CN110960433A - Composition containing strip crystals and application thereof - Google Patents
Composition containing strip crystals and application thereof Download PDFInfo
- Publication number
- CN110960433A CN110960433A CN201911098059.8A CN201911098059A CN110960433A CN 110960433 A CN110960433 A CN 110960433A CN 201911098059 A CN201911098059 A CN 201911098059A CN 110960433 A CN110960433 A CN 110960433A
- Authority
- CN
- China
- Prior art keywords
- composition containing
- ethylene glycol
- elongated crystals
- anionic surfactant
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
- A61K8/375—Esters of carboxylic acids the alcohol moiety containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
Abstract
The invention belongs to the field of daily chemicals. The composition containing the long-strip crystals comprises the following components in percentage by weight: 14-37% of anionic surfactant, 4-10% of crystalline ethylene glycol dialkyl acid ester compound, 4-10% of polyalcohol compound, 0.1-2% of cationic guar gum derivative and the balance of water. The composition has the capability of efficiently and directionally forming long-strip crystals, so that the composition has good stability, suspension capability and higher melting point, and the problem of suspension capability reduction caused by high-temperature damage to the structure and external force shearing can be effectively avoided. The composition can be used as a silicone oil suspending agent to be applied to a system containing silicone oil, is simple and convenient to use, and can be pre-produced and stored for a long time.
Description
Technical Field
The invention belongs to the field of daily chemicals, and relates to a composition containing long-strip crystals and application thereof.
Background
The polydimethylsiloxane has methyl-encapsulated and soft Si-O bonds in the skeleton, the attractive force among polydimethylsiloxane molecules is weak dispersion force, and the properties enable the silicone oil to have extremely low surface energy, spreadability and lubricity, so the polysiloxane is an excellent hair conditioner and can spread a smooth hydrophobic film on hair when being spread on the hair, and the glossiness and the softness of the hair are increased. However, how highly hydrophobic polydimethylsiloxane maintains its proper dispersion and suspension in the product, and product stability are currently the biggest challenges. In order to suspend the silicone oil particles added to the product, it is necessary to suspend by adding a suspending agent such as xanthan gum, carbomer-based compounds, and the like.
The carbomer compound suspension system for increasing the yield value is the most widely used suspension system at present, and although the formed reticular cross-linked structure enables the yield value of the whole system to be improved and has a suspension effect, the carbomer is poor in ion resistance, the shelf period of the product collapses along with the change of the ion concentration of the system, so that the product is unstable in layering and the like, the main component of the shampoo is an anionic surfactant, and a large amount of ionic surfactant in the system can shield the carbomer suspension agent, so that the carbomer suspension agent is difficult to unfold into a net shape and loses the suspension effect. In addition, the applicant finds through experiments that the carbomer suspending agent has certain suspending capacity on the emulsified polydimethylsiloxane emulsion which is processed and treated, and has poor suspending capacity on the non-emulsified high-viscosity polydimethylsiloxane, the emulsified polydimethylsiloxane is wrapped by the emulsifying agent, certain repulsive force is provided between silicone oil particles, and the carbomer suspending agent has significance on increasing the yield value of the system on the premise that the carbomer is used. For silicone oil particles which are not treated to be emulsified, carbomer merely forming a network structure to increase the yield value of the system is difficult to fix the silicone oil particles because the viscosity is reduced and the yield value is difficult to play a role in the environment of high temperature (40-48 ℃) due to the low surface energy and the strong hydrophobicity of the silicone oil itself. Meanwhile, the applicant of the patent finds that the suspending capacity of the carbomer suspending agent with the dosage of 0.4 percent is 5 times stronger than that of non-emulsified silicone oil through experimental comparison. Using a carbomer-based suspending agent with a solid content of 0.4%, delamination occurred at high temperatures (48 ℃) in most cases within one to two weeks for shampoo compositions containing non-emulsified dimethicone with a viscosity of about 10 to 30 ten thousand, and delamination occurred at high temperatures (48 ℃) in most cases within 2 to 3 months for shampoo compositions containing emulsified dimethicone emulsions with a viscosity of about 10 to 30 ten thousand, which passed a one month stability test.
