量%;最优选地,≥0.09重量%)的重量平均分子量MW为750,000道尔顿到10,000,000(优选地,≥1,000,000;更优选地,≥2,000,000;再更优选地,≥4,000,000;优选地,≤8,000,000;更优选地,≤7,000,000;最优选地,≤6,000,000)的聚氧化乙烯。
优选地,本发明的粉末状洗衣清洁剂调配物包含≤1重量%(优选地,≤0.8重量%;更优选地,≤0.6重量%;最优选地,≤0.5重量%)的聚氧化乙烯。
优选地,用于本发明的粉末状洗衣清洁剂调配物的聚氧化乙烯的重量平均分子量MW≥750,000(优选地,≥1,000,000;更优选地,≥2,000,000;再更优选地,≥4,000,000)道尔顿。
优选地,用于本发明的粉末状洗衣清洁剂调配物的聚氧化乙烯的重量平均分子量MW≤10,000,000(优选地,≤8,000,000;更优选地,≤7,000,000;最优选地,≤6,000,000)道尔顿。
优选地,本发明的粉末状洗衣清洁剂调配物包含0.01到5重量%的重量平均分子量MW为1,000到20,000(优选地,≥1,500;更优选地,≥2,500;再更优选地,≥3,000;优选地,≤15,000;更优选地,≤10,000;再更优选地,≤7,000;最优选地,≤6,000)的聚(丙烯酸)。
优选地,本发明的粉末状洗衣清洁剂调配物包含≥0.01重量%(优选地,≥0.1重量%;更优选地,≥0.5重量%;最优选地,≥0.75重量%)的重量平均分子量MW为1,000到20,000(优选地,≥1,500;更优选地,≥2,500;再更优选地,≥3,000;优选地,≤15,000;更优选地,≤10,000;再更优选地,≤7,000;最优选地,≤6,000)的聚(丙烯酸)。
优选地,本发明的粉末状洗衣清洁剂调配物包含≤5重量%(优选地,≤4重量%;更优选地,≤3重量%;再更优选地,≤2重量%;最优选地,≤1.5重量%)的重量平均分子量MW为1,000到20,000(优选地,≥1,500;更优选地,≥2,500;再更优选地,≥3,000;优选地,≤15,000;更优选地,≤10,000;再更优选地,≤7,000;最优选地,≤6,000)的聚(丙烯酸)。
优选地,用于本发明的粉末状洗衣清洁剂调配物的聚(丙烯酸)的重量平均分子量MW≥1,000(优选地,≥1,500;更优选地,≥2,500;最优选地,≥3,000)道尔顿。
优选地,用于本发明的粉末状洗衣清洁剂调配物的聚(丙烯酸)的重量平均分子量MW≤20,000(优选地,≤15,000;≤10,000;再更优选地,≤7,000;最优选地,≤6,000)道尔顿。
优选地,本发明的粉末状洗衣清洁剂调配物进一步包含一或多种选自由以下组成的群组的任选地存在的成分:漂白剂、漂白活化剂、抗再沉积剂、稳定剂、发泡调节剂、酶、光学增亮剂、填充剂、加工助剂和芳香剂。
优选地,本发明的粉末状洗衣清洁剂调配物进一步包含0到10重量%的漂白剂。优选漂白剂包括例如过硼酸钠和过碳酸钠。
优选地,本发明的粉末状洗衣清洁剂调配物进一步包含0到10重量%的漂白活化剂。优选漂白活化剂包括例如四乙酰基乙二胺(TAED)和壬酰氧基苯磺酸钠(NOBS)。
优选地,本发明的粉末状洗衣清洁剂调配物进一步包含0到2重量%的抗再沉积剂。优选抗再沉积剂包括例如羧甲基纤维素和纤维素醚。
优选地,本发明的粉末状洗衣清洁剂调配物进一步包含0到1重量%的稳定剂。优选稳定剂包括例如膦酸盐。
优选地,本发明的粉末状洗衣清洁剂调配物进一步包含0到2重量%的酶。优选酶包括例如蛋白酶、纤维素酶、淀粉酶和脂肪酶。
优选地,本发明的粉末状洗衣清洁剂调配物进一步包含0到0.3重量%的光学增亮剂。优选光学增亮剂包括例如荧光增白剂。
优选地,本发明的粉末状洗衣清洁剂调配物进一步包含0到50重量%(优选地,5到40重量%;更优选地,10到35重量%;20到35重量%)的填充剂。优选填充剂包括例如硫酸钠和氯化钠。
优选地,本发明的粉末状洗衣清洁剂调配物可由熟知制造方法产生。举例来说,本发明的粉末状清洁剂调配物可使用包括喷雾干燥所述组分的各种组合的技术产生。
优选地,本发明的清洗织物的方法包含:提供织物;提供洗涤水;提供漂洗水;提供本发明的粉末状洗衣清洁剂;混合粉末状洗衣清洁剂和洗涤水,形成洗衣液;用洗衣液处理织物;和用漂洗水漂洗织物。
优选地,在本发明的清洗织物的方法中,通过使用熟知手洗技术,用洗衣液处理织物。优选地,将粉末状洗衣清洁剂与洗涤水以1:100到1:1,000的粉末状洗衣清洁剂与洗涤水的重量比混合。
本发明的一些实施例现将详细描述于以下实例中。
表1:基本清洁剂组合物
表1
<u>成分</u> | <u>(重量%)</u> |
直链烷基苯磺酸盐 | 14-20 |
三聚磷酸钠 | 7-10 |
轻质苏打(碳酸钠) | 25-35 |
增白剂<sup>1</sup> | 0.07 |
斑点-苏打-橙色 | 0.5 |
斑点-苏打-超船舶涂布 | 0.5 |
沸石 | 7-10 |
硫酸钠 | 5-10 |
香料玫瑰和茉莉 | 0.6 |
Folcal U-Ppt.碳酸钙 | 2-8 |
白云石 | 2-6 |
NaCl | 其余 |
比较实例C1-C4和实例1-2:洗衣清洁剂组合物
粉末状洗衣清洁剂调配物在比较实例C1-C4和实例1-2中的每一者中制备,所述调配物具有阐述于表2中的组合物。
表2
清洁剂测试
发泡测试方案:
○制备含有0.3重量%的洗衣清洁剂组合物水溶液的测试溶液
○将50mL的测试溶液转移到带有盖子的250mL有刻度的玻璃筒
○在发泡测量装置中将筒以30rpm以360度旋转摇动30秒,随后将筒放置于平坦表面上
○等待30秒直到水层分离
○一旦校平发泡水平,将筒倒置
○立刻测量筒中的发泡高度(以mm为单位)-此在时间=0分钟时为初始发泡体积
○在t=5分钟、10分钟、15分钟和20分钟时再次测量发泡高度
针对比较实例C1-C4和实例1-2,洗衣清洁剂组合物的发泡测试方案的结果在表3中报导。
表3
Claims (10)
1.一种粉末状洗衣清洁剂调配物,其包含:
5到50重量%的清洁剂表面活性剂;
25到80重量%的助洗剂;
0.01到1重量%的重量平均分子量MW为750,000道尔顿到10,000,000道尔顿的聚氧化乙烯;和
0.01到5重量%的重量平均分子量MW为1,000到20,000的聚(丙烯酸)。
2.根据权利要求1所述的粉末状洗衣清洁剂调配物,其含有0.05到0.5重量%的重量平均分子量MW为2,000,000到8,000,000道尔顿的所述聚氧化乙烯。
3.根据权利要求2所述的粉末状洗衣清洁剂调配物,其含有0.05到0.5重量%的重量平均分子量MW为4,000,000到6,000,000的所述聚氧化乙烯。
4.根据权利要求1所述的粉末状洗衣清洁剂调配物,其含有0.1到4重量%的重量平均分子量MW为2,500到6,000的所述聚(丙烯酸)。
5.根据权利要求4所述的粉末状洗衣清洁剂调配物,其含有0.1到4重量%的重量平均分子量MW为2,500到6,000的所述聚(丙烯酸)。
6.根据权利要求5所述的粉末状洗衣清洁剂调配物,其中所述清洁剂表面活性剂为直链烷基苯磺酸盐。
7.根据权利要求6所述的粉末状洗衣清洁剂调配物,其中所述清洁剂表面活性剂为直链C10-20烷基苯磺酸盐。
8.一种清洗织物的方法,其包含:
提供织物;
提供洗涤水;
提供漂洗水;
提供根据权利要求1所述的粉末状洗衣清洁剂;
混合所述粉末状洗衣清洁剂和所述洗涤水,形成洗衣液;
用所述洗衣液处理所述织物;和
用所述漂洗水漂洗所述织物。
9.根据权利要求8所述的清洗织物的方法,其中所述织物是用所述洗衣液通过手洗处理。
10.根据权利要求9所述的方法,其中将所述粉末状洗衣清洁剂与所述洗涤水以1:100到1:1,000的重量比混合。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IN201741031240 | 2017-09-04 | ||
IN201741031240 | 2017-09-04 | ||
PCT/US2018/045475 WO2019045958A1 (en) | 2017-09-04 | 2018-08-07 | DETERGENT FORMULATION OF LAUNDRY POWDER |
Publications (1)
Publication Number | Publication Date |
---|---|
CN111032841A true CN111032841A (zh) | 2020-04-17 |
Family
ID=63364194
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201880055705.XA Pending CN111032841A (zh) | 2017-09-04 | 2018-08-07 | 粉末状洗衣清洁剂调配物 |
Country Status (9)
Country | Link |
---|---|
US (1) | US20200231905A1 (zh) |
EP (1) | EP3679116B1 (zh) |
JP (1) | JP7314120B2 (zh) |
CN (1) | CN111032841A (zh) |
BR (1) | BR112020003997A2 (zh) |
ES (1) | ES2970681T3 (zh) |
MX (1) | MX2020002202A (zh) |
TW (1) | TW201930579A (zh) |
WO (1) | WO2019045958A1 (zh) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20220275308A1 (en) * | 2019-10-08 | 2022-09-01 | Dow Silicones Corporation | Aqueous liquid hand dishwashing detergent formulation |
EP4242287A1 (en) * | 2022-03-07 | 2023-09-13 | Henkel AG & Co. KGaA | Laundry detergent |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0299575A1 (en) * | 1987-07-14 | 1989-01-18 | The Procter & Gamble Company | Detergent compositions |
WO1997036975A1 (en) * | 1996-03-29 | 1997-10-09 | The Procter & Gamble Company | Detergent composition comprising acrylic acid-based polymer and amino tricarboxylic acid-based compound |
CN1319129A (zh) * | 1998-09-21 | 2001-10-24 | 宝洁公司 | 用于洗衣用洗涤粉的助洗剂附聚物 |
CN101198308A (zh) * | 2005-06-13 | 2008-06-11 | 3M创新有限公司 | 可起泡的醇组合物、体系和使用方法 |
CN103468444A (zh) * | 2013-09-06 | 2013-12-25 | 广州立白企业集团有限公司 | 一种洗衣皂粉组合物 |
CN105324477A (zh) * | 2013-06-13 | 2016-02-10 | 宝洁公司 | 颗粒状衣物洗涤剂 |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3380307D1 (en) * | 1982-12-23 | 1989-09-07 | Procter & Gamble | Ethoxylated amine polymers having clay soil removal/anti-redeposition properties useful in detergent compositions |
US5405413A (en) * | 1993-06-24 | 1995-04-11 | The Procter & Gamble Co. | Bleaching compounds comprising acyl valerolactam bleach activators |
AUPN502195A0 (en) * | 1995-08-25 | 1995-09-14 | Procter & Gamble Company, The | Detergent composition with bleach system stabilized by enzymes |
US6165970A (en) * | 1996-03-29 | 2000-12-26 | The Procter & Gamble Company | Detergent composition comprising acrylic acid-based polymer and amino tricarboxylic acid-based compound |
US5863887A (en) * | 1997-12-01 | 1999-01-26 | Precision Fabrics Group, Inc. | Laundry compositions having antistatic and fabric softening properties, and laundry detergent sheets containing the same |
AU5444100A (en) * | 1999-05-26 | 2000-12-12 | Procter & Gamble Company, The | Detergent compostitions comprising polymeric suds enhancers which have improved mildness and skin feel |
GB0124308D0 (en) * | 2001-10-10 | 2001-11-28 | Unilever Plc | Detergent compositions |
US7057023B2 (en) * | 2002-01-11 | 2006-06-06 | Nexia Biotechnologies Inc. | Methods and apparatus for spinning spider silk protein |
JP4424618B2 (ja) * | 2004-02-13 | 2010-03-03 | 花王株式会社 | 洗剤組成物 |
JP2006199969A (ja) * | 2004-02-13 | 2006-08-03 | Kao Corp | 洗濯方法 |
EP1767613A1 (en) * | 2005-09-23 | 2007-03-28 | Takasago International Corporation | Process for the manufacture of a spray dried powder |
CN102844419B (zh) * | 2010-04-16 | 2015-02-04 | 狮王株式会社 | 洗涤剂组合物 |
US9828569B2 (en) * | 2013-06-13 | 2017-11-28 | The Procter & Gamble Company | Granular laundry detergent |
US9375343B2 (en) | 2013-06-18 | 2016-06-28 | Covidien Lp | Patient positioning system |
JP6219246B2 (ja) * | 2014-04-23 | 2017-10-25 | 花王株式会社 | 衣料用粉末洗剤組成物 |
MY182371A (en) * | 2014-09-17 | 2021-01-21 | Lion Corp | Powder detergent for clothing |
CN104558637B (zh) * | 2015-01-28 | 2017-11-21 | 上海化工研究院有限公司 | 一种提高高分子量聚环氧乙烷溶解速度的方法 |
EP3301169A1 (en) * | 2016-10-03 | 2018-04-04 | The Procter & Gamble Company | Laundry detergent composition |
-
2018
- 2018-08-07 ES ES18759497T patent/ES2970681T3/es active Active
- 2018-08-07 WO PCT/US2018/045475 patent/WO2019045958A1/en unknown
- 2018-08-07 MX MX2020002202A patent/MX2020002202A/es unknown
- 2018-08-07 BR BR112020003997-7A patent/BR112020003997A2/pt not_active Application Discontinuation
- 2018-08-07 EP EP18759497.3A patent/EP3679116B1/en active Active
- 2018-08-07 US US16/639,141 patent/US20200231905A1/en active Pending
- 2018-08-07 JP JP2020511893A patent/JP7314120B2/ja active Active
- 2018-08-07 CN CN201880055705.XA patent/CN111032841A/zh active Pending
- 2018-08-15 TW TW107128425A patent/TW201930579A/zh unknown
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0299575A1 (en) * | 1987-07-14 | 1989-01-18 | The Procter & Gamble Company | Detergent compositions |
WO1997036975A1 (en) * | 1996-03-29 | 1997-10-09 | The Procter & Gamble Company | Detergent composition comprising acrylic acid-based polymer and amino tricarboxylic acid-based compound |
CN1319129A (zh) * | 1998-09-21 | 2001-10-24 | 宝洁公司 | 用于洗衣用洗涤粉的助洗剂附聚物 |
CN101198308A (zh) * | 2005-06-13 | 2008-06-11 | 3M创新有限公司 | 可起泡的醇组合物、体系和使用方法 |
CN105324477A (zh) * | 2013-06-13 | 2016-02-10 | 宝洁公司 | 颗粒状衣物洗涤剂 |
CN103468444A (zh) * | 2013-09-06 | 2013-12-25 | 广州立白企业集团有限公司 | 一种洗衣皂粉组合物 |
Also Published As
Publication number | Publication date |
---|---|
TW201930579A (zh) | 2019-08-01 |
EP3679116A1 (en) | 2020-07-15 |
MX2020002202A (es) | 2020-07-20 |
ES2970681T3 (es) | 2024-05-30 |
JP2020532611A (ja) | 2020-11-12 |
WO2019045958A1 (en) | 2019-03-07 |
BR112020003997A2 (pt) | 2020-09-01 |
JP7314120B2 (ja) | 2023-07-25 |
US20200231905A1 (en) | 2020-07-23 |
EP3679116B1 (en) | 2023-12-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CA2573996C (en) | A highly water-soluble solid laundry detergent composition that forms a clear wash liquor upon dissolution in water | |
CA1120821A (en) | Method of preparing a dry blended laundry detergent containing coarse granular particles | |
US8129323B2 (en) | Solid laundry detergent composition comprising alkyl benzene sulphonate, carbonate salt and carboxylate polymer | |
JP6219246B2 (ja) | 衣料用粉末洗剤組成物 | |
WO2014103690A1 (ja) | 衣料用粉末洗剤組成物 | |
US20070161539A1 (en) | Method of regulating degree of polymerization of an alkali metal silicate in solution using pH | |
WO2015143644A1 (en) | Cleaning compositions containing cationic polymers, and methods of making and using same | |
JP2009504836A (ja) | アルキルベンゼンスルホネートおよび水和性物質を含む固体洗濯洗浄組成物 | |
CN111032841A (zh) | 粉末状洗衣清洁剂调配物 | |
CN112839630A (zh) | 包含泡沫促进硅酮的清洁组合物 | |
JP5432345B2 (ja) | 衣料用粉末洗剤組成物及びその製造方法 | |
JP5250714B2 (ja) | 衣料用粉末洗剤組成物 | |
JP5250715B2 (ja) | 衣料用粉末洗剤組成物 | |
JPS601918B2 (ja) | 再汚染の少ない無燐洗剤組成物 | |
JPH0234699A (ja) | 液体洗剤組成物 | |
US3832309A (en) | Detergent formulations | |
JP5876023B2 (ja) | 衣料用粉末洗剤組成物 | |
JP4163058B2 (ja) | 漂白剤含有洗浄剤組成物 | |
JP2002060789A (ja) | 洗剤組成物 | |
WO2019075684A1 (en) | CLEANING COMPOSITIONS CONTAINING FATTY ACID MIXTURE | |
WO2000034430A1 (en) | Detergent bar composition | |
MXPA06009553A (en) | Laundry detergent composition comprising an anionic detersive surfactant sulphamic acid and/water soluble salts thereof | |
RO112514B1 (ro) | Detergent granulat, cu spumare redusa |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination |