CN110997129A - 用于静电除尘器的吸附剂组合物 - Google Patents

用于静电除尘器的吸附剂组合物 Download PDF

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Publication number
CN110997129A
CN110997129A CN201880049441.7A CN201880049441A CN110997129A CN 110997129 A CN110997129 A CN 110997129A CN 201880049441 A CN201880049441 A CN 201880049441A CN 110997129 A CN110997129 A CN 110997129A
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Prior art keywords
calcium
sorbent composition
powdered
metal ion
flue gas
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CN201880049441.7A
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English (en)
Chinese (zh)
Inventor
罗德尼·傅
格雷戈里·马丁·菲利佩利
约翰·海斯沃尔夫
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Lhoist Recherche et Developpement SA
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Lhoist Recherche et Developpement SA
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Priority claimed from US15/657,294 external-priority patent/US10898876B2/en
Application filed by Lhoist Recherche et Developpement SA filed Critical Lhoist Recherche et Developpement SA
Publication of CN110997129A publication Critical patent/CN110997129A/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/043—Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/48—Sulfur compounds
    • B01D53/50—Sulfur oxides
    • B01D53/508—Sulfur oxides by treating the gases with solids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81—Solid phase processes
    • B01D53/83—Solid phase processes with moving reactants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0225—Compounds of Fe, Ru, Os, Co, Rh, Ir, Ni, Pd, Pt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0233—Compounds of Cu, Ag, Au
    • B01J20/0237—Compounds of Cu
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0296—Nitrates of compounds other than those provided for in B01J20/04
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/041—Oxides or hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28059—Surface area, e.g. B.E.T specific surface area being less than 100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28071—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
    • B03C3/00—Separating dispersed particles from gases or vapour, e.g. air, by electrostatic effect
    • B03C3/01—Pretreatment of the gases prior to electrostatic precipitation
    • B03C3/013—Conditioning by chemical additives, e.g. with SO3
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/402—Alkaline earth metal or magnesium compounds of magnesium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/40—Alkaline earth metal or magnesium compounds
    • B01D2251/404—Alkaline earth metal or magnesium compounds of calcium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/604—Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/60—Inorganic bases or salts
    • B01D2251/606—Carbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/102—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/11—Clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/112—Metals or metal compounds not provided for in B01D2253/104 or B01D2253/106
    • B01D2253/1122—Metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2258/00—Sources of waste gases
    • B01D2258/02—Other waste gases
    • B01D2258/0283—Flue gases
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2220/00—Aspects relating to sorbent materials
    • B01J2220/40—Aspects relating to the composition of sorbent or filter aid materials
    • B01J2220/42—Materials comprising a mixture of inorganic materials
CN201880049441.7A 2017-07-24 2018-07-24 用于静电除尘器的吸附剂组合物 Pending CN110997129A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP2017068625 2017-07-24
US15/657,294 2017-07-24
US15/657,294 US10898876B2 (en) 2017-07-24 2017-07-24 Sorbent composition for an electrostatic precipitator
EPPCT/EP2017/068625 2017-07-24
PCT/EP2018/070012 WO2019020613A1 (en) 2017-07-24 2018-07-24 SORBENT COMPOSITION FOR ELECTROSTATIC PRECIPITATOR

Publications (1)

Publication Number Publication Date
CN110997129A true CN110997129A (zh) 2020-04-10

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ID=62916705

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CN201880049441.7A Pending CN110997129A (zh) 2017-07-24 2018-07-24 用于静电除尘器的吸附剂组合物

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EP (1) EP3658275A1 (es)
JP (1) JP2020528004A (es)
KR (1) KR20200035038A (es)
CN (1) CN110997129A (es)
BE (1) BE1025964B1 (es)
BR (1) BR112020001082A2 (es)
CA (1) CA3070255A1 (es)
CL (1) CL2020000143A1 (es)
CO (1) CO2020000463A2 (es)
SG (1) SG11202000483QA (es)
WO (1) WO2019020613A1 (es)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5234877A (en) * 1990-07-16 1993-08-10 Board Of Trustees Operating Michigan State University Composite clay materials for removal of SOx from gas streams
US5298473A (en) * 1990-07-16 1994-03-29 Board Of Trustees Operating Michigan State University Hydrated lime clay composites for the removal of SOx from flue gas streams
US5334564A (en) * 1990-07-16 1994-08-02 Board Of Trustees Operating Michigan State University Method for the preparation of highly reactive clay composites for the removal of SOx from flue gas streams
WO2005028083A1 (ja) * 2003-09-18 2005-03-31 Japan Science And Technology Agency 乾式脱硫プロセス用新規脱硫剤
CN101370735A (zh) * 2005-06-28 2009-02-18 勒瓦研究开发股份有限公司 粉末状石灰组合物，其生产方法及其用途
US20150110698A1 (en) * 2012-03-30 2015-04-23 Fuel Tech, Inc. Process for Sulfur Dioxide, Hydrochloric Acid and Mercury Mediation
US20160151760A1 (en) * 2013-07-18 2016-06-02 Novinda Corporation Carbonate Modified Compositions for Reduction of Flue Gas Resistivity
CN106413857A (zh) * 2014-06-04 2017-02-15 索尔维公司 使用水溶性硅酸盐源和含有钙和/或镁的材料稳定包含在含钠粉煤灰中的至少一种重金属

Family Cites Families (12)

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Publication number Priority date Publication date Assignee Title
US4439351A (en) 1982-07-06 1984-03-27 Calgon Corporation Use of anionic or cationic polymers to lower the electrical resistivity of fly ash
US4502872A (en) 1983-03-31 1985-03-05 Combustion Engineering, Inc. Discharge electrode wire assembly for electrostatic precipitator
DE3620024A1 (de) 1986-06-13 1987-12-17 Fels Werke Peine Salzgitter Verfahren zur herstellung von feinkoernigem calciumhydroxid
US5223239A (en) 1990-07-24 1993-06-29 Research Corporation Technologies, Inc. Method of preparing hydrated lime
US5173279A (en) 1990-11-21 1992-12-22 Lhoist Recherche Et Developpement S.A. Method and composition for treating flue or exhaust gases utilizing modified calcium hydroxide
US5705141A (en) 1990-11-21 1998-01-06 Lhoist Researche Et Developpement S.A. Calcium and/or magnesium hydroxide, and preparation and use thereof
BE1009692A3 (fr) 1995-10-19 1997-07-01 Lhoist Rech & Dev Sa PARTICULES DE Ca(OH)2.
US6126910A (en) 1997-10-14 2000-10-03 Wilhelm; James H. Method for removing acid gases from flue gas
US6797035B2 (en) * 2002-08-30 2004-09-28 Ada Environmental Solutions, Llc Oxidizing additives for control of particulate emissions
US6803025B2 (en) 2002-12-05 2004-10-12 Frank B. Meserole Process for removing SO3/H2SO4 from flue gases
DK1967276T3 (da) 2007-03-05 2019-08-12 General Electric Technology Gmbh En fremgangsmåde til at bestemme støvbelastningen af et elektrostatisk filter og en fremgangsmåde og en indretning til at styre bankningen af et elektrostatisk filter
WO2015119880A1 (en) 2014-02-04 2015-08-13 Novinda Corporation Flue-gas treatment aid

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5234877A (en) * 1990-07-16 1993-08-10 Board Of Trustees Operating Michigan State University Composite clay materials for removal of SOx from gas streams
US5298473A (en) * 1990-07-16 1994-03-29 Board Of Trustees Operating Michigan State University Hydrated lime clay composites for the removal of SOx from flue gas streams
US5334564A (en) * 1990-07-16 1994-08-02 Board Of Trustees Operating Michigan State University Method for the preparation of highly reactive clay composites for the removal of SOx from flue gas streams
WO2005028083A1 (ja) * 2003-09-18 2005-03-31 Japan Science And Technology Agency 乾式脱硫プロセス用新規脱硫剤
CN101370735A (zh) * 2005-06-28 2009-02-18 勒瓦研究开发股份有限公司 粉末状石灰组合物，其生产方法及其用途
CN103626216A (zh) * 2005-06-28 2014-03-12 勒瓦研究开发股份有限公司 粉末状石灰组合物，其生产方法及其用途
US20150110698A1 (en) * 2012-03-30 2015-04-23 Fuel Tech, Inc. Process for Sulfur Dioxide, Hydrochloric Acid and Mercury Mediation
US20160151760A1 (en) * 2013-07-18 2016-06-02 Novinda Corporation Carbonate Modified Compositions for Reduction of Flue Gas Resistivity
CN106413857A (zh) * 2014-06-04 2017-02-15 索尔维公司 使用水溶性硅酸盐源和含有钙和/或镁的材料稳定包含在含钠粉煤灰中的至少一种重金属

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Publication number Publication date
BE1025964A1 (fr) 2019-08-23
BR112020001082A2 (pt) 2020-07-21
EP3658275A1 (en) 2020-06-03
CO2020000463A2 (es) 2020-05-05
SG11202000483QA (en) 2020-02-27
CA3070255A1 (en) 2019-01-31
KR20200035038A (ko) 2020-04-01
BE1025964B1 (fr) 2019-08-28
JP2020528004A (ja) 2020-09-17
CL2020000143A1 (es) 2020-05-29
WO2019020613A1 (en) 2019-01-31

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