From the above, carbomer-based suspending agents are still insufficient as suspending agents for silicone oil-containing products. The applicant finds through experiments that the crystalline long-chain acyl derivative has different effects due to different types of crystallization agents, matching of the crystallization agents, solubilizing agents or surfactants and different crystal forms, and the crystalline long-chain acyl derivative is not simply added into a system to have suspensibility. Crystalline long chain acyl derivatives (preferably ethylene glycol distearate) such as used in chinese patent application No. 00809131.5 also have limitations in that shampoo compositions containing 30 kilo-viscosity silicone oils prepared using 5% ethylene glycol distearate as the suspending agent and 25% sodium dodecylpolyether sulfate as the anionic surfactant exhibit delamination at elevated temperatures (48 ℃) for one month.
The applicant found through experiments that the crystalline form of the long-chain acyl derivative having crystallinity shows a dense strand shape, a round shape, and a long strip shape depending on the system. The long-chain acyl derivative belongs to an ester compound and is insoluble in water and an aqueous solvent, if a compound with an emulsifying effect in a system is mainly a surfactant, if the emulsifying capacity is too strong, the long-chain acyl derivative is fully wrapped by the emulsifier, so that the long-chain acyl derivative cannot be well crystallized or can not be crystallized into a round shape without a suspending effect. Conversely, insufficient emulsification in the system can result in too strong crystallization and dense strand formation. Although the crystalline raw material long-chain acyl derivative has good crystallinity and a certain suspension effect, the product prepared by the prior art has poor suspension capability and poor reproducibility, so that the crystalline raw material long-chain acyl derivative is not widely applied to the field as a suspending agent.
Disclosure of Invention
The invention aims to provide a composition containing long-strip crystals, which has the capability of efficiently forming the long-strip crystals in an oriented manner, and the composition has good stability, suspension capability and higher melting point due to the formation of the long-strip crystals, and can effectively avoid the problem of reduced suspension capability caused by high-temperature damage to the structure and external force shearing. The composition can be used as a silicone oil suspending agent to be applied to a system containing silicone oil, is simple and convenient to use, and can be pre-produced and stored for a long time.
The technical scheme of the invention is as follows:
the composition containing the long-strip crystals comprises the following components in percentage by weight: 14-37% of anionic surfactant, 4-10% of crystalline ethylene glycol dialkyl acid ester compound, 4-10% of polyalcohol compound, 0.1-2% of cationic guar gum derivative and the balance of water.
Further, the anionic surfactant is an anionic surfactant containing 3 or 4 oxygen atoms and no nitrogen atom.
Further, the anionic surfactant is at least one of monoalkyl sulfonate, monoalkyl α olefin sulfonate, monoalkyl sulfate, monoalkyl carboxylate and monoalkyl phosphate salt.
Furthermore, the melting point of the crystalline ethylene glycol dialkyl acid ester compound is 60-75 ℃, and the structural formula is as follows:
wherein R1 and R2 are linear aliphatic residues having 12 to 20 carbon atoms.
Further, the crystalline ethylene glycol dialkyl acid ester compound is one of ethylene glycol dimyristate, ethylene glycol dipalmitate and ethylene glycol distearate.
Further, the polyol compound is a polyol compound having the same number of carbon atoms and hydroxyl groups, and has a structural formula: wherein n = 1-8.
Further, the polyol compound is at least one of glycerol, xylitol and sorbitol.
Furthermore, the cationic guar gum derivative has the charge density of 0.5-1.0 meq/g and the molecular weight of 400000-1500000 g/mol.
The application of the composition containing the long-strip-shaped crystals as a silicon oil suspending agent.
The shampoo composition is characterized by comprising the following components in percentage by weight: the composition containing elongated crystals according to claim 1 to 50%, anionic surfactant 1 to 15%, organic conditioning oil 0.01 to 2%, preservative 0.01 to 1%, perfume 0.01 to 3%, viscosity modifier 0.01 to 4%, nonionic surfactant 0.01 to 5%, higher fatty alcohol 0.01 to 5%, anti-inflammatory agent 0.01 to 2%, chelating agent 0.005 to 0.2%, ultraviolet absorber 0.01 to 2%, plant extract derivative 0.0001 to 5%, and balance water.
The invention has the following beneficial effects:
the applicant finds that the hydrophilicity of the surfactant is basically on a group containing nitrogen and oxygen, and the surfactant has a hydrophilic effect due to the fact that nitrogen and oxygen form a hydrogen hydration bond, the selected anionic surfactant is an anionic surfactant which has 3 or 4 oxygen atoms and does not contain nitrogen atoms, the hydrophilicity is low, the cmc (critical micelle concentration value of surface activity) value is small, and a rod-shaped micelle and a net-shaped micelle are formed more easily, the micelle structure can prevent a crystalline glycol dialkyl acid ester compound from being solubilized into the interior of a spherical micelle, so that more crystalline glycol dialkyl acid ester compounds are inserted into a fence of the micelle formed by the anionic surfactant and are mutually crosslinked and crystallized with an anionic surface, and crystals formed by the crosslinking and combining crystallization mode have a better strip shape.
The melting point of the selected crystal type ethylene glycol dialkyl acid ester compound is 60-75 ℃, the applicant finds through experiments that the crystal type ethylene glycol dialkyl acid ester compound is not too high, the optimal emulsification temperature in the emulsification process is 85 ℃, the melting point of the solid ester compound is lower than the emulsification temperature by 10 ℃, the optimal emulsification effect can be achieved, and the efficiency of cross-linking and combining the anionic surfactant and the crystal type ethylene glycol dialkyl acid ester compound is the highest. Meanwhile, if the crystallization temperature of the crystal prepared by the melting point of less than 60 ℃ is too low, the crystal state of the crystal is lost due to the dissolution at the high temperature (48 ℃) and the suspension effect of the composition is lost.
The selected polyalcohol compounds are polyalcohol compounds with the same carbon atom number and hydroxyl number, and the applicant finds through experiments that when the carbon atom number is equal to the carbon atom number, the polyalcohol has high affinity to water and is insoluble or slightly soluble in oil. The compound with the solubility property and the capability of forming the hydrated hydrogen bond improves the interaction between water and the anionic surfactant or micelle by changing the structure, dielectric constant or dissolution parameter of the water, reduces the hydration degree of hydrophilic groups of the anionic surfactant, thereby promoting the micellization and the conversion of the anionic surfactant to rod-shaped and net-shaped micelles and reducing the cmc value of the anionic surfactant.
The applicant experiments find that the cationic guar gum derivative selected by the composition system has strong swelling and dispersing capacity in the system, so that the system has excellent flocculation capacity and a wide flocculation range, the network structure of the cationic guar gum derivative in the system and the flocculation capacity of the cationic guar gum derivative and an anionic surfactant are the key for ensuring that the long-strip-shaped crystal cross-linked network combined by the anionic surfactant and the crystalline glycol dialkyl acid ester compound is distributed in the composition, and the continuous dispersion and cross-linking of the long-strip-shaped crystal in the system are realized, so that the composition has the effect of resisting the spontaneous coalescence and deposition of silicone oil, and can play a role of suspending the silicone oil.
The components of the invention are synergistic, and the invention has the advantages of efficiently and directionally pulling the crystalline glycol dialkyl acid ester compound to crystallize to a required form, forming a strip-shaped crystal with good stability and excellent suspension capability, simultaneously enabling the composition to have a higher melting point (50-58 ℃), effectively avoiding the problem of suspension capability reduction caused by high-temperature structure damage, and simultaneously enabling the ions in the system and external force shearing during the manufacturing not to influence the suspension capability.
Drawings
FIG. 1 is a microscopic image of compositions containing elongated crystals of examples 1-5;
FIG. 2 is a microscopic image of the composition of comparative example 1;
FIG. 3 is a microscopic image of the composition of comparative example 2;
FIG. 4 is a microscopic image of the composition of comparative example 3;
fig. 5 is a microscopic image of shampoo of sample 1.
Detailed Description
The present invention will be described in detail with reference to examples, which are only preferred embodiments of the present invention and are not intended to limit the present invention.
Examples
The following table shows the formulations (unit:%) of the compositions of examples 1 to 5 containing elongated crystals according to the invention, prepared by stirring and mixing as conventional in the art.
| Components | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 |
| Anionic surface activity Sex agent | Dodecyl sulfonate 28% | Dodecyl α olefin sulfonic acid 35 percent of salt | Dodecyl sulfate salt 25% | Dodecyl carboxylate 32% | Dodecyl phosphate salt 30% |
| Crystalline ethylene glycol Dialkyl acid esters Compound (I) | Ethylene glycol distearate 5% | Ethylene glycol distearate 6% | Ethylene glycol dipalmitate 7% | Ethylene glycol dimyristic acid 8% of ester | Ethylene glycol dimyristate acid ester 9% |
| Polyol compounds Article (A) | 4 percent of glycerin | 5 percent of glycerin | Xylitol 8 percent | Sorbitol 10% | Sorbitol 7% |
| Cationic guar gum Derivatives of the same | 1% of a charge density of 0.5 meq/g, molecular weight 400000 g/mol | 0.5% of a charge density of 0.6meq/g, molecular weight 700000 g/mol | 0.1% of its charge density 0.7meq/g, molecule In an amount of 1000000 g mol | 1% of a charge density of 0.8 meq/g, molecular weight Is 1200000 g/mol | 0.5% of a charge density of 1.0 meq/g, molecular weight 1500000 g/mol |
| Water (W) | Make up to 100% | Make up to 100% | Make up to 100% | Make up to 100% | Make up to 100%. |
Comparative example
The following table shows the formulation of the compositions of the invention containing crystals in the form of long strands according to comparative examples 1 to 3 (unit:%), prepared by mixing with stirring, as is conventional in the art.
| Components | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Ethylene glycol distearate | 7.14 | 10 | / |
| Carbomer 940 | / | / | 4.29 |
| Cationic guar gum derivatives | 3.57 | 4.12 | 3.57 |
| Glycerol | 15.71 | 12.54 | 15.71 |
| Sodium dodecyl polyether sulfate | 21.43 | 14 | 21.43 |
| Water (W) | Make up to 100% | Make up to 100% | Make up to 100%. |
The crystals of the compositions containing elongated crystals of the present invention, examples 1 to 5 and comparative examples 1 to 3 were observed using a microscope, and the crystal morphologies of examples 1 to 5 were shown as a to e in FIG. 1, respectively, and were all single elongated crystals; the crystal morphology of comparative example 1 is shown in fig. 2, which is a round crystal; the crystal morphology of comparative example 2 is shown in fig. 3, which is a dense strand-like crystal; comparative example 3 had no crystal, and the microscopical state thereof is shown in FIG. 4. Therefore, the invention has the capability of efficiently and directionally forming the long-strip-shaped crystals.
Shampoo composition
The following table shows the formulation of samples 1-8 of shampoo compositions of the invention (unit:%) prepared by conventional mixing and stirring techniques used in the art.
| Components | Sample 1 | Sample 2 | Sample 3 | Sample No. 4 | Sample No. 5 | Sample No. 6 | Sample 7 | Sample 8 |
| Silicon oil suspending agent | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Sodium dodecyl polyether sulfate | 10 | 10 | 10 | 10 | 10 | 8 | 8 | 8 |
| Sodium dodecyl sulfate | / | / | / | / | / | 2 | 2 | 2 |
| 50 ten thousand viscosity silicone oil | 2 | 2 | 2 | 2 | 2 | 2 | 2 | 2 |
| Phenoxyethanol | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
| Essence | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
| Sodium chloride | 1 | 1 | 1 | 1 | 1 | 1 | 1 | 1 |
| Cocoamidopropyl betaine | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 |
| Octadecanol | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
| EDTA-2Na | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 |
| Water (W) | Make up to 100% | Make up to 100% | Make up to 100% | Make up to 100% | Make up to 100% | Make up to 100% | Make up to 100% | Make up to 100%. |
Sample 1 of the shampoo composition of the present invention was observed with a microscope, and the microscopic examination result is shown in fig. 5, in which the silicone oil particles were wrapped with the long-striped crystals. Samples 1-8 were tested for stability and the results are shown in the following table.
| Sample (I) | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 |
| Stability at 48 ℃ for 15 days | By passing | By passing | By passing | By passing | By passing | Layering | By passing | By passing |
| One month stability at 48 ℃ | By passing | By passing | By passing | By passing | By passing | Layering | Layering | Layering |
| Two month stability at 48 ℃ | By passing | By passing | By passing | By passing | By passing | Layering | Layering | Layering |
| Three month stability at 48 ℃ | By passing | By passing | Light demulsification | By passing | Light demulsification | Layering | Layering | And (5) layering. |
Therefore, the composition containing the long-strip-shaped crystals has good stability, suspension capacity and higher melting point, and can effectively avoid the problem of suspension capacity reduction caused by high-temperature damage to the structure and external force shearing. The composition can be used as a silicone oil suspending agent to be applied to a system containing silicone oil, is simple and convenient to use, and can be pre-produced and stored for a long time.
Claims (10)
1. The composition containing elongated crystals is characterized by comprising the following components in percentage by weight: 14-37% of anionic surfactant, 4-10% of crystalline ethylene glycol dialkyl acid ester compound, 4-10% of polyalcohol compound, 0.1-2% of cationic guar gum derivative and the balance of water.
2. The composition containing elongated crystals according to claim 1, wherein the anionic surfactant is an anionic surfactant containing 3 or 4 oxygen atoms and no nitrogen atom.
3. The composition containing elongated crystals according to claim 1 or 2, wherein the anionic surfactant is at least one of monoalkyl sulfonate, monoalkyl α olefin sulfonate, monoalkyl sulfate, monoalkyl carboxylate, monoalkyl phosphate salt.
4. The composition containing elongated crystals according to claim 1, wherein the crystalline glycol dialkyl acid ester compound has a melting point of 60-75 ℃ and a structural formula of:
wherein R1 and R2 are linear aliphatic residues having 12 to 20 carbon atoms.
5. The composition containing elongated crystals according to claim 1 or 4, wherein the crystalline ethylene glycol dialkyl acid ester compound is one of ethylene glycol dimyristate, ethylene glycol dipalmitate and ethylene glycol distearate.
6. The composition containing elongated crystals according to claim 1, wherein the polyol compound is a polyol compound having the same number of carbon atoms as the number of hydroxyl groups, and has a structural formula of:
wherein n = 1-8.
7. The composition containing elongated crystals according to claim 1 or 6, wherein the polyol compound is at least one of glycerin, xylitol, and sorbitol.
8. The composition containing elongated crystals according to claim 1, wherein the cationic guar derivative has a charge density of 0.5-1.0 meq/g and a molecular weight of 400000-.
9. Use of the composition containing elongated crystals of claim 1 as a silicone oil suspension.
10. The shampoo composition is characterized by comprising the following components in percentage by weight: the composition containing elongated crystals according to claim 1 to 50%, anionic surfactant 1 to 15%, organic conditioning oil 0.01 to 2%, preservative 0.01 to 1%, perfume 0.01 to 3%, viscosity modifier 0.01 to 4%, nonionic surfactant 0.01 to 5%, higher fatty alcohol 0.01 to 5%, anti-inflammatory agent 0.01 to 2%, chelating agent 0.005 to 0.2%, ultraviolet absorber 0.01 to 2%, plant extract derivative 0.0001 to 5%, and balance water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911098059.8A CN110960433B (en) | 2019-11-12 | 2019-11-12 | Composition containing strip crystals and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201911098059.8A CN110960433B (en) | 2019-11-12 | 2019-11-12 | Composition containing strip crystals and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN110960433A true CN110960433A (en) | 2020-04-07 |
| CN110960433B CN110960433B (en) | 2023-03-03 |
Family
ID=70030698
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201911098059.8A Active CN110960433B (en) | 2019-11-12 | 2019-11-12 | Composition containing strip crystals and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN110960433B (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1909876A (en) * | 2004-01-15 | 2007-02-07 | 罗迪亚公司 | Pearlizer concentrate and its use in personal care compositions |
| WO2014073456A1 (en) * | 2012-11-08 | 2014-05-15 | ライオン株式会社 | Shampoo composition |
| CN105050578A (en) * | 2013-03-21 | 2015-11-11 | 狮王株式会社 | Shampoo composition |
| CN105307630A (en) * | 2013-06-27 | 2016-02-03 | 狮王株式会社 | Shampoo composition |
| WO2016080109A1 (en) * | 2014-11-21 | 2016-05-26 | ライオン株式会社 | Shampoo composition |
-
2019
- 2019-11-12 CN CN201911098059.8A patent/CN110960433B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1909876A (en) * | 2004-01-15 | 2007-02-07 | 罗迪亚公司 | Pearlizer concentrate and its use in personal care compositions |
| WO2014073456A1 (en) * | 2012-11-08 | 2014-05-15 | ライオン株式会社 | Shampoo composition |
| CN105050578A (en) * | 2013-03-21 | 2015-11-11 | 狮王株式会社 | Shampoo composition |
| CN105307630A (en) * | 2013-06-27 | 2016-02-03 | 狮王株式会社 | Shampoo composition |
| WO2016080109A1 (en) * | 2014-11-21 | 2016-05-26 | ライオン株式会社 | Shampoo composition |
Non-Patent Citations (2)
| Title |
|---|
| 唐海秋等: "小分子多元醇对阴离子表面活性剂聚集行为的影响", 《中国化学会第十四届胶体与界面化学会议论文摘要集-第2分会：溶液中的聚集与分子组装》 * |
| 裘炳毅，高志红编: "《现代化妆品科学与技术 中》", 31 March 2016, 中国轻工业出版社 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN110960433B (en) | 2023-03-03 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101099289B1 (en) | Solvated nonionic surfactants and fatty acids | |
| KR20090125105A (en) | Structured surfactant compositions | |
| CN101035889A (en) | Low pH structured surfactant compositions | |
| JP2003516338A (en) | Stabilized antimicrobial agent system and method of making same | |
| EP3498811A1 (en) | Surfactant composition | |
| US11653645B2 (en) | Foam sanitizer composition | |
| JPH10513179A (en) | Roll-on antiperspirant composition | |
| JP3512422B2 (en) | Hair conditioning composition | |
| Pandya et al. | SLES/CMEA mixed surfactant system: Effect of electrolyte on interfacial behavior and microstructures in aqueous media | |
| JP2007084482A (en) | Hair detergent composition | |
| EP1743016B1 (en) | Solvated nonionic surfactants | |
| CN110960433B (en) | Composition containing strip crystals and application thereof | |
| EP2138153A1 (en) | Method for production of pearlescent composition | |
| DD295309A5 (en) | FIBER CONDITIONING COMPOSITION AND USE THEREOF | |
| KR100766209B1 (en) | Conditioning composition and hair cosmetic containing the same | |
| CN1822881B (en) | Solvated nonionic surfactants and fatty acids | |
| EP3467079A1 (en) | Surfactant composition | |
| CN112752562B (en) | Oil-in-water emulsion | |
| CN111607464A (en) | Concentrated foam vehicle washing liquid and preparation method thereof | |
| AU695480B2 (en) | Improved alkyl polyglycosides | |
| KR102565630B1 (en) | Cosmetic composition containing phenoxyethanol | |
| JPH10182343A (en) | Iridescent composition and its production | |
| CN113197792B (en) | Polysiloxane quaternary ammonium salt microemulsion and preparation method and application thereof | |
| WO2022163336A1 (en) | Ceramide-containing composition | |
| CN114042005A (en) | Suspension composition containing lamellar liquid crystal and preparation process thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